Graphene-based valley filter and method for operating the same
09741796 ยท 2017-08-22
Assignee
Inventors
Cpc classification
H10D30/6734
ELECTRICITY
H10D30/6757
ELECTRICITY
H10D30/6741
ELECTRICITY
International classification
H01L29/16
ELECTRICITY
H01L29/786
ELECTRICITY
Abstract
A graphene-based valley filter includes a bottom gate, a bilayer graphene and two top gates. The bilayer graphene is deposited on the bottom gate and includes scattering defects. The top gates are deposited on the bilayer graphene. The top gates define a channel in the bilayer graphene, and the scattering defects are located in the vicinity of the channel. A vertical electric field is formed to open a band gap and produce electronic energy subbands in the channel. A transverse in-plane electric field is formed to produce pseudospin splitting in the subbands of the bilayer graphene. The scattering defects are for producing scattering between two opposite energy valley states of the bilayer graphene, couples subband states of opposite pseudospins and opens a pseudogap at a crossing point of the two subbands. Electrons are passed through the channel to become valley polarized in the bilayer graphene.
Claims
1. A graphene-based valley filter, comprising: a bottom gate; a bilayer graphene deposited on the bottom gate, wherein the bilayer graphene comprises scattering defects; and two top gates deposited on the bilayer graphene, wherein the two top gates define a channel in the bilayer graphene, and the scattering defects are located in the vicinity of the channel; wherein a vertical electric field is applied between the bottom gate and the top gates to open a band gap as well as produce electronic energy subbands in the bilayer graphene channel, a transverse in-plane electric field is applied between the top gates to produce pseudospin splitting in the subbands of the bilayer graphene channel, the scattering defects are configured to produce a scattering between two energy valley states with opposite pseudospins in the bilayer graphene, couple subband states of opposite pseudospins and opens a pseudogap at a crossing point of the two subbands, and when a small bias is applied, electrons are driven to pass through the channel to become valley polarized in the bilayer graphene.
2. The device of claim 1, wherein the channel is in the form of a quantum wire or a nanoribbon.
3. The device of claim 1, wherein the scattering defects are formed by rough edges of the bilayer graphene in the vicinity of the channel.
4. The device of claim 1, wherein the scattering defects are formed by performing ion implantation to the bilayer graphene in the vicinity of the channel.
5. The device of claim 1, wherein the scattering defects are formed from graphene oxide in the vicinity of the channel.
6. The device of claim 1, wherein the bilayer graphene comprise a first layer and a second layer, the first layer is stacked on the second layer with a normal stacking distance, and the second layer is rotated with respect to the first layer by a specified angle.
7. The device of claim 1, further comprising an insulation layer deposited between the top gates and the bilayer graphene and between the bilayer graphene and the bottom gate.
8. The device of claim 1, wherein the vertical electric field is formed by applying a DC bias across the bottom gate and the top gates.
9. A graphene-based valley filter, comprising: a bottom gate; a boron nitride layer deposited on the bottom gate; a monolayer graphene formed on the boron nitride layer, wherein the graphene layer comprises scattering defects; and two top gates formed on the graphene layer, wherein the two top gates define a channel in the graphene layer/boron nitride layer structure, and the scattering defects are located in the vicinity of the channel; wherein a vertical electric field is applied between the bottom gate and the top gates to produce electronic energy subbands in the graphene layer, a transverse in-plane electric field is applied between the top gates to produce pseudospin splitting in the energy subbands of the graphene layer, the scattering defects are configured to produce a scattering between two energy valley states with opposite pseudospins in the graphene layer, couple subband states of opposite pseudospins and opens a pseudogap at a crossing point of the two subbands, and when a small bias is applied, electrons are driven to pass through the channel to become valley polarized in the graphene layer.
10. The device of claim 9, wherein the boron nitride layer is hexagonal.
11. The device of claim 9, wherein the graphene layer is stacked on the boron nitride layer with a normal stacking distance, and the graphene layer is rotated with respect to the boron nitride layer by a specified angle.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The present disclosure can be more fully understood by reading the following detailed description of the embodiment, with reference made to the accompanying drawings as follows:
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DETAILED DESCRIPTION
(15) Reference will now be made in detail to the present embodiments of the disclosure, examples of which are illustrated in the accompanying drawings. Wherever possible, the same reference numbers are used in the drawings and the description to refer to the same or like parts.
