Decorative member

Abstract

To provide a decorative member that has a small transmission loss of a millimeter wave and excellent metallic luster. The decorative member includes a base material made of a synthetic resin and a film body that made of an agglomeration of inorganic fine particles having at least a metal surface. An attenuation rate when a millimeter wave having a frequency of 18 to 300 GHz transmits is 0.001 to 2 dB, and an L* value (brightness) is 45 to 95.

Claims

1. A decorative member comprising: a base material made of a synthetic resin; and a film body that is positioned on the base material, wherein the film body contains only an agglomeration of only inorganic fine particles having at least a metal surface, and does not contain any synthetic resin, and wherein an attenuation rate when a millimeter wave having a frequency in a range of 18 GHz to 300 GHz transmits is in a range of 0.001 dB to 2 dB, and an L* value (brightness) is in a range of 45 to 95.

2. The decorative member according to claim 1, wherein the attenuation rate is an attenuation rate when a millimeter wave having a frequency in a range of 18 GHz to 100 GHz transmits.

3. The decorative member according to claim 1, wherein the L* value (brightness) is in a range of 50 to 95.

4. The decorative member according to claim 1, wherein the L* value (brightness) is in a range of 60 to 95.

5. The decorative member according to claim 1, wherein the inorganic fine particle has a surface including a gold coating layer or a silver coating layer.

6. The decorative member according to claim 1, wherein the inorganic fine particle is a gold fine particle or a silver fine particle.

7. The decorative member according to claim 1, wherein the inorganic fine particles have an average particle diameter in a range of 1 nm to 100 nm.

8. The decorative member according to claim 7, wherein the inorganic fine particles have an average particle diameter in a range of 10 nm to 70 nm.

9. The decorative member according to claim 1, wherein the film body has a thickness in a range of 10 nm to 300 nm.

10. The decorative member according to claim 1, further comprising a protective coating layer positioned on the film body.

11. The decorative member according to claim 1, further comprising a base layer positioned between the base material and the film body.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 is an explanatory cross-sectional view illustrating a configuration of a decorative member of the present invention.

DESCRIPTION OF PREFERRED EMBODIMENTS

(2) Subsequently, an embodiment of the present invention will be further described in detail with reference to the attached drawing.

(3) A decorative member 1 of this embodiment is employed, for example, for an emblem or the like disposed on a path of the millimeter wave to be transmitted and received by, for example, a radio wave transmitting and receiving device, such as a millimeter-wave radar mounted to a vehicle or the like. The decorative member 1 includes, or example, a base material 2 made of a synthetic resin, an undercoat 3 positioned on the base material 2 as a base layer, a film body 4 that is positioned on the undercoat 3 and includes an agglomeration of inorganic fine particles having at least a metal surface, and a guard coat 5 positioned on the film body 4 as a protective coating layer.

(4) The synthetic resin constituting the base material 2 can be listed, for example: a polycarbonate resin, an acrylic resin, an epoxy resin, a polystyrene resin, a polyethylene terephthalate resin, a polyurethane resin, a polyethylene resin, a polypropylene resin, and an ABS resin.

(5) The undercoat 3 may be anything, as long as an adhesiveness of the film body 4 to the base material 2 can be improved. For example, the undercoat 3 can include a coating material where a synthetic resin, such as a two-component urethane coating material, an epoxy coating material, a UV curable coating material, and an air-dry coating material, is used as the main agent. An example of the coating material can include a mixture at a mass ratio of 100:25:120 of a main agent (product name: EC-MM82-1003X), which is manufactured by Musashi Paint Co., Ltd., a curing agent (product name: Z-EC-H-400), and a thinner (product name: Z-EC-K785).

