3D Light Field Detector, Sensor and Methods of Fabrication Thereof
20250311454 ยท 2025-10-02
Inventors
Cpc classification
H10F39/011
ELECTRICITY
H10F77/1625
ELECTRICITY
H04N23/90
ELECTRICITY
International classification
H04N23/90
ELECTRICITY
H10F77/162
ELECTRICITY
H10F77/14
ELECTRICITY
H10F39/00
ELECTRICITY
Abstract
The present disclosure concerns a light field detector for converting a vector of an 5 electromagnetic radiation into a chromatic output, comprising at least one azimuth detector on a transparent substrate and the at least one azimuth detector comprising at least two luminescent nanocrystal pixels having different emission wavelengths relative to each other. The present disclosure also concerns a light field sensor comprising the light field detector thereof and methods of fabricating the light field 10 detector.
Claims
1. A light field detector for converting a vector of an electromagnetic radiation into a chromatic output, comprising at least one azimuth detector on a transparent substrate and the at least one azimuth detector comprising at least two luminescent nanocrystal pixels having different emission wavelengths relative to each other.
2. The light field detector according to claim 1, comprising at least two said azimuth detectors oriented perpendicularly to each other.
3. The light field detector according to claim 1, comprising at least three azimuth detectors, the at least three azimuth detectors configured to cooperate to convert the vector of electromagnetic radiation into a CIE XYZ tristimulus value.
4. The light field detector according to claim 1, comprising at least three azimuth detectors, wherein the at least three azimuth detectors are oriented such that a first and second azimuth detector are parallel to each other and a third azimuth detector is substantially perpendicular to the first and second azimuth detector.
5. The light field detector according to claim 1, wherein the at least two luminescent nanocrystal pixels are parallel to each other; or wherein the at least two luminescent nanocrystal pixels is three luminescent nanocrystal pixels, wherein three luminescent nanocrystal pixels are stacked such that they form a semi-cylindrical configuration or a rectangular pyramidal configuration.
6. The light field detector according to claim 1, wherein the emission wavelengths correspond to colours red, green, or blue.
7. (canceled)
8. (canceled)
9. The light field detector according to claim 1, wherein the luminescent nanocrystals pixels comprises perovskite nanocrystals, ZnS:Cu.sup.2+/Mn.sup.2+, SrAl.sub.2O.sub.4:Eu.sup.2+/Dy.sup.3+ phosphors, upconversion nanoparticles, black phosphorus, or a combination thereof.
10. The light field detector according to claim 9, wherein the perovskite nanocrystal is CsPbX.sub.3, wherein X is selected from Cl, Br and/or I, wherein the perovskite nanocrystals are characterised by an emission wavelength of about 445 nm, about 523 nm, or about 652 nm.
11. (canceled)
12. The light field detector according to claim 1, wherein each azimuth detector is characterised by a size of about 11 m.sup.2 to about 200200 m.sup.2.
13. The light field detector according to claim 1, wherein the 3D light field detector is characterised by an angular change detection limit of less than 0.015 and/or an azimuth detector density of about 80 azimuth detectors per mm.sup.2 to about 200 azimuth detectors per mm.sup.2.
14. (canceled)
15. The light field detector according to claim 1, wherein the transparent substrate is a polymer substrate, or preferably PDMS.
16. The light field detector according to claim 1, wherein the electromagnetic radiation has a wavelength of about 0.002 nm to about 500 nm.
17. A light field sensor, comprising: a) a light field detector according to claim 1; and b) a colour charge-coupled device (CCD) electromagnetically coupled to the light field detector for converting the chromatic output into an electric signal.
18. The light field sensor according to claim 17, further comprising a computer system configured to convert the electric signal into a spatial coordinate in a three-dimensional Cartesian coordinate system.
19. The light field sensor according to claim 17, wherein the sensor is characterised by an accuracy of about 0.5 mm at a distance of about 0.5 m and/or a spatial sampling density of about 300 points/mm.sup.2 to about 600 points/mm.sup.2.
20. (canceled)
21. A method of fabricating a light field detector, comprising: a) forming or positioning at least one azimuth detector on a transparent substrate, wherein each azimuth detector comprises at least two luminescent nanocrystal pixels having different emission wavelengths relative to each other.
