SEMICONDUCTOR DEVICES
20170077223 ยท 2017-03-16
Inventors
Cpc classification
H10D62/021
ELECTRICITY
H10D62/832
ELECTRICITY
H01L21/02636
ELECTRICITY
H10D62/116
ELECTRICITY
H10D64/021
ELECTRICITY
H10D30/022
ELECTRICITY
H10D64/015
ELECTRICITY
H01L21/0262
ELECTRICITY
H10D30/601
ELECTRICITY
H10D30/797
ELECTRICITY
H10D30/608
ELECTRICITY
H10D62/822
ELECTRICITY
H10D30/0227
ELECTRICITY
International classification
H01L29/06
ELECTRICITY
H01L29/66
ELECTRICITY
H01L29/24
ELECTRICITY
H01L29/267
ELECTRICITY
H01L29/08
ELECTRICITY
H01L29/161
ELECTRICITY
H01L29/165
ELECTRICITY
Abstract
A method is provided for fabricating a semiconductor device. The method includes providing a semiconductor substrate having a gate structure; and forming offset sidewall spacers around the gate structure. The method also includes forming trenches in the semiconductor substrate at outside of the gate structure; and forming isolation layers on side surfaces of the trenches to prevent diffusions between subsequently formed doping regions. Further, the method includes removing at least portions of the offset sidewall spacers to expose portions of the surface of the semiconductor substrate between the gate structure and the trenches; and forming filling layers with a top surface higher than the surface of the semiconductor substrate by filling the trenches and covering portions of the surface of the semiconductor substrate between the trenches and the gate structure. Further, the method also includes forming doping regions configured as raised source/drain regions in the filling layers.
Claims
1.-14. (canceled)
15. A semiconductor device, comprising: a semiconductor substrate having a first surface; a gate structure formed on the first surface of the semiconductor substrate; offset sidewall spacers covering side surfaces of the gate structure and exposing portions of the first surface of the semiconductor substrate; filling layers formed in the semiconductor substrate at outside of the gate structure and on portions of the first surface of the semiconductor substrate between the offset sidewall spacers of the gate structure and side surfaces of the filling layers; doping regions configured as raised source/drain regions formed in the filling layers; and isolation layers formed between side surfaces of the filling layers and the semiconductor substrate to prevent diffusions between the doping regions, wherein the filling layers are formed by: forming trenches in the semiconductor substrate at outside of the gate structure; forming isolation layers on side surfaces of the trenches; and filling up the trenches.
16. The semiconductor device according to claim 15, wherein: the doped regions include lightly doped regions and heavily doped regions; and surfaces of the doping regions are higher than the surface of the semiconductor substrate so as to be configured as the raised source/drain regions.
17. The semiconductor device according to claim 15, wherein: the isolation layers are made of silicon oxide, silicon nitride or silicon oxynitride.
18. The semiconductor device according to claim 15, wherein: pocket regions are formed in the doping regions.
19. The semiconductor device according to claim 15, wherein: the filling layers are made of Si, SiGe, SiGeB, SiC, or SiCP.
20. The semiconductor device according to claim 15, wherein: metal silicide layers are formed on the filling layers.
21. The semiconductor device according to claim 15, wherein: the offset sidewall spacers are multiple-stacked structures comprising a silicon oxide layer and a silicon nitride layer.
22. The semiconductor device according to claim 15, wherein: the filling layers with the top surface higher than the first surface cover entire portions of the first surface of the semiconductor substrate between the trenches and the gate structure.
23. The semiconductor device according to claim 15, wherein: the isolation layers have a uniform thickness based on the side surfaces of the trenches, the isolation layers without being formed on a bottom of the trenches.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0010]
[0011]
[0012]
DETAILED DESCRIPTION
[0013] Reference will now be made in detail to exemplary embodiments of the invention, which are illustrated in the accompanying drawings. Wherever possible, the same reference numbers will be used throughout the drawings to refer to the same or like parts.