(6) The film body 4 includes the agglomeration of the inorganic fine particles having at least the metal surface. An example of the inorganic fine particle can include one that includes a gold coating layer or a silver coating layer on surfaces of non-metallic fine particles, such as alumina, or one itself that is made of a metal of gold fine particles, silver fine particles, or the like. Further, the inorganic fine particles can employ ones that have an average particle diameter in a range of 1 to 100 nm, preferably in a range of 10 to 50 nm.

(7) The film body 4 can be formed by applying an inorganic fine particle dispersion liquid produced by dispersing the inorganic fine particles into a volatile solvent over the undercoat 3 and vaporizing the volatile solvent. The inorganic fine particle dispersion liquid may be diluted using the volatile solvent as a diluent (thinner).

(8) The volatile solvent can be listed, for example: isopropanol, methanol, ethanol, toluene, xylene, ethyl acetate, butyl acetate, methyl ethyl ketone, and cyclohexanenone, any one of the volatile solvents may be employed alone, and two or more of them may be mixed to be employed. The volatile sol vent, in which the inorganic fine particles are dispersed, and the volatile solvent, which is employed as the diluent, may be the same, and may be different.

(9) An example of the inorganic fine particle dispersion liquid can include one that contains a propylene glycol monomethyl ether as a dispersion medium and 5 mass % of the silver fine particles having the average particle diameter of 20 nm.

(10) The film body 4 is formed as described above and thus can have a thickness in, for example, a range of 10 to 300 nm.

(11) The guard coat 5 may be anything, as long as individual inorganic fine particles can be avoided from separating to fall from the film body 4. For example, the guard coat 5 can include a coating material where a synthetic resin, such as a two-component urethane coating material, an epoxy coating material, a UV curable coating material, and an air-dry coating material, is used as the main agent. An example of the coating material can include a mixture at a mass ratio of 100:15:80 of a main agent (product name: EC-MT62-1003X), which is manufactured by Musashi Paint Co., Ltd., a curing agent (product name: Z-EC-H-760), and the thinner (product name: Z-EC-K785).

(12) In the decorative member 1 of this embodiment, which has the above-described configuration, an attenuation rate as an index of a transmission loss when a millimeter wave having a frequency in a range of 18 to 300 GHz transmits is in a range of 0.001 to 2 dB, and an L* value (brightness) as an index of metallic luster is in a range of 50 to 95, preferably in a range of 60 to 95.

(13) Note that, the decorative member 1 of this embodiment is configured to include the undercoat 3 positioned between the base material 2 and the film body 4 as the base layer, and the guard coat 5 positioned on the film body 4 as the protective coating layer. However, the decorative member 1 of this embodiment may be configured not to include any one of the undercoat 3 and the guard coat 5, or both of them in some cases.

(14) Next, examples of the present invention are described.

EXAMPLES

Example 1

(15) In this example, first, a coating material where the main agent (product name: EC-MM82-1003X), which is manufactured by Musashi Paint Co., Ltd., the curing agent (product name: Z-EC-H-400), and the thinner (product name: Z-EC-K785) were mixed at a mass ratio of 100:25:120 was applied over the base material 2 (length of 150 mm, width of 70 mm, thickness of 3 mm) made of a polycarbonate resin, and then was baked at 100° C. for 30 minutes to form the undercoat 3 having the thickness of 20 μm.

(16) Next, a silver fine particle dispersion liquid was applied over the undercoat 3, and then was baked at 110° for 30 minutes to form the film body 4 made of the agglomeration of the silver fine particles and have the thickness of 20 nm. The silver fine particle dispersion liquid contains a propylene glycol monomethyl ether as the dispersion medium and 5 mass % of the silver fine particles having the average particle diameter of 20 nm. Note that, the thickness of the film body 4 was measured with a transmission electron microscope.

(17) Next, a coating material where the main agent (product name: EC-MT62-1003X), which is manufactured by Musashi Paint Co., Ltd., re curing agent (product name: Z-EC-H-760), and the thinner (product name: Z-EC-K785) were mixed at amass ratio of 100:15:80 was applied over the film body 4, and then was baked at 100° C. for 30 minutes to form the guard coat having the thickness of 20 μm, so as to obtain the decorative member 1.