22. The method according to claim 21, wherein the step of forming or positioning at least one azimuth detector comprises lithographically patterning the at least two luminescent nanocrystal pixels in a silicon template and curing a polymer over the at least two luminescent nanocrystal pixels in order to form the transparent substrate.
23. The method according to claim 21, wherein the step of forming or positioning at least one azimuth detector further comprises lithographically patterning a third luminescent nanocrystal pixel in another silicon template and adhering it to the transparent substrate patterned with the at least two luminescent nanocrystal pixels.
24. The method according to claim 21, wherein each of the at least two luminescent nanocrystal pixels comprises nanocrystals dispersed in a polymer matrix; wherein the at least two luminescent nanocrystal pixels is each independently characterised by a nanocrystal density of about 0.001 mol/mL to about 0.01 mol/mL.
25. (canceled)
26. The method according to claim 21, wherein a) forming or positioning at least one azimuth detector on a transparent substrate comprises arraying a plurality of azimuth detectors on a transparent substrate such that each azimuth detector is oriented perpendicularly to a neighbouring azimuth detector, wherein each azimuth detector comprises at least two luminescent nanocrystal pixels having different emission wavelengths relative to each other.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0034] Embodiments of the present invention will now be described, by way of non-limiting example, with reference to the drawings in which:
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DETAILED DESCRIPTION
[0046] Light-field detection is a technology that captures both the intensity and the precise direction of light rays in free space. However, current light-field detection techniques either require complex microlens arrays or are limited to the ultraviolet-visible wavelength ranges. The present invention provides a scalable method based on lithographically patterned perovskite nanocrystal arrays that can determine the radiation vector of incident rays in the wavelength range from X-rays to visible light (0.002-700 nm). Multicolor-emitting perovskite nanocrystals can convert light rays from a specific direction into a pixelated color output with an angular resolution of 0.0018, which is two orders of magnitude higher than conventional angle-sensing photodetectors. 3D light-field detection and spatial positioning of light sources are possible by modifying nanocrystal arrays with specific orientations. The validity of 3D object imaging and visible light/X-ray wavefront imaging is validated by combining pixelated perovskite nanocrystal arrays with a color charge-coupled device. The ability to image light fields beyond optical wavelengths through color-contrast encoding could open up new applications from 3D phase-contrast imaging to robotics, virtual reality, tomographic biological imaging, and satellite autonomous navigation.
[0047] Inspired by the versatility of color encoding in data visualization, the inventors hypothesized that color contrast encoding could be used to visualize directions of light rays. To test the hypothesis, inorganic perovskite nanocrystals were selected as candidates because they have excellent optoelectronic properties. They also exhibit highly efficient and tunable emission with high color saturation across the visible spectrum under X-ray or visible light irradiation. A fundamental design for 3D light-field detection involves lithographical patterning of perovskite nanocrystals on a transparent substrate (
[0048] The basic unit of the light field detector or 3D light-field sensor is a single azimuth detector comprising multicolor-emitting perovskite nanocrystals. Since the absorption of light or radiation of the patterned nanocrystals changes with the incident direction of light, there is a mapping between the color of luminescence and the azimuth angle of excitation light. When incident light strikes patterned nanocrystals, the azimuth angle a between the incident light and the reference plane can be detected by measuring the color output of the basic unit (
[0049] In the three-dimensional Cartesian coordinate system, two detectors (A and B) are perpendicular to the XOY plane at coordinates (b, 0, 0) and coordinates (0, 0, 0), and a third detector (C) is arranged parallel to the XOY plane along the Y axis. Assuming that the X axis is the reference direction, the projection of the light or radiation source S onto the XOY plane is S, the angle between the line (connecting S and detector A) and the reference direction is a.sub.1, and the angle between the line (connecting S and detector B) and the reference direction is a.sub.2. The angle between the line (connecting S and the detector C) and the XOY plane is a.sub.3. a.sub.1, a.sub.2, and a.sub.3 are determined by the color of the luminescence of azimuth detectors A, B and C, respectively. Therefore, the spatial position (x, y, z) of the source S can be solved by the following formula:
[0050] Accordingly, the present invention provides a 3D light field detector for converting a vector of an electromagnetic radiation into a chromatic output, comprising at least one azimuth detector on a transparent substrate, the at least one azimuth detector comprising at least two luminescent nanocrystal pixels having different emission wavelengths relative to each other.