(16) The present disclosure provides a graphene-based valley filter in which a valley filtering is accomplished by the combination of: opening bandgap in a bilayer graphene with a vertical electrical field; shifting valley-dependent subbands with a transverse in-plane electric field; and lifting degeneracy by boundary scattering. The graphene-based valley filter of the present disclosure can function as a building block for valleytronics, and can be capable of converting signals between electrical and valleytronic forms, thereby leading to integration of electronic and valleytronic components.
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(18) The graphene-based valley filter 100 includes a bottom gate 101, a bilayer graphene 102 and two top gates 103. The bilayer graphene 102 is deposited on the bottom gate 101, and the bilayer graphene 102 includes a plurality of scattering defects 105 formed thereon. In more details, the two top gates 103 define a channel in the bilayer graphene 102, and the scattering defects 105 are formed in the vicinity of the channel. The scattering defects 105 can be formed by various methods. For example, the scattering defects 105 can be formed by rough edges of the bilayer graphene 102 in the vicinity of the channel or by performing on implantation to the bilayer graphene 102 in the vicinity of the channel. The scattering defects 105 can also be formed from graphene oxide in the vicinity of the channel.
(19) The channel is in the form of a quantum wire or a nanoribbon. In more detail, the quantum wire or the nanoribbon is formed by arranging graphene unit cell along a straight line direction. Furthermore, the scattering defects 105 are formed along the edges of the channel.
(20) The bilayer graphene 102 includes a first layer 102a and a second layer 102b. The first layer 102a is stacked on the second layer 102b with a normal stacking distance, and the second layer 102b is rotated with respect to the first layer 102a by a specified angle. This kind of stacking structure is the so-called A-B Bernal stacking. In one embodiment, the bilayer graphene 102 can be replaced by depositing monolayer graphene on a boron nitride layer. For example, the monolayer graphene can be deposited on the hexagonal boron nitride layer in the same form of A-B Bernal stacking to form a graphene layer/boron nitride layer structure similar as the bilayer graphene 102.
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(22) In
(23) In
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(25) K scattering between the two energy valley states K and K, couple subband states of opposite pseudospins and open a pseudogap at the crossing point of the two subbands. When a small bias is applied along the x-direction, an electron can be driven to transport in the channel. And for the passing electron to become valley polarized, its corresponding electronic energy level must be inside the pseudogap, which intersects the subbands at two points, corresponding to left- and right-moving electron states, respectively. Since these two states carry primarily opposite pseudospins, valley polarization can be generated by placing the Fermi level E in the pseudogap. The polarity of valley polarization can be switched by reversing either the moving direction of the electron, or the direction of the transverse in-plane electric field .
(26) According to one embodiment, a method for operating the graphene-based valley filter is provided. The method includes: a vertical electric field is applied across a bilayer graphene to open bandgaps in the bilayer graphene, wherein the bandgaps define the channel of electron transport in the bilayer graphene and lead to the formation of electronic energy subbands in the channel; a transverse in-plane electric field is applied across the bilayer graphene to produce pseudospin splitting in the subbands of the bilayer graphene; two energy valley states K and K of the bilayer graphene are scattered into each other by scattering defects formed on the bilayer graphene, and subband states of opposite pseudospins are coupled thereby opening a pseudogap at the crossing point of the two subbands; electrons are passed through a channel in the bilayer graphene to generate valley polarizations; and the valley polarizations are switched by reversing the transverse in-plane electric field.
(27) In the following section, the detailed operating mechanisms of the valley filter in the present disclosure are explained by utilizing theoretical calculations.
Valley-Orbit Interaction (VOI)
(28) The novel mechanism exploited is the so-called valley-orbit interaction (VOI) that couples the valley pseudospin to an in-plane electric field. The VOI exists in gapped graphene and is similar to the Rashba spin-orbit interaction (SOI), but with a significant difference. The VOI in monolayer graphene is given by:
(29)
which is valley conserving (= being the valley index for K/K, 2 energy gap, m=electron effective mass, V=potential energy, p=momentum operator, z=unit vector normal to the graphene plane).
