HERMETICALLY-SEALED MEMS DEVICE AND ITS FABRICATION
20170050844 · 2017-02-23
Inventors
Cpc classification
H01L2224/83193
ELECTRICITY
H01L2224/05138
ELECTRICITY
H01L2224/279
ELECTRICITY
B81C2201/053
PERFORMING OPERATIONS; TRANSPORTING
B81C1/00285
PERFORMING OPERATIONS; TRANSPORTING
B81C2203/0109
PERFORMING OPERATIONS; TRANSPORTING
B81C2201/0188
PERFORMING OPERATIONS; TRANSPORTING
H01L2224/05163
ELECTRICITY
B81C2201/0198
PERFORMING OPERATIONS; TRANSPORTING
B81C1/00269
PERFORMING OPERATIONS; TRANSPORTING
H01L2224/04026
ELECTRICITY
H01L2224/8381
ELECTRICITY
H01L2924/00014
ELECTRICITY
B81B7/0038
PERFORMING OPERATIONS; TRANSPORTING
G02B6/4208
PHYSICS
G02B6/4248
PHYSICS
H01L2224/05163
ELECTRICITY
H01L2224/32227
ELECTRICITY
H01L2224/8381
ELECTRICITY
H01L2224/29006
ELECTRICITY
H01L2224/29023
ELECTRICITY
H01L2224/05138
ELECTRICITY
H01L2224/279
ELECTRICITY
B81C2203/019
PERFORMING OPERATIONS; TRANSPORTING
G02B26/0833
PHYSICS
H01L2224/0345
ELECTRICITY
H01L2224/94
ELECTRICITY
H01L2224/83121
ELECTRICITY
H01L2924/0002
ELECTRICITY
B81C2201/0108
PERFORMING OPERATIONS; TRANSPORTING
H01L24/94
ELECTRICITY
G02B6/4204
PHYSICS
H01L2224/039
ELECTRICITY
H01L2224/039
ELECTRICITY
H01L2224/83121
ELECTRICITY
B81C1/00293
PERFORMING OPERATIONS; TRANSPORTING
H01L2924/00014
ELECTRICITY
H01L2224/05562
ELECTRICITY
B81C2203/0118
PERFORMING OPERATIONS; TRANSPORTING
H01L2224/0345
ELECTRICITY
H01L2224/94
ELECTRICITY
B82Y30/00
PERFORMING OPERATIONS; TRANSPORTING
International classification
Abstract
A hermetic package comprising a substrate (110) having a surface with a MEMS structure (101) of a first height (101a), the substrate hermetically sealed to a cap (120) forming a cavity over the MEMS structure; the cap attached to the substrate surface by a vertical stack (130) of metal layers adhering to the substrate surface and to the cap, the stack having a continuous outline surrounding the MEMS structure while spaced from the MEMS structure by a distance (140); the stack having a bottom first metal seed film (131a) adhering to the substrate and a bottom second metal seed film (131b) adhering to the bottom first seed film, both seed films of a first width (131c) and a common sidewall (138); further a top first metal seed film (132a) adhering to the cap and a top second metal seed film (132b) adhering to the top first seed film, both seed films with a second width (132c) smaller than the first width and a common sidewall (139); the bottom and top metal seed films tied to a metal layer (135) including gold-indium intermetallic compounds, layer (135) having a second height (133a) greater than the first height and encasing the seed films and common sidewalls.
Claims
1. A method for fabricating a MEMS device comprising the steps of: providing a substrate including a MEMS structure having at least a portion raised to a first height above a substrate surface, the structure protected by a sacrificial polymer; depositing a first seed layer including a Group IVA-metal over the substrate surface; depositing a second seed layer including a metal of high conductivity over the first seed layer, forming a first vertical pile; forming a first mask layer over a region of the second seed layer, the region having a first width and a contour continuously peripherally surrounding the MEMS structure and laterally spaced from the MEMS structure; etching the first pile un-covered by the first mask layer, leaving the first pile of first width un-etched while creating sidewalls for the first pile, then removing the first mask layer; plating a first vertical stack of one or more metal layers over the width and sidewalls of the first pile, the first stack including a top layer of a first metal having a height equal to or greater than the first height; removing the sacrificial polymer; dispensing a getter and passivation material; providing a cap having a surface with a second pile of seed layers with sidewalls and a lateral continuous contour similar to but of lesser or greater lateral width than the contour of the first pile, and further with a second stack of one or more metal layers over the width and sidewalls of the second pile, the second stack including a top layer of a second metal; aligning the cap and the substrate to bring the top layer of the second metal into contact with the top layer of the first metal, with a greater lateral spacing of the first or second metal of the top layer of lesser lateral width than the lateral spacing of the second or first metal of the top layer of greater lateral width from the MEMS structure; and applying thermal energy to the one of the first and second metals having a lower melting temperature to liquefy and dissolve the one of the first and second metal into the other of the first and second metals by forming one or more intermetallic compounds of the first and second metals.