[0014]
[0015] As shown in
[0016] When the size of the semiconductor device formed by the above-mentioned process is continuously shrunk, the semiconductor device may have a short channel effect. In order to prevent the short channel effect, the channel length of the semiconductor device may need to be greater than a certain length L.sub.min. The certain length L.sub.min, may be described as L.sub.min=A[x.sub.jd.sub.ox(W.sub.s+W.sub.d).sup.2].sup.1/3. Wherein L.sub.min may refer to a minimum channel length of the semiconductor device for obtaining the sub-threshold characteristics of the channel region; x.sub.j may refer to a junction depth of the depletion layers of the heavily doped regions; W.sub.d and W.sub.s may refer to the widths of the depletion layers of the heavily doped regions at both sides of the gate structure, respectively; and d.sub.ox may refer to the thickness of the gate oxide layer. Thus, in order to obtain a semiconductor device with a relatively short channel length, it may need to reduce the thickness of the gate oxide layer, the width of the depletion layers of the heavily doped regions and the junction depth.
[0017] However, the thickness of the gate oxide layer may have reached its limitation. For example, when the thickness of the gate oxide layer is approximately 40 , a tunneling current may be generated; and the tunneling current may penetrate through the gate oxide layer to flow from the gate structure to the semiconductor substrate, thus the semiconductor device may fail.
[0018] Further, the width of the depletion layers of the heavily doped regions may be inversely promotional to the doping concentration of the semiconductor substrate. Although increasing the doping concentration of the semiconductor substrate may decrease the width of the depletion layers, however, the junction capacitance and the threshold voltage may also be increased simultaneously. Therefore, the width of the depletion layers may not be continuously decreased.
[0019] Therefore, it may be an effective way to prevent the short channel effect by reducing the junction depth of the heavily doped regions. The junction depth of the heavily doped regions may be dependent of an ion implantation process or a diffusion process for forming the heavily doped regions. Because of the limitation of the ion implantation process and the short channel effect, it may be difficult to form a relatively shallow junction, such as a depth of 500 , etc. Generally, a pre-amorphous process may significantly lower the short channel effect of the ion implantation process, however, defects caused by the ion implantation process may be unable to be removed by a thermal annealing process; and the defects may increase the leakage current of the semiconductor device. Thus, although the short channel effect may be prevented by penetrating through an amorphous layer or an oxide layer using the ion implantation process, it may be unable to effectively eliminate the short channel effect; and the source to drain punch may still exist in the semiconductor device. According to the disclosed methods and the device structures, the source to drain punch and the short channel effect may be overcome by forming isolation layers between doping regions.
[0020]
[0021] As shown in
[0022] As shown in
[0023] The semiconductor substrate 100 may include any appropriate semiconductor materials, such as silicon, silicon on insulator (SOI), germanium on insulator (GOI), silicon germanium, carborundum, indium antimonide, lead telluride, indium arsenide, indium phosphide, gallium arsenide, gallium antimonite, or alloy semiconductor, etc. In one embodiment, the semiconductor substrate 100 is made of silicon. The semiconductor substrate 100 provides a base for subsequent processes and structures.
[0024] Referring to
[0025] The gate oxide layer 111 may be made of any appropriate material, such as silicon oxide, silicon oxynitride, or high-K dielectric material, etc. Various processes may be used to form the gate oxide layer 111, such as a chemical vapor deposition (CVD) process, a physical vapor deposition (PVD) process, an atomic layer deposition (ALD) process, a flowable chemical vapor deposition (FCVD) process, a thermal oxidation process, or a sputtering process, etc.
[0026] The gate electrode layer 112 may be made of any appropriate material, such as poly silicon, doped poly silicon, or metal material, etc. Various processes may be used to form the gate electrode layer 112, such as a CVD process, a PVD process, an FCVD process, a sputtering process, or an electro plating process, etc.
