Microelectromechanical (MEMS) manipulators for control of nanoparticle coupling interactions
09548677 ยท 2017-01-17
Assignee
Inventors
- Daniel Lopez (Chicago, IL, US)
- Gary Wiederrecht (Elmhurst, IL, US)
- David J. Gosztola (Naperville, IL, US)
- Derrick C. Mancini (Riverside, IL, US)
Cpc classification
G02F1/17
PHYSICS
Y10T74/20354
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10T74/2036
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
H02N1/08
ELECTRICITY
G02F1/17
PHYSICS
H02N1/00
ELECTRICITY
Abstract
A nanopositioning system for producing a coupling interaction between a first nanoparticle and a second nanoparticle. A first MEMS positioning assembly includes an electrostatic comb drive actuator configured to selectively displace a first nanoparticle in a first dimension and an electrode configured to selectively displace the first nanoparticle in a second dimensions. Accordingly, the first nanoparticle may be selectively positioned in two dimensions to modulate the distance between the first nanoparticle and a second nanoparticle that may be coupled to a second MEMS positioning assembly. Modulating the distance between the first and second nanoparticles obtains a coupling interaction between the nanoparticles that alters at least one material property of the nanoparticles applicable to a variety of sensing and control applications.
Claims
1. A method for selectively modifying a property of a plurality of nanoparticles through a coupling interaction between the plurality of nanoparticles, comprising: providing a first nanoparticle; providing a first MEMS positioning assembly having a first positioning portion, the first MEMS positioning assembly configured to selectively displace the first positioning portion along a first axis in response to a first voltage and to selectively displace the first positioning portion along a second axis substantially normal to the first axis in response to a second voltage; associating the first nanoparticle with the first positioning portion; providing a second nanoparticle spaced a distance from the first nanoparticle; modulating the distance between the first nanoparticle and the second nanoparticle by displacement of the first positioning portion along at least one of the first axis and the second axis to obtain a coupling interaction between the first nanoparticle and the second nanoparticle.
2. The method of claim 1, wherein the first nanoparticle and the second nanoparticle are incorporated in a device, and wherein the device is selected from the group consisting of: a plasmonic switch, an optical switch, a plasmon modulator, a surface enhanced Raman scattering sensor, a nanoscale antennae, a charge transport, a heterodyne sensor, and a multiplexer.
3. The method of claim 1, wherein at least one the first nanoparticle and the second nanoparticle is selected from the group consisting of a: nanodot, nanosphere, nanorod, nanotube, and nanopyramid.
4. The method of claim 1, wherein the distance between the first nanoparticle and the second nanoparticle is modulated to within about 1 nanometer of resolution.
5. The method of claim 1, further comprising: providing a second MEMS positioning assembly having a second positioning portion, the second MEMS positioning assembly configured to selectively displace the second positioning portion along a third axis in response to a third voltage and to selectively displace the second positioning portion along a fourth axis substantially normal to the third axis in response to a fourth voltage; and associating the second nanoparticle with the second positioning portion.
6. The method of claim 5, wherein the third axis and the first axis are co-planar.
7. The method of claim 6, wherein the second axis and the fourth axis are-coplanar.
8. The method of claim 7, wherein the first axis and third axis are non-co-axial.
9. The method of claim 5, wherein the first MEMS positioning assembly is displaceable along a fifth axis perpendicular to the first axis and third axis and the second MEMS positioning assembly is displaceable along a sixth axis perpendicular to the second axis and the fourth axis, the fifth axis and the sixth axis being co-planar.
10. The method of claim 5, wherein the first nanoparticle is a first plasmonic nanoparticle and the second nanoparticle is a second plasmonic nanoparticle and further comprising controlling the flow of plasmons between the first plasmonic nanoparticle and the second plasmonic nanoparticle by modulating the distance between the first plasmonic nanoparticle and the second plasmonic nanoparticle.
11. A nanopositioning system for producing a coupling interaction between a first nanostructure and a second nanostructure, comprising: a first microelectromechanical system (MEMS) positioning assembly, the first MEMS positioning assembly including a first static comb drive actuator and a first dynamic comb drive actuator, the first static comb drive actuator configured to selectively displace the first dynamic comb drive actuator along a first axis in relation to the first static comb drive actuator upon application of a first voltage to the first static comb-drive actuator; a first micro-needle associated with the first MEMS positioning assembly and axially displaceable along the first axis; a second MEMS positioning assembly, the second MEMS positioning assembly including a second static comb drive actuator and a second dynamic comb drive actuator, the second static comb drive actuator configured to selectively displace the second dynamic comb drive actuator along a third axis in relation to the second static comb drive actuator upon application of a second voltage to the second static comb-drive actuator; a second micro-needle associated with the second MEMS positioning assembly and axially displaceable along the third axis; the first micro-needle and the second micro-needle being substantially parallel and coplanar; wherein the first micro-needle is selectively positionable along the first axis by operation of the first MEMS positioning assembly and the first positioning electrode to modulate a distance between the first micro-needle and the second micro-needle.
