COMPOSITE MATERIAL AND METHOD FOR MANUFACTURING SAME
20250296300 ยท 2025-09-25
Inventors
Cpc classification
B32B2255/28
PERFORMING OPERATIONS; TRANSPORTING
B32B2250/44
PERFORMING OPERATIONS; TRANSPORTING
E04F15/02
FIXED CONSTRUCTIONS
B32B27/12
PERFORMING OPERATIONS; TRANSPORTING
B32B27/304
PERFORMING OPERATIONS; TRANSPORTING
B32B2250/26
PERFORMING OPERATIONS; TRANSPORTING
B32B29/005
PERFORMING OPERATIONS; TRANSPORTING
B32B25/042
PERFORMING OPERATIONS; TRANSPORTING
B32B5/18
PERFORMING OPERATIONS; TRANSPORTING
B32B7/12
PERFORMING OPERATIONS; TRANSPORTING
B32B2307/718
PERFORMING OPERATIONS; TRANSPORTING
B32B3/06
PERFORMING OPERATIONS; TRANSPORTING
B32B21/10
PERFORMING OPERATIONS; TRANSPORTING
B32B3/266
PERFORMING OPERATIONS; TRANSPORTING
B32B21/02
PERFORMING OPERATIONS; TRANSPORTING
B32B21/045
PERFORMING OPERATIONS; TRANSPORTING
B32B3/30
PERFORMING OPERATIONS; TRANSPORTING
B32B25/10
PERFORMING OPERATIONS; TRANSPORTING
B32B29/02
PERFORMING OPERATIONS; TRANSPORTING
International classification
B32B29/00
PERFORMING OPERATIONS; TRANSPORTING
B32B29/02
PERFORMING OPERATIONS; TRANSPORTING
B32B7/12
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A composite material and a method for manufacturing same such that the composite material includes a laminate structure and a substrate. The substrate is a flexible substrate. The laminate structure has an upper surface and a lower surface. The laminate structure includes at least one paper and a resin, for example at least one resin impregnated paper. The laminate structure is bonded to the substrate. The laminate structure includes a plurality of slots extending from the upper surface of the laminate structure towards the substrate to thereby impart flexibility on the composite material.
Claims
1.-32. (Cancelled).
33. A composite material comprising a laminate structure and a substrate, said laminate structure having an upper surface and a lower surface, said laminate structure comprising at least one paper and a resin, said laminate structure being bonded to said substrate, said laminate structure including a plurality of slots extending from said upper surface of said laminate structure towards said substrate.
34. The composite material according to claim 33, wherein the laminate structure has a laminate structure thickness and wherein at least 50% of the slots of said plurality of slots have a depth corresponding to at least 70% of the laminate structure thickness.
35. The composite material according to claim 33, wherein the laminate structure comprises a dcor layer in the form of a printed and/or colored paper layer impregnated with a first resin, and at least one additional layer, said at least one additional layer being an overlay on an upper surface of said dcor layer and/or a core layer on a lower surface of said dcor layer.
36. The composite material according to claim 33, wherein the laminate structure comprises a dcor layer in the form of a printed paper layer which is not impregnated, and at least two additional layers, which two additional layers are resin impregnated papers with the dcor layer sandwiched between said two additional layers, and with said at least one additional layer being a resin impregnated overlay on an upper surface of said dcor layer and/or a resin impregnated core layer on a lower surface of said dcor layer.
37. The composite material according to claim 34, wherein said laminate structure thickness is between 0.2 and 4.0 mm.
38. The composite material according to claim 33, wherein said laminate structure is bonded to said substrate by means of an adhesive layer.
39. The composite material according to claim 33, wherein said laminated structure is directly bonded to said substrate.
40. The composite material according to claim 33, wherein said plurality of slots forms a pattern comprising intersecting slots,.
