SEALING DEVICE
20180017160 ยท 2018-01-18
Assignee
Inventors
- Shinji KATO (Tokyo, JP)
- Takashi Kobayashi (Tokyo, JP)
- Yoshinori Sugiura (Tokyo, JP)
- Kenji Sakuragi (Tokyo, JP)
Cpc classification
F15B15/1428
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F16J9/26
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
C08J5/04
CHEMISTRY; METALLURGY
F16J9/28
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F16J15/166
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F16J15/3284
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
F16J9/26
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F16J9/28
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F15B15/14
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
Problem: Provided is a sealing device which has reduced wear of a metallic member in sliding portions having electric-resistance welded carbon steel and a fiber reinforced resin member. Means for resolution: A sealing device having a mechanism in which a metallic member and a resin member relatively slide, wherein the metallic member is formed from electric-resistance welded carbon steel, and the resin member is formed from a carbon-fiber reinforced synthetic resin.
Claims
1. A sealing device having a mechanism in which a metallic member and a resin member relatively slide, characterized in that the metallic member comprises electric-resistance welded carbon steel, and the resin member comprises a carbon-fiber reinforced synthetic resin.
2. The sealing device according to claim 1, wherein the electric-resistance welded carbon steel is electric-resistance welded carbon steel which has not been subjected to hot treatment or cold treatment.
3. The sealing device according to claim 1, wherein the electric-resistance welded carbon steel has a metallographic structure having 20 m or less ferrite crystals dispersed.
4. The sealing device according to claim 1, wherein the electric-resistance welded carbon steel is the electric-resistance welded carbon steel having a cross-section hardness distribution which exhibits a constant value from the surface to a depth of 50 m.
5. The sealing device according to claim 1, wherein the electric-resistance welded carbon steel contains elements of C: 0.06 to 0.12%, Si: 0.40% or less, Mn: 0.10 to 15%, P: 0.03% or less, and S: 0.02% or less.
6. The sealing device according to claim 1, wherein the resin member comprises an engineering plastic.
7. The sealing device according to claim 6, wherein the engineering plastic is selected from a polyamide resin, an epoxy resin, and a fluororesin.
8. The sealing device according to claim 1, wherein the resin member contains a carbon fiber in an amount of 5 to 15% by weight.
9. The sealing device according to claim 1, wherein the metallic member is a cylinder tube, and the resin member is a backup ring provided in a piston.
Description
BRIEF DESCRIPTION OF DRAWINGS
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DESCRIPTION OF EMBODIMENTS
[0027] The invention is directed to a sealing device having a mechanism in which a metallic member and a resin member relatively slide, characterized in that the metallic member comprises electric-resistance welded carbon steel, and the resin member comprises a carbon-fiber reinforced resin, and, by the invention, prevention of blackening of hydraulic oil and reduction of the abrasion wear of the metallic member at the sliding surface caused due to sliding of the both members for a long time have been achieved.
[0028] The invention solves the problems caused due to sliding of a conventional member made of a glass-fiber reinforced synthetic resin and a member formed from electric-resistance welded carbon steel.
