Localized elastic strain relaxed buffer
09799513 ยท 2017-10-24
Assignee
Inventors
- Veeraraghavan S. Basker (Schenectady, NY, US)
- Oleg Gluschenkov (Tannersville, NY, US)
- Shogo MOCHIZUKI (Clifton Park, NY, US)
- Alexander Reznicek (Troy, NY, US)
Cpc classification
H10D62/116
ELECTRICITY
H01L21/02694
ELECTRICITY
H01L21/02667
ELECTRICITY
International classification
H01L29/06
ELECTRICITY
H01L29/08
ELECTRICITY
H01L21/02
ELECTRICITY
H01L29/16
ELECTRICITY
H01L29/161
ELECTRICITY
H01L29/10
ELECTRICITY
Abstract
A strain relaxed buffer layer is fabricated by melting an underlying layer beneath a strained semiconductor layer, which allows the strained semiconductor layer to elastically relax. Upon recrystallization of the underlying layer, crystalline defects are trapped in the underlying layer. Semiconductor layers having different melting points, such as silicon germanium layers having different atomic percentages of germanium, are formed on a semiconductor substrate. An annealing process causes melting of only the silicon germanium layer that has the higher germanium content and therefore the lower melting point. The silicon germanium layer having the lower germanium content is elastically relaxed upon melting of the adjoining silicon germanium layer and can be used as a substrate for growing strained semiconductor layers such as channel layers of field-effect transistors.
Claims
1. A fabrication method comprising: obtaining a structure including a semiconductor substrate layer comprising silicon, a strained epitaxial first layer having the composition Si.sub.1-xGe.sub.x on the substrate layer, and a strained epitaxial second layer in direct contact with the first layer and having the composition Si.sub.1-yGe.sub.y wherein y is less than x; forming recesses extending through the first and second layers; subsequent to forming the recesses, melting the first layer while the substrate layer and the second layer remain in a solid state, thereby causing elastic relaxation of the second layer; and recrystallizing the first layer following elastic relaxation of the second layer.
2. The method of claim 1, wherein x is between 0.3 and 1.0, further including avoiding any plastic relaxation of the second layer during a temperature ramp up stage preliminary to melting the first layer.
3. The method of claim 2, wherein y is between 0.1 and 0.4.
4. A fabrication method comprising: obtaining a structure including a semiconductor substrate layer comprising silicon, a strained epitaxial first layer having the composition Si.sub.1-xGe.sub.x on the substrate layer, and a strained epitaxial second layer in direct contact with the first layer and having the composition Si.sub.1-yGe.sub.y wherein y is less than x, and wherein y is between 0.1 and 0.4; melting the first layer while the substrate layer and the second layer remain in a solid state, thereby causing elastic relaxation of the second layer; recrystallizing the first layer following elastic relaxation of the second layer; and forming recesses extending through the first and second layers prior to melting the first layer.
5. The method of claim 1, wherein the strained, epitaxial first and second layers are pseudomorphic.
6. The method claim 1, wherein the strained, epitaxial first layer has a thickness between 3-25 nm.
7. The method of claim 1, wherein the strained, epitaxial second layer has a thickness between 20-1,000 nm and is thicker than the strained, epitaxial first layer.
8. The method of claim 1, wherein the second layer expands laterally into the recesses during the elastic relaxation thereof.
9. The method of claim 8, further including causing a first one of the recesses to have a width sufficient to facilitate lateral expansion of a first portion of the second layer and a second portion of the second layer into the first one of the recesses without contacting each during the elastic relaxation thereof.
10. The method of claim 9, further including causing the first layer to remain in a molten state for a selected time and causing the distances between recesses to be proportional to the selected time in which the first layer is in the molten state.
11. The method of claim 1, wherein the melting point of the strained, epitaxial first layer is at least 50 C. less than the melting point of the strained, epitaxial second layer.
12. The method of claim 1, further including electrically isolating regions of the relaxed second layer, forming a tensile strained first semiconductor layer directly on an nFET region of the relaxed second layer and forming a compressive strained second semiconductor layer on a pFET region of the relaxed second layer.
13. The method of claim 1, wherein x is between 0.3 and 1.0, y is between 0.1 and 0.4, each of the first and second layers having substantially uniform compositions.
14. The method of claim 1, wherein obtaining the structure includes epitaxially depositing the first layer directly on the substrate layer and epitaxially depositing the second layer directly on the first layer.