(18) Next, in the decorative member 1 obtained in this example, the attenuation rate as the index of the transmission loss when the millimeter wave transmits, and the L* value (brightness) as the index of metallic luster were measured.

(19) The attenuation rate was measured with respect to the millimeter wave having a frequency band of 18 to 26.5 and 70 to 90 GHz by a transmission attenuation rate measuring device (product name: Vector Network Analyzer N5227A) manufactured by KEYCOM Corporation while installing the guard coat of the decorative member of this example using a transmission attenuation rate measuring tool with a dielectric lens manufactured by KEYCOM Corporation such that the guard coat was disposed to face a transmitting side of the device. The results are illustrated in Table 1.

(20) Further, the L* value (brightness) was measured from a side of the base material 2 made of a polycarbonate resin by using a spectrophotometer (product name: CM-600d) manufactured by KONICA MINOLTA, INC. as an L* value (brightness) in an SCI method, where regular reflection lights were included, using a D65 light source. The results are illustrated in Table 1.

Example 2

(21) In this example, the decorative member 1 was obtained in exactly the sane manner as Example 1 except that the silver fine particles had the average particle diameter of 13 nm, and the thickness of the film body 4 was 50 nm. Next, for the decorative member obtained in this example, the attenuation rate as the index of the transmission loss when the millimeter wave transmits, and the L* value (brightness) as the index of metallic luster were measured in exactly the same manner as Example 1. The results are illustrated in Table 1.

Example 3

(22) In this example, the decorative member 1 was obtained in exactly the same manner as Example 1 except that the silver fine particles had the average particle diameter of 70 nm, and the thickness of the film body 4 was 50 nm. Next, for the decorative member obtained in this example, the attenuation rate as the index of the transmission loss when the millimeter wave transmits, and the L* value (brightness) as the index of metallic luster were measured in exactly the same manner as Example 1. The results are illustrated in Table 1.

Example 4

(23) In this example, the decorative member 1 was obtained in exactly the same manner as Example 1 except that the thickness of the film body 4 was 50 nm. Next, for the decorative member 1 obtained in this example, the attenuation rate as the index of the transmission loss when the millimeter wave transmits, and the L* value (brightness) as the index of metallic luster were measured in exactly the same manner as Example 1. The results are illustrated in Table 1.

Example 5

(24) In this example, the decorative member 1 was obtained in exactly the same manner as Example 1 except that the thickness of the film body was 100 nm. Next, for the decorative member 1 obtained in this example, the attenuation rate as the index of the transmission loss when the millimeter wave transmits, and the L* value (brightness) as the index of metallic luster were measured in exactly the same manner as Example 1. The results are illustrated in Table 1.

Example 6

(25) In this example, the decorative member 1 was obtained in exactly the same manner as Example 1 except that the thickness of the film body 4 was 150 nm. Next, for the decorative member obtained in this example, the attenuation rate as the index of the transmission loss when the millimeter wave transmits, and the L* value (brightness) as the index of metallic luster were measured in exactly the same manner as Example 1. The results are illustrated in Table 1.

Example 7

(26) In this example, the decorative member 1 was obtained in exactly the same manner as Example 1 except that the silver fine particles had the average particle diameter of 30 nm, and the thickness of the film body 4 was 300 nm. Next, for the decorative member obtained in this example, the attenuation rate as the index of the transmission loss when the millimeter wave transmits, and the L* value (brightness) as the index of metallic luster were measured in exactly the same manner as Example 1. The results are illustrated in Table 1.

Example 8

(27) In this example, the decorative member 1 was obtained in exactly the same manner as Example 1 except that the undercoat 3 and the guard coat 5 were not formed at all, and the thickness of the film body 4 was 50 nm. Next, for the decorative member obtained in this example, the attenuation rate as the index of the transmission loss when the millimeter wave transmits, and the L* value (brightness) as the index of metallic luster were measured in exactly the same manner as Example 1. The results are illustrated in Table 1.

