Device to adjust gas concentration in fluids
09857342 ยท 2018-01-02
Assignee
Inventors
Cpc classification
C12G1/06
CHEMISTRY; METALLURGY
International classification
G01N33/00
PHYSICS
C12G1/06
CHEMISTRY; METALLURGY
Abstract
A device to adjust concentration of a first gas in a fluid to a target concentration (C.sub.f) is provided. The device includes a container, having a first opening, the container is configured to receive a first volume (V.sub.L) of the fluid through the first opening. Wherein the fluid has an initial concentration (C.sub.i) of the first gas and a second volume (V.sub.C) of the container is determined based on the initial concentration (C.sub.i) of the first gas in the fluid, a target concentration (C.sub.f) of the first gas in the fluid, a partition coefficient () of the first gas, and the first volume (V.sub.L), and configured to adjust pressure in the container at a predetermined pressure of the first gas to adjust the first gas concentration in the fluid to the target concentration (C.sub.f); wherein the second volume (V.sub.C) and the first volume (V.sub.L) are correlated by:
in that M is an amount of the first gas required to be introduced in the container to adjust the first gas concentration in the fluid to the target concentration (C.sub.f).
Claims
1. A device to adjust concentration of a first gas in a fluid to a target concentration (C.sub.f) comprising: a container, the container comprises a first opening, the container is configured to receive a first volume (V.sub.L) of the fluid through the first opening, wherein the fluid has an initial concentration (C.sub.i) of the first gas and wherein a second volume (V.sub.C) of the container is determined based on the initial concentration (C.sub.i) of the first gas in the fluid, a target concentration (C.sub.f) of the first gas in the fluid, a partition coefficient () of the first gas, and the first volume (V.sub.L), and configured to adjust pressure in the container at a predetermined pressure of the first gas to adjust the first gas concentration in the fluid to the target concentration (C.sub.f) wherein the second volume (V.sub.C) and the first volume (V.sub.L) are correlated by:
2. The device of claim 1, wherein the device is configured to adjust concentration of the first gas in the fluid by adjusting the second volume (V.sub.C).
3. The device of claim 1, wherein the device is configured to adjust concentration of the first gas in the fluid for a predetermined value of the second volume (V.sub.C) by adjusting the first volume (V.sub.L).
4. The device of claim 1, wherein the container is provided with a second opening, the second opening is configured to adjust pressure in the container at the predetermined pressure with the first gas, wherein, the predetermined pressure is a partial pressure of the first gas and is determined by solubility parameter of the first gas.
5. The device of claim 1, wherein the device further comprises a third opening, the third opening is configured to dispense the fluid out of the container.
6. The device of claim 1, wherein, the device further comprises a seal configured to seal the container.
7. The device of claim 1, wherein the device is provided with a jacket, the jacket providing thermal insulation to the container.
8. The device of claim 7 wherein, the jacket is supplied with one or more of temperature control agents and the temperature control agents include one or more of dry ice, liquid nitrogen, chilled water, refrigerants, heat transfer fluids, compressed air, ice heating agents and electric coils.
9. The device of claim 1, wherein the predetermined pressure is a partial pressure of the first gas in a headspace of the container, wherein the headspace is volume of the container that is unoccupied by the fluid.
10. The device of claim 1, wherein the container is provided with a second opening to introduce the amount (M) of the first gas in the container.
11. The device of claim 1 wherein the container is configured to educe the first gas from the fluid.
12. The device of claim 1, wherein the container is provided with a piston to adjust pressure in the container.
13. The device of claim 12, wherein the piston is provided to adjust concentration of the first gas in the fluid by adjusting the second volume (V.sub.C).
14. The device of claim 1, wherein the first opening is configured to adjust pressure in the container.
15. The device of claim 14, wherein the first opening is configured to introduce the amount (M) of the first gas in the container.
16. The device of claim 14 wherein the first opening is configured to educe the first gas from the fluid.
17. The device of claim 5, wherein the third opening is operable by an actuator.
18. The device of claim 1, wherein the first gas is selected from a group consisting of carbon dioxide, oxygen, air, argon, neon, xenon, helium, nitrogen, nitrous oxide, hydrocarbons, halocarbons, halohydrocarbons and a combination thereof.
19. The device of claim 1, wherein the fluid is any one or more of beer, coffee, milk, cream, batter, dough, ice cream, wine, alcoholic beverage, cider, fruit juices and milkshake.