41. The composite material according to claim 40, wherein the grid structure is made up of laminate structure islands and said plurality of slots, wherein the laminate structure islands combine to provide a laminate structure surface area, wherein the laminate structure islands and the plurality of slots extends over a grid structure surface area, wherein the ratio of laminate structure surface area to grid structure surface area lies between 30% and 95%.
42. The composite material according to claim 33, wherein said plurality of slots is rectilinear.
43. The composite material according to claim 33, wherein said plurality of slots has a slot width at said upper surface of said laminate structure, said slot width being at least 5% of said laminate structure thickness.
44. The composite material according to claim 33, wherein said plurality of slots is at least partially filled with a lacquer.
45. The composite material according to claim 44, wherein said lacquer is PU-based, acrylic-based or latex, the lacquer being transparent and/or colored.
46. The composite material according to claim 44, wherein the lacquer comprises additives selected from the group consisting of anti-abrasive particles including corundum, matting agents, easy-cleaning additives, and anti-slip additives.
47. The composite material according to claim 44, wherein the laminate structure comprises a dcor layer in the form of a printed and/or colored paper layer impregnated with a first resin, and at least one additional layer, said at least one additional layer being an overlay on an upper surface of said dcor layer and/or a core layer on a lower surface of said dcor layer, wherein said additional layer is said overlay and said lacquer fills said plurality of slots up to said overlay such that said overlay is exposed.
48. The composite material according to claim 44, wherein said lacquer completely fills said plurality of slots and forms an upper surface of said composite material.
49. The composite material according to claim 33, wherein said substrate is selected from the group consisting of woven or nonwoven webs, textile cloths, foamed sheets, thermoplastic films, elastomeric sheets, rubber sheets and metal foils.
50. The composite material according to claim 49, wherein said substrate has a basis weight of from 150 to 600 gsm and/or a substrate thickness of between 0.1 and 3.0 mm.
51. The composite material according to claim 33, wherein said substrate has a substrate thickness of between 25% and 300% of the laminate structure thickness.
52. The composite material of claim 33, wherein the substrate is a flexible substrate.
Description
[0051] In the following, various non-limiting aspects of the present invention will be described in greater detail by way of example only and with reference to the attached drawings, in which:
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[0060] In the drawings, reference number 10 denotes a composite material in accordance with the present disclosure. With reference to
[0061] As is illustrated in
[0062] The laminate structure 12 may be a so-called HPL (High Pressure Laminate) or a CPL (Continuous Pressed Laminate). Both laminates consist of cellulose fiber sheets, preferably papers, impregnated with thermosetting resins. CPL is preferably produced in continuous double belt presses with a pressure between 30 and 70 bar and temperatures between 140 C. and 190 C., or using press rollers. HPL can be produced in a discontinuous press. When the resin cures, a substantially rigid laminate structure is attained.
[0063] By way of example, the paper layer forming the dcor layer 20 may be constituted by a 50-160 g/m.sup.2 printed paper impregnated with a similar amount of resin. One example is a 70 g/m.sup.2 printed paper impregnated with about 70 g/m.sup.2 of a thermosetting resin such as UF, MUF or MF. The decor layer may be a pigmented paper layer of any desirable colour. For example the paper layer can be incorporated with colorants. The dcor layer may be printed with any image, such as a wood print, a stone print, a carbon-fibre image, a fancy pattern or a logo with or without text. The image may be printed using any known printing technique, such as digital printing, rotogravure, etc. Due to its boundless flexibility, digital printing using computer-controlled ink jet printers is preferred.
[0064] The overlay 22 is provided when increased wear/scratch resistance of the laminate structure 12 is desired. The overlay 22 generally comprises a paper layer impregnated with a thermosetting resin which is compatible with, preferably identical to, the resin used in the decor layer 20. To ensure transparency after curing, the paper layer should be thin, for example about 25 g/m.sup.2, and consist essentially entirely of pure alpha-cellulose. The amount of resin may be about 3 times the basis weight of the paper. Thus, for a paper layer of 25 g/m.sup.2, the amount of resin may be about 75 g/m.sup.2. To improve abrasion resistance, and as is illustrated in
[0065] Each core layer 26 may be a resin impregnated kraft paper, for example sodium kraft paper. Typically, the kraft paper may have a basis weight of 70-300 g/m.sup.2. The resin amount may be between 70 and 300 g/m.sup.2.
