Avalanche photodiode array
12205967 · 2025-01-21
Assignee
Inventors
- Rainer Richter (Munich, DE)
- Florian Schopper (Munich, DE)
- Jelena Ninkovic (Munich, DE)
- Alexander Bähr (Gröbenzell, DE)
Cpc classification
H10F39/011
ELECTRICITY
H10F30/225
ELECTRICITY
H10F39/18
ELECTRICITY
International classification
H10F39/00
ELECTRICITY
H10F39/18
ELECTRICITY
Abstract
An avalanche photodiode array for detecting electromagnetic radiation comprises: a semiconductor substrate (100) having a first main surface (101) and a second main surface (102), which are opposite one another, a plurality of n-doped anode regions (1) formed at the first main surface (101) and separated from one another by pixel isolation regions (7), a p-doped cathode region (3) arranged at the second main surface (102) opposite the anode regions, a drift region (4) between the plurality of anode regions (1) and the cathode region (3), and a p-doped multiplication layer (2) arranged below the plurality of anode regions (1) and below the pixel isolation regions (7), and is characterized by an n-doped field reduction layer (9) arranged below the plurality of anode regions (1) and the pixel isolation regions (7) and above the multiplication layer (2).
Claims
1. An avalanche photodiode array for detecting electromagnetic radiation comprising a semiconductor substrate that comprises a first main surface and a second main surface which are opposed to each other, a plurality of n-doped anode regions formed at the main surface and separated from each other by pixel insulation regions, a p-doped cathode region arranged at the second main surface opposite to the anode regions, a drift region between the plurality of anode regions and the cathode region and a p-doped multiplication layer arranged below the plurality of anode regions and below the pixel insulation regions, characterized by an n-doped field reduction layer arranged below the plurality of anode regions and the pixel insulation regions and above the multiplication layer.
2. The avalanche photodiode array according to claim 1, wherein a p-doped semiconductor region is formed at the first main surface in a pixel insulation region located between each two anode regions.
3. The avalanche photodiode array according to claim 2, wherein the p-doped semiconductor region is at a distance to the anode regions adjoining thereto.
4. The avalanche photodiode array according to claim 1, wherein an n-doped semiconductor region is formed at the first main surface in a pixel insulation region between each two anode regions.
5. The avalanche photodiode array according to claim 1, wherein a pixel insulation region is formed at the first main surface between each two anode regions, in which pixel insulation region a recess extending from the first main surface into the depth of the semiconductor substrate is present.
6. The avalanche photodiode array according to claim 5, wherein at least the bottom of the recess is covered with an insulator, preferably the whole recess is filled with the insulator.
7. The avalanche photodiode array according to claim 6, wherein a potential control electrode is formed on the top of the insulator opposite to the bottom.
8. The avalanche photodiode array according to claim 6, wherein an n-doped interface doping layer is arranged below the bottom of the recess and immediately adjoining the insulator.
9. The avalanche photodiode array according to claim 1, in which the first main surface is connected to a second semiconductor substrate via an insulating layer and each of the plurality of anode regions is electrically connected through the insulating layer with one respective pixel of a read-out amplifier array formed in the second semiconductor substrate.
10. A method of manufacturing an avalanche photodiode array according to claim 5, wherein the recess is formed by a local oxidation of the semiconductor substrate by means of a LOCOS technique.
11. The method according to claim 10, wherein before carrying out the local oxidation, donors are introduced into the semiconductor substrate at the positions to be locally oxidized with a dose between 3.Math.10.sup.11/cm.sup.2 and 10.sup.12/cm.sup.2, preferably by means of implantation, at the positions to be locally oxidized.
12. The method according to claim 11, wherein an n-doped field reduction layer is formed below the plurality of anode regions and the pixel insulation regions and above of the multiplication layer by carrying out a diffusion step by which dopants that have been introduced into the anode regions diffuse so far into semiconductor substrate that the diffused dopants form the field reduction layer together with the interface doping layer.
13. An avalanche photodiode array for detecting electromagnetic radiation comprising a semiconductor substrate comprising a first main surface and a second main surface opposed to each other, a plurality of n-doped anode regions formed at the first main surface and separated from each other by pixel insulation regions, a p-doped cathode region arranged at the second main surface opposite to the anode regions, a drift region between the plurality of anode regions and the cathode region and a p-doped multiplication layer arranged below the plurality of anode regions and below the pixel insulation regions, characterized in that each of the pixel insulation regions comprises a recess extending from the first main surface into the depth of the semiconductor substrate.