[0051] The light field detector may comprise at least two said azimuth detectors oriented perpendicularly to each other.
[0052] In some embodiments, the light field detector comprises at least three azimuth detectors, the at least three azimuth detectors configured to cooperate with each other to convert the vector of electromagnetic radiation into a CIE XYZ tristimulus value. The CIE color model is a mapping system that uses tristimulus (a combination of 3 color values that are close to red/green/blue) values, which are plotted on a 3D space. When these values are combined, they can reproduce any color that a human eye can perceive. In this way, a color output from the combination of the three azimuth detectors enables determination of an absolute position of a light source.
[0053] In some embodiments, the at least three azimuth detectors are oriented such that a first and second azimuth detector are parallel to each other and a third azimuth detector is substantially perpendicular to the first and second azimuth detector.
[0054] In some embodiments, the light field detector comprises an array of azimuth detectors on a transparent substrate, each azimuth detector oriented perpendicularly to a neighbouring azimuth detector; [0055] wherein each azimuth detector comprises at least two luminescent nanocrystal pixels having different emission wavelengths relative to each other.
[0056] In some embodiments, the light field detector comprises an array of azimuth detectors on a transparent substrate, wherein each azimuth detector is in a same orientation relative to an alternate azimuth detector.
[0057] In some embodiments, the at least two luminescent nanocrystal pixels are parallel to each other. In other embodiments, at least two luminescent nanocrystal pixels are arranged at an angle relative to each other. The angle may be less than 90, or less than 45.
[0058] Each luminescent nanocrystal pixel is configured to emit a wavelength of a particular colour. The at least two luminescent nanocrystal pixels are configured to emit wavelengths which are different from each other. In some embodiments, the emission wavelengths each correspond to colours of red, green, or blue. In some embodiments, the emission wavelengths correspond to at least two colours selected from red, green, or blue. Other colours can also be used.
[0059] In some embodiments, the at least two luminescent nanocrystal pixels is three luminescent nanocrystal pixels. The three luminescent nanocrystal pixels can be stacked together such that they form a semi-cylindrical configuration or a rectangular pyramidal configuration. In this regard, each luminescent nanocrystal pixel is configured such that it has a rectangular morphology or forms a sector of a cylinder.
[0060] Each luminescent nanocrystal pixel comprises a plurality of nanocrystals. Each luminescent nanocrystal pixel comprises a particular type of nanocrystals or combination thereof in order to have an emission wavelength of a specific colour. By combining luminescent nanocrystal pixels each of separate and different or different ratios of nanocrystals, the luminescent nanocrystal pixels may each emit light of a different wavelength when excited. In some embodiments, the luminescent nanocrystals pixels comprises perovskite nanocrystals, ZnS:Cu.sup.2+/Mn.sup.2+, SrAl.sub.2O.sub.4:Eu.sup.2+/Dy.sup.3+ phosphors, upconversion nanoparticles, black phosphorus, or a combination thereof. In some embodiments, the luminescent nanocrystals pixels comprises perovskite nanocrystals. In some embodiments, the luminescent nanocrystals pixels comprises isotropic nanocrystals.
[0061] In some embodiments, the perovskite nanocrystal is CsPbX.sub.3, wherein X is selected from Cl, Br and/or I. For example, the perovskite nanocrystals may be CsPbBr.sub.3 and/or CsPbCl.sub.3.
[0062] In some embodiments, the nanocrystals are characterised by a particle size of about 10 nm to about 50 nm. In other embodiments, the particle size is about 10 nm to about 40 nm, about 10 nm to about 30 nm or about 10 nm to about 20 nm. In other embodiments, the particle size is about 20 nm.
[0063] In some embodiments, the perovskite nanocrystals (and hence the luminescent nanocrystals pixels) are characterised by an emission wavelength of about 445 nm, about 523 nm, or about 652 nm. Depending on the colour selected, the wavelength can be altered.