[Metallic Member]
[0029] With respect to the metallic member in the invention, a steel material which has a relatively high strength though it has a low carbon content, and has excellent weldability and which has almost no pearlite structure is used. Specifically, preferred is a steel material which is electric-resistance welded carbon steel and which has not been subjected to hot finishing or cold finishing. With respect to the composition and properties of the steel material, the component standard values are shown in Table 1, the surface hardness is shown in Table 2, the cross-section hardness is shown in Table 3, and the structure and micro-hardness are shown in
TABLE-US-00001 TABLE 1 Component standard values (%) C Si Mn P S EG pipe 0.06-0.12 0.40 0.10-15 0.03 0.02 Forged pipe 0.12-0.18 0.35 0.30-0.90 0.04 0.04
TABLE-US-00002 TABLE 2 Results of surface hardness test (HRC scale) HV (converted 1 2 3 Av. value) EG pipe 13.8 15.8 16.3 15.3 215 Forged pipe 16.9 16.8 14.6 16.1 219
TABLE-US-00003 TABLE 3 Results of cross-section hardness test (HV) 1 2 3 4 5 6 Av. EG pipe 211.7 199.4 182.3 168.3 177.8 160.4 183.3 Forged Ferrite 159.5 155.8 164.3 146.3 167.2 156.7 158.3 pipe portion Pearlite 213.1 217.5 234.9 234.5 198.1 260.2 226.4 portion
[0030] The metallic member comprising electric-resistance welded carbon steel is of a metallographic structure having fine ferrite distributed as shown in
[0031] Electric-resistance welding carbon steel is generally used as a material for producing mainly a steel pipe by electric resistance welding. With respect to the steel pipe produced from electric-resistance welding carbon steel, generally, the degree of freedom of the size of the outer diameter is low, but the welded seam (seam portion) is welded by electric resistance welding so that the structure of the material is melted, and therefore the electric-resistance welded pipe has a high strength at the seam portion, as compared to the forge welded steel pipe. The electric-resistance welded steel pipe inevitably suffers generation of a weld bead (weld metal deposited on the surface or back surface by welding) at the seam portion by electric resistance welding, but the portions other than the seam portion are not heated and therefore the pipe has excellent surface appearance. According to the use of the pipe, the pipe is finished by removing the weld bead. Further, the pipe is subjected to cold finishing or hot finishing if necessary. With respect to the use of the electric-resistance welded steel pipe, the electric-resistance welded steel pipe is widely used in a line pipe for transferring petroleum, gas, or the like, a gas pipe, a steel pipe for automobile and other machine structures, a steel pipe for boiler, a cylinder tube, and the like. The pipe formed from electric-resistance welded carbon steel has excellent weldability, and is of a steel type that has a relatively high strength though it has a low carbon content, and therefore the use of the pipe as a cylinder tube is spreading.
[Resin Member]
[0032] The resin member in the invention comprises a carbon-fiber reinforced synthetic resin, and it is preferred that the carbon fiber is uniformly distributed in the synthetic resin so as not to cause the sliding surface with the metallic member to have an uneven surface or have unevenness in the hardness. The synthetic resin used is preferably one which is generally called an engineering plastic, and examples of such synthetic resins include polyamide, polycarbonate, polyacetal, modified polyphenylene ether, polybutylene terephthalate, polyphenylene terephthalate, polyphenylene sulfide, polyarylate, polyamide-imide, polyether imide, polyether ether ketone, polysulfone, polyether sulfone, an epoxy resin, and a fluororesin.
[0033] With respect to the carbon fiber used in the invention, there is no particular limitation, and any carbon fiber can be used as long as it is used as a reinforcing material or filler for a resin material, and the carbon fiber is contained in the resin generally in an amount of 5 to 15%.
[Studies on Wear of the Metallic Member using an Actual Machine]
[0034] The present inventors have found, when inspecting a cylinder for operating machines, that the inner surface of a cylinder tube has a portion which has worn more markedly than the cylinder tube conventionally used and blackening of the hydraulic oil has progressed, and they have conducted extensive and intensive studies in an attempt to elucidate the above phenomena and solve the problems of them to produce an operating machine which enables a stable operation.
[0035] With respect to the material for the cylinder, there were two types of pipes, i.e., an electric welded pipe formed from electric-resistance welded carbon steel (hereinafter, frequently referred to as EG pipe or electric-resistance welded steel pipe) and a forged pipe (forged steel pipe). A piston was provided in the cylinder, and a seal ring (carbon-fiber reinforced fluororesin), a backup ring (glass-fiber reinforced polyamide 66 resin), a bearing, and a fluororesin layer were provided in the piston.
[0036] With respect to the inner surface of the cylinder tube, the surface state was examined by means of an FE-SEM (field emission scanning electron microscope). The black portion was ion-polished and then, subjected to SEM (scanning electron microscope) examination, EBSD (electron beam backscattering diffractometry) analysis, and XRD (X-ray diffractometry) analysis, and the results described below were obtained.
[0037]
[0038] The XRD analysis of the black portions shows that a peak considered to be ascribed to Fe.sub.3O.sub.4 is detected, though very slightly, from the black portion of the EG pipe, and it is considered that the black portion of the cylinder tube has Fe.sub.3O.sub.4 formed in a slight amount. The observation of the appearance of the backup ring shows that there is a sliding surface having deposited thereon a black substance which looks like a wear powder, and that a partially cracking is seen in the end of the backup ring. The results of close observation of the black portion and the other portions of the backup ring are shown in
[Influence of Type of the Hydraulic Oil on Abrasion Wear of the Metallic Member]
[0039] From the above-mentioned test using an actual machine, it is presumed that wear of the inner surface of the cylinder is caused by the polyamide resin having a glass fiber, but a test was conducted on the assumption that the composition or additive of the hydraulic oil influences the abrasion wear. This test was made in order to clarify the cause of wear of the inner surface of the cylinder.