20. The device of claim 1, further comprises a handle attached to the container.
Description
BRIEF DESCRIPTION OF DRAWINGS
(1) The subject matter shall now be described with reference to the accompanying figures, wherein:
(2)
(3)
(4)
(5)
DETAILED DESCRIPTION
(6) Before the present subject matter is described in further detail, it is to be understood that the subject matter is not limited to the particular embodiments described, and may vary as such. It is also to be understood that the terminology used herein is for the purpose of describing particular embodiments only, and is not intended to be limiting. It must be noted that as used herein, the singular forms a, an, and the include plural referents unless the context clearly dictates otherwise. Further, the following description uses beer and water as examples for describing the present subject matter. It shall become clear to a person skilled in the art, after reading this specification, that the present subject matter may be practiced for fluids other than beer or water, without regards to whether the fluids are edible or not.
(7) Normally, beers contain a dissolved carbon dioxide level between 2.0 and 3.5 v/v depending on the beer style. At the end of fermentation, a carbon dioxide concentration level between 0.7 to 1.5 v/v is commonly seen. During finishing operations, additional carbon dioxide gas is injected into the beer, either directly into a flowing stream of beer or sparging a tank of beer. The final carbonation levels are tightly controlled to within 10% of the target depending on the beer style. However, achieving such level of control is not a simple matter. For example, a higher line back pressure or tank counter pressure can cause too much carbon dioxide dissolution. On the other hand, lower pressures or lower carbon dioxide injection rates can result in flat beer.
(8) Producing nitrogenated beers, is significantly more complicated. Dissolved concentrations of both carbon dioxide and nitrogen should be tightly controlled. For optimal product quality, carbon dioxide concentration is targeted to a specific value within the range of 0.9 to 1.7 v/v and a nitrogen concentration is targeted to a specific value within the range of 0.015 v/v to 0.075 v/v. However, achieving such precisely controlled gas levels is extremely difficult because of the widely different solubility of nitrogen and carbon dioxide. Nitrogen or a mixture of nitrogen and carbon dioxide are injected directly into either a filled tank or a flowing stream of fermented beer containing about 1 v/v carbonation. The product quality is very variable because of the complexity involved with managing pressures, temperatures, composition of the injection gas, and the pressures at the receiving tanks. For example, too high a back pressure can cause too much carbon dioxide dissolution. Lower pressures or lower carbon dioxide content in the injected gas results in flat beer. Too much nitrogen injection can cause stripping of carbon dioxide from the beer. All the foam created during the process can result in stripping the beer of hops, bitterness, aroma or flavor, and foam-positive agents such as foam protein. The difficulties are compounded when nitrogen addition is required. The present subject matter provides a method and a device to ensure that the carbon dioxide and/or nitrogen concentration in a beer is adjusted to its desired level.
(9) The present subject matter becomes of particular interest when it is desired to convert a normally carbonated beer produced by a brewery into a nitrogenated beer style at the point of dispense for serving. The present subject matter provides a solution that enables adjusting gas concentration in a beer without requiring highly sophisticated skills and precision equipment. In addition the present subject matter provides options for a lay person to exercise his creativity to create his own type of beer by adjusting gas concentration to suit his/her taste.
(10) For example, the carbon dioxide concentration in a typical beer ranges between 2.0 and 3.5 v/v. However, in a nitrogenated beer, the concentration of carbon dioxide ranges between 0.9 to 1.7 v/v and nitrogen between 0.010 to 0.075 v/v. To convert a normal beer with carbon dioxide concentration 2.0-3.5 v/v, into a nitrogenated beer the carbon dioxide concentration must be reduced from 2.0-3.5 v/v to 0.9-1.7 v/v and nitrogen must be added. Removing a measured amount (or a close approximate) of carbon dioxide in controlled manner at the time of dispense is difficult. Similarly, adding a precise amount of nitrogen without upsetting the carbon dioxide balance is a significant challenge. The present subject matter provides solution to this problem.
(11) According to one embodiment, the present subject matter provides a method and a device to adjust concentration of a first gas in a fluid by controlling a first volume of fluid (V.sub.L) and a second volume (V.sub.C) of a container. The fluid has an initial concentration (C.sub.i) of the first gas. The objective is to adjust the concentration of the first gas to a target concentration (C.sub.f). According to the present subject matter, the relationship between the first volume and the second volume and the initial concentration and final concentration may be expressed as follows:
(12)
(13) Where is a partition coefficient of the first gas in the fluid and M is an amount of the first gas that is added to the container for achieving the target concentration.