12. The nanopositioning system of claim 11 wherein a first boom couples the first micro-needle to the first MEMS positioning assembly and a second boom couples the second micro-needle to the second MEMS positioning assembly.
13. The nanopositioning system of claim 12, wherein the first micro-needle and the second micro-needle are non-coaxial and configured to extend along the respective first axis and third axis.
14. The nanopositioning system of claim 13, wherein the first boom and the second boom are laterally offset by a distance equal to the first micro-needle width.
15. The nanopositioning system of claim 11, wherein the first micro-needle and the second micro-needle are coaxial such that the first axis and the third axis are the same.
16. The nanopositioning system of claim 11, wherein the first MEMS positioning assembly comprises: a first restoring force element having a first end and a second end, the first end operatively connected to the first the dynamic comb drive actuator and the second end operatively connected to the first static comb drive actuator; a first positioning electrode configured to selectively displace the first dynamic comb drive actuator along a second axis, perpendicular to the first axis, in relation to the first static comb drive actuator; and the first micro-needle operatively connected to the first dynamic comb drive actuator; the first micro-needle is selectively positionable along the first axis and along the second axis by operation of the first MEMS positioning assembly and the first positioning electrode to modulate the distance between the first micro-needle and the second micro-needle.
17. The nanopositioning system of claim 16, wherein the second MEMS positioning assembly comprises: a second restoring force element having a first end and a second end, the first end operatively attached to the second dynamic comb drive actuator and the second end attached to the second static comb drive actuator; a second positioning electrode configured to selectively displace the second dynamic comb drive actuator along a fourth axis in relation to the second static comb drive actuator; the second micro-needle operatively connected to the second dynamic comb drive actuator; and the second micro-needle is selectively positionable along the third axis and along the fourth axis by operation of the second MEMS positioning assembly and the second positioning electrode to modulate the distance between the first micro-needle and the second micro-needle.
18. A plasmonic switch comprising the nanopositioning system of claim 11, further comprising a first plasmonic nanoparticle associated with the first micro-needle and a second plasmonic nanoparticle associated with the second microneedle, wherein modulating the distance between the first plasmonic nanoparticle and the second plasmonic nanoparticle by the nanopositioning system controls the flow of plasmons.
19. A Surface Enhanced Ramon Scattering Sensor comprising the nanopositioning system of claim 11 in communication with a surface enhanced Raman spectroscope.
20. A plasmonic antennae comprising the nanpositioning system of claim 11 and further comprising a first triangular structure having an apex at a distal end of the first micro-needle and a second triangular having an apex at a distal end of the second micro-needle.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION OF EMBODIMENTS
(8) An exemplary nanoparticle MEMS positioning system 10 shown in
(9) With reference to
(10) The dynamic comb portion 25 is disposed in an actuator opening 31 in a base portion 30 of the MEMS positioning system 10. Each of the comb bases 27 associated with a dynamic comb portion 25 is coupled to a dynamic link 32. The dynamic link 32 and each of the comb bases 27 that are associated with the dynamic comb portion 25 may include a plurality of openings 37 to minimize the mass of the releasable comb portion 21. The dynamic link 32 may include a boom 33 that extends away from the base portion 30. As depicted in
(11) With reference to
(12) By applying a voltage to the MEMS positioning system 10 the electrostatically actuated comb-drive actuators 20 move the nanopositioners closer together or further apart along a substantially linear first axis. In particular, applying a voltage to the first electrical contact 90 the dynamic comb portion 25 moves generally along the X axis as shown in
(13) The MEMS positioning system 10 is reversible. That is, the MEMS positioning system 10 is selectively moveable between the orientations of
(14) As shown in
(15) The MEMS positioning system 10 may also include a lateral electrode 80. As shown in
(16) With reference to
(17) A nanostructure 60 as shown in
(18) Various nanostructures may be associated with the MEMS positioning system 10 using standard deposition tools. For example, electron beam lithography is one technique that may be used to form the desired nanostructure that may be associated with the MEMS positioning system 10. Alternatively, a focused ion beam technique may be used to directly deposit the nanostructure on the MEMS positioning system 10. As seen in
(19) A nanostructure MEMS positioning system may comprise two or more MEMS positioning systems 10 configured for interaction such that two or more nanostructures 60 may be selectively positioned with respect to each other. As depicted in