[0040] As rings to be tested, like those in the actual machine, a glass-fiber reinforced polyamide 66 material ring and a standard ring made of steel were prepared, and combined with the EG pipe material and the forged pipe material to perform a block-on-ring test. The method and conditions for the block-on-ring test are as shown in the following Examples.
[0041] As oils for test, HP46 (JX) and 46HN (Idemitsu) were used. Further, tests were made on the combinations of the pipe material with the recovered HP46 oil, an oil obtained by adding chlorine in an amount of 0.1% to HP46, or SU8 (base oil) to study the influence of the components mixed into the hydraulic oil.
[0042] The results of the test are shown in
[Difference in Structure Between the EG Pipe Material and the Forged Pipe Material]
[0043]
[0044] The results of the measurement of hardness distribution from the surface are shown in
[0045] Hereinabove, an explanation has been made on the cause of the problems due to sliding of the metallic member and the resin member by exemplifying the cylinder of the operating machine as a specific example of the invention. Problems similar to those of the invention are considered to be caused in the metallic member and the resin member used in other machines and parts, and the invention advantageously solves the problems of this type.
[Steel Pipe Formed from Electric-Resistance Welded Carbon Steel]
[0046] Next, the backup ring and the steel pipe formed from electric-resistance welded carbon steel are described below.
[0047] A specific example of the application of the invention is an operating machine and, for example, the invention is used for sealing a moving part or fixed part using a backup ring and an O-ring in an arm cylinder tube, a bucket cylinder tube, or the like of, e.g., a power shovel. In such a machine, when the fluid pressure is too high or the gap for the axis is too large, the O-ring slips off toward the low pressure side, and suffers gauging, so that the sealing properties become poor. The backup ring prevents such a slipping-off phenomenon, and is in the state of sliding with the inner surface of the cylinder. Further, the backup ring has an effect that, even when it is under a low pressure such that the O-ring is free of a slipping off problem, the backup ring prevents accidents, such as plucking and a damage in torsion, which are main causes of a damage of the O-ring, to remarkably elongate the life of the O-ring. After fitted, the backup ring is required to undergo plastic deformation to fill the gap as the pressure increases, and further is required not to slip off due to the operating pressure. According to the fluid pressure and the size of the gap, and, when used for sliding, according to roughness of the surface, and conditions for use, such as a sliding rate, a material, such as leather, a hard rubber, a fluororesin, polyamide, or a soft metal, is used depending on the respective uses. Recently, a fluororesin, polyamide, or the like is mainly used.
[0048] In the production of the steel pipe from electric-resistance welded carbon steel, a steel strip (coiled material) at room temperature is used as a material, and the steel strip is continuously drawn using a machine, such as an uncoiler or a leveler, and the edge faces of the steel strip on both sides are subjected to edge treatment for welding the ends put together. After the edge treatment, the steel strip in the width direction is deformed into a circular form to be formed into a pipe shape, and, immediately before welding, a large current locally flow the both ends of the steel strip so that the contacted portion of the ends is instantly in a high-temperature state, and the ends are put together as such and welded by electric resistance welding to be formed into a pipe. The hot formed pipe is cut into a predetermined length, and cooled to room temperature, and then finished using a sizing machine so as to have a predetermined size. Then, the resultant pipe is continuously subjected to a series of steps of pipe end treatments, such as beveling and thread cutting, coating, plating, marking, finished pipe inspection, and the like, and thus is finally finished as a product.
EXAMPLE 1
[Blackening of a Hydraulic Oil and Abrasion Test for the Metallic Member by a Block-On-Ring Test]
[0049] The results of the above-mentioned test using an actual machine strongly suggest that the backup ring affects blackening of the hydraulic oil and wear of the metallic member. Therefore, using a test machine similar to the actual machine, studies were made on the method for solving problems of blackening of the hydraulic oil and wear of the metallic member. A test called block-on-ring test was conducted as described below. This test was found to be able to reproduce the problem phenomenon caused in the actual machine, and therefore, using the method of this test, the analysis and solution of the problems were studied. As described below, the results have clearly shown that the problems caused due to the resin member formed from a glass-fiber reinforced epoxy resin are solved by the invention.
