PRINTED PACKAGING LAMINATE, METHOD FOR MANUFACTURING OF THE PACKAGING LAMINATE AND PACKAGING CONTAINER

Abstract

A laminated packaging material for food packaging, comprises a core layer of paper or paperboard, which on a first side intended to be directed towards the outside of a packaging container, has, in the following order, a dry pre-coating for receiving a printed dcor of an aqueous, pigment-based, ink-jet printing ink, a pigment-based ink-jet printed ink dcor layer and further laminated onto the printed dcor layer, a protective outermost layer of a thermoplastic polymer. Also disclosed is a method for manufacturing of the packaging laminate and to a packaging container that is made from the laminated packaging material as well as to a pre-coating composition for use in the laminated packaging material and in the manufacturing thereof.

Claims

1-30. (canceled)

31. A laminated packaging material for food packaging, comprising a substrate layer, which on the substrate surface of its first side, intended to be directed towards the outside of a packaging container made from the packaging material, has applied to it, in the following order, a pre-coating for receiving a printed dcor layer of an aqueous pigment-based ink-jet printing ink, a pigment-based ink-jet printed dcor layer and further laminated onto the printed dcor layer, an outermost layer of a thermoplastic polymer, the pre-coating composition comprising: an aqueous soluble multivalent cation salt and a polymer binder in which the applied salt concentration at the substrate surface is from 0.02 g/m.sup.2 to 0.05 g/m.sup.2 dry coating weight, and the weight ratio of the multivalent cation salt to the polymer binder is 1:10 to 2:5 calculated on solid matter; the pre-coating composition is applied onto the substrate surface at from 0.1 g/m.sup.2 to 0.5 g/m.sup.2 total dry coating weight; and the multivalent cation salt is CaCl.sub.2.

32. Laminated packaging material according to claim 31, wherein the polymer binder is a hydrophilic polymer.

33. Laminated packaging material according to claim 31, wherein the weight ratio of the multivalent cation salt to the polymer binder is 1:5 to 2:5 calculated on solid matter.

34. Laminated packaging material according to claim 31, wherein the pre-coating composition is applied onto the substrate surface at from 0.1 g/m.sup.2 to 0.3 g/m.sup.2.

35. Laminated packaging material according to claim 31, wherein the polymer binder is a polymer selected from the group consisting of polyvinyl alcohol (PVOH) or modified polyvinylalcohol, water dispersible ethylene vinyl alcohol (EVOH), polysaccharides, including cellulose, cellulose derivatives, CMC, starch and starch derivatives, acrylic-based (co-)polymers and combinations of two or more thereof.

36. Laminated packaging material according to claim 31, wherein the polymer binder is crosslinked.

37. Laminated packaging material according to claim 31, wherein the substrate is a paper or paperboard constituting a core layer of the laminated packaging material.

38. Laminated packaging material according to claim 31, wherein the substrate layer is further laminated to an innermost layer of a thermoplastic polymer on its second side, which is intended to be directed towards the inside of a packaging container.

39. Laminated packaging material according to claim 38, further comprising a gas barrier layer between the substrate layer and the innermost layer.

40. Laminated packaging material according to claim 31, wherein the polymer binder comprises a cross-linked aceto-acetylated polyvinyl alcohol.

41. Laminated packaging material according to claim 31, wherein the polymer binder comprises a polyvinyl alcohol having a saponification degree of from 79% to 99.99%.

42. Laminated packaging material according to claim 31, wherein the polymer binder is cross-linked with a dialdehyde compound, preferably glyoxal.