14. The avalanche photodiode array according to claim 13, wherein an n-doped field reduction layer is arranged below the plurality of anode regions and below the pixel insulation regions and above the multiplication layer.
15. The avalanche photodiode array according to claim 13, wherein at least the bottom of the recess is covered with an insulator, preferably the whole recess is filled with the insulator.
16. The avalanche photodiode array according to claim 15, wherein a potential control electrode is formed at the top side of the insulator opposite to the bottom.
17. The avalanche photodiode array according to claim 15, wherein an n-doped interface doping layer is arranged below the bottom of the recess (20) immediately adjoining the insulator.
18. The avalanche photodiode array according to claim 13, in which the first main surface is connected to a second semiconductor substrate via an insulating layer and each of the plurality of anode regions is electrically connected through the insulating layer with one respective pixel of a read-out amplifier array formed in the second semiconductor substrate.
19. A method of manufacturing an avalanche photodiode array according to claim 13, wherein the recess is formed by a local oxidation of the semiconductor substrate by means of a LOCOS technique.
20. The method according to claim 19, wherein before carrying out the local oxidation, donors are introduced into the semiconductor substrate at the positions to be locally oxidized with a dose between 3.Math.10.sup.11/cm.sup.2 and 10.sup.12/cm.sup.2, preferably by means of implantation, at the positions to be locally oxidized.
Description
(1) Further features and utilities of the invention will become apparent from the description of embodiments based on the attached figures.
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FIRST EMBODIMENT
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(10) At the edge of the array, measures have to be taken in order to avoid that the behavior of the edge pixels differs too much from the behavior of the pixels in the center of the array. In particular, suitable protective structures (such as guard rings) must also be provided there for a controlled lowering of the field in order to avoid undesired charge carrier generation at this position. The mentioned measures are sufficiently known in the prior art, so that they are not discussed in detail here, particularly as the invention is not focused on the suitable design of the edge of the array.
(11) While in
(12) Reference number 4 designates a weakly p-doped or n-doped or only intrinsically conducting drift region 4, reference sign 2 designates a p-doped multiplication layer. In SLIKs, the drift region would be lower-ohmic than in RT-APDs as in the latter case at least parts of the drift region take over the function of the multiplication layer.
(13) Even if this is not directly apparent from
(14) Above of the multiplication layer 2, meaning with regard to the direction perpendicular to the main surfaces, an n-doped field reduction layer 9 is arranged below the anode regions 1 and the pixel insulation regions 7. As in the case of the multiplication layer 2, in a preferred implementation the field reduction layer 9 extends in a plane parallel to the first main surface 101 across the whole area of the APD array. In the same way, the field reduction layer 9 preferably extends as homogeneously as possible below the anode regions 1 and the pixel insulation regions 7.
(15) In order to provide for a homogenous amplification in the whole APD array, a lateral distribution of the electric field below the n-doped anode regions 1 and below the pixel insulation regions 7, which is as homogeneous as possible, is necessary. This objective is achieved by the presence of the field reduction layer 9 which acts like an intermediate anode having a large area. As the field reduction layer 9, which is completely depleted in the operation of the APD array, reduces the electric field up to a value far below the onset of carrier multiplication, the field reduction layer 9 also provides for a significant reduction of the electric fields at the edges of the anode regions and at the pixel insulation regions 7. Thereby, breakdowns at the edges of the pixels are avoided and the long-term stability is improved as the injection of high energy (hot) charge carriers into the insulator at the semiconductor insulator interfaces is avoided.
(16) There are different possibilities for the design of the pixel insulation regions 7, each of which can be applied in combination with the mentioned field reduction layer 9: As can be seen in
(17) While in
(18) A further possibility for an insulation of the anode regions 1 from each other is to insert a MOS insulating structure in the pixel insulation region 7 between each two anode regions 1 instead of the stop region 8 or the p-spray insulation. In fact it is sufficient to form such MOS insulating structure only in a part of the pixel insulation region 7 between two anode regions 1 such that an insulation of the adjoining anode regions from each other is guaranteed (for quadratic anode regions 1 e.g. in the form of a cross grid). However, the MOS insulating structure may of course also take up the complete pixel insulation region 7.