2. The method of claim 1 wherein the Group IVA-metal is selected from a group including titanium, zirconium, hafnium, and alloys thereof with chromium, molybdenum, and tungsten.
3. The method of claim 2 wherein the metal of high conductivity is selected from a group having high electrical conductivity and low cost, including copper, aluminum, beryllium, magnesium, silver and gold.
4. The method of claim 1 wherein the one or more intermetallic compounds have melting temperatures greater than the melting temperature of the one of the first and second metals and less than the melting temperature of the other of the first and second metals.
5. The method of claim 1 wherein melting temperatures of the other of the first and second metals and of the one or more intermetallic compounds are greater than 260 C.
6. The method of claim 5 wherein the melting temperature of the one or the first and second metals is less than 260 C.
7. The method of claim 1 wherein the one of the first and second metals is indium and the other of the first and second metals is gold.
8. The method of claim 1 wherein the steps of depositing comprise the method of electrolytic plating.
9. The method of claim 1 wherein the step of providing a cap includes the steps of: providing a cap material element; depositing a third seed layer including a Group IVA-metal over a surface of the cap material element; depositing a fourth seed layer including a metal of high conductivity over the third seed layer, forming a second vertical pile; covering a region of the second pile with a second mask layer, the region having the lateral continuous contour similar to but of lesser or greater lateral width than the contour of the etched first pile; etching the second pile un-covered by the second mask layer, leaving the second pile of second width un-etched while creating sidewalls for the second pile, then removing the second mask layer; and plating a second vertical stack of one or more metal layers over the width and sidewalls of the second pile, the second stack including a top layer of a second metal having a height equal to or greater than the first height.
10. A method for fabricating a MEMS device comprising the steps of: providing a substrate including a MEMS structure having at least a portion raised to a first height above a substrate surface, the structure protected by a sacrificial polymer; depositing a first seed layer including a Group VA-metal over the substrate surface; depositing a second seed layer including a metal of high conductivity over the first seed layer; forming a first mask layer over a region of the second seed layer, the region having a first width and a contour continuously peripherally surrounding the MEMS structure and laterally spaced from the MEMS structure; etching the second seed layer un-covered by the first mask layer, leaving the second seed layer of first width and the first seed layer un-etched while creating sidewalls for the first seed layer, then removing the first mask layer; forming a second mask layer over a region of the substrate including the first seed layer, the mask layer having a thickness greater than the first height; patterning the second mask layer with an opening greater than the first width to expose an underlying portion of the first seed layer, the opening having a lateral continuous contour similar to but of greater lateral width than the contour of the un-etched second seed layer; plating a first vertical stack of one or more metal layers over the width and sidewalls of the second seed layer and the first seed layer within the opening, the first stack including a top layer of a first metal having a height equal to or greater than the first height, then removing the second mask layer; etching the first seed layer un-covered by the first vertical metal stack; removing the sacrificial polymer; dispensing a getter and passivation material; providing a cap having a surface with a second pile of seed layers with sidewalls and a lateral continuous contour similar to but of lesser or greater lateral width than the contour of the first pile, and further with a second stack of one or more metal layer over the width and sidewalls of the second pile, the second stack including a top layer of a second metal; aligning the cap and the substrate to bring the top layer of the second metal into contact with the top layer of the first metal, with a greater lateral spacing of the first or second metal of the top layer of lesser lateral width than the lateral spacing of the second or first metal of the top layer of greater lateral width from the MEMS structure; and applying thermal energy to the one of the first and second metals having a lower melting temperature to liquefy and dissolve the one of the first and second metal into the other of the first and second metals by forming one or more intermetallic compounds of the first and second metals.
11. The method of claim 10 wherein the Group VA-metal is selected from a group including vanadium, niobium, tantalum, and alloys and compounds thereof.
12. The method of claim 10 wherein the metal of high conductivity is selected from a group having high electrical conductivity and low cost, including copper, aluminum, beryllium, magnesium, silver and gold.