43. Laminated packaging material according to claim 31, wherein the polymer binder is cross-linked with glyoxal.

44. Laminated packaging material according to claim 31, wherein the ink-jet ink is an aqueous pigment-based ink.

45. A laminated packaging material for food packaging, comprising a substrate layer, which on the substrate surface of its first side, intended to be directed towards the outside of a packaging container made from the packaging material, has applied to it, in the following order, a pre-coating for receiving a printed dcor layer of an aqueous pigment-based ink-jet printing ink, a pigment-based ink-jet printed dcor layer and further laminated onto the printed dcor layer, an outermost layer of a thermoplastic polymer, the pre-coating composition comprising: an aqueous soluble multivalent cation salt and a polymer binder in which the applied salt concentration at the substrate surface is from 0.02 g/m.sup.2 to 0.05 g/m.sup.2 dry coating weight, and the weight ratio of the multivalent cation salt to the polymer binder is 1:10 to 2:5 calculated on solid matter; the pre-coating composition is applied onto the substrate surface at from 0.1 g/m.sup.2 to 0.5 g/m.sup.2 total dry coating weight; the multivalent cation salt is calcium, magnesium or aluminium salt with a chloride or acetate counter ion; and the concentration of the multivalent cation salt is at a calcium ion equivalent to from 0.02 g/m.sup.2 to 0.1 g/m.sup.2 of calcium chloride.

46. Method of manufacturing a laminated packaging material comprising: continuously applying a pre-coating composition onto a substrate surface of a moving substrate to produce a pre-coated substrate web, the pre-coating composition being comprised of an aqueous soluble multivalent cation salt and a polymer binder in which the applied salt concentration at the substrate surface is from 0.02 g/m.sup.2 to 0.05 g/m.sup.2 dry coating weight, and the weight ratio of the multivalent cation salt to the polymer binder is 1:10 to 2:5 calculated on solid matter; transporting the pre-coated substrate web through a drying station to at least partially dry the applied pre-coating composition by evaporating off water; printing an aqueous pigment-based ink-jet dcor layer onto the pre-coated substrate surface after transporting the pre-coated substrate web through the drying station to produce a pre-coated and printed substrate web; transporting the pre-coated and printed substrate web through a drying station to evaporate off water from the printed dcor layer; and applying a layer of a thermoplastic polymer. onto the pre-coated and printed substrate web after transporting the pre-coated and printed substrate web through the drying station.

47. Method according to claim 46, wherein the polymer binder is a hydrophilic polymer.

48. Method according to claim 46, wherein the weight ratio of the multivalent cation salt to the polymer binder is 1:5 to 2:5 calculated on solid matter.

49. Method according to claim 46, wherein the pre-coating composition is applied onto the substrate surface at from 0.1 g/m.sup.2 to 0.3 g/m.sup.2.

50. Method according to claim 46, wherein the polymer binder is a polymer selected from the group consisting of polyvinyl alcohol (PVOH) or modified polyvinylalcohol, water dispersible ethylene vinyl alcohol (EVOH), polysaccharides, including cellulose, cellulose derivatives, CMC, starch and starch derivatives, acrylic-based (co-)polymers and combinations of two or more thereof.

Description

[0089] In the following, preferred embodiments of the invention will be described with reference to the drawings, of which:

[0090] FIGS. 1a and 1b are schematically showing, in cross-section, different embodiments of a laminated packaging material produced according to the invention,

[0091] FIG. 2 is grammatically showing a method of flexography coating of a pre-coating composition onto a substrate layer,

[0092] FIG. 3 is schematically showing the method of manufacturing the packaging laminates described in FIGS. 1a,

[0093] FIGS. 4a and 4b are showing examples of packaging containers produced from the packaging laminate according to the invention, and

[0094] FIG. 5 is showing the principle of how such packaging containers are manufactured from the packaging laminate in a continuous form, fill and seal process.

[0095] In FIG. 1a there is thus shown, in cross-section, an example of a laminated packaging material 10a for aseptic packaging and long-term storage under ambient conditions. A paperboard for liquid food packaging, so-called liquid paperboard 11, has a pre-coating 12, which made the outer surface of the paperboard 11 receptive to an aqueous type pigment-based inkjet ink layer 13, has an extrusion-coated outermost heat sealable layer of low density polyethylene 14, applied after the pre-coat and print operations onto the printed dcor layer 13. On the opposite side of the liquid paperboard core layer, an aluminium foil gas barrier 15 is laminated to the paperboard by means of an interjacent layer of polyolefin 16, preferably low density polyethylene or functionalised polyethylene copolymer. An innermost liquid tight and heat sealable layer 17 of low density polyethylene, preferably blended or copolymerised with a linear low density polyethylene in order to optimise sealing properties, is applied, most commonly by means of extrusion coating onto the inside of the aluminium foil.