(30) Therefore, the VOI does not induce the flip-type scattering. A similar effect but with a more complex expression also exists in bilayer graphene.
The Electron Transport Through the Channel of the Graphene-Based Valley Filter
(31) The mechanism of the electron transported through the channel of the graphene-based valley filter in the present disclosure can be explained as follows. To a lowest-order approximation, the channel length is assumed to be infinite, the electronic energy subband structure in the channel is calculated while taking into account scattering defects, and the electron transport in the channel based on the subband structure is discussed. A linearized, four-component continuum theory is used for the subband structure calculation. A tight-binding calculation is also carried out to confirm that the continuum theory is a good approximation for the energy range of interest in the present disclosure. The Hamiltonian can be represented by:
H.sub.+.sub.+=E.sub.+
.sub.({right arrow over (r)})=().sub.A1.sup.()({right arrow over (r)}).sub.B1.sup.()({right arrow over (r)}).sub.A2.sup.()({right arrow over (r)}).sub.B2.sup.()({right arrow over (r)})).sup.1,(1)
where H.sub.+ is the Hamiltonian, and .sub. is the envelope wave function. Here, the subscript or superscript + () denotes the K (K) valley, with the corresponding wave vector given by
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for the K (K) point, and a.sub.0=1.42 is the inter-carbon distance.
(33) The four components in .sub. refer to the wave amplitudes on the four atoms (A1, B1, A2, and B2) in a bilayer graphene unit cell. The Hamiltonian H.sub. for bilayer graphene can be represented by:
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Here 0, 1, and 3 are the tight-binding parameters representing various hopping energies, 2 is the chemical potential difference between the layers due to the gate biases applied, and V is the potential energy due to the transverse in-plane electric field. V and in the Hamiltonian are determined by the various gate biases and are both modeled with piecewise constant functions described below.
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(36) The difference between V.sub.1 and V.sub.3 gives an in-plane electric field transverse to the wire, which is modeled with a step potential in Regions II-1 and II-2 given above. The boundaries y=W.sub.1+W.sub.2/2 and y=W.sub.2/2W.sub.3 (defect lines are taken to be the edges of graphene oxide. It is known that the oxidation in graphene consumes electrons and, therefore, given that the conduction and valence bands in graphene are derived from -electron states, the presence of oxide edges here leads to a hard-wall boundary condition for the electron wave function at y=W.sub.1+W.sub.2/2 and y=W.sub.2/2W.sub.3.
(37) Now solving Eqn. (1) for a given k.sub.x, the wave vector along the channel. Due to time reversal symmetry, the solutions to Eqn. (1) for the two valley pseudospins are doubly degenerate. Therefore, the total wave function is generally of the form
({right arrow over (r)})=[e.sup.i
(38) A mixed state of the two degenerate solutions. In view of V and both being piecewise constant, we proceed as follows.
(39) First, solving for ({right arrow over (r)}) in each region of constant potential (labeled by N, N=I, II-1, II-2, and III), as described below. Then calculating, in each region, the bulk complex band structure E(k.sub..sup.(N); k.sub.x), where k.sub..sup.(N) (with being valley indices) is the y-component of bulk wave vector in the region. In general, k.sub..sup.(N) is a complex number. For a given E and a given k.sub.x, there are four bulk solutions for each valley, with k.sub..sup.(N)'s and the corresponding wave functions being, respectively, k.sub.j.sup.(N) and
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for j=1-4, .sub.j.sup.(N) denotes a four-component column vector. Next, a general bulk solution in each region can be represented by:
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(42) Matching the bulk solutions between different regions, and enforcing the hard-wall boundary conditions: .sup.(I)(
Valley Polarization While Electrons Pass Through the Channel
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(44) The valley filter configuration specified by W.sub.1=W.sub.3=120 , W.sub.2=100 , .sub.1=.sub.3=100 meV, .sub.2=20 meV, and V.sub.1V.sub.3=70 meV are considered. In
(45) Next, based on the calculation of the subband structure, in
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where .sub.({right arrow over (r)}) are the two pseudospin components in Eqn. (3).