15. A semiconductor structure comprising: a semiconductor substrate layer; a recrystallized Si.sub.1-xGe.sub.x layer containing defects on the substrate layer; and an elastically strain relaxed, defect-free Si.sub.1-yGe.sub.y layer in direct contact with the recrystallized Si.sub.1-xGe.sub.x layer, and further wherein y is less than x.
16. The semiconductor structure of claim 15, wherein x is between 0.3 and 1.0 and y is between 0.1 and 0.4.
17. The semiconductor structure of claim 16, further including a plurality of recesses extending through the recrystallized Si.sub.1-xGe.sub.x layer and the strain relaxed Si.sub.1-yGe.sub.y layer.
18. The semiconductor structure of claim 17, wherein the strain relaxed Si.sub.1-yGe.sub.y layer includes electrically isolated nFET and pFET regions, further including a tensile strained semiconductor layer on the nFET region and a compressive strained semiconductor layer on the pFET region.
19. The semiconductor structure of claim 18, wherein the tensile strained semiconductor layer consists essentially of silicon and the compressive strained semiconductor layer consists essentially of silicon germanium.
20. The semiconductor structure of claim 18, wherein the recrystallized Si.sub.1-xGe.sub.x layer has a thickness between 3-25 nm, the strain relaxed Si.sub.1-yGe.sub.y layer has a greater thickness than the recrystallized Si.sub.1-xGe.sub.x layer, and the substrate layer has a greater thickness than both the recrystallized Si.sub.1-xGe.sub.x layer and the strain relaxed Si.sub.1-yGe.sub.y layer.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The following drawings are presented by way of example only and without limitation, wherein like reference numerals (when used) indicate corresponding elements throughout the several views, and wherein:
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(7) It is to be appreciated that elements in the figures are illustrated for simplicity and clarity. Common but well-understood elements that may be useful or necessary in a commercially feasible embodiment may not be shown in order to facilitate a less hindered view of the illustrated embodiments.
DETAILED DESCRIPTION
(8) Principles of the present disclosure will be described herein in the context of illustrative embodiments. It is to be appreciated, however, that the specific embodiments and/or methods illustratively shown and described herein are to be considered exemplary as opposed to limiting. Moreover, it will become apparent to those skilled in the art given the teachings herein that numerous modifications can be made to the embodiments shown that are within the scope of the claims. That is, no limitations with respect to the embodiments shown and described herein are intended or should be inferred.
(9) One or more embodiments provide a structure wherein a strain relaxed silicon germanium buffer is provided for subsequent growth of a strain-engineered semiconductor layer thereon.
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(11) The exemplary structure 20 shown in
(12) Referring to
(13) As schematically illustrated in
L<velocity of elastic expansion*anneal (melt) time=3e5 cm/s*1e-7 sec=300 m;
astrain*L=0.01*300 m=3 m.
The lateral expansion of the top Si.sub.1-yGe.sub.y layer 26 upon melting of the underlying Si.sub.1-xGe.sub.x layer 24 occurs at a maximum velocity (Rayleigh wave velocity) that depends on its physical properties. Such expansion occurs during the time the Si.sub.1-xGe.sub.x layer 24 is molten. It is expected that the expansion of the top Si.sub.1-yGe.sub.y layer 26 will not exceed the speed of sound (in air). As an example, an expansion velocity of 3e5 cm/s over an anneal time of one hundred nanoseconds (1e-7 seconds) provides a maximum length L between recesses 27 of the top Si.sub.1-yGe.sub.y layer 26 of about three hundred microns. The dimension a of the recesses 27 is sufficient to ensure the top Si.sub.1-yGe.sub.y layers 26 of adjoining areas of a wafer do not come into contact with each other as they expand. In exemplary embodiments having one percent strain and top Si.sub.1-yGe.sub.y layers 26 having lengths of three hundred microns, the minimum dimension of a is about three microns. The layers 26 expand in all directions, two of which are schematically shown in
(14) The annealing time is an important consideration in the fabrication of the relaxed buffer layer. The Si.sub.1-yGe.sub.y layer 26 will elastically relax due to the loss of the underlying template once it is in the molten state, forming a defect-free buffer layer 26. A relatively short anneal duration prevents the molten Si.sub.1-xGe.sub.x layer 24 from being displaced, possibly resulting in delamination of the Si.sub.1-yGe.sub.y layer 26 from the Si.sub.1-xGe.sub.x layer. Such delamination is possible if the duration of the Si.sub.1-xGe.sub.x layer in the molten state is beyond acceptable limits. Annealing times of less than one microsecond are employed in one or more embodiments, and are in a range of 100-250 microseconds in some embodiments. Displacement of the Si.sub.1-xGe.sub.x layer in the molten state could also adversely affect regrowth of the layer upon cooling, as described further below with respect to