[0027] Further, in one embodiment, the gate structure 110 may also include a top mask layer 113 formed on the surface of the gate electrode layer 112. The top mask layer 113 may be used to prevent a subsequent ion implantation process from implanting doping ions into the gate oxide layer 111 and/or the gate electrode layer 112. If the doping ions are implanted into the gate oxide layer 111 and/or the gate electrode layer 112, the electrical properties of the gate structure 110 may be affected. The top mask layer 113 may also be used as a mask for subsequently forming trenches in the semiconductor substrate 100.
[0028] The top mask layer 113 may be made of any appropriate material, such as silicon oxide, silicon nitride, silicon oxynitride, or silicon carbonitride, etc. In one embodiment, the top mask layer 113 is made of silicon nitride.
[0029] Various processes may be used to form the top mask layer 113, such as a CVD process, a PVD process, an ALD process, or an FCVD process, etc.
[0030] Further, referring to
[0031] The isolation structures 101 may be made of any appropriate material, such as silicon oxide, silicon nitride, silicon oxynitride etc. In one embodiment, the isolation structures 101 are shallow trench isolation (STI) structures made of silicon oxide.
[0032] Returning to
[0033] As shown in
[0034] The offset sidewall spacers may expose the surface of the semiconductor substrate 100 at both sides of the gate structure 110. The offset sidewall spacers may be used as a mask for subsequently etching the semiconductor substrate 100. The offset sidewall spacers may also be used to protect the side surfaces of the gate structure 110. Further, in one embodiment, the offset sidewall spacers may be used as a mask for subsequently forming lightly doped drain regions.
[0035] The first layer 102 and the second layer 103 of the offset sidewall spacers may be made of any appropriate material, such as one more of silicon oxide, silicon nitride, silicon oxynitride, or silicon carbonitride, etc. In one embodiment, the first layer 102 is made of silicon oxide; and the second layer is made of silicon nitride. For illustrative purposes, a silicon oxide layer 102 may be used to refer to the first layer 102; and a silicon nitride layer 103 may be used to refer to the second layer 103. After subsequently removing the silicon nitride layer 103, the silicon oxide layer 102 of the offset sidewall spacers may be used as the mask to subsequently form the lightly doped regions.
[0036] In certain other embodiments, the offset sidewall spacers are single layer structures made of silicon nitride. In certain other embodiments, the offset sidewall spacers are triple-layer structures. That is, the offset sidewalls pacers have a silicon oxide-silicon nitride-silicon oxide structure.
[0037] The offset sidewall spacers may be formed by an etch back process. Specifically, the etch back process for forming the offset sidewall spacers may include forming an offset spacer material layer (not shown) on the surfaces of the gate structure 110, followed by an etch back process. The offset spacer material layer may be one layer, or two layers, etc., which may depend on the final structure of the offset sidewall spacers.
[0038] Various processes may be used to form the offset sidewall spacer material layer, such as a CVD process, a PVD process, or an FCVD process, etc. The etch back process may include a dry etching process, a wet etching process, or an ion beam etching process, etc.
[0039] Returning to
[0040] As shown in
[0041] Various processes may be used to form the trenches 104, such as a dry etching process, a wet etching process, or an ion beam etching process, etc. In one embodiment, the trenches 104 are formed by a dry etching process.
[0042] In one embodiment, the etching gas of the dry etching process may include CF.sub.4 and He, etc. The flow of CF.sub.4 may be in a range of approximately 200 sccm-500 sccm. The flow of He may be in a range of 1000 sccm-2000 sccm. The pressure of the etching chamber may be in a range of approximately 1 Pa-10 Pa. The radio frequency power of the dry etching process may be in a range of approximately 250W-350W. The frequency of the radio frequency may be in a range of approximately 0-13.56 MHz.
[0043] Returning to
[0044] As shown in
[0045] The isolation layers 105 may be made of any appropriate material, such as one or more of silicon oxide, silicon nitride, or silicon oxynitride, etc. The isolation layers 105 may be single layer structures, or multiple stacked structures. In one embodiment, the isolation layers 105 are single layer structures made of silicon oxide.