(19) A previously mentioned MOS insulating structure is constructed such that a conductive insulated control layer (separated from the semiconductor substrate by an insulating layer) is arranged above the first main surface 101. A potential relative to the anode regions is applied to the conductive insulated control layer. The potential is able to deplete the electron accumulation layer which forms at the silicon-silicon dioxide-interface due to positive fixed charges, so that as a result the anode regions 1 are insulated from one another.
(20) The inventors recognized an even further possibility of designing the pixel insulation regions 7. When forming the stop region 8 and when forming the spray insulation, it is possible to use an n-doping instead of a p-doping. At first this appears to be absurd as an electron layer connecting the anode regions 1 with each other shall in fact be avoided. However, the inventors recognized that the negative space charge of the multiplication layer, which in operation is created by applying a reverse voltage between the anode regions 1 and the cathode region 3, provides for a complete depletion of the semiconductor in the pixel insulation region 7. Accordingly, in fact one can do without the three previously mentioned additional insulation measures. However, a combination of the n-doping with the above-mentioned MOS insulation structure may be advantageous in order to react by means of its potential to doping variations caused by the technology or in order to implement a rather precise adjustment of the avalanche amplification below the pixel insulation region. However, from the complete depletion of the semiconductor in the pixel insulation region 7 only by way of the mentioned reverse voltage there will also result a lowering of the potential with respect to the anode regions, which leads to field inhomogeneities and thus to a lower amplification below the pixel insulation region 7, meaning to a lower signal at these positions. Here, by introducing an n-doping into the pixel insulation regions it is possible to counter the field inhomogeneities. Which doping parameters do have to be selected here in detail, depends on the doping parameters of the multiplication layer 2 and of the field reduction layer 9 as well as on the reverse voltage applied in operation and can be found by the skilled person in the individual case easily by a device simulation.
(21) In the following, the steps for manufacturing an inventive APD array will be outlined, wherein steps that are not explicitly mentioned are identical or analogous to those applied in the manufacture of APD arrays known in the prior art.
(22) In order to form the cathode region 3, acceptors (e.g. boron) are introduced into a usually high-ohmic semiconductor substrate (e.g. 2 kOhm-cm) at the second main surface (thus the backside) thereof. At the opposed first main surface, the anode regions 1 are formed by introducing donors (e.g. As or P) with a high dose. They should be introduced in both cases preferably by implantation. The dose should be such that the formation of an ohmic junction with the contacts (depending on the metallization that is used) is possible. In most cases, for this the dose must be between 10.sup.14/cm.sup.2 and 10.sup.16/cm.sup.2. In the figures, reference number 15 generally designates a contact, independent of its functional purpose or its position. As already mentioned above, in the cathode region 3 it is also possible to choose a different dose outside of the contact region, in particular also a lower dose (down to e.g. 10.sup.12/cm.sup.2). In order to achieve a high detection efficiency of photons that have a small absorption length, meaning light in the UV range or soft X-rays, apart from the direct implantation of boron into silicon there are also other possibilities of technologically implementing the formation of the cathode. Such possibilities are covered by the term thin entrance window. For example, the growing of a very thin silicon epitaxial layer having a high boron concentration or the epitaxial growing of pure boron layers or the deposition of very thin polysilicon layers having also a high boron concentration, are known. The invention is not limited to a specific technological embodiment of the cathode region.
(23) The multiplication layer 2 can e.g. be formed by means of a p-doped epitaxial layer. Here, the thickness of the epitaxial layer (e.g. 2-50 m) depends on the doping that has been chosen (e.g. between 10.sup.14/cm.sup.3 and 5.Math.10.sup.15/cm.sup.3) and should be the lower the higher the doping.
(24) The way in which the multiplication layer is formed has an effect on the electric field distribution when the APD array is operated:
(25) A constant p-doping of the multiplication layer 2, e.g. inside of an epitaxial layer, results in a linear increase of the electric field with a maximum at the junction of the multiplication layer 2 and the n-doped field reduction layer 9. However, such inhomogeneous vertical field distributions lead to a poor k factor and to an increased excess noise, because the holes do considerably contribute to the multiplication at least at the field maximum. More homogenous vertical electric field can be implemented by creating the multiplication layer 2 by means of ion implantation with high energies. If in such a case the p-doping decreases considerably between the concentration maximum and the n-doped layer 9, the vertical electric field in this region is nearly constant.
