MOS devices having epitaxy regions with reduced facets
09853155 ยท 2017-12-26
Assignee
Inventors
- Chii-Horng Li (Zhubei, TW)
- Hsueh-Chang Sung (Zhubei, TW)
- Kun-Mu LI (Zhudong Township, TW)
- Tze-Liang Lee (Hsinchu, TW)
- Tsz-Mei KWOK (Hsinchu, TW)
Cpc classification
H10D62/021
ELECTRICITY
H01L21/76855
ELECTRICITY
H10D30/022
ELECTRICITY
H10D84/0133
ELECTRICITY
H10D30/797
ELECTRICITY
H01L21/28
ELECTRICITY
H10D30/608
ELECTRICITY
H10D30/0275
ELECTRICITY
H10D62/822
ELECTRICITY
H10D64/256
ELECTRICITY
International classification
H01L29/165
ELECTRICITY
Abstract
An integrated circuit structure includes a gate stack over a semiconductor substrate, and an opening extending into the semiconductor substrate, wherein the opening is adjacent to the gate stack. A first silicon germanium region is disposed in the opening, wherein the first silicon germanium region has a first germanium percentage. A second silicon germanium region is over the first silicon germanium region. The second silicon germanium region comprises a portion in the opening. The second silicon germanium region has a second germanium percentage greater than the first germanium percentage. A silicon cap substantially free from germanium is over the second silicon germanium region.
Claims
1. An integrated circuit structure comprising: a semiconductor substrate; a gate stack over the semiconductor substrate; a first silicon germanium region having a first germanium percentage and disposed in the semiconductor substrate adjacent the gate stack; a capping layer over the first silicon germanium region, wherein the capping layer has a lower germanium percentage than the first silicon germanium region; and a silicide region extending into the capping layer, wherein the silicide region comprises a higher germanium percentage than the capping layer.
2. The integrated circuit structure of claim 1 further comprising a second silicon germanium region under the first silicon germanium region, wherein the second silicon germanium region has a lower germanium percentage than the first silicon germanium region, and wherein the first silicon germanium region is disposed between the second silicon germanium region and the capping layer along a direction perpendicular to a major surface of the semiconductor substrate.
3. The integrated circuit structure of claim 2, wherein the second silicon germanium region has a lower p-type impurity concentration than the first silicon germanium region.
4. The integrated circuit structure of claim 1, wherein the capping layer has a higher p-type impurity concentration than the first silicon germanium region.
5. The integrated circuit structure of claim 4, wherein a ratio of a first p-type impurity concentration of the capping layer to a second p-type impurity concentration of the first silicon germanium region is 5 to 15.
6. The integrated circuit structure of claim 1, wherein the silicide region extends into the first silicon germanium region.
7. The integrated circuit structure of claim 1, wherein a germanium percentage of the capping layer is less than two percent.
8. The integrated circuit structure of claim 1 further comprising a gate spacer extending along a sidewall of the gate stack, wherein the gate spacer laterally spaces the first silicon germanium region apart from the gate stack at a top surface of the semiconductor substrate.
9. A semiconductor device comprising: a semiconductor substrate; a transistor at a top surface of the semiconductor substrate, wherein the transistor comprises: a gate stack; and a source/drain region comprising: a first germanium-containing semiconductor region; a second germanium-containing semiconductor region on the first germanium-containing semiconductor region, wherein the second germanium-containing semiconductor region has a higher germanium percentage than the first germanium-containing semiconductor region; and a capping layer on the second germanium-containing semiconductor region, wherein the capping layer has a lower germanium percentage than the second germanium-containing semiconductor region; and a silicide region extending into the capping layer, wherein a line parallel to a major surface of the semiconductor substrate extends from a first portion of the capping layer through the silicide region to a second portion of the capping layer, and wherein a germanium percentage of the silicide region is greater than a silicon percentage of the silicide region.
10. The semiconductor device of claim 9, wherein the germanium percentage of the silicide region is greater than respective germanium percentages of the first portion of the capping layer and the second portion of the capping layer.
11. The semiconductor device of claim 9, wherein a p-type impurity concentration increases from the first germanium-containing semiconductor region through the second germanium-containing semiconductor region to the capping layer.
12. The semiconductor device of claim 9, wherein the first germanium-containing semiconductor region, the second germanium-containing semiconductor region, and the capping layer each comprise silicon.