[0064] In some embodiments, each azimuth detector is characterised by a size of about 11 m.sup.2 to about 200200 m.sup.2, or about 11 m.sup.2 to about 100100 m.sup.2. The size of the azimuth detector is an accumulation of the luminescent nanocrystal pixels.
[0065] In some embodiments, the azimuth detectors are spaced apart from each other by about 5 m to about 20 m. In other embodiments, the spacing is about 5 m to about 18 m, about 5 m to about 16 m, about 5 m to about 14 m, about 5 m to about 12 m, about 5 m to about 10 m, about 5 m to about 8 m, or about 5 m to about 7 m.
[0066] In some embodiments, the azimuth detectors are characterised by an azimuth detector density of about 80 azimuth detectors per mm.sup.2 to about 200 azimuth detectors per mm.sup.2. In other embodiments, the azimuth detector density is about 100 azimuth detectors per mm.sup.2,
[0067] In some embodiments, the 3D light field detector is characterised by an angular change detection limit of less than 0.015, or less than 0.003, or preferably about 0.0018. The angular change detection limit is the vector sensitivity.
[0068] In some embodiments, the transparent substrate is a polymer substrate, or preferably PDMS.
[0069] In some embodiments, the electromagnetic radiation has a wavelength of about 0.002 nm to about 700 nm, or about 0.002 nm to about 500 nm.
[0070] The present invention also provides a 3D light field sensor, comprising: [0071] a) a 3D light field detector as disclosed herein; and [0072] b) a colour charge-coupled device (CCD) electromagnetically coupled to the 3D light field detector for converting the chromatic output into an electric signal.
[0073] In some embodiments, the 3D light field detector is coated on the colour CCD.
[0074] The colour CCD may be SONY ICX274AL sensor with a chip size of 10 mm14 mm (horizontal by vertical), providing 24-bit RGB true colors. Alternatively, a 30-bit color display with 10-bit color depth may be used.
[0075] The CCD may have a photosensitive area of about 10 mm by about 20 mm, or about 10 mm by about 14 mm. The CCD may have a pixel size of about 1 by 1 m.sup.2 to about 5 by 5 m.sup.2, or about 2.52.5 m.sup.2.
[0076] In some embodiments, the 3D light field sensor further comprises a lenses for light collection.
[0077] In some embodiments, the 3D light field sensor further comprises a computer system or controller configured to convert the electric signal into a spatial coordinate in a three-dimensional Cartesian coordinate system. As will be understood, the controller will generally be embodied by electronic components, particularly electronic components programmed to convert the electric signal into a spatial coordinate based on the formula as mentioned herein.
[0078] In some embodiments, the sensor is characterised by an accuracy of about 0.5 mm at a distance of about 0.5 m.
[0079] In some embodiments, the sensor is characterised by a spatial sampling density of about 300 points/mm.sup.2 to about 600 points/mm.sup.2, or about 400 points/mm.sup.2.
[0080] The present invention also provides a wavefront sensor, comprising the 3D light field sensor as disclosed herein. The 3D light field sensor may be about 5 mm to about 100 mm away from a light source.
[0081] The present invention also provides a method of fabricating a 3D light field detector, comprising: [0082] a) forming or positioning at least one azimuth detector on a transparent substrate; [0083] wherein the at least one azimuth detector comprises at least two luminescent nanocrystal pixels having different emission wavelengths relative to each other.
[0084] In some embodiments, the step of forming or positioning at least one azimuth detector comprises lithographically patterning the at least two luminescent nanocrystal pixels in a silicon template and curing a polymer over the at least two luminescent nanocrystal pixels in order to form the transparent substrate.
[0085] In some embodiments, each of the at least two luminescent nanocrystal pixels comprises a plurality of nanocrystals dispersed in a polymer matrix. In some embodiments, the plurality of nanocrystals is homogenously dispersed in the polymer matrix. In some embodiments, the at least two luminescent nanocrystal pixels is each independently characterised by a nanocrystal density of about 0.001 mol/mL to about 0.01 mol/mL. In other embodiments, the nanocrystal density of about 0.002 mol/mL to about 0.01 mol/mL, about 0.003 mol/mL to about 0.01 mol/mL, about 0.004 mol/mL to about 0.01 mol/mL, about 0.004 mol/mL to about 0.009 mol/mL, about 0.004 mol/mL to about 0.008 mol/mL, about 0.004 mol/mL to about 0.007 mol/mL, or about 0.004 mol/mL to about 0.006 mol/mL.