[0050] In the block-on-ring test, as shown in
[0051] Rings formed from a glass-fiber reinforced epoxy resin and a carbon-fiber reinforced epoxy resin, respectively, and blocks respectively having the same metal compositions as those of the EG pipe (electric-resistance welded carbon steel) and the forged pipe (conventional pipe) were prepared and subjected to block-on-ring test. The test was conducted under conditions such that the oil temperature was 80 C., the number of revolutions of the ring was 163 rpm, and the load was 5 kg for 3.3 hours. The sliding distance was 2.47 km, and the sliding rate was 0.3 m/sec. The results of the test are shown in
TABLE-US-00004 TABLE 4 Combination (1) Glass fiber vs EG pipe (2) Glass fiber vs Forged pipe (3) Carbon fiber vs EG pipe (4) Carbon fiber vs Forged pipe
[0052] In the combination of the ring made of a glass-fiber reinforced epoxy and the EG pipe, not only a large wear mark is recognized in the sliding surface of the metallic member, but also the hydraulic oil 3 has suffered blackening. On the other hand, in the combination of the ring made of a glass-fiber reinforced epoxy and the forged pipe, the wear mark in the sliding surface was small, and thus the wear was at such a level that there was no problem from a practical point of view. The hydraulic oil 3 had no change in color. In contrast, in the combination of the ring made of a carbon-fiber reinforced epoxy and the EG pipe, the wear mark in the sliding surface of the metallic block 2 was markedly reduced, and the result has shown that the wear is smaller than that in the combination of the glass fiber and the forged pipe. Further, also in the combination of the glass fiber and the forged pipe, the result has shown that the abrasion wear is reduced. Further, it has been found that, when using the carbon-fiber reinforced epoxy ring, a blackening phenomenon of the hydraulic oil does not occur, irrespective of the material for the metallic member.
[0053] As apparent from the results of the above test, the test has demonstrated that, by using the ring comprising a carbon-fiber reinforced synthetic resin in the invention, irrespective of the metal material, the abrasion wear of the metal caused by sliding is reduced, and a blackening phenomenon of the hydraulic oil 3 does not occur.
Example 2
[0054] In the present Example, for further checking by a block-on-ring test of a comparison of the wearing properties with respect to the tube material between the carbon-fiber reinforced synthetic resin and the glass-fiber reinforced synthetic resin conventionally used, the exposure state of the fiber in the cross-section of the ring and the 3-D shape of the wear mark were studied.
[Materials used for Test and the Like]
[0055] Using the materials shown below, a test was conducted using the materials in combination.
[0056] With respect to each fiber to be contained in the ring for test, the fiber was added in an amount of 10% by weight, based on the weight of the epoxy resin. As an oil for test, HP46 oil (manufactured by JX) was used.
[0057] The properties of the glass fiber and carbon fiber used are shown in Table 5, the combinations of the material for the block and the material for the ring are shown in Table 6, and the appearance of each ring is shown in
TABLE-US-00005 TABLE 5 Specific Epoxy weight gravity (g/cm3) Mohs Vickers ratio Glass fiber 2.54 6.5 900 2.12 Carbon fiber 1.8 10 2,000 1.50 Alumina 3.95 3.29 Cr2O3 5.22 4.35 Epoxy 1.2 (M80) 1
TABLE-US-00006 TABLE 6 Block material Ring material {circle around (1)} EG pipe Epoxy resin + Glass fiber {circle around (2)} EG pipe Epoxy resin + Carbon fiber {circle around (3)} Forged pipe Epoxy resin + Glass fiber {circle around (4)} Forged pipe Epoxy resin + Carbon fiber
TABLE-US-00007 TABLE 7 Ring Oil Test Number of material temperature time revolutions Load Epoxy + 80 C. 2.3 h 163 rpm 5 kg Sliding distance Glass fiber 2.47 km Epoxy + Sliding rate Carbon 0.3 m/sec fiber
[Test Items]
[0058] Abrasion test method: LFW block-on-ring test [0059] Comparison of abrasion wear: Examination under a microscope, comparison of 3-D image by a laser displacement method
[Test Results]
[0060] The appearances of the formed glass reinforced epoxy ring and carbon-fiber reinforced epoxy ring are shown in
[0061] 3-D shapes obtained by measuring the sliding surfaces of the blocks using a laser after completion of the present test are shown in
[0062] The observation of the individual wearing surfaces has confirmed that the epoxy material having a glass fiber causes the tube material to markedly wear, whereas the epoxy resin material having a carbon fiber causes the pipe material to relatively slightly wear.