[0066] Depending i.a. on the intended application and the number of paper layers, the laminate structure 12 may have a thickness t.sub.1 of between 0.20 mm and 4.0 mm, preferably between 0.5 mm and 2.5 mm.
[0067] In accordance with one aspect of the present invention, the laminate structure 12 is bonded to the substrate 14. The choice of material for the substrate will depend on the intended use of the composite material, and may include woven or nonwoven webs, textile cloths, foamed sheets (preferably a flexible foamed sheet) and extruded films. The substrate 14 may have a basis weight of from 150 to 3000 g/m.sup.2 and/or a substrate thickness t.sub.2 of between 0.10 and 3.0 mm. In one embodiment, the substrate thickness t.sub.2 may be between 25% and 300% of the laminate structure thickness t.sub.1.
[0068] Bonding of the laminate structure 12 to the substrate may be attained by means of an adhesive layer 32. Alternatively, and as is illustrated in
[0069] To render the composite material 10 flexible, the laminate structure 12 includes a plurality of slots 34 extending from the upper surface 16 of the laminate structure 12 towards the substrate 14. The plurality of slots 34 may have a depth d corresponding to at least 70% of the laminate structure thickness t.sub.1, preferably at least 90% of the laminate structure thickness t.sub.1. In some embodiments, the plurality of slots 34 extends through at least 99% of the laminate structure thickness t.sub.1 or, as illustrated in the drawings, through the entire thickness of the laminate structure 12. The plurality of slots 34 may extend over the entire upper surface 16 of the laminate structure 12 or only in selected regions in which flexibility of the composite material 10 is desired.
[0070] As is depicted in
[0071] The degree of flexibility of the composite material 10 will, at least in part, be dictated by the dimensions of the plurality of slots 34 and the distribution density of the slots. In various embodiments, the plurality of slots 34 may have a slot width w at the upper surface 16 of the laminate structure 12 which is at least 5% of the laminate structure thickness t.sub.1, preferably at least 10%, more preferably at least 20% and most preferably at least 30% of the laminate structure thickness t.sub.1. The actual widths of the slots making up the plurality of slots 34 may vary. Irrespective of any variation in the width of the slots 34, the laminate structure islands 38 combine to provide a laminate structure surface area The grid structure 38 made up of the laminate structure islands 38 and the plurality of slots 34 extends over a grid structure surface area. The ratio of laminate structure surface area to grid structure surface area may lie between 30% and 95%.
[0072] With particular reference to
[0073] The profile denoted P.sub.6 is similar to that of P.sub.3 except that the opening 40 is more rounded. The profile P.sub.7 has a V or truncated V-shape. In this embodiment, the slot has opposing side walls 44, each of which subtends an angle A from a normal N to the upper surface 16 of between 5 and 60, preferably up to 45. With reference to
[0074] In accordance with a further aspect of the present invention, the plurality of slots 34 may be at least partially filled with a lacquer 50. In the examples a) to d) illustrated in
[0075] In a similar vein,
[0076] The lacquer itself, as well as the additional lacquer layer 54, may be water-based and/or curable (such as curable by thermal energy or UV/LED radiation). The specific composition of the lacquer will influence the flexible properties of the composite material and may be chosen to impart a desired degree of flexibility. Typically, the lacquer will be PU-based, acrylic-based or latex. It is not inconceivable that the lacquer may be in the form of a thermosetting plastic. To impart a desired visual effect, the lacquer may by transparent, translucent and/or coloured. The lacquer may comprise additives selected from the group consisting of anti-abrasive particles such as corundum, matting agents, easy-cleaning additives, and anti-slip additives.
