STRESS MEMORIZATION AND DEFECT SUPPRESSION TECHNIQUES FOR NMOS TRANSISTOR DEVICES
20170278949 ยท 2017-09-28
Assignee
Inventors
Cpc classification
H10D30/797
ELECTRICITY
H10D62/021
ELECTRICITY
H10D30/796
ELECTRICITY
International classification
H01L29/66
ELECTRICITY
H01L21/324
ELECTRICITY
Abstract
Disclosed are methods for stress memorization techniques. In one illustrative embodiment, the present disclosure is directed to a method involving fabricating an NMOS transistor device having a substrate and a gate structure disposed over the substrate, the substrate including a channel region underlying, at least partially, the gate structure, the fabricating including: forming a source and drain cavity in the substrate; with an in situ doped semiconductor material, epitaxially growing a source and drain region within the source and drain cavity; performing an amorphization ion implantation process by implanting an amorphization ion material into the source and drain region; forming a capping material layer above the NMOS transistor device; with the capping material layer in position, performing a stress forming anneal process to thereby form stacking faults in the source and drain region; and removing the capping material layer.
Claims
1. A method comprising: fabricating an NMOS transistor device comprising a substrate and a gate structure disposed over the substrate, the substrate comprising a channel region underlying, at least partially, the gate structure, the fabricating comprising: forming a source and drain cavity in the substrate, wherein the source and drain cavity is separated by the channel region; epitaxially growing a source and drain region within the source and drain cavity; performing a source and drain ion implantation process by implanting a source and drain dopant material into the source and drain region and performing a carbon implantation process by implanting carbon into the source and drain region; wherein the source and drain ion implantation process and the carbon implantation process are performed sequentially or concurrently; performing a source and drain activation anneal process to activate the source and drain dopant material; performing an amorphization ion implantation process by implanting an amorphization ion material into the source and drain region; forming a capping material layer above the NMOS transistor device; with the capping material layer in position, performing a stress forming anneal process to thereby form stacking faults in the source and drain region; and removing the capping material layer.
2. The method of claim 1, wherein the source and drain region is a raised source and drain region.
3. The method of claim 1, wherein the source and drain dopant material is selected from the group consisting of germanium, carbon, arsenic, phosphorus, antimony, and mixtures thereof.
4. The method of claim 1, wherein the amorphization ion material is selected from the group consisting of germanium, carbon, silicon, arsenic, antimony, and mixtures thereof.
5. The method of claim 1, further comprising: subsequent to performing the source and drain activation anneal process and prior to performing the amorphization ion implantation process, performing a supplementary carbon implantation process by implanting carbon into the source and drain region.
6. The method of claim 1, further comprising: prior to forming the source and drain cavity in the substrate, performing an extension ion implantation process by implanting an extension dopant material into the substrate to thereby form a doped extension implant region in the substrate, the doped extension implant region separated by the channel region; and performing an extension dopant activation anneal process to activate the extension dopant material.
7. The method of claim 6, wherein the extension dopant material is selected from the group consisting of germanium, carbon, arsenic, phosphorus, antimony, and mixtures thereof.
8. A method comprising: fabricating an NMOS transistor device comprising a substrate and a gate structure disposed over the substrate, the substrate comprising a channel region underlying, at least partially, the gate structure, the fabricating comprising: performing a source and drain ion implantation process by implanting a source and drain dopant material into a source and drain region, wherein the source and drain region is separated by the channel region, and performing a carbon implantation process by implanting carbon into the source and drain region; wherein the source and drain ion implantation process and the carbon implantation process are performed sequentially or concurrently; performing a source and drain activation anneal process to activate the source and drain dopant material; performing an amorphization ion implantation process by implanting an amorphization ion material into the source and drain region; forming a capping material layer above the NMOS transistor device; with the capping material layer in position, performing a stress forming anneal process to thereby form stacking faults in the source and drain region; and removing the capping material layer.
9. The method of claim 8, wherein the source and drain dopant material is selected from the group consisting of germanium, carbon, arsenic, phosphorus, antimony, and mixtures thereof.
10. The method of claim 8, wherein the amorphization ion material is selected from the group consisting of germanium, carbon, silicon, arsenic, antimony, and mixtures thereof.
11. The method of claim 8, further comprising: subsequent to performing the source and drain activation anneal process and prior to performing the amorphization ion implantation process, performing a supplementary carbon implantation process by implanting carbon into the source and drain region.
12. The method of claim 8, further comprising: prior to performing the source and drain ion implantation process, performing an extension ion implantation process by implanting an extension dopant material into the substrate to thereby form a doped extension implant region in the substrate, the doped extension implant region separated by the channel region; and performing an extension dopant activation anneal process to activate the extension dopant material.