Example 3
[0063] In the wear problem of the cylinder tube in the actual machine, the cause of wear was expected to reside in the hard glass fiber in the resin material used as the backup ring. As a method for solving this problem, for studying a change of the reinforcing material added to the backup ring from a glass fiber to a carbon fiber, a polyamide resin having nylon 66 reinforced with a glass fiber or a carbon fiber was used.
[0064] In the test method, a block-on-ring test was conducted in the same manner as in Example 1 with respect to a glass-fiber reinforced nylon 66 resin and a carbon-fiber reinforced nylon 66 resin. As a result, it has been found that, like Example 1, the combination of the carbon-fiber reinforced nylon 66 resin and the EG pipe material is suitable for reducing the abrasion wear.
Conclusion
[0065] As described above, the invention is (1) a sealing device having a mechanism in which a metallic member and a resin member relatively slide, characterized in that the metallic member comprises electric-resistance welded carbon steel, and the resin member comprises a carbon-fiber reinforced synthetic resin, and, by using the member comprising electric-resistance welded carbon steel and the member comprising a carbon-fiber reinforced synthetic resin in combination, the invention exhibits an effect such that blackening of hydraulic oil and a phenomenon of increase of the abrasion wear of the electric-resistance welded carbon steel caused due to sliding of the member comprising electric-resistance welded carbon steel and a member comprising a glass-fiber reinforced synthetic resin can be solved, and includes the following (2) to (9) embodiments.
[0066] (2) The sealing device according to item (1) above, wherein the electric-resistance welded carbon steel is the electric-resistance welded carbon steel which has not been subjected to hot treatment or cold treatment.
[0067] (3) The sealing device according to item (1) or (2) above, wherein the electric-resistance welded carbon steel has a metallographic structure having 20 m or less ferrite crystals dispersed.
[0068] (4) The sealing device according to any one of items (1) to (3) above, wherein the electric-resistance welded carbon steel is the electric-resistance welded carbon steel having a cross-section hardness distribution which exhibits a constant value from the surface to a depth of 50 m.
[0069] (5) The sealing device according to any one of items (1) to (4) above, wherein the electric-resistance welded carbon steel contains elements of C: 0.06 to 0.12%, Si: 0.40% or less, Mn: 0.10 to 15%, P: 0.03% or less, and S: 0.02% or less.
[0070] (6) The sealing device according to any one of items (1) to (5) above, wherein the resin member comprises an engineering plastic.
[0071] (7) The sealing device according to item (6) above, wherein the engineering plastic is selected from a polyamide resin, an epoxy resin, and a fluororesin.
[0072] (8) The sealing device according to any one of items (1) to (7) above, wherein the resin member contains a carbon fiber in an amount of 5 to 15% by weight.
[0073] (9) The sealing device according to any one of items (1) to (8) above, wherein the metallic member is a cylinder tube, and the resin member is a backup ring provided in a piston.
INDUSTRIAL APPLICABILITY
[0074] The invention is directed to a sealing device having a mechanism in which a metallic member and a resin member relatively slide, wherein the metallic member comprises electric-resistance welded carbon steel, and the resin member comprises a carbon-fiber reinforced synthetic resin, and the sealing device can reduce wear of the metallic member at the sliding surface, and therefore can be applied to general apparatuses having a sliding mechanism having a metallic member and a fiber reinforced resin member, and thus, in apparatuses having such a sliding mechanism, there is no need to replace or repair a sliding member for a long operation term, and the safety can be ensured.
[0075] Particularly, the improvement of the safety and life of an apparatus having a cylinder which needs the sealing device is considered to exhibit remarkable economical effects in a wide variety of industrial fields.
REFERENCE SIGNS LIST
[0076] 1: Fiber reinforced resin ring [0077] 2: Metallic block [0078] 3: Hydraulic oil [0079] 4: Direction of rotation [0080] 5: Load