(26) When the multiplication layer 2 is formed e.g. by ion implantation of boron with high energy, the dose should be smaller than the one for the cathode region 3. As the multiplication layer 2 shall be located closer to the first main surface 101, the implantation is carried out at the first main surface 101, e.g. with an energy between 500 keV and 12 MeV and a dose between 10.sup.12/cm.sup.2 and 4.Math.10.sup.12/cm.sup.2.
(27) The deeper the maximum of the implantation, meaning the further the same is away from the first main surface, the more extended the multiplication layer will be and the lower the electric field can be set in order to achieve a certain amplification. Small electrical field strengths on the other hand lead to a small k factor and thus, as with SLIK-APDs, to a small excess noise.
(28) The field reduction layer 9 can also be introduced by means of ion implantation (e.g. of P), wherein the implantation is carried out at the first main surface 101 with high energy. The energy has to be set such that the field reduction layer 9 is adjoining to the multiplication layer 2 at the side of the first main surface 101 (e.g. between 400 keV and 1 MeV). Preferably, the dose is by two to three orders of magnitude smaller than the one for the formation of the anode regions 1, e.g. in the range between 7.Math.10.sup.11/cm.sup.2 and 3.Math.12.sup.12/cm.sup.2. Here, the dose is set such that the electric field is reduced by a large proportion in the field reduction layer 9, wherein, however, the layer stays depleted in sensor operation.
Second Embodiment
(29) The sectional view of a second embodiment of an inventive APD array that is shown in
(30) The p-doped region between the anode regions 1, which has been described with respect to the first embodiment, meaning the stop region 8 or the p spray insulation, can have negative effects on the fill factor. As the diode between the n-doped anode regions 1 and the p-doped region has to be reverse biased for a separation of the anode regions from each other, the potential of the p-doped region is more negative than the one of the adjoining anode regions 1. This leads to a more negative potential of the portion of the multiplication layer 2 located below the p-doped region. As a result, the electric field and thus the amplification at this portion are lowered. The same applies to the above-mentioned MOS insulation region. Accordingly, the amplification across the APD array will be no longer homogenous, even if the field reduction layer 9 is able counteract this inhomogeneity.
(31) For some applications, the homogeneity of the amplification does only play a minor role. In particular, if the dimensions and areas, respectively, of the anode regions 1 are not too small, i.e. large with respect to the width and area, respectively, of the pixel insulation regions, signal losses that occur in the pixel insulation regions can often be neglected. Therefore, for such applications the pixel insulation regions that were described in combination with the first embodiment can be used. On the other hand, there are applications in which a high position resolution, thus small pixels, or a good fill factor are necessary. For example, in spectroscopy, signal losses at the pixel boundaries are troublesome. For these applications the APD arrays of the second embodiment are particularly suited.
(32) As shown in
(33) The width of the pixel insulation regions 70 should be preferably small. Thereby, the potential difference between the interface 10 and the regions below the anode regions 1 laterally adjoining it in the depleted semiconductor is kept small, thus providing for a homogenous charge collection and amplification. At the same time this keeps the area proportion of the pixel insulation regions small, which also has positive effects on the fill factor. A further advantage of narrow pixel insulation regions lies in the fact that the proportion of the surface leakage current that is generated at the SiSiO.sub.2 interface 10 is kept small. To be specific, the proportion of holes of the surface generation current is also amplified in the multiplication layer 2 and in particular enhances noise.
(34) In a preferred implementation of the second embodiment, the potential of the interface 10 is adjusted by means of a conductive control layer 11 (e.g. made of metal or polysilicon) on the surface of the insulator 6 by means of the MOS effect. If the potential is adjusted along an imaginary line extending the interface into the adjacent semiconductor layers below the anode regions 1 (meaning parallel to the first main surface) such as to be nearly constant, also the potential distribution and field distribution parallel to the semiconductor surface will be very homogenous, leading to a very uniform amplification in the whole APD array. A conductive control layer 11, which is located between the anode regions and surrounds each anode region will then form a grid which at the edge of the APD array can be preferably set to a fixed potential.