13. The method of claim 12, wherein the extension dopant material is selected from the group consisting of germanium, carbon, arsenic, phosphorus, antimony, and mixtures thereof.
14. A method comprising: fabricating an NMOS transistor device comprising a substrate and a gate structure disposed over the substrate, the substrate comprising a channel region underlying, at least partially, the gate structure, the fabricating comprising: forming a source and drain cavity in the substrate, wherein the source and drain cavity is separated by the channel region; with an in situ doped semiconductor material, epitaxially growing a source and drain region within the source and drain cavity; performing an amorphization ion implantation process by implanting an amorphization ion material into the source and drain region; forming a capping material layer above the NMOS transistor device; with the capping material layer in position, performing a stress forming anneal process to thereby form stacking faults in the source and drain region; and removing the capping material layer.
15. The method of claim 14, wherein the source and drain region is a raised source and drain region.
16. The method of claim 14, wherein the in situ doped semiconductor material is doped with carbon, phosphorus, and mixtures thereof.
17. The method of claim 14, wherein the amorphization ion material is selected from the group consisting of germanium, carbon, silicon, arsenic, antimony, and mixtures thereof.
18. The method of claim 14, wherein the amorphization ion material is silicon and/or germanium.
19. The method of claim 14, further comprising: prior to forming the source and drain cavity in the substrate, performing an extension ion implantation process by implanting an extension dopant material into the substrate to thereby form a doped extension implant region in the substrate, the doped extension implant region separated by the channel region; and performing an extension dopant activation anneal process to activate the extension dopant material.
20. The method of claim 19, wherein the extension dopant material is selected from the group consisting of germanium, carbon, arsenic, phosphorus, antimony, and mixtures thereof.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0053] The disclosure may be understood by reference to the following description taken in conjunction with the accompanying drawings, in which like reference numerals identify like elements, and in which:
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[0061] While the subject matter disclosed herein is susceptible to various modifications and alternative forms, specific embodiments thereof have been shown by way of example in the drawings and are herein described in detail. It should be understood, however, that the description herein of specific embodiments is not intended to limit the disclosure to the particular forms disclosed, but on the contrary, the intention is to cover all modifications, equivalents, and alternatives falling within the spirit and scope of the disclosure as defined by the appended claims.
DETAILED DESCRIPTION OF THE INVENTION
[0062] Certain terms are used throughout the disclosure to refer to particular components. However, different entities may refer to a component by different names. This document does not intend to distinguish between components that differ in name but not function. The terms including and comprising are used herein in open-ended fashion, and thus mean including, but not limited to.
[0063] The singular forms a, an, and the include plural referents unless the context clearly dictates otherwise.
[0064] Approximating language, as used herein throughout the specification and claims, may be applied to modify any quantitative representation that could permissibly vary without resulting in a change in the basic function to which it is related. Accordingly, a value modified by a term or terms, such as about, is not to be limited to the precise value specified. In some instances, the approximating language may correspond to the precision of an instrument for measuring the value.
[0065] The present subject matter will now be described with reference to the attached figures. Various structures, systems, and devices are schematically depicted in the drawings for purposes of explanation only. The attached drawings are included to describe and explain illustrative examples of the present disclosure. The words and phrases used herein should be understood and interpreted to have a meaning consistent with the understanding of those words and phrases by those in the industry. No special definition of a term or phrase, i.e., a definition that is different from the ordinary and customary meaning as understood by those in the industry, is intended to be implied by consistent usage of the term or phrase herein. To the extent that a term or phrase is intended to have a special meaning, such a special definition will be expressly set forth in the specification in a definitional manner that directly and unequivocally provides the special definition for the term or phrase.
[0066] The present disclosure is directed to various stress memorization techniques that may be employed when manufacturing transistor devices. As will be readily apparent, the present method is applicable to a variety of devices, including, but not limited to, logic devices, memory devices, etc., and the methods disclosed herein may be employed to form N-type or P-type semiconductor devices. Additionally, various doped regions, e.g., source/drain regions, halo implant regions, well regions and the like, are not depicted in the attached drawings. Of course, the inventions disclosed herein should not be considered to be limited to the illustrative examples depicted and described herein. The various components and structures of the devices disclosed herein may be formed using a variety of different materials and by performing a variety of known techniques, e.g., a chemical vapor deposition (CVD) process, an atomic layer deposition (ALD) process, a thermal growth process, spin-coating techniques, etc. The thicknesses of these various layers of material may also vary depending upon the particular application. With reference to the attached figures, various illustrative embodiments of the methods and devices disclosed herein will now be described in more detail.