[0096] FIG. 1b shows a similar packaging laminate 10b as described in FIG. 1a, with the difference that the substrate that is pre-coated 12 and printed by an ink-jet dcor layer 13, is a premanufactured, biaxially oriented film of polyethylene terephthalate (BOPET) or polypropylene (BOPP) 18, which is laminated to a liquid paperboard 11, by means of a suitable adhesive or an interjacent extrusion lamination polyolefin 19, and finally extrusion coated by the outermost heat sealable layer 14. The inside layers essentially remaining the same or similar, since the package is intended for the similar purpose of liquid good or beverage packaging.

[0097] FIG. 2 schematically shows how the pre-coating may be applied according to a preferred embodiment of the invention, i.e. by means of a flexographic method employing an anilox roller for transfer of the aqueous pre-coating composition to the substrate surface. The anilox roll 1 is rotated in the direction of rotation of the arrow, partly within the pre-coating composition chamber 3 positioned axially along the roll 1 for taking up the pre-coating solution in the cells engraved on the circumferential surface of the roll 1. Picked up excess of the pre-coating solution is scraped off from the roll 1 by an upper doctor blade (obscured in the figure) abutting against the circumferential surface, on exit from the ink chamber 3. The pre-coating composition thus remaining in the engraved cells accompanies the rotating anilox roll 1 and is transferred to an impression cylinder 2 rotating in transfer contact with the anilox roll 1. The pre-coating composition thus transferred to the impression cylinder 2 accompanies the rotating impression cylinder 2 for transfer to a web substrate surface 16 which is led through the nip between the impression cylinder 2 and a counter pressure cylinder 17 rotating adjacent the impression cylinder 2. After drying of the transferred pre-coating composition on the surface of the web, the web is forwarded for further processing, i.e. to the ink-jet printing station in accordance with the invention.

[0098] FIG. 3 shows schematically a method 30 of manufacturing the laminated packaging material of FIG. 1a. A roll of paperboard is passing a pre-coating anilox roller application station, i.e. a flexographic printing station in order to apply the aqueous pre-coating composition in a thin, even layer, and is subsequently lead through a drying station for evaporating off the water of the applied coating. In the next step the pre-coated web is forwarded through an inkjet printing station with multiple colours corresponding to the CMYK colour set-up and is printed according to a digitally signalled and controlled printing pattern. After the ink-jet printer, a final drying station dries the thus applied inkjet dcor layer. In a final step, for the part of the packaging material that is on the outside of the paperboard, a heat sealable and liquid tight low density polyethylene (LDPE) is applied onto the printed dcor layer by extrusion coating.

[0099] The laminate layers of the inside may be applied before or after the printing operation and the extrusion coating of the outermost polyethylene layer, and are most commonly laminated by extrusion lamination of the aluminium foil to the paperboard and subsequently coating the inside of the aluminium foil with the innermost heat sealable polyethylene layers (not shown in FIG. 3).

[0100] Alternatively, the laminated packaging material of FIG. 1b is manufactured by a preceding lamination step (not shown), in which a pre-manufactured polymer film is laminated to a core layer of paper or paperboard, such as liquid paperboard, by means of a suitable adhesive or an interjacent extrusion lamination polyolefin, thus bonding the not-to-be-printed side of the film and the paperboard to each other. The other, outer, side of the polymer film is then pre-coated by passing the laminate of paper and polymer film through a pre-coating anilox roller application station 31, i.e. a flexographic printing station in order to apply the aqueous pre-coating composition in a thin, even layer. In the next step the pre-coated web is forwarded through a drying station 32 to at least partly dry the pre-coating by evaporating off the water, whereafter the web is lead to an inkjet printing station 33 with multiple colours corresponding to the CMYK colour set-up and is printed according to a digitally signalled and controlled printing pattern. After the ink-jet printer, a final drying station 34 dries the thus applied pre-coating and inkjet dcor layer are finally dried altogether. In a final step, for the part of the packaging material that is on the outside of the paperboard, a heat sealable and liquid tight low density polyethylene (LDPE) is applied onto the printed dcor layer by means of extrusion coating in a melt extrusion station 35.

[0101] The laminate layers of the inside may be applied before or after the printing operation and the extrusion coating of the outermost polyethylene layer, and are most commonly laminated by extrusion lamination of the aluminium foil to the paperboard and subsequently coating the inside of the aluminium foil with the innermost heat sealable polyethylene layers (not shown).