(35) A further preferred implementation of the second embodiment is shown in
(36) Usually, the potential at the interface 10 can be adjusted in a much more precise and flexible way by means of the conductive control layer 11. A combination of a conductive control layer 11 with an interface doping layer 12, as shown in
(37) The charge carriers generated by avalanche multiplication alter the space charge in the multiplication layer, in particular after electrons and holes have been separated by the electric field. The electrons will drift with high speed to the nearby anodes and after that do no longer contribute to the space charge. The holes have a slightly smaller mobility and will drift the longer way to the cathode. Its influence on the space charge is higher. For a short time, they will compensate a part of the negative space charge of the acceptors located in the multiplication layer and thus reduce the electric field and the amplification of the APD. Due to geometry, the capacitive coupling of the generated charge carriers below the anode regions and below the pixel insulation regions differs slightly. This is due to the fact that the distance between the multiplication layer and the anode regions which are at a fixed potential is smaller than the distance between the multiplication layer and the conductive control layer. This is assisted by the larger relative permittivity of silicon as compared to silicon dioxide. It results that the potential change and change of the field strength in the multiplication layer due to the generated charge carriers is slightly smaller below the anodes than below the pixel insulation regions. Such space charge effects can be corrected by means of the conductive control layer 11 in that the electric field in the multiplication layer is slightly increased by a positive voltage at the control layer.
(38) Even if in each of
(39) The deepening of the interface 10 with respect to the first main surface 101 can be technologically implemented with the local oxidation process (LOCOS) known from microelectronics. When using the LOCOS process, the known bird's beak region will occur in which the oxide thickness increases starting from the edge of the anode regions 1 leading to a gradual deepening of the interface 10 (
(40) The mentioned technological measures can be applied either individually or also in arbitrary combination and can be combined with the use of an interface doping layer 12. They are also not tied to the use of the LOCOS process. For example, it is also possible to deepen the interface 10 by an etching process instead of or in combination with the LOCOS process. If a shallow phosphorous doping is introduced into the pixel insulation regions 70 before the local oxidation (e.g. by means of an implantation with a dose between 3.Math.10.sup.11/cm.sup.2 and 10.sup.12/cm.sup.2), due to the segregation behavior of phosphorous at the silicon-silicon dioxide-interface 10 the dopants will move into the semiconductor in order to form there the interface doping layer 12.
(41) In order to make the technological process more cost-efficient, there is also the possibility of assembling the field reduction layer 9 from the n-doped interface doping layer 12 and the tails of the doping of the anode regions 1 laterally adjoining it. In this case, the n-doped field reduction layer 9 is not completely separated from the highly doped anode regions 1. Its doping may gradually change into the doping of the anodes. It can even be formed by a lower-doped tail 1a of the anode doping and may change laterally into the doping of the interface layer 12 (
(42) Apart from setting the voltage at the conductive control layer 11 and/or the doping parameters of the interface doping layer 12, there are further technological possibilities of controlling the potential at the interface 10 and thus the homogeneity of the amplification. The potential difference between the interface 10 and the regions laterally adjoining it can be decreased by a deeper SiO.sub.2Si interface (thicker LOCOS layer) or by a shallower anode doping (doping with arsenic instead of phosphorous). Both measures will lead to a more negative potential under the anode regions 1 at the level of the SiO.sub.2Si interface and thus will expand the margin for adjusting a homogenous lateral electric field in the multiplication layer 2 while at the same time guaranteeing the electrical insulation of neighboring anode regions 1.
(43) For the operation of the inventive APD array, it is advantageous, if the electric field strengths that occur are not so high. In such case, no amplification or only a small amplification of the hole current generated at the interface 10 will occur. Thus, SLIK-APD arrays are a preferred embodiment of the invention.
(44) A uniform position-independent amplification, which exists when the sum of the signals of neighboring pixels is independent from the entrance position of the light signal at the backside of the diode, makes it also possible to realize very small pixels as they are used in pin diode arrays.
(45) The multiplication region and the cathode region can be technologically implemented in the same way as in the first embodiment. Also, all statements made with respect to the first embodiment that are not related to the pixel insulation region may be transferred in the same way to the second embodiment.