[0046] In one embodiment, a process for forming the isolation layers 105 may include forming an isolation material layer on the surfaces of the trenches 104, the offset sidewall spacers, and the gate structure 110; and followed by removing the isolation material layer on the surfaces of the gate structure 110 and bottom surfaces of the trenches 104 by an etching process. Thus, isolation layers 105 may be formed on the side surfaces of the trenches 104.
[0047] The isolation material layer may be formed by any appropriate process, such as a CVD process, a PVD process, an ALD process, or an FCVD process, etc.
[0048] Various processes may be used to etch the isolation material layer, such as a dry etching process, a wet etching process, or an ion beam etching process. In one embodiment, an anisotropic dry etching process is used to etch the isolation material layer to form isolation layers 105.
[0049] The anisotropic dry etching process may be a plasma dry etching process. The source power of the plasma dry etching process may be in a range of approximately 500W-1500W or approximately 500W-1000W. The bias power of the plasma dry etching process may be in a range of approximately 1000W-2500W. The pressure of the reaction chamber may be in a range of approximately 10 mTorr-100 mTorr. The etching gas may include C.sub.4F.sub.8 or C.sub.4F.sub.6, etc. The etching gas may also include N.sub.2, O.sub.2, CO.sub.2, or Ar, etc.
[0050] Returning to
[0051] As shown in
[0052] In one embodiment, the silicon nitride layers 103 of the offset sidewall spacers are removed; and portions of the surface of the semiconductor substrate 100 between the isolation layers 105 and the silicon oxide layers 102 of the offset sidewall spacers are exposed. Subsequently formed filling layers may connect with the exposed portion of the surface of the semiconductor substrate 100 between the isolation layers 105 and the silicon oxide layers 102. That is, the subsequently formed filling layers may connect with the semiconductor substrate 100 under the gate structure 110. After subsequently forming doping regions in the filling layers, the doping regions may electrically connect with the channel region the semiconductor device under the gate structure 110; and may be configures as source/drain regions.
[0053] Various processes may be used to remove the silicon nitride layers 103, such as a dry etching process, a wet etching process, or an ion beam etching process, etc. In one embodiment, the silicon nitride layers 103 are removed by a wet etching process.
[0054] The etching solution of the wet etching process may include any appropriate chemicals. In one embodiment, the etching solution is a hot phosphoric acid solution. The temperature of the hot phosphoric acid solution may be in a range of approximately 70 C.-200 C. The mass percentage of phosphoric acid may be in a range of approximately 70%-85%.
[0055] After removing the silicon nitride layers 103 of the offset sidewall spacers, the silicon oxide layers 102 of the offset sidewall spacers may be used as a mask layer for subsequently forming lightly doped regions, thus the fabrication process may be simplified. Further, the silicon oxide layers 102 may also be used to prevent a filling material layer subsequently formed in the trenches 104 from being formed on the surfaces of the gate structure 110.
[0056] In certain other embodiments, the silicon nitride layers 103 may be removed before forming the isolation layers 105.
[0057] Returning to
[0058] As shown in
[0059] The filling layers 106 may be made of any appropriate material, such as Si, SiGe, SiGeB, SiC, or SiCP, etc.
[0060] In one embodiment, the semiconductor device may be an NMOS transistor. The filling layers 106 may be made of Si, SiGe, or SiGeB. When the filling layers 106 are made of
[0061] SiGe or SiGeB, the filling layers 106 may provide a tensile stress to the channel region of the semiconductor device, thus the carrier mobility of the semiconductor device may increased; and the speed of the semiconductor device may be increased.
[0062] In certain other embodiments, the semiconductor device may be a PMOS transistor. The filling layers 106 may be made of Si, SiC, or SiCP. When the filling layers 106 are made of SiC or SiCP, the filling layers 106 may provide a compressive stress to the channel region of the semiconductor device, thus the carrier mobility of the semiconductor device may be increased; and the speed of the semiconductor device may be increased.