[0067]
[0068] At the point of fabrication depicted in
[0069] With continuing reference to
[0070] Thus, with reference to
[0071] Various stress memorization methods are described below with reference to
[0072] With reference to
[0073] forming a source and drain cavity 210 in the substrate 201, wherein the source and drain cavity 210 is separated by the channel region 230, as shown in
[0074] epitaxially growing a source and drain region 211 within the source and drain cavity 210, as shown in
[0075] performing a source and drain ion implantation process 212 by implanting a source and drain dopant material into the source and drain region 211, as shown in
[0076] performing an amorphization ion implantation process 214 by implanting an amorphization ion material into the source and drain region 211, as shown in
[0077] forming a capping material layer 216 above the NMOS transistor device 200, as shown in
[0078] with the capping material layer 216 in position, performing a multipurpose anneal process 217 to thereby activate the source and drain dopant material and to form stacking faults 218 in the source and drain region 211, as shown in
[0079] removing the capping material layer 216, with the resulting NMOS transistor device depicted in
[0080] In one embodiment, the source and drain region 211 is a raised source and drain region.
[0081] In the above described method, prior to forming the source and drain cavity 210, the method may further include performing an extension ion implantation process 207 as described above with reference to
[0082] In another embodiment, with reference to
[0083] performing a source and drain ion implantation process 212 by implanting a source and drain dopant material into a source and drain region 211, wherein the source and drain region 211 is separated by the channel region 230, as shown in
[0084] performing an amorphization ion implantation process 214 by implanting an amorphization ion material into the source and drain region 211, as shown in
[0085] forming a capping material layer 216 above the NMOS transistor device 200, as shown in
[0086] with the capping material layer 216 in position, performing a multipurpose anneal process 217 to thereby activate the source and drain dopant material and to form stacking faults 218 in the source and drain region 211, as shown in
[0087] removing the capping material layer 216, with the resulting NMOS transistor device depicted in
[0088] In one embodiment, the source and drain dopant material may be selected from the group which includes germanium, carbon, arsenic, phosphorus, antimony and mixtures thereof. In one embodiment, the amorphization ion material may be selected from the group which includes germanium, carbon, silicon, arsenic, antimony, and mixtures thereof.
[0089] In the above described method, prior to performing the source and drain ion implantation process 212, the method may further include performing an extension ion implantation process 207 as described above with reference to
[0090] In another embodiment, with reference to
[0091] forming a source and drain cavity 210 in the substrate 201, wherein the source and drain cavity 210 is separated by the channel region 230, as shown in
[0092] epitaxially growing a source and drain region 211 within the source and drain cavity 210, as shown in
[0093] performing a source and drain ion implantation process 212 by implanting a source and drain dopant material into the source and drain region 211, as shown in
[0094] performing a source and drain activation anneal process 219 to activate the source and drain dopant material, as shown in
[0095] performing an amorphization ion implantation process 214 by implanting an amorphization ion material into the source and drain region 211, as shown in
[0096] forming a capping material layer 216 above the NMOS transistor device 200, as shown in
[0097] with the capping material layer 216 in position, performing a stress forming anneal process 220 to thereby form stacking faults 218 in the source and drain region 211, as shown in
[0098] removing the capping material layer 216, with the resulting NMOS transistor device depicted in
[0099] In one embodiment, the source and drain region is a raised source and drain region. In one embodiment, the source and drain dopant material may be selected from the group which includes germanium, carbon, arsenic, phosphorus, antimony, and mixtures thereof. In one embodiment, the amorphization ion material is selected from the group which includes germanium, carbon, silicon, arsenic, antimony, and mixtures thereof.
[0100] In one embodiment, subsequent to performing the source and drain activation anneal process 219 and prior to performing the amorphization ion implantation process 214, performing a supplementary carbon implantation process by implanting carbon into the source and drain region 211.
[0101] In the above described method, prior to forming the source and drain cavity 210, the method may further include performing an extension ion implantation process 207 as described above with reference to
[0102] In another embodiment, with reference to
[0103] performing a source and drain ion implantation process 212 by implanting a source and drain dopant material into a source and drain region 210, wherein the source and drain region is separated by the channel region 230, as shown in
[0104] performing a source and drain activation anneal process 219 to activate the source and drain dopant material, as shown in
[0105] performing an amorphization ion implantation process 214 by implanting an amorphization ion material into the source and drain region 211, as shown in
[0106] forming a capping material layer 216 above the NMOS transistor device 200, as shown in
[0107] with the capping material layer 216 in position, performing a stress forming anneal process 220 to thereby form stacking faults 218 in the source and drain region 211, as shown in
[0108] removing the capping material layer 216, with the resulting NMOS transistor device depicted in
[0109] In one embodiment, the source and drain dopant material may be selected from the group which includes germanium, carbon, arsenic, phosphorus, antimony, and mixtures thereof. In one embodiment, the amorphization ion material may be selected from the group which includes germanium, carbon, silicon, arsenic, antimony, and mixtures thereof.