[0086] In some embodiments, the plurality of nanocrystals is dispersed in a transparent polymer matrix. The polymer may be a silicon based polymer.
[0087] In other embodiments, the method comprises: [0088] a) forming or positioning at least three azimuth detectors on a transparent substrate such that the at least three azimuth detectors are configured to cooperate to convert the vector of electromagnetic radiation into a CIE XYZ tristimulus value; [0089] wherein the at least one azimuth detector comprises at least two luminescent nanocrystal pixels having different emission wavelengths relative to each other.
[0090] In other embodiments, the method comprises: [0091] a) arraying azimuth detectors on a transparent substrate such that each azimuth detector is oriented perpendicularly to a neighbouring azimuth detector; [0092] wherein each azimuth detector comprises at least two luminescent nanocrystal pixels having different emission wavelengths relative to each other.
[0093] In some embodiments, the step of arraying the azimuth detectors comprises lithographically patterning the at least two luminescent nanocrystal pixels in a silicon template and curing a polymer over the at least two luminescent nanocrystal pixels in order to form the transparent substrate.
[0094] In some embodiments, the step of arraying the azimuth detectors further comprises lithographically patterning a third luminescent nanocrystal pixel in another silicon template and adhering it to the transparent substrate patterned with the at least two luminescent nanocrystal pixels.
[0095] The present invention also provides a method of fabricating a 3D light field sensor, comprising electromagnetically coupling a colour charge-coupled device (CCD) to the 3D light field detector for converting the chromatic output into an electric signal.
[0096] Each azimuth detector comprising multicolor-emitting materials which converts EM rays incident from a specific direction into a unique color output. In this way, light fields can be measured without complex microlens arrays and photonic crystal processing. This is applicable to a variety of color-tunable luminescent materials, and has no wavelength and polarization dependence.
[0097] When two azimuth detectors arranged perpendicular to each other, they can realize 3D light-field sensing. In the arrangement with three azimuth detectors, correlation of the three azimuth angles a.sub.1, a.sub.2, and a.sub.3 encoded in the color outputs of the three azimuth detectors enables absolute position determination of a light source. Compared with conventional angle detectors, the azimuth detector arrays can be easily modified with specific orientations to achieve more advanced applications, such as source localization, which cannot be achieved by conventional angle detectors.
[0098] In some embodiments, an array for 3D light-field imaging detector was designed and fabricated, in which adjacent azimuthal detectors are aligned perpendicular to each other. 3D light field imaging arrays can be used for 3D imaging of objects and wavefronts. The two azimuthal detectors are perpendicular to each other, allowing each detector pixel to be multiplexed, thereby increasing the imaging resolution. Importantly, the detector arrays are fabricated on a transparent substrate film through a simple demolding process, which can be directly integrated into a color CCD to construct a light-field image senor without complicated fabrication processes.
[0099] In particular, a single azimuth detector composed of perovskite nanocrystal can enable light-field detection in the wavelength range of 0.002-500 nm with 0.0018 angular resolution. Further, a thin film fabricated with patterned perovskite nanocrystal arrays is integrated on a color CCD for 3D imaging of objects and wavefronts. With the current structure design, a vector sensitivity of 0.015 and a wavelength response range of 0.002-500 nm can be achieved, which is about 100 times and 200 times better than conventional microlens-based detection methods, respectively.
[0100] A detailed description of the workings of the invention is laid out below. In the embodiments that follows, the invention is described in relation to some conditions for consistency to showcase the present invention. However, the skilled person would understand that the invention is not limited to such.
[0101] As an example, inorganic perovskite nanocrystals (CsPbX.sub.3; X=Cl, Br, I) was synthesised. Three sets of perovskite quantum dots were selected with emissions at 445 nm, 523 nm, and 652 nm to construct a single azimuth detector. When light is incident from 0 to 360 degrees relative to the reference direction, the detected color gamut forms a large triangle on the CIE xy chromaticity diagram (
[0102] Single azimuth detectors with different color gamuts