[0063] Various processes may be used to form the filling layers 106, such as a CVD process, a PVD process, an ALD process, an FCVD process, or an epitaxial growth process, etc. In one embodiment, the filling layers 106 are formed by a selective epitaxial growth process.
[0064] In one embodiment, the filling layers 106 are made of Si. The source gas of the selective epitaxial growth process may include a silicon source gas, H.sub.2 and HCl, etc. The silicon source gas may be SiH.sub.4 or SiH.sub.2Cl.sub.2, etc. The flow of the silicon source gas may be in a range of approximately 1 sccm-1000 sccm. The flow of HCl may be in a range of approximately 1 sccm-1000 sccm. The flow of H.sub.2 may be in a range of approximately 100 sccm-10000 sccm.
[0065] The temperature of the reaction chamber of the selective epitaxial growth process may be in a range of approximately 700 sccm-800 sccm. The pressure of the reaction chamber may be in a range of approximately 1 Torr-100 Torr
[0066] The selective epitaxial growth process may have the characteristic that material may only be formed on certain types of substrates. For example, the material for the filling layers 106 may only be formed on the surface of a single crystal substrate. In one embodiment, the filling layers 106 formed by the selective epitaxial growth process may only be selectively formed on the bottom surfaces of the trenches 104. Further, the filling layers 106 formed by the selectively epitaxial growth process may also be selectively formed on the surface of the semiconductor substrate 100 between the isolation layers 105 and the gate structure 110.
[0067] Referring to
[0068] In one embodiment, the silicon oxide layers 102 are formed around the gate structure 110, when the filling layer 106 is formed in the trench 104 by the selective epitaxial growth process, the material of the filling layer 106 may unlikely be formed on the surface of the gate structure 110. Thus, the reliability of the semiconductor device may be improved.
[0069] Returning to
[0070] As shown in
[0071] Further, referring to
[0072] In one embodiment, if the semiconductor device is a PMOS transistor, the ions of the ion implantation process may be P-type ions. The P-type ions may be boron ions or indium ions, etc. The energy of the ion implantation process may be in a range of approximately 1 keV-10 keV. The dose of the ion implantation process may be in a range of approximately 1E14atom/cm.sup.21E15atom/cm.sup.2.
[0073] In certain other embodiments, if the semiconductor device is an NMOS transistor, the ions of the ion implantation process may be N-type ions. The N-type ions may be phosphorous ions or arsenic ions, etc. The energy of the ion implantation process may be in a range of approximately 1 keV-10 keV. The dose of the ion implantation process may be in a range of approximately 1E13atom/cm.sup.21E16atom/cm.sup.2.
[0074] Further, after forming the lightly doped regions 107, a thermal annealing process may be performed. The thermal annealing process may repair the crystal lattice damages of the semiconductor substrate 100 caused by the ion implantation process. The thermal annealing process may also cause the implanted ions to redistribute in the filling layers 106.
[0075] Returning to
[0076] As shown in
[0077] The main sidewall spacers 108 may be made of any appropriate material, such as silicon oxide, silicon nitride, or silicon oxynitride, etc. The main sidewall spacers 108 may be single layer structures, or multiple stacked structures, etc.
[0078] A process for forming the main sidewall spacers 108 may include forming a main sidewall spacer material layer to cover the gate structure 110, the oxide layers 102, the filling layers 106 and the isolation structures 101; and followed by removing portions the main sidewall spacer material layer on the top surface of the gate structure 110, the top surfaces of the filling layers 106 and the top surfaces of the isolation structures 101. Thus, the main sidewall spacers 108 may be formed on the side surfaces of the oxide layers 102.