13. The semiconductor device of claim 9, wherein the silicide region further extends into the second germanium-containing semiconductor region.
14. The semiconductor device of claim 9, wherein the second germanium-containing semiconductor region extends above an interface between the gate stack and the semiconductor substrate.
15. The semiconductor device of claim 9, wherein a first portion of second germanium-containing semiconductor region is disposed over a second portion of second germanium-containing semiconductor region, wherein the first portion of the second germanium-containing semiconductor region has a higher germanium percentage than the second portion of the second germanium-containing semiconductor region, wherein a germanium percentage is substantially constant throughout the first portion of the second germanium-containing semiconductor region, and wherein a germanium percentage is substantially constant through the second portion of the second germanium-containing semiconductor region.
16. The semiconductor device of claim 15, wherein a germanium percentage difference between the first portion of the second germanium-containing semiconductor region and the second portion of the second germanium-containing semiconductor region is at least 10%.
17. A transistor comprising: a gate stack; and a source/drain region comprising: a first silicon germanium region having a first germanium percentage; a second silicon germanium region over the first silicon germanium region and having a second germanium percentage greater than the first germanium percentage; a capping layer over the second silicon germanium region, wherein a germanium percentage throughout the source/drain region is highest at an interface between the second silicon germanium region and the capping layer; and a silicide extending into at least the capping layer, wherein the silicide comprises a higher germanium percentage than the capping layer.
18. The transistor of claim 17, wherein a p-type impurity concentration throughout the source/drain region is highest in the capping layer.
19. The transistor of claim 17, wherein the capping layer is substantially free of germanium.
20. The transistor of claim 17, wherein the second germanium percentage varies throughout the second silicon germanium region from a bottom of the second silicon germanium region to the interface between the second silicon germanium region and the capping layer.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) For a more complete understanding of the embodiments, and the advantages thereof, reference is now made to the following descriptions taken in conjunction with the accompanying drawings, in which:
(2)
(3)
DETAILED DESCRIPTION OF ILLUSTRATIVE EMBODIMENTS
(4) The making and using of the embodiments of the disclosure are discussed in detail below. It should be appreciated, however, that the embodiments provide many applicable concepts that can be embodied in a wide variety of specific contexts. The specific embodiments discussed are illustrative, and do not limit the scope of the disclosure.
(5) A process for forming a Metal-Oxide-Semiconductor (MOS) device is provided in accordance with various exemplary embodiments. The intermediate stages of forming the MOS device are illustrated. The variations of the embodiments are discussed. Throughout the various views and illustrative embodiments, like reference numbers are used to designate like elements.
(6) To enhance the performance of MOS devices, stress may be introduced in the channel region of a MOS device to improve carrier mobility. Generally, it is desirable to induce a tensile stress in the channel region of an n-type MOS (NMOS) device in a source-to-drain direction, and to induce a compressive stress in the channel region of a p-type MOS (PMOS) device in a source-to-drain direction.
(7) One of the methods for applying compressive stress to the channel regions of PMOS devices is growing SiGe stressors in the source and drain regions. Such a method typically includes the steps of forming a gate stack on a semiconductor substrate, forming spacers on sidewalls of the gate stack, forming recesses in the silicon substrate along gate spacers, epitaxially growing SiGe stressors in the recesses, and annealing. Since SiGe has a lattice constant greater than that of silicon, it expands after annealing and applies a compressive stress to the channel region, which is located between a source SiGe stressor and a drain SiGe stressor.
(8)
(9) Gate stacks 22 are formed over substrate 20, and include gate dielectrics 24 and gate electrodes 26. Gate dielectrics 24 may comprise silicon oxide and/or a high-k material having a high k value, for example, higher than about 7. Gate electrodes 26 may include commonly used conductive materials such as doped polysilicon, metals, metal silicides, metal nitrides, and combinations thereof. Gate stacks 22 may also include hard masks 28, which may comprise silicon nitride, for example, although other materials such as silicon carbide, silicon oxynitride, and the like may also be used. In the embodiments in which replacement gates are formed, hard mask 28 may be, or may not be, formed.