FURTHER MODIFICATIONS
(46) Modern pin diode arrays as they are currently used are connected to the read-out electronics directly by flip-chip technique. The minimum pixel sizes are in the range of approximately 50 m50 m. On the one hand, this limit is due to the minimum distance between neighboring bump bonds which currently is in this range. On the other hand it is due to the area requirement of transistor circuits in the read-out chip. It is to be expected that the trend to a further miniaturization in microelectronics will continue, so that the request for still smaller pixels is foreseeable.
(47) For some years detector systems have been developed in which the read-out electronics is monolithically connected to the sensors by the SOI technology (silicon on insulator). In this case, the bump bond technology which in comparison is expensive and requiring much space is dispensed with. Up to now, classical pin diode arrays have been used for this technology known as SOIPIX. Therefore, in the context of the present invention the idea arose to replace the classical pin diode arrays by APD arrays. Accordingly, with such an approach the field of application of detectors comprising APD arrays can be expanded due to the improved time resolution and the higher sensitivity. An application of the SOIPIX technology in combination with the inventive APD arrays is in particular advantageous because not only simpler amplifiers having less space or power requirements can be used due to the intrinsic amplification of the APD arrays, so that for e.g. smaller pixels for an improved position resolution are realizable. The present invention also allows an implementation of APD arrays having smaller pixels making it particularly interesting for a combination with the SOIPIX technology.
(48) By way of example,
(49) The above-mentioned conductive control layer 11 can be integrated into the SOI layer 13 as doped silicon layer 14, which capacitively controls the potential of the interface 10. Alternatively, the conductive control layer may also be formed as polysilicon or metal electrode. Due to the limited dielectric strength of the very thin oxides in the SOI electronics, the control voltage for the conductive control layer 14 mayif at allbe only in the range of a few volts. Here, it is beneficial to use the interface doping layer 12 for shifting the control voltage into a range suitable for the SOI electronics.
(50) The invention is not limited to a specific shape of the individual anode regions. These may have e.g. a quadratic or rectangular shape. A different anode shape and/or anode size at different positions in the APD array is also conceivable, usually leading to a different shape and size of the pixels.
(51) As is apparent from the above description, each of the possible designs according to the second embodiment can be combined with each of the possible designs according to the first embodiment.
(52) Furthermore, it is clear that the present invention is directed to APD pixel arrays in which the pixel structure results from anode regions 1 that are separated from one another, whereas the cathodes of the individual diodes are all connected to one another in that the whole array has a homogenous unstructured cathode region 3. The missing pixel structure in the cathode region 3 formed in the second main surface 102 is advantageous because in the inventive APD pixel arrays the radiation is incident on the second main surface 102, which thus is the radiation entrance side in the detection.
(53) Finally, it shall be mentioned that the invention can be applied in particular to silicon-based APD arrays and can preferably be applied in Reach-Through-APDs or SLIK-APDs that are suited for the detection of electromagnetic radiation. The inventive APD arrays can in particular be used for the detection of visible light, of UV radiation or of X-rays having an energy of the X-ray photons between 100 eV and 5 keV. The total wavelength range in which a detection can take place depends on the configuration of the radiation entrance window at the second main surface. The range for the above-specified radiation, when converted to wavelengths, comprises approximately the range between 0.2 nm to 700 nm.
(54) In sensor operation, the described APD pixel arrays are substantially operated such that by the application of a reverse voltage between the cathode region 3 and the anode regions 1 the whole semiconductor between the cathode region 3 and the anode regions 1 except the cathode region 3 and the anode regions 1 itself as well as p-stop regions 8 or p-spray regions in the pixel insulation region 7, as the case may be, is depleted.
REFERENCE NUMBERS
(55) 1anode region (n+-doped)not depleted 1alower-doped tail of the anode (1)depleted 2multiplication layer (p-doped) 3cathode region (p+-doped) 4drift region (weakly doped) 5light entrance window 6insulating layer (preferably SiO.sub.2) 7pixel insulation region 8p-doping (p-stop) 9n-doped field reduction layer (depleted) 10bottom of the recess 20 and interface between insulating layer 6 and semiconductor substrate 100, respectively 11conductive control layer 12n-doped depleted interface doping layer in the insulation region 70 13second semiconductor substrate with integrated read-out electronicsSOI layer 14conductive control layer integrated in the second semiconductor substrate 13 15contact 20recess 70pixel insulation region 100semiconductor substrate 101first main surface 102second main surface