[0079] The main sidewall spacer material layer may be formed by any appropriate process, such as a CVD process, a PVD process, or an FCVD process, etc. In one embodiment, the main sidewall spacer material layer is formed by a CVD process. The main sidewall spacer material layer on the top surface of the gate structure 110, the top surfaces of the filling layers 106 and the top surfaces of the isolation structures 101 may be removed by any appropriate process, such as a dry etching process, a wet etching process, or an ion beam etching process, etc.
[0080] Returning to
[0081] As shown in
[0082] Various processes may be used to dope the filling layers 106 to form the heavily doped regions 109, such as an ion implantation process, or a thermal diffusion process, etc. In one embodiment, the filling layers 106 are doped by an ion implantation process to form the heavily doped regions 109.
[0083] In one embodiment, when the semiconductor device is a PMOS transistor, the implanted ions are P-type ions. The P-type ions may be boron ions, or indium ions, etc. The energy of the ion implantation process may be in a range of approximately 1 keV-50 keV. The dose of the ion implantation process may be in a range of approximately 1E15atom/cm.sup.25E19atom/cm.sup.2.
[0084] In certain other embodiments, when the semiconductor device is an NMOS transistor, the implanted ions are N-type ions. The N-type ions may be phosphorous ions, or arsenic ions, etc. The energy of the ion implantation process may be in a range of approximately 1 keV-100 keV. The dose of the ion implantation process may be in a range of approximately 1E14atom/cm.sup.25E18atom/cm.sup.2.
[0085] After forming the heavily doped regions 109, a thermal annealing process may be performed. The thermal annealing process may be used to repair the crystal lattice damages caused by the ion implantation process.
[0086] Further, metal silicide layers may be formed on the surfaces of the filling layers 106 in the heavily doped regions 109. The metal silicide layers may be used to reduce the contact resistance of the filling layers 106 with other devices and interconnection structures, etc. After forming the metal silicide layers, contacts may be formed to connect the semiconductor device with other devices and interconnection structures, etc.
[0087] In one embodiment, referring to
[0088] In certain other embodiments, besides the lightly doped regions 107 and the heavily doped regions 109, the doping regions may also include pocket regions (not shown). The doping type of the pocket regions may be opposite to the doping type of the lightly doped regions 107. The pocket regions may also reduce the short channel effect to a certain extend.
[0089] Referring to
[0090] Referring to
[0091] By using the disclosed methods and device structures, diffusions between doping regions may be avoided, thus the source to drain punch of the semiconductor device may be prevented; and the breakdown voltage of the semiconductor device may be increased. Therefore, the requirements for the device miniaturization may be matched; and the electrical properties of the semiconductor devices may be optimized. Further, stress may be generated to the channel region of the semiconductor device, the carrier mobility of the semiconductor device may be increased, thus the speed of the semiconductor device may be increased; and the electrical properties of the semiconductor device may be optimized. Further, some fabrication steps of the semiconductor device may be omitted, thus the production efficiency may be improved.
[0092] Thus, a semiconductor device may be formed by the above disclosed processes and methods; and a corresponding semiconductor device is illustrated in
[0093] Further, the semiconductor device includes filling layers 106 with a surface higher than the surface of the semiconductor substrate 100 formed in the semiconductor substrate 100 and on portions of the surface of the semiconductor substrate 100 between the side surfaces of the filling layers 106 and the semiconductor substrate 100 to prevent diffusions between doping regions. Further, the semiconductor device also includes doping regions including lightly doped regions 109 and heavily doped regions 107 configured as raised source/drain regions formed in the filling layers 106 and shallow trench isolation structures 101 formed in the semiconductor substrate 100.
[0094] The above detailed descriptions only illustrate certain exemplary embodiments of the present invention, and are not intended to limit the scope of the present invention. Those skilled in the art can understand the specification as whole and technical features in the various embodiments can be combined into other embodiments understandable to those persons of ordinary skill in the art. Any equivalent or modification thereof, without departing from the spirit and principle of the present invention, falls within the true scope of the present invention.