[0110] In one embodiment, the method of further includes: subsequent to performing the source and drain activation anneal process 219 and prior to performing the amorphization ion implantation process 214, performing a supplementary carbon implantation process by implanting carbon into the source and drain region 211.
[0111] In the above described method, prior to performing the source and drain ion implantation process 212, the method may further include performing an extension ion implantation process 207 as described above with reference to
[0112] In another embodiment, with reference to
[0113] forming a source and drain cavity 210 in the substrate 201, wherein the source and drain cavity 210 is separated by the channel region 230, as shown in
[0114] with an in situ doped semiconductor material, epitaxially growing a source and drain region 211 within the source and drain cavity 210, as shown in
[0115] performing an amorphization ion implantation process 214 by implanting an amorphization ion material into the source and drain region 211, as shown in
[0116] forming a capping material layer 216 above the NMOS transistor device 200, as shown in
[0117] with the capping material layer 216 in position, performing a stress forming anneal process 220 to thereby form stacking faults 218 in the source and drain region 211, as shown in
[0118] removing the capping material layer 216, with the resulting NMOS transistor device depicted in
[0119] In one embodiment, the source and drain region is a raised source and drain region. In one embodiment, the in situ doped semiconductor material is doped with carbon, phosphorus, and mixtures thereof. In one embodiment, the amorphization ion material is selected from the group which includes germanium, carbon, silicon, arsenic, antimony, and mixtures thereof. In another embodiment, the amorphization ion material is silicon and/or germanium.
[0120] In the above described method, prior to forming the source and drain cavity 210, the method may further include performing an extension ion implantation process 207 as described above with reference to
[0121] In yet another embodiment, with reference to
[0122] forming a source and drain cavity 210 in the substrate 201, wherein the source and drain cavity 210 is separated by the channel region 230, as shown in
[0123] with an in situ doped semiconductor material, epitaxially growing a source and drain region 211 within the source and drain cavity 210, as shown in
[0124] performing an amorphization ion implantation process 214 by implanting an amorphization ion material into the source and drain region 211, as shown in
[0125] forming a capping material layer 216 above the NMOS transistor device 200, as shown in
[0126] with the capping material layer 216 in position, performing a stress forming anneal process 220 to thereby form stacking faults 218 in the source and drain region 211, as shown in
[0127] removing the capping material layer 216, with the resulting NMOS transistor device depicted in
[0128] In one embodiment, the source and drain region is a raised source and drain region. In one embodiment, the in situ doped semiconductor material is doped with carbon, phosphorus, and mixtures thereof. In the above described method, prior to forming the source and drain cavity 210, the method may further include performing an extension ion implantation process 207 as described above with reference to
[0129] With respect to the methods described herein, the implant energy and implant dose of the extension ion implantation process 207 may vary depending upon the application and the selected process flow. For example, the extension ion implantation process 207 may be performed using an implant energy that falls within the range of about 1 keV to about 90 keV and a dose of the extension dopant material may fall within the range of about 1.0E13 ions/cm.sup.2 to about 5.0E15 ions/cm.sup.2. The extension dopant material may be selected from the group that includes germanium, carbon, arsenic, phosphorus, antimony and mixtures thereof.
[0130] With respect to the methods described herein, the implant energy and implant dose of the source and drain ion implantation process 212 may vary depending upon the application and the selected process flow. For example, the source and drain ion implantation process 212 may be performed using an implant energy that falls within the range of about 0.1 keV to about 50 keV and a dose of the source and drain dopant material may fall within the range of about 1.0E13 ions/cm.sup.2 to about 9.9E15 ions/cm.sup.2. The source and drain dopant material may be selected from the group that includes germanium, carbon, arsenic, phosphorus, antimony and mixtures thereof.
[0131] With respect to the methods described herein, the implant energy and implant dose of the carbon implantation process 213 may vary depending upon the application and the selected process flow. For example, the carbon implantation process 213 may be performed using an implant energy that falls within the range of about 1 keV to about 50 keV and a dose of the carbon may fall within the range of about 1.0E13 ions/cm.sup.2 to about 5.0E15 ions/cm.sup.2.