(15) Cooling of the structure results in recrystallization of the Si.sub.1-xGe.sub.x layer 24, forming a recrystallized Si.sub.1-xGe.sub.x layer 24 in direct contact with the strain relaxed layer 26 in the exemplary structure. Crystalline defects such as stacking faults and dislocations could be introduced during the recrystallization process, but are trapped in the recrystallized layer 24. Defects 28 are schematically illustrated within the recrystallized layer. The structure 30 as schematically illustrated in
(16) One or more semiconductor layers can be epitaxially grown on the strain relaxed layer 26 and used to form electronic devices such as field effect transistors. Areas of the structure, for example nFET and pFET regions, can be electrically isolated by forming shallow trench isolation regions (not shown). Some areas can be employed for forming nFET devices while other areas are used to form pFET devices. In some exemplary embodiments, dual channel FinFET devices are formed. Patterning techniques familiar to those skilled in the art facilitate trench formation and subsequent filling of the trenches with one or more electrically insulating material(s) such as silicon dioxide. The filling process can be done by any suitable deposition process (e.g., by CVD, spin-on) followed by removal of the oxide from areas other than the STI regions. CMP (chemical mechanical planarization) to the top of the strained Si.sub.1-yGe.sub.y layer 26 or an etch-back process can be employed to remove excess oxide from the structure. The shallow trench isolation (STI) process provides regions that electrically isolate active areas of the structure. As discussed above, tensile or compressive strain can be introduced into the channel regions of such electronic devices by growing semiconductor layers on the strain relaxed SiGe layer 26 having more or less germanium content than the strain relaxed SiGe layer 26. Epitaxial Si.sub.1-zGe.sub.z layers are grown on the strain relaxed Si.sub.1-yGe.sub.y layer 26. In embodiments wherein an epitaxial layer consists essentially of silicon (z=0), a tensile strained layer is obtained. In embodiments wherein z is greater than y, a compressively strained SiGe layer is obtained. As known in the art, compressively strained channels enhance the performance of PMOS devices while NMOS devices benefit from tensile strain. For example, a silicon layer 38A grown directly on an underlying relaxed SiGe layer undergoes tensile strain due to the larger lattice spacing of the SiGe layer. As further shown in
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(18) It is to be appreciated that the various layers and/or regions shown in the accompanying figures may not be drawn to scale. Furthermore, one or more semiconductor layers of a type commonly used in some integrated circuit devices or other layers may not be explicitly shown in a given figure for ease of explanation. This does not imply that the semiconductor layer(s) or other layer(s) not explicitly shown are omitted in the actual integrated circuit device.
(19) Given the discussion thus far, it will be appreciated that, in general terms, an exemplary fabrication method includes obtaining a structure 20 including a semiconductor substrate layer 22 comprising silicon, a strained epitaxial first layer 24 having the composition Si.sub.1-xGe.sub.x on the substrate layer, and a strained epitaxial second layer 26 in direct contact with the first layer and having the composition Si.sub.1-yGe.sub.y, wherein y is less than x so that the second layer has a higher melting point than the first layer. The method further includes melting the first layer 24 while the substrate layer and the second layer remain in a solid state, thereby causing elastic relaxation of the second layer.
(20) Given the discussion thus far, it will also be appreciated that an exemplary semiconductor structure is provided that includes a semiconductor substrate layer 22, a recrystallized Si.sub.1-xGe.sub.x layer 24 on the substrate layer, and an elastically strain relaxed defect-free Si.sub.1-yGe.sub.y layer 26 in direct contact with the recrystallized Si.sub.1-xGe.sub.x layer, the value of y being less than x. Elastic relaxation is characterized by the absence of defects in the layer 26. The recrystallized Si.sub.1-xGe.sub.x layer 24, however, contains defects 28. In one or more embodiments, x is between 0.6 and 1.0 and y is between 0.1 and 0.4. In some embodiments, portions of the strain relaxed Si.sub.1-yGe.sub.y layer 26 are electrically isolated and a tensile silicon layer directly contacts an nFET region of the relaxed Si.sub.1-yGe.sub.y layer 26 and a silicon germanium layer under compressive strain directly contacts a pFET region of the relaxed Si.sub.1-yGe.sub.y layer 26. In one or more embodiments, the recrystallized layer 24 has a thickness of less than twenty-five nanometers. The relaxed, defect-free layer 26 has a greater thickness than the recrystallized Si.sub.1-xGe.sub.x layer 24, and is at least ten times as thick as the recrystallized Se.sub.1-xGe.sub.x layer 24 in some embodiments. The substrate layer is thicker than the relaxed, defect-free layer 26 in one or more embodiments.