Example 9

(28) In this example, the decorative member 1 was obtained in exactly the same manner as Example 8 except that the silver fine particles had the average particle diameter of 30 nm, and the thickness of the film body 4 was 10 nm. Next, for the decorative member obtained in this example, the attenuation rate as the index of the transmission loss when the millimeter wave transmits, and the L* value (brightness) as the index of metallic luster were measured in exactly the same manner as Example 1. The results are illustrated in Table 1.

Example 10

(29) In this example, first, instead of the silver fine particle dispersion liquid of Example 1, a gold fine particle dispersion liquid that contains a propylene glycol monomethyl ether as the dispersion medium and 10 mass % of the gold fine particles having the average particle diameter of 30 nm was prepared. Next, the gold fine particle dispersion liquid was diluted with toluene to prepare a gold fine particle dispersion liquid that contains 2.5 mass % of the gold fine particle having the average particle diameter of 30 nm.

(30) Next, the decorative member 1 was obtained in exactly the same manner as Example 1 except that the film body 4 that was made of the agglomeration of the gold fine particles and had the thickness of 20 nm was formed using the gold fine particle dispersion liquid containing 2.5 mass % of the gold fine particles having the average particle diameter of 30 nm, which was obtained in this example. Subsequently, in the decorative member obtained in this comparative example, the attenuation rate as the index of the transmission loss when the millimeter wave transmits, and the L* value (brightness) as the index of metallic luster were measured in exactly the same manner as Example 1. The results are illustrated in Table 2.

Comparative Example 1

(31) In this comparative example, the decorative member 1 was obtained in exactly the same manner as Example 1 except that the undercoat 3 was not formed, and a synthetic resin layer that was made of an acrylic urethane resin and had a thickness of 50 nm was formed instead of the film body 4. The synthetic resin layer was made of the acrylic urethane resin where the main agent (product name: EC-MM82-1003X), which is manufactured by Musashi Paint Co., Ltd., and the curing agent (product name: Z-EC-H-400), were mixed at a mass ratio of 100:10, and contained 2.4 g of the silver fine particles having the average particle diameter of 20 nm per 1 gram.

(32) Next, in the decorative member 1 obtained in this comparative example, the attenuation rate as the index of the transmission loss when the millimeter wave transmits, and the L* value (brightness) as the index of metallic luster were measured in exactly the same manner as Example 1 The results are illustrated in Table 3.

Comparative Example 2

(33) In this comparative example, the decorative member was obtained in exactly the same manner as Example 1 except that the silver coating layer having a thickness of 100 nm was formed instead of the film body 4. Unlike the film body 4, which was made of the agglomeration of the silver fine particles of Examples 1 to 4, the silver coating layer was in a state where the silver fine particles were mutually coupled to be continuous by applying a silver fine particle dispersion liquid (the average particle diameter of the silver fine particles is 10 nm) manufactured by Musashi Paint Co., Ltd. over the undercoat 3, and then baking it at 100° C. for 30 minutes.

(34) The silver fine particle dispersion liquid, which is manufactured by Musashi Paint Co., Ltd., was a mixture at a weight ratio of 100:200 of EC MIRROR AGENT AG IKY M/C AG (product name) and MPC thinner (product name, which is manufactured by Musashi Paint Co., Ltd. Next, in the decorative member 1 obtained in this comparative example, the attenuation rate as the index of the transmission loss when the millimeter wave transmits, and the L* value (brightness) as the index of metallic luster were measured in exactly the same manner as Example 1. The results are illustrated in Table 3.