13. The method of claim 10 wherein the one or more intermetallic compounds have melting temperatures greater than the melting temperature of the one of the first and second metals and less than the melting temperature of the other of the first and second metals.
14. The method of claim 10 wherein melting temperatures of the other of the first and second metals and of the one or more intermetallic compounds are greater than 260 C.
15. The method of claim 14 wherein the melting temperature of the one or the first and second metals is less than 260 C.
16. The method of claim 10 wherein the one of the first and second metals is indium and the other of the first and second metals is gold.
17. The method of claim 10 wherein the steps of depositing comprise the method of electrolytic plating.
18. The method of claim 10 wherein the step of providing a cap includes the steps of: providing a cap material element; depositing a third seed layer including a Group VA-metal over a surface of the cap material element; depositing a fourth seed layer including a metal of high conductivity over the third seed layer; forming a second vertical pile; covering a region of the second pile with a second mask layer, the region having the lateral continuous contour similar to but of lesser or greater lateral width than the contour of the etched first pile; etching the second pile un-covered by the second mask layer, leaving the second pile of second width un-etched while creating sidewalls for the second pile, then removing the second mask layer; and plating a second vertical stack of one or more metal layers over the width and sidewalls of the second pile, the second stack including a top layer of a second metal having a height equal to or greater than the first height.
19. A hermetic package of a microelectromechanical system (MEMS) structure comprising: a substrate having a surface with a MEMS structure of a first height, the substrate hermetically sealed to a cap forming a cavity over the MEMS structure; the cap attached to the substrate surface by a vertical stack of metal layers adhering to the substrate surface and to the cap, the stack having a continuous outline surrounding the MEMS structure while spaced from the MEMS structure by a distance; and the stack having a bottom first metal seed film adhering to the substrate and a bottom second metal seed film adhering to the bottom first seed film, both seed films of a first width and a first common sidewall, and further a top first metal seed film adhering to the cap and a top second metal seed film adhering to the top first seed film, both seed films with a second width smaller than the first width and a second common sidewall, the bottom and top metal seed films tied to a metal layer including gold-indium intermetallic compounds, the metal layer encasing the seed films and the first and second common sidewalls and having a second height greater than the first height.
20. The package of claim 19 wherein the bottom and top first metal seed films are selected from the IVA Group of the Periodic Table of Elements including titanium, zirconium, hafnium and alloys thereof with chromium, molybdenum, and tungsten.
21. The package of claim 19 wherein the bottom and top second metal seed films are selected from a group including copper, aluminum, beryllium, magnesium, and alloys thereof.
22. A hermetic package of a microelectromechanical system (MEMS) structure comprising: a substrate having a surface with a MEMS structure of a first height, the substrate hermetically sealed to a cap forming a cavity over the MEMS structure; the cap attached to the substrate surface by a vertical stack of metal layers adhering to the substrate surface and to the cap, the stack having a continuous outline surrounding the MEMS structure while spaced from the MEMS structure by a distance; and the stack having a bottom first metal seed film adhering to the substrate and a bottom second metal seed film adhering to the bottom first seed film, the first bottom seed film having a first width and the second bottom seed film having a second width greater than the first width, and further a top first metal seed film adhering to the cap and a top second metal seed film adhering to the top first seed film, both the top first and top second seed films with a third width smaller than the first width and a common sidewall, the bottom and top metal seed films tied to a metal layer including gold-indium intermetallic compounds, the metal layer having a width equal to the second width and a second height greater than the first height, the metal layer encasing the first bottom seed film and the first and second top seed films and common sidewalls.
23. The package of claim 22 wherein the bottom and top first metal seed films are selected from the VA Group of the Periodic Table of Elements including vanadium, niobium, tantalum and alloys thereof.
24. The package of claim 22 wherein the bottom and top second metal seed films are selected from a group including copper, aluminum, beryllium, magnesium, and alloys thereof.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION OF EXAMPLE EMBODIMENTS
[0035] Life test and stress test data indicated that the lubricating and passivating characteristics of compounds deposited in hermetic packages of MEMS devices with moving parts may deteriorate over time. Applicants found in detailed investigations that the chief culprit for the compound degradation may be exposed surfaces of copper layers needed in high-conductivity seed layers and low-resistance traces for plating uniformity.
[0036] Applicants solved the problem of lubricant degradation when they discovered a methodology to deposit the bond metals so that they extend not only over the width but also over the sidewalls of patterned seed metal piles, thereby encapsulating the copper of the seed metal layers. The methodology is based on using photoresist invers to existing practice, namely covering the region intended for plating rather than exposing the region.