(14) The partition coefficient is related to the Henry's Law solubility parameter H for the gas-fluid pair (units atm/(v/v)) in the following manner:
(15)
(16) wherein, T represents the absolute temperature of the fluid (units: K), and T.sup.R and p.sup.R are the absolute temperature and pressure conditions at which the gas volumes are referenced, typically 273 K and 1 atm. The dissolved concentration of the gas (C) is related to its existing partial pressure (p) under the conditions when the gas and the fluid are in thermodynamic equilibrium as defined by the Henry's Law solubility parameter H in the manner:
p=HC
(17) The Henry's law solubility parameter is dependent on the nature of the gas-fluid pair, and the temperature. Therefore, partition function and the Henry's law solubility parameter could said to be related solubility parameters. Values of H in various units are available from published literature (for example, Perry's Chemical Engineers' Handbook 5.sup.th Edition (McGraw Hill) for many gases in water, and the American Society of Brewing Chemists for data for carbon dioxide-beer system). The solubility parameters for water and beer are similar. Generally, solubility of carbon dioxide in beer is smaller than solubility in water by about 10%.
(18) The following discussion explains adjusting gas concentration in water according to the present subject matter. It shall become clear, after reading this specification, to a person skilled in the art that the procedure may be applied to beer or other fluids instead of water if the corresponding values of the partition coefficient and other parameters are substituted to practice the present method without departing from the basic concept of the present subject matter.
(19) Equation (1) for carbon dioxide may be written as follows:
(20)
The subscript CO2 denotes the parameters as described for the equation (1) but associated with the carbon dioxide. The present example assumes that water at 38 F. with an initial carbon dioxide concentration 2.65 v/v needs to be adjusted to a target concentration of 1.25 v/v. Because the target concentration is lower than the initial concentration no additional gas needs to be added, i.e., M.sub.CO2=0. The ratio of the initial concentration and target concentration is 2.12. The partition coefficient for the carbon dioxide in water at 38 F. is about 0.65 (for beer the partition coefficient is about 0.70). Upon appropriate adjustment for the unit conversions, substituting by these values in the equation (2), a linear relationship between the first and the second volume is obtained.
(21)
(22) That is, in a container having a volume 2.72 liters, pouring 1 liter of water having carbon dioxide concentration of 2.65 v/v and agitating the water and allowing the water to settle to achieve substantial equilibrium shall provide water with carbon dioxide at the target concentration 1.25 v/v. The remaining carbon dioxide is educed from the water and occupies volume of the container that is unoccupied (headspace) by the water. The final partial pressure of carbon dioxide may be determined by the equation p=HC. Thus partial pressure for the carbon dioxide turns out to be p=0.83 atm (H=0.66 atm/(v/v)). The product with the thus adjusted carbonation level may now be dispensed and served, or further processed using further adaptations as described below.
(23) Now, that the carbon dioxide concentration in the water is adjusted to 1.25 v/v, the method may be further adapted to also adjust nitrogen concentration in the water to obtain desired nitrogen concentration. For the adjusting nitrogen concentration in the water the equation (1) may be written as follows:
(24)
(25) The subscript N2 denotes the parameters as described for the equation (1) but associated with the nitrogen. In the present case, the ratio of the first volume and the second volume is:
(26)
(27) Assuming that the initial concentration of the nitrogen in the water is zero then C.sub.iN2=0. If a target concentration of nitrogen C.sub.fN2=0.035 v/v is desired, considering that the partition coefficient of the nitrogen .sub.N2=44.9, a value of M.sub.N2=2.72V.sub.L is required to be added. This addition may be achieved by charging the container to a nitrogen partial pressure of 1.59 atm, as determined by the equation p=HC with H=45.5 and C=0.035 v/v.
(28) During this process, the container is never vented. Thus, the total pressure in the container is the sum of the partial pressures of carbon dioxide (0.83 atm) and nitrogen (1.59 atm), i.e., the total pressure at the end of the process is expected to be 2.42 atm abs.
(29) It should be understood that when the process is performed in ambient air, a significant portion of M.sub.N2 is provided from the ambient air rather than the injection port. A small amount of oxygen is also entrained in the process and exerts a corresponding partial pressure. The final total pressure could therefore be correspondingly slightly greater than the 2.42 atm value noted above.
(30) It is also possible to add air instead of pure nitrogen. For example if it is desired to add C.sub.f=0.040 v/v of air to the water at 1.25 v/v carbonation prepared as described above, an amount M.sub.air=2.60V.sub.L would be required to be added. When the method of the present subject matter is performed in ambient air, a portion of this total air requirement is provided by ambient air entrainment. Corresponding final air partial pressure would be 1.51 atm. The final total pressure would be p.sub.CO2+p.sub.air=0.83+1.51=2.34 atm abs.
(31) Another example may illustrate the present subject matter in which the carbon dioxide concentration in water at 38 F. is increased. If the initial concentration of carbon dioxide in the water were zero, then equation (1) can be reduced accordingly using C.sub.i=0. An amount of M for target concentration C.sub.f=2.65 v/v may be determined based on the water volume (V.sub.L), the container volume (V.sub.C), and the partition coefficient (.sub.CO2). The amount of carbon dioxide required to be injected M.sub.CO2 would now depend on the container size because only a portion M.sub.CO2(.sub.CO2.Math.C.sub.f.Math.(V.sub.CV).sub.L) of the total injected amount M.sub.CO2 will dissolve in the water. For example, if the same container size as in the earlier examples V.sub.C=2.72.Math.V.sub.L is used, based on equation (2), a total amount of M=5.62 times V.sub.L is required to be introduced in the container. The corresponding final carbon dioxide partial pressure would be p=HC.sub.f=(0.66)(2.65)=1.75 atm.