(35) TABLE-US-00001 TABLE 1 EXAMPLE 1 2 3 4 5 UNDERCOAT 20 20 20 20 20 THICKNESS (μm) FILM BODY 20 50 50 50 100 THICKNESS (nm) AVERAGE PARTICLE 20 13 70 20 20 DIAMETER OF SILVER FINE PARTICLES (nm) GUARD COAT 20 20 20 20 20 THICKNESS (μm) ATTENUATION 18 GHz 1.03 1.05 1.08 1.03 1.02 RATE OF 24 GHz 0.53 0.85 1.12 0.47 0.43 MILLIMETER 26.5 GHz   0.26 0.64 0.99 0.21 0.18 WAVE (dB) 70 GHz 0.86 0.29 1.62 1 1.12 76.5 GHz   1.28 0.6 1.52 1.25 1.21 90 GHz 0.44 1.35 0.42 0.39 0.44 L* VALUE (BRIGHTNESS) 70 62 58 71 74

(36) TABLE-US-00002 TABLE 2 EXAMPLE 6 7 8 9 10 UNDERCOAT 20 20 — — 20 THICKNESS (μm) FILM BODY 150 300 50 10 20 THICKNESS (nm) AVERAGE PARTICLE 20 30 20 30 30 DIAMETER OF SILVER (GOLD) FINE PARTICLES (nm) GUARD COAT 20 20 — — 20 THICKNESS (μm) ATTENU- 18 GHz 1.05 1.06 1.00 1.10 1.91 ATION 24 GHz 0.86 0.87 0.42 1.10 1.47 RATE OF 26.5 GHz   0.65 0.66 0.18 0.96 1.21 MILLI- 70 GHz 0.25 −0.32 1.16 1.28 1.42 METER 76.5 GHz   0.44 −0.47 1.12 0.91 1.49 WAVE (dB) 90 GHz 1.32 −1.27 0.44 0.26 0.60 L* VALUE 73 74 83 52 47 (BRIGHTNESS)

(37) TABLE-US-00003 TABLE 3 COMPARATIVE EXAMPLE 1 2 UNDERCOAT THICKNESS (μm) — 20 THICKNESS OF SYNTHETIC 50 100 RESIN LAYER OR SILVER COATING LAYER (nm) AVERAGE PARTICLE DIAMETER 20 10 OF SILVER FINE PARTICLES (nm) GUARD COAT THICKNESS (μm) 20 20 ATTENUATION   18 GHz 1.10 27.30 RATE OF   24 GHZ 1.12 29.50 MILLIMETER WAVE 26.5 GHz 1.10 30.60 (dB)   70 GHz 1.20 28.91 76.5 GHz 1.05 26.89   90 GHz 0.27 30.61 L* VALUE (BRIGHTNESS) 43 66

(38) From Tables 1 to 3, it is apparent that, compared with the decorative member 1 of Comparative Example 1, the decorative members 1 of Examples 1 to 10 have similar attenuation rates as the index of the transmission loss when the millimeter wave transmits, and large L* values (brightness) as the index of metallic luster.

(39) Further, it is apparent that the decorative members 1 of Examples 1 to 10 have the L* values (brightness) of 45 or more as the index of metallic luster, and small attenuation rates as the index of the transmission loss when the millimeter wave transmits compared with the decorative member 1 of Comparative Example 2.

(40) Therefore, it is apparent that the decorative members of Examples 1 to 10 have small transmission losses of the millimeter wave, and moreover, excellent metallic luster.

(41) Furthermore, it is apparent that while the decorative members 1 of Examples 1 to 9, which include the film body 4 made of the agglomeration of the silver fine particles, have the L* values (brightness) of 50 or more as the index of metallic luster, the decorative member 1 of Example 10, which includes the film body 4 made of the agglomeration of the gold fine particles, has the L* value (brightness) of 47 as the index of metallic luster, and it is apparent that the film body 4 made of the agglomeration of the silver fine particles ensures obtaining the L* value larger than that of the case of being made of the agglomeration of the gold fine particles.