(20) Additionally, the MEMS positioning systems 10 may be configured to modulate the position of the attached nanostructures in a second dimension, e.g. along the Y axis. For example, displacement in the second dimension, substantially normal to axial displacement along the X axis, is achieved via the lateral electrode 80 (see
(21) In other embodiments, other nanostructure 60 placement configurations may be used, depending on, for example, the application and/or structure. For example,
(22) The described embodiments may provide opportunities to develop new sensor technologies and switchable control of energy flow in various forms, e.g., optical, electronic, heat, etc. In particular, the present embodiments may be applied to create coupled plasmonic nanoparticles, a key element under development for opto-electronic applications, including sensors, communications, interconnects and wavefront control. The foregoing systems and methods have numerous applications, including, but not limited to:
(23) An Optical or Plasmonic Switch
(24) Plasmons are of significant interest for next generation sub-wavelength waveguides, but researchers currently do not have a reliable way to externally control the flow of plasmons between nanostructures. An optical or plasmonic switch may be constructed by, for example, bringing together a first plasmonic nanoparticle and a second plasmonic nanoparticle using the devices and methods already described. By modulating the distance between the first plasmonic nanoparticle and the second plasmonic nanoparticle, a shift in the resonance of the particles may be used as a nanoscale optical switch by varying the absorption at different wavelengths. According to the embodiments described herein, an electrically addressable plasmonic switch might be formed by modulating the distance between the nanostructures, i.e., decreasing the distance between the nanostructures to induce plasmon flow and then separating the nanostructures to turn off plasmon flow.
(25) A Spatial Plasmon Modulator
(26) A critical limitation in the area of optical interconnects is the absence of a technology to modulate optical signals that are smaller than the wavelength of the light used in the signal. Plasmons are electromagnetic waves localized in very small regions; but there is not a reliable method to manipulate plasmons in a controlled manner. Integration of metallic nanoparticles with MEMS or NEMS devices as in the described embodiments may allow for control of the relative amplitude or phase of various plasmons in arbitrary spatial locations. In doing so, an ideal device for applications like inter-chip optical interconnects may be constructed. Devices constructed according the various embodiments described herein may have the potential to reliably and controllably manipulate plasmons for such applications.
(27) A Sensor, and in a Particular Embodiment a Surface Enhanced Raman Scattering (SERS) Sensor
(28) Tuning the distance between nanoparticles according to embodiments described herein can optimize field confinement and enhancement effects that other SERS nanostructures cannot currently approach. By positioning molecules in this small region, molecular spectroscopy of a single molecule can be achievable through SERS techniques. The gains in field strength are not limited to SERS, as other material properties such as absorption and emission can be modified through controllable field enhancement by modulation of nanoparticle position.
(29) Tunable Nanoscale Antennae
(30) Plasmonic antennae that can operate at the nanoscale are key to next generation nanophotonic structures. Antennae act to collect and confine electromagnetic waves for use in photonic devices. A bow-tie configuration, such as depicted in
(31) Nanoscale Control of Energy and Charge Transport
(32) In addition to plasmon coupling, new techniques to control energy and charge transport within nanostructures are needed. By placing energy or charge donors and acceptors on opposing nanopositioners, tunable control of energy and charge flow could be achieved. This applies to both organic and inorganic materials that are integrated with the nanopositioners.
(33) Advanced Heterodyne Methods of Detection
(34) Embodiments described herein could also enable the positioning of nanoparticles to be modulated through the use of an AC field and the ability to use lock-in detection of the modulated properties for extraordinarily enhanced signal to noise in sensing and spectroscopy applications.
(35) Multiplexing
(36) Embodiments of the MEMS positioning devices described herein could permit multiplexing of a signal across multiple nanopositioners for parallel signal processing and achieve corresponding gains in efficiency for sensing and spectroscopy.
(37) The foregoing description of embodiments of the present invention has been presented for purposes of illustration and description. It is not intended to be exhaustive or to limit the present invention to the precise form disclosed, and modifications and variations are possible in light of the above teachings or may be acquired from practice of the present invention. The embodiments were chosen and described in order to explain the principles of the present invention and its practical application to enable one skilled in the art to utilize the present invention in various embodiments, and with various modifications, as are suited to the particular use contemplated.