(47) Before presenting further numerical results of valley polarization, two useful symmetry-based properties of the polarization are considered. Specifically, the temperature valley filter defined by W.sub.1=W.sub.3, (y)=(y) and V(y)=V(y). Here, V and do not have to be piecewise constant.
Effect of Reversing the In-Plane Electric Field
(48) Considering an electron state in the symmetric structure, with the wave function for a specific k.sub.x being:
({right arrow over (r)})=[e.sup.i
.sub.+({right arrow over (r)})=e.sup.ik,x(A.sub.1(y)B.sub.1(y)A.sub.2(y)B.sub.2(y,
.sub.({right arrow over (r)})=e.sup.ik,x(A.sub.1(y)B.sub.1(y)A.sub.1(y)B.sub.2(y.(6)
where .sub.({right arrow over (r)}) satisfies the equation H.sub..sub.({right arrow over (r)})=E.sub.({right arrow over (r)}) and ({right arrow over (r)}) satisfies the boundary conditions:
(x,y=W.sub.1+W.sub.2/2)=0,
(x,y=W.sub.3W.sub.2/2)=0.
(49) The effect of reversing the in-plane electric field can be investigated by considering a potential U(y) with U(y)=V(y). It can be verified that, with the reversal, a solution denoted by ({right arrow over (r)}) and degenerate with ({right arrow over (r)}) (meaning that both have the same wave vector and the same energy) exists and can be represented by:
({right arrow over (r)})=[e.sup.i
.sub.+(x,y)=.sub.(x,),
.sub.(x,y)=.sub.+(x,).(7)
(50) Note that the switch of K and K amplitudes in ({right arrow over (r)}), when compared to those in ({right arrow over (r)}). In other words, if the original electron state is primarily K-polarized (i.e., |.sub.+({right arrow over (r)})|>>|.sub.({right arrow over (r)})|) with valley polarization P, then reversing the field will lead to K-polarization with the polarization given by P. This permits us to electrically switch the device between K and K valley polarization.
Effect of Reversing
(51) It can easily verify that in association with the solution ({right arrow over (r)}) in Eqn. (6), there is always a solution:
({right arrow over (r)})=[e.sup.i
.sub.+({right arrow over (r)})=.sub.({right arrow over (r)})*=e.sup.ik,x(A.sub.1(y)*B.sub.1(y)*A.sub.2(y)*B.sub.2(y)*,
.sub.({right arrow over (r)})=.sub.+({right arrow over (r)})*=e.sup.ik,x(A.sub.1(y)*B.sub.1(y)*A.sub.2(y)*B.sub.2(y).(8)
(52) Which is degenerate with ({right arrow over (r)}) in energy but with the wave vector being reversed, e.g., k.sub.x.fwdarw.k.sub.x. As expressed in Eqn. (8), the roles of the valleys are also switched here in comparison to those in ({right arrow over (r)}). Therefore, if the state with k.sub.x carries polarization P, then the state with k.sub.x carries the reversed polarization P.
(53) The structure parameters can be further modified to increase the operational energy range of the valley filter. For the valley filter configuration in
(54)
(55) In conclusion, the present disclosure provides a graphene-based valley filter which is constructed by patterning a quantum, wire on bilayer graphene. The graphene-based valley filter has the following features: (a) all electrical gate control; (b) electrically switchable valley polarity, (c) robustness against configuration fluctuation, and (d) potential for room temperature operation. Moreover, a semiconductor device combining two valley filters demonstrates a capability of integrating electronic and valleytronic signal. This result shows great potential on producing a switching device which can be applied in valley-based information processing.
(56) Although the present disclosure has been described in considerable detail with reference to certain embodiments thereof, other embodiments are possible. Therefore, the spirit and scope of the appended claims should not be limited to the description of the embodiments contained herein.
(57) It will be apparent to those skilled in the an that various modifications and variations can be made to the structure of the present disclosure without departing from the scope or spirit of the disclosure. In view of the foregoing, it is intended that the present disclosure covers modifications and variations of this disclosure provided they fall within the scope of the following claims.