[0037] The exemplary embodiment 100 of
[0038] Substrate 110 may, for example, be a chip or chip area like that of an integrated circuit chip comprising semiconductor material such as silicon, silicon germanium, or gallium arsenide. Semiconductor chips are impermeable to water molecules and thus hermetic. The substrate may include circuit components of an integrated circuit (IC) protected by an overcoat 111. In the package portion illustrated in
[0039] As illustrated on
[0040] As illustrated in
[0041] Vertical stack 130 of
[0042] In an example implementation, bottom layer 137 is joined to seed film 131, is made of copper, and has a thickness of about 2 m. Intermediate layer 136 is joined to layer 137, is made of nickel which acts as a barrier layer against metal diffusion, and has a thickness of about 1 m. Layer 136 fully encapsulates layer 137; consequently, when layer 136 is made of nickel, out-diffusion of underlying copper is inhibited. Top metal layer 135 has its bottom joined to intermediate layer 136, its top joined to seed film 132b, and a width that varies upwardly and inwardly from width 130a to width 130b. A lower portion of layer 135 of generally uniform width 130a has a thickness 133a of between about 5 m and 10 m, and the upper portion of layer 135 of tapered or stepped width has a thickness 134a of between about 2 m and 4 m. For some MEMS devices, enhanced adhesion can be achieved and any out-diffusion of copper from seed film 132b can be inhibited by the addition of a nickel layer of about 1 m thickness between the upper portion of thickness 134a and seed film 132b.
[0043] For the example MEMS device illustrated in
[0044] An example embodiment of a wafer-level process flow for the fabrication of low-temperature hermetically sealed MEMS structure devices is illustrated with reference to
[0045]
[0046] The layout of the package features is next defined and the substrate surface is covered with a patterned metallic seed film for anchoring the package sealing structures.
[0047] In order to pattern protective layer 201, a photoresist layer 301 (see
[0048] The next processes steps involve defining the layout of the package features and to cover the substrate surface with patterned metallic seed films for anchoring the package seal structures. In order to pattern protective layer 201, a photoresist layer 301 (see
[0049] In the next process step, illustrated in
[0050] As illustrated in
[0051]
[0052]
[0053] In the next process steps, indicated in
[0054]
[0055]
[0056] As illustrated in
[0057]
[0058] The process step shown in
[0059] In some implementations, metal layer 1034 may be a composite metal layer comprising a plurality of successively formed metal layers, such as a bottom layer of about 200 nm thickness of titanium deposited over the metallic seed layer 132b, followed by an intermediate layer of indium deposited over the titanium, and then a top layer of gold of about 100 nm thickness deposited over the indium intermediate layer.
[0060] The resulting wafer scale cap structure, illustrated in
[0061] As mentioned, for some MEMS devices, such as DMDs, chemical gettering substances, lubricants, corrosion inhibitants and/or other materials (generally designated 601 in
[0062]
[0063] Without delay and with the indium layer and gold layer in contact, thermal energy is applied in order to raise the temperature until the indium metal is liquefied at about 156 C. It is preferred to keep the temperature between about 156 and 200 C., since this temperature range is low compared to typical processing temperatures of silicon components and MEMS structures. Since the amount of indium is small relative to the amount of gold, after a short period of time the indium metal is dissolved into the gold layer by forming gold-indium intermetallic compounds (the interaction is often referred to as a transient liquid phase process). Among the formed compounds are the indium-rich compound AuIn.sub.2 and the compound AuIn. The oversized gold surface (relative to the indium surface in contact with the gold surface) acts to capture excess liquid indium to form intermetallic compounds 601 before liquid indium can enter sidewise into the MEMS structure headspace. An occasional residual indium metal squeezed sidewise is neutralized by the distance 140 of the gold perimeter to the MEMS structures 101. As indicated in
[0064] After the transient liquid phase wafer-level assembly process described with reference to
[0065] In contrast to the low temperature range of 156 to 200 C. for forming gold-indium intermetallics, any re-melting of the intermetallic compounds would require much higher temperatures, for example about 509 C. for AuIn and about 540 C. for AuIn.sub.2. Consequently, additional device processing after package assembly is possible with less concern about thermal degradation of the hermetic seal. An example is the solder processes utilized for attachment to external parts such as other components and circuit boards.