(32) According to a further aspect of the present subject matter, the method is practiced in a temperature controlled environment. Generally, the subject matter may be practiced at the room temperature, however in some other cases, a jacket for controlling temperature may be provided along with the device of the present subject.
(33) Following Table 1 shows examples of adjusting different gas concentrations in water at 38 F. according to the present subject matter. The partition coefficient and solubility data listed in this table are obtained from the Perry's Chemical Engineers' Handbook for water. As long as the ratio V.sub.C/V.sub.L for the container and liquid volume are as listed and the initial and final gas compositions are adhered to, the final total pressure can be estimated by adding up all the partial pressures of the respective gases. To apply the teachings of the present subject matter to a fluid other than water, or for use with other gases than those listed, it is recommended that the H and values for the respective gases in the fluid of interest be used for a more accurate estimation, Although following table list only few gases. It shall become clear to a person skilled in the art, after reading this specification, that other similar method can be practiced with any gas other than those listed below as well as any fluid other than the water. A non-exhaustive list of gases includes methane, helium, argon, xenon, hydrogen, halocarbons, hydrocarbons, halohydrocarbons, etc. A non-exhaustive list of fluids includes coffee, cream, batter, dough, milkshake, ciders, fruit juice, alcoholic beverages, wines, ice cream etc.
(34) TABLE-US-00001 TABLE 1 Henry's Law Gas Final Solubility Initial Target added M, partial Container Partition Parameter, Conc., Ci, Conc., Cf, xV.sub.L at ref pressure, Vol:LiqVol Gas Coefficient, H, atm/(v/v) v/v v/v cond. atm abs Vc/Vl Description CO2 0.65 0.66 2.65 1.25 0.00 0.83 2.72 Decarbonation CO2 0.65 0.66 0.00 2.65 5.62 1.75 2.72 Carbonation N2 44.90 45.50 0.00 0.035 2.74 1.59 2.72 Nitrogenation O2 21.80 22.04 0.00 0.019 0.74 0.42 2.72 Oxygen addition, Low Level O2 21.80 22.04 0.00 0.035 1.35 0.77 2.72 Oxygen addition, High Level Air 37.20 37.70 0.00 0.040 2.60 1.51 2.72 Aeration Ar 25.10 25.40 0.00 0.035 1.55 0.89 2.72 Argon addition He 101.33 102.57 0.00 0.035 6.15 3.59 2.72 Helium addition H2 47.46 48.04 0.00 0.035 2.90 1.68 2.72 Hydrogen addition
(35) The present subject matter further provides a device to adjust gas concentrations in a fluid. A schematic diagram according to one embodiment of the device 100 of the present subject matter is shown in
(36) In one embodiment, the device 100 is designed for adjusting gas concentration of in a one liter of beer having initial carbon dioxide concentration of 2.65 v/v. The partition coefficient for carbon dioxide in beer is about 0.7. If the volume of the container 101 is 2.72 liter, dispensing the beer according in the device 100 and following the steps of the method according to the present subject matter shall result in a beer having carbon dioxide concentration 1.20 v/v. The beer may be then further processed for nitrogenation or further adjusting carbonation according to the method of present subject matter by pressurizing the container 101 with an amount (M) as explained in the aforementioned description. Similarly, for obtaining a target concentration of 0.65 v/v carbon dioxide in the beer from initial concentration 2.65 v/v, half a liter of the beer may be dispensed in the container 101. The nitrogenation or further carbonation of the beer may follow as explained earlier.
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(40) While the subject matter may be susceptible to various modifications and alternative forms, specific embodiments have been shown by way of example in the drawings and have been described herein. Alternate embodiments or modifications may be practiced without departing from the spirit of the present subject matter. The drawings shown are schematic drawings and may not be to the scale. While the drawings show some features of the subject matter, some features may be omitted. Alternatively, in some other cases some features may be emphasized while others are not. Further, the methods disclosed herein may be performed in manner and/or order in which the methods are explained. Alternatively, the methods may be performed in manner or order different than what is explained without departing from the spirit of the present subject matter. It should be understood that the subject matter is not intended to be limited to the particular forms disclosed. Rather, the subject matter is to cover all modifications, equivalents, and alternatives falling within the spirit and scope of the subject matter as defined by the following appended claims.