[0102] FIG. 4a shows a preferred example of a packaging container 40 produced from any of the packaging laminates 10 according to the invention. The packaging container is particularly suitable for beverages, sauces, soups or the like. Typically, such a package has a volume of about 100 to 1000 ml. It may be of any configuration, but is preferably brick-shaped, having longitudinal and transversal seals 41 and 42, respectively, and optionally an opening device 43. In another embodiment, not shown, the packaging container may be shaped as a wedge. In order to obtain such a wedge-shape, only the bottom part of the package is fold formed such that the transversal heat seal of the bottom is hidden under the triangular corner flaps, which are folded and sealed against the bottom of the package. The top section transversal seal is left unfolded. In this way the half-folded packaging container is still is easy to handle and dimensionally stable when put on a shelf in the food store or on a table or the like.

[0103] FIG. 4b shows an alternative, preferred example of a packaging container 40b produced from the packaging laminates 10 according to the invention. Since the packaging laminate for this type of package is thinner by having a thinner paper core layer, it is not dimensionally stable enough to form a parallelepipedic packaging container, and is not fold formed after transversal sealing 42b. It will thus remain a pillow-shaped pouch-like container and distributed and sold like this.

[0104] FIG. 5 shows the principle as described in the introduction of the present application, i.e. a web of packaging material is formed into a tube 51 by the longitudinal edges 52, 52 of the web being united to one another in an overlap joint 53. The tube is filled 54 with the intended liquid food product and is divided into individual packages by repeated transversal seals 55 of the tube at a pre-determined distance from one another below the level of the filled contents in the tube. The packages 56 are separated by incisions in the transversal seals and are given the desired geometric configuration by fold formation along prepared crease lines in the material.

[0105] The invention is not limited by the embodiments shown and described above, but may be varied within the scope of the claims.

Examples

[0106] Lamination experiments were made on samples made from pre-coating bare liquid paperboards with similar pre-coating compositions having only differences in salt concentration of the aqueous pre-coating composition.

[0107] Substrate samples 1-3 were thus pre-coated with an aqueous pre-coating composition comprising a binder of PVOH with a saponification degree of 88% (GH17 PVA) a dialdehyde crosslinking compound and a salt concentration of 2 wt % CaCl2, to the dry coating weights as listed in table 1.

[0108] Substrate sample 4 was pre-coated with a composition comprising CaCl2 salt only, without a polymer binder, at a solution concentration of 10 wt %.

[0109] The pre-coated samples were dried, and subsequently extrusion coated with a layer of 12 g/m2 of LDPE, and the adhesion was measured as soon as possible after the lamination.

[0110] It had been seen in previous test runs, where conventional and much higher amounts of salt was pre-coated onto the paperboard, that the initial adhesion of the extrusion coated thermoplastic layer of LDPE was very bad, or non-existing, and only a minimal force directed to it caused the LDPE layer to fall off. Strangely enough, when the samples had been allowed to lie still for a few weeks, the adhesion was improved to almost an acceptable level. It has thus been seen that it is important to measure the adhesion within one week after the extrusion coating of the LDPE layer onto the pre-coating and subsequently printed surface. Furthermore, it had been seen that there was good initial adhesion also when a pre-coating solution was not used, i.e. there was no fixing salt applied to the surface to be printed. A fixing salt pre-treatment is, however, necessary for the subsequent printing performance in terms of image quality.

[0111] The adhesion properties between the outer extrusion coating layers and the printed pre-coated substrate are obtained through an internal peel test approach based on 180 degree peeling using a tensile tester, preferably an Instron tester or a like.

TABLE-US-00001 Paperboard Dry total Coating weight Adhesion to LDPE substrate coating weight of salt covering layer sample (g/m.sup.2) (g/m.sup.2) (N/m) 1 0.15 0.040 82 2 0.21 0.055 70 3 0.37 0.100 37 4 0.15 0.140 0

[0112] The conclusion from these and further examples, is that the salt concentration should be very low, compared to what has previously been believed, in order to achieve the necessary adhesion to the polyethylene outermost coating layer, for laminated packaging material suitable for liquid food packaging.