[0132] With respect to the methods described herein, the implant energy and implant dose of the supplementary carbon implantation process may vary depending upon the application and the selected process flow. For example, the supplementary carbon implantation process may be performed using an implant energy that falls within the range of about 1 keV to about 50 keV and a dose of the carbon may fall within the range of about 1.0E13 ions/cm.sup.2 to about 5.0E15 ions/cm.sup.2.
[0133] With respect to the methods described herein, the implant energy and implant dose of the amorphization ion implantation process 214 may vary depending upon the application and the selected process flow. For example, the amorphization ion implantation process 214 may be performed using an implant energy that falls within the range of about 10 keV to about 90 keV and a dose of the amorphization ion material may fall within the range of about 1.0E14 ions/cm.sup.2 to about 9.9E15 ions/cm.sup.2. In one embodiment, the amorphization ion material is selected from the group consisting of germanium, carbon, silicon, arsenic, antimony, and mixtures thereof.
[0134] With respect to the methods described herein, the extension dopant activation anneal process may be performed in an inert ambient (e.g., N.sub.2) at a temperature that falls within the range of from about 600 C. to about 800 C. The duration of such extension dopant activation anneal process may be about 10 minutes. In another embodiment, the extension dopant activation anneal process may be a rapid thermal spike anneal process performed in an inert ambient at a temperature that falls within the range of from about 950 C. to about 1050 C. The extension dopant activation anneal process activates the implanted extension dopant materials.
[0135] With respect to the methods described herein, the multipurpose anneal process 217 may be performed in an inert ambient (e.g., N.sub.2) at a temperature that falls within the range of from about 600 C. to about 800 C. The duration of such multipurpose anneal process 217 may be about 10 minutes. In another embodiment, the multipurpose anneal process 217 may be a rapid thermal spike anneal process performed in an inert ambient at a temperature that falls within the range of from about 950 C. to about 1050 C. The multipurpose anneal process simultaneously activates the implanted source and drain dopant materials and forms staking faults 218.
[0136] With respect to the methods described herein, the source and drain activation anneal process 219 may be performed in an inert ambient (e.g., N.sub.2) at a temperature that falls within the range of from about 600 C. to about 800 C. The duration of such source and drain activation anneal process 219 may be about 10 minutes. In another embodiment, the source and drain activation anneal process 219 may be a rapid thermal spike anneal process performed in an inert ambient at a temperature that falls within the range of from about 950 C. to about 1050 C. The source and drain activation anneal process activates the implanted source and drain dopant materials.
[0137] With respect to the methods described herein, the stress forming anneal process 220 may be performed in an inert ambient (e.g., N.sub.2) at a temperature that falls within the range of from about 600 C. to about 800 C. The duration of such stress forming anneal process 220 may be about 10 minutes. In another embodiment, the stress forming anneal process 220 may be a rapid thermal spike anneal process performed in an inert ambient at a temperature that falls within the range of from about 950 C. to about 1050 C. The stress forming anneal process forms staking faults 218.
[0138] In any of the described embodiments, the gate structure 203 may include a high-k gate insulation layer and a gate electrode, wherein the gate electrode includes at least one layer of metal. In another embodiment, the gate structure may include a silicon dioxide gate insulation layer and a gate electrode, wherein the gate electrode includes a layer of polysilicon.
[0139] When forming a capping material layer 216 above the NMOS transistor device 200 in any of the described embodiments, a thin (about 2-4 nm) liner layer 215 may be conformably deposited on the device 200 by performing a CVD or an ALD process. The liner layer 215 may be composed of silicon dioxide. Thereafter, the capping material layer 216 may be formed above the transistor 200. The capping material layer 216 may include a material such as silicon nitride and it may have a thickness of about 20-80 nm. The capping material layer 216 may be formed with or without any intrinsic stress.
[0140] Accordingly, in any of the described embodiments, the capping material layer 216 may include silicon nitride. In another embodiment, the capping material layer 216 may include a layer of silicon nitride deposited over a layer of silicon oxide.
[0141] With respect to all of the described embodiments, after removal of the capping material layer, additional processing operations may be performed to incorporate the device into an integrated circuit, e.g., the formation of source/drain contacts, the formation of a gate contact, and the formation of various metallization layers above the device 200.
[0142] The particular embodiments disclosed above are illustrative only, as the invention may be modified and practiced in different but equivalent manners apparent to those skilled in the art having the benefit of teachings herein. For example, the process steps set forth above may be performed in a different order. Furthermore, no limitations are intended to the details of construction or design herein shown, other than as described in the claims below. It is therefore evident that the particular embodiments disclosed above may be altered or modified and all such variations are considered within the scope and spirit of the invention. Accordingly, the protection sought herein as set forth in the claims below.