[0066]
[0067] As
[0068] Seed metal layers 1231a and 131b are deposited in a process step analogous to the deposition step described in conjunction with
[0069] The described example embodiments are merely illustrative and not intended to be construed in a limiting sense. The disclosed principles apply to any semiconductor material for the chips, including silicon, silicon germanium, gallium arsenide, gallium nitride, or any other semiconductor or compound material used in manufacturing. The same principles may be applied both to MEMS components formed over the substrate surface and to MEMS components formed within the substrate. The caps used in packaging the components may be flat, curved, or any other geometry that suits individual needs and preferences. The caps may be transparent or completely opaque to all or specific wavelengths or ranges of wavelengths of visible light, infrared light, radio frequency or radiation in other portions of the electromagnetic spectrum.
[0070] The contacting metal layers of the stacks formed on the substrate and cap may be other than gold and indium, with other suitable choices being disclosed in application Ser. No. 13/671,734 filed Nov. 8, 2012, the entirety of which is incorporated by reference herein. Also, the relative widths of the metal stacks can be reversed, with the wider stacks being formed on the cap and the narrower stack being formed on the substrate. In such case, the top layer of the wider stack formed on the cap instead of the substrate will be formed of the higher melting temperature meta; (e.g., gold) and the top layer of the narrower stack formed on the substrate instead of the cap will be formed of the lower melting temperature metal. In such case, too, it may be advantageous to join the substrate from above to the cap, rather than join the cap from above to the substrate, to assist collection of liquefied lower melting temperature metal on the wider higher melting temperature metal.
[0071] For fully hermetic MEMS packages, the described approach realized that general eutectic bonding may offer low temperature sealing of packages and thus be compatible with low temperature MEMS structures, but the resulting seals would de-bond at the same low temperatures as the sealing process and thus not allow post-sealing temperatures above the sealing temperature as required by some customer board assembly and device operations.
[0072] The problem is addressed of sealing low cost hermetic packages at low temperaturesand thus permitting lubrication of surface MEMS structuresbut allowing device operation at temperatures significantly above the sealing temperature. In the example gold/indium system approach a methodology is based on a transient liquid phase sealing technique at low temperatures, which creates intermetallic compounds re-melting only at much higher temperatures. Yet, in a configuration wherein the gold amount is in excess, the indium amount is restricted and kept within confined borders. In the described process flow, indium and gold are kept separate until immediately before sealing, creating a thermally stable solution. Making the indium bond line asymmetrical relative to the gold bond line, and especially selecting in indium bond line significantly narrower than the gold bond line, allows the gold surface to react with any excess indium before it can enter the MEMS device area, capturing the indium as intermetallic compounds.
[0073] In an example new package design, the package structures are electrically isolated from the MEMS structures; any copper used in seed layer and metallization stacks is inhibited by overlaying metal barriers from diffusing into the MEMS operating space. The temperature range, in which the indium is consumed by the gold, does not have to be much higher than the indium melting temperature (156.63 C.); it is preferably in the range from about 156 to 200 C. On the other hand, the re-melting temperatures of indium-gold intermetallic compounds are much higher: for AuIn 509.6 C., for AuIn.sub.2 540.7 C. It is thus a technical advantage for hermetic low temperature MEMS structures (especially with the need for temperature-sensitive lubricants) that the assembly temperature can be kept under 200 C., while applications and operations at much higher post-assembly temperatures can reliably be tolerated. Another advantage is that the cost of hermetic MEMS packages fabricated by this method compares well with the cost of conventional non-hermetic MEMS packages.
[0074] The described example packaging method separates indium and gold from each other until right at the assembly step, thus creating a thermally stable solution in contrast to known methods, where indium bodies are placed in contact with gold bodies during the fabrication process. Since indium and gold diffuse rapidly at elevated temperatures, and significantly even at ambient temperature, intermetallic compound are continuously produced at these interfaces. When the assembly temperature is reached, the intermetallic compounds do not re-melt and can thus not participate in the bonding process. Consequently, these interfaces may not be thermally stable at ambient temperature, are preferably not exposed before assembly to processing steps requiring elevated temperatures, and have limited shelf life before assembly.
[0075] The described example packaging method uses asymmetrical bond line widths. In particular, the indium bond line is significantly narrower than the gold bond line. Consequently, the gold surface can react with any excess indium and can capture it as intermetallic compounds. With contacting surfaces of the indium body and the gold body at the same width, as melted indium has a strong tendency to push out of a bonding surface during an assembly step, there may be a greater chance to enter the MEMS device area.
[0076] Those skilled in the art will appreciate that many other embodiments and variations are possible within the scope of the claimed invention.