(21) At least a portion of the techniques described above may be implemented in an integrated circuit. In forming integrated circuits, identical dies are typically fabricated in a repeated pattern on a surface of a semiconductor wafer. Each die includes a device described herein, and may include other structures and/or circuits. The individual dies are cut or diced from the wafer, then packaged as an integrated circuit. One skilled in the art would know how to dice wafers and package die to produce integrated circuits.
(22) Those skilled in the art will appreciate that the exemplary structures discussed above can be distributed in raw form (i.e., a single wafer having multiple unpackaged chips), as bare dies, in packaged form, or incorporated as parts of intermediate products or end products that benefit from having electronic devices and associated structures formed in accordance with one or more of the exemplary embodiments.
(23) The illustrations of embodiments described herein are intended to provide a general understanding of the various embodiments, and they are not intended to serve as a complete description of all the elements and features of apparatus and systems that might make use of the circuits and techniques described herein. Many other embodiments will become apparent to those skilled in the art given the teachings herein; other embodiments are utilized and derived therefrom, such that structural and logical substitutions and changes can be made without departing from the scope of this disclosure. It should also be noted that, in some alternative implementations, some of the steps of the exemplary methods may occur out of the order noted in the figures. For example, two steps shown in succession may, in fact, be executed substantially concurrently, or certain steps may sometimes be executed in the reverse order, depending upon the functionality involved. The drawings are also merely representational and are not drawn to scale. Accordingly, the specification and drawings are to be regarded in an illustrative rather than a restrictive sense.
(24) Embodiments are referred to herein, individually and/or collectively, by the term embodiment merely for convenience and without intending to limit the scope of this application to any single embodiment or inventive concept if more than one is, in fact, shown. Thus, although specific embodiments have been illustrated and described herein, it should be understood that an arrangement achieving the same purpose can be substituted for the specific embodiment(s) shown; that is, this disclosure is intended to cover any and all adaptations or variations of various embodiments. Combinations of the above embodiments, and other embodiments not specifically described herein, will become apparent to those of skill in the art given the teachings herein.
(25) The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting. As used herein, the singular forms a, an and the are intended to include the plural forms as well, unless the context clearly indicates otherwise. It will be further understood that the terms comprises and/or comprising, when used in this specification, specify the presence of stated features, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, steps, operations, elements, components, and/or groups thereof. Terms such as above and below are used to indicate relative positioning of elements or structures to each other as opposed to relative elevation.
(26) The corresponding structures, materials, acts, and equivalents of any means or step-plus-function elements in the claims below are intended to include any structure, material, or act for performing the function in combination with other claimed elements as specifically claimed. The description of the various embodiments has been presented for purposes of illustration and description, but is not intended to be exhaustive or limited to the forms disclosed. Many modifications and variations will be apparent to those of ordinary skill in the art without departing from the scope and spirit thereof. The embodiments were chosen and described in order to best explain principles and practical applications, and to enable others of ordinary skill in the art to understand the various embodiments with various modifications as are suited to the particular use contemplated.
(27) The abstract is provided to comply with 37 C.F.R. 1.72(b), which requires an abstract that will allow the reader to quickly ascertain the nature of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims. In addition, in the foregoing Detailed Description, it can be seen that various features are grouped together in a single embodiment for the purpose of streamlining the disclosure. This method of disclosure is not to be interpreted as reflecting an intention that the claimed embodiments require more features than are expressly recited in each claim. Rather, as the appended claims reflect, the claimed subject matter may lie in less than all features of a single embodiment. Thus the following claims are hereby incorporated into the Detailed Description, with each claim standing on its own as separately claimed subject matter.
(28) Given the teachings provided herein, one of ordinary skill in the art will be able to contemplate other implementations and applications of the techniques and disclosed embodiments. Although illustrative embodiments have been described herein with reference to the accompanying drawings, it is to be understood that illustrative embodiments are not limited to those precise embodiments, and that various other changes and modifications are made therein by one skilled in the art without departing from the scope of the appended claims.