[0077] An advantage offered by an embodiment having an additional lacquer layer 54, such as example c) of
[0078] A further aspect of the present invention relates to a method for manufacturing a composite material of the type described above in relation to
[0082] The step i) of composing the laminate structure includes compiling the various paper layers, e.g. one or more core layers 26, the dcor layer 20 and/or the overlay, together with possibly an additional resin. In embodiments in which the laminate structure is an HPL (High Pressure Laminate) or a CPL (Continuous Pressed Laminate), the constituent paper layers are each impregnated with resin or some paper layers are impregnated with resin, and are brought into overlying relationship with each other and united under heat and pressure such that the resin cures to create a substantially rigid laminate structure 12. The step ii) of bonding the laminate structure to the substrate 14 may then be attained by providing the substrate and/or the laminate structure with an adhesive layer 32.
[0083] In an alternative embodiment, the step of composing the laminate structure includes bringing the constituent paper layers into overlying relationship not only with each other but also with the substrate to form a stack. The stack is then subjected to heat and pressure, for example in a continuous press or in a short-cycle press, to thereby directly bond the laminate structure to the substrate. The resulting composite material may be termed a DPL (Direct Pressure Laminate).
[0084] Irrespective of how the laminate structure 12 is bonded to the substrate 14, a plurality of slots 34 is formed in the laminate structure. In accordance with step iii) of the method according to the invention, the plurality of slots 34 extends from the upper surface 16 of the laminate structure 12 towards the substrate 14. In one embodiment of the method according to the present invention, the plurality of slots 34 may be formed simultaneously with the bonding of the laminate structure to the substrate. This can be attained by providing the press with a press plate having projections corresponding to the plurality of slots. Alternatively, the plurality of slots may be formed once the laminate structure has been bonded to the substrate. The plurality of slots may be formed in a milling operation, or using a laser, for example a CO.sub.2 laser.
[0085] A method for forming the plurality of slots 34 is depicted in
[0086] The laminate structure 12 of
[0087] With reference to
[0088] In a further aspect of the invention, the composite material 10 described above may be used in a decorative panel 60. Thus, and with reference to
[0089] The carrier substrate has a thickness t.sub.3. The thickness will depend i.a. on the intended use of the decorative panel 60 and may lie between 1.0 mm and 20.0 mm, preferably between 3.0 mm and 15.0 mm. The carrier substrate thickness t.sub.3 may be sufficient to allow the carrier substrate 62 to be provided with mechanical coupling parts 64 enabling adjacent decorative panels 60 to be coupled together. In
[0090] In a particular embodiment, the decorative panel 60 may include a composite material 10 that has a substrate 14 of a foamed material. This provides a cushioning effect for any load placed on the decorative panel. This may be advantageous when the decorative panel is used in a floor covering.
[0091] The composite material of the present invention may be used for any applications in which flexibility of the composite material is desirable. For example, the composite material may exhibit drapeability, thereby mimicking a fabric. This allows the composite material to be used in applications such as clothing, footwear, home furnishings, upholstery, interior surfaces for vehicles, luggage, flooring-for example as an alternative to a carpet-, covering of metal surfacesfor example surfaces of refrigerators or heaters, etc.