(10) As shown in
(11) Referring to
(12) As also shown in
(13) Next, as shown in
(14)
(15) As shown in
(16) During the epitaxy, desired p-type impurities may be doped while the growth proceeds. For example, when boron is to be doped, B.sub.2H.sub.6 may be included in the process gases. In some embodiments, the impurity concentration of p-type impurities such as boron in epitaxy layers 38 is lower than about 1E19/cm.sup.3, and may be between about 1E18/cm.sup.3 and about 1E20/cm.sup.3. In alternative embodiments, during the epitaxy of layers 38, no p-type impurity is added. Epitaxy layers 38 may have a first germanium atomic percentage between about 10 percent and about 30 percent, for example, although different germanium percentages may also be used.
(17) Referring to
(18) Furthermore, during the epitaxy, a p-type impurity such as boron may be in-situ doped with the proceeding of the epitaxy. The p-type impurity concentration C42 in epitaxy layers 42 may be higher than the p-type impurity concentration in epitaxy layers 38. For example, p-type impurity concentration C42 is between about 1E20/cm.sup.3 and about 8E20/cm.sup.3.
(19) Epitaxy layers 42 may also include a lower layer and an upper layer with different germanium percentages, wherein each of the lower layer and the upper layer has a substantially uniform germanium percentage.
(20) In some embodiments, in each of epitaxy layers 38 and 42, the germanium percentage is substantially uniform. In alternative embodiments, either one or both of epitaxy layers 38 and 42 has a gradually and continuously changed germanium percentage. During the respective epitaxy, the flow rate of the germanium-containing precursor (such as GeH.sub.4) may be gradually and continuously increased. In these embodiments, in the layer in which the germanium percentage gradually changes, the lower portions of the layer have germanium percentages lower than the germanium percentages of the upper layers.
(21) After the formation of epitaxy layers 42, capping layers 44 are formed through epitaxy, as shown in
(22) During the epitaxy of capping layer 44, a p-type impurity such as boron may be in-situ doped with the proceeding of the epitaxy. In some embodiments, the concentration of the p-type impurity in capping layers 44 is higher than the p-type impurity concentration in epitaxy layers 42 and 38. In some embodiments, a ratio of the p-type impurity concentration C44 in capping layers 44 to the p-type impurity concentration C42 in epitaxy layers 42 is greater than about 10. Ratio C44/C42 may also be between about 5 and about 15. In some embodiments, p-type impurity concentration C44 is between about 1E21 and about 8E21/cm.sup.3. The growth of epitaxy layers 38, 42, and 44 may be in-situ performed in a same chamber, with no vacuum break therein.
(23) Next, referring to
(24)
(25)
(26)
(27) In the embodiments of the present disclosure, by forming low-germanium-containing capping layers, the facets that are formed on germanium epitaxy regions is reduced since silicon has the tendency of able to be formed close to gate spacers, while germanium is expelled by gate spacers, hence forming severe facets. The facets result in the reduction in the landing area of source/drain contact plugs, hence higher contact resistance. Furthermore, with facets, the silicide metal may have extrusions to penetrate to LDD regions. In the embodiments of the present disclosure, these problems are at least reduced, and sometimes eliminated.
(28) In accordance with some embodiments, an integrated circuit structure includes a gate stack over a semiconductor substrate, and an opening extending into the semiconductor substrate, wherein the opening is adjacent to the gate stack. A first silicon germanium region is disposed in the opening, wherein the first silicon germanium region has a first germanium percentage. A second silicon germanium region is over the first silicon germanium region. The second silicon germanium region comprises a portion in the opening. The second silicon germanium region has a second germanium percentage greater than the first germanium percentage. A silicon cap substantially free from germanium is over the second silicon germanium region.
(29) In accordance with other embodiments, an integrated circuit structure includes a semiconductor substrate, and a gate stack over the semiconductor substrate, wherein the gate stack is comprised in a MOS device. A source/drain region of the MOS device extends into the semiconductor substrate. The source/drain region includes a first silicon germanium region, wherein the first silicon germanium region has a first germanium percentage, and a second silicon germanium region over the first silicon germanium region. The second silicon germanium region has a second germanium percentage greater than the first germanium percentage. The second silicon germanium region includes a top portion having a highest germanium percentage among the source/drain region. A silicon cap is overlying and contacting the top portion of the second silicon germanium region.
(30) In accordance with yet other embodiments, a method includes forming a gate stack over a semiconductor substrate, forming an opening extending into the semiconductor substrate, wherein the opening is on a side of the gate stack, and performing a first epitaxy to grow a first silicon germanium region in the opening. The first silicon germanium region has a first germanium percentage. A second epitaxy is performed to grow a second silicon germanium region over the first silicon germanium region, wherein the second silicon germanium region has a second germanium percentage greater than the first germanium percentage. A third epitaxy is performed to grow a silicon cap substantially free from germanium over the second silicon germanium region. The method further includes forming a silicide region extending into the silicon cap, wherein the silicide region includes a higher a germanium percentage than the silicon cap.
(31) In accordance with another embodiment, a method includes patterning a first opening in a semiconductor substrate, epitaxially growing a first epitaxy region in the first opening, and epitaxially growing a second epitaxy region on the first epitaxy region. The second epitaxy region includes a lower germanium percentage than the first epitaxy region. The method further includes depositing an inter-layer dielectric (ILD) over the second epitaxy region, patterning a second opening in the ILD, and exposing a portion of the second epitaxy region. A silicidation is performed on the portion of the second epitaxy region to form a silicide region. The silicide region further extends into the first epitaxy region.
(32) In accordance with yet another embodiment, a method includes etching an opening in a semiconductor substrate between adjacent gate spacers, forming a first semiconductor region in the opening using a first epitaxy process, and forming a second semiconductor region over the first semiconductor region using a second epitaxy process. The second epitaxy process includes using a higher percentage of germanium gases than the first epitaxy process. The method further includes forming a capping region over the second semiconductor region using a third epitaxy process. The third epitaxy process includes using a lower percentage of germanium gases than the second epitaxy process. The method further includes depositing a dielectric layer between the adjacent gate spacers and over the capping region, exposing the capping region, and after exposing the capping region forming a silicide region extending through the capping region. The silicide region includes a higher percentage of germanium than the capping region. A contact is formed extending through the dielectric layer and contacting the silicide region.
(33) In accordance with an embodiment, an integrated circuit structure including a semiconductor substrate; a gate stack over the semiconductor substrate; a first silicon germanium region having a first germanium percentage and disposed in the semiconductor substrate adjacent the gate stack; a capping layer over the first silicon germanium region; and a silicide region extending into the capping layer. The capping layer has a lower germanium percentage than the first silicon germanium region, and the silicide region comprises a higher a germanium percentage than the capping layer.
(34) In accordance with an embodiment, a semiconductor device includes a semiconductor substrate and a transistor at a top surface of the semiconductor substrate. The transistor includes a gate stack and a source/drain region having a first germanium-containing semiconductor region; a second germanium-containing semiconductor region on the first germanium-containing semiconductor region, wherein the second germanium-containing semiconductor region has a higher germanium percentage than the first germanium-containing semiconductor region; and a capping layer on the second germanium-containing semiconductor region, wherein the capping layer has a lower germanium percentage than the second germanium-containing semiconductor region. The semiconductor device further includes a silicide region extending into the capping layer. A line parallel to a major surface of the semiconductor substrate extends from a first portion of the capping layer through the silicide region to a second portion of the capping layer, and a germanium percentage of the silicide region is greater than a silicon percentage of the silicide region.
(35) In accordance with an embodiment, transistor includes gate stack and a source/drain region comprising a first silicon germanium region having a first germanium percentage; a second silicon germanium region over the first silicon germanium region and having a second germanium percentage greater than the first germanium percentage; a capping layer over the second silicon germanium region, wherein a germanium percentage throughout the source/drain region is highest at an interface between the second silicon germanium region and the capping layer; and a silicide extending into at least the capping layer. The silicide comprises a higher germanium percentage than the capping layer.
(36) Although the embodiments and their advantages have been described in detail, it should be understood that various changes, substitutions and alterations can be made herein without departing from the spirit and scope of the embodiments as defined by the appended claims. Moreover, the scope of the present application is not intended to be limited to the particular embodiments of the process, machine, manufacture, and composition of matter, means, methods and steps described in the specification. As one of ordinary skill in the art will readily appreciate from the disclosure, processes, machines, manufacture, compositions of matter, means, methods, or steps, presently existing or later to be developed, that perform substantially the same function or achieve substantially the same result as the corresponding embodiments described herein may be utilized according to the disclosure. Accordingly, the appended claims are intended to include within their scope such processes, machines, manufacture, compositions of matter, means, methods, or steps. In addition, each claim constitutes a separate embodiment, and the combination of various claims and embodiments are within the scope of the disclosure.