[0092] Here below three specific examples are discussed:
EXAMPLE 1
[0093] The built up (from top to bottom) is the following: [0094] Impregnated overlay paper with a thermoset melamine formaldehyde resin: alpha-cellulose paper 20 gsm, impregnated with resin towards 100 gsm, including 15 gsm corundum (particle size of corundum: 50-80 micron) [0095] non-impregnated decor paper: digitally printed 70 gsm paper [0096] impregnated overlay paper with a thermoset melamine formaldehyde resin: alpha-cellulose paper 20 gsm, impregnated with resin towards 100 gsm [0097] Impregnated kraft papers (with a MF/PF mixture): 2 sheets of 160 gsm kraft paper each treated with resin towards 280 gsm [0098] between 50 and 200 gsm glue application [0099] microfiber textile backing (1 mm thickness, 500 gsm, being a mixture of PU and PA)
[0100] In this example firstly a HPL is created comprising said papers resulting in a thickness of between 650 and 800 m, as such creating the laminate structure. Then this HPL is glued to said microfiber textile backing (said substrate) resulting in a thickness of between 1,65 and 1,8 mm. Then a pattern is lasered with the aid of a CO.sub.2 laser throughout the entire thickness of the HPL, the pattern comprising squares.
EXAMPLE 2
[0101] In this example the use of melamine resin is avoided to reduce the hardness, resulting in easier lasercutting (and also less toxic fumes/emissions/dust during lasercutting) and a more flexible end product.
[0102] The built up (from top to bottom) is the following: [0103] Impregnated overlay paper with a waterbased polyurethane dispersion resin: alpha-cellulose paper 20 gsm, impregnated with resin towards 100 gsm, including small micro particles to enhance scratch resistance (corundum platelets of between 5 and 15 micron) [0104] impregnated decor paper: digitally printed 70 gsm paper, with a PU dispersion towards 130 gsm. [0105] Impregnated kraft papers (with a PU dispersion): 2 sheets of 160 gsm kraft paper each treated with resin towards 280 gsm [0106] between 50 and 200 gsm glue application [0107] microfiber textile backing (1 mm thickness, 500 gsm, being a mixture of PU and PA)
[0108] In this example firstly a HPL is created comprising said papers resulting in a thickness of between 650 and 800 m, as such creating the laminate structure. Then this HPL is glued to said microfiber textile backing (said substrate) resulting in a thickness of between 1,65 and 1,8 mm. Then a pattern is lasered with the aid of a CO.sub.2 laser throughout the entire thickness of the HPL, the pattern comprising squares.
EXAMPLE 3
[0109] In this example an acrylic resin is used and the pattern (the grid structure) is created by pressing. No additional laser and/or cutting step is needed.
[0110] The built up (from top to bottom) is the following: [0111] impregnated decor paper: digitally printed 70 gsm paper, with an acrylic thermoset coating [0112] impregnated kraft papers (with a PU/acrylic dispersion): 2 sheets of 160 gsm kraft paper each treated with resin towards 280 gsm [0113] between 50 and 200 gsm glue application [0114] rubber matt (3 mm thickness, density of 700 kg/m.sup.3, shore hardness 40 A)
[0115] These layers are pressed in one pressing operation, wherein an embossed pressing plate is used on top. The pressing conditions can be 180 C., pressure of 80 kg/cm.sup.2 and this during 30 seconds. The rubber matt is here the substrate, the said papers form the laminate structure and the said glue connects the laminate structure to the substrate. The embossed pressing plate forms the slots during the pressing operation, as such forming the composite material in one pressing operation.
[0116] According to a deviating variant, the invention concerns a composite material comprising a laminate structure, as mentioned above, slots as mentioned abovewhich do or do not go through the entire thickness of the laminate structureand optionally a lacquer as mentioned above, wherein this composite material does not comprise said substrate, such that said deviating variant only comprises a laminate structure, slots and optionally a lacquer.
[0117] The invention also concerns two other deviating variants being a method to produce the abovementioned deviating composite material and a decorative panel comprising a carrier substrate and said deviating composite material. The additional features of the first mentioned composite material, method and decorative panel are also combinable with the above-mentioned deviating variants, according to all non-contradictory combinations. With the aid of said deviating composite material, shine-trough effects/see through effects can be created, better acoustic properties can be obtained, a breathable structure can be created.
[0118] The invention has been described above by way of non-limiting embodiments and examples. The skilled person will understand that the invention may be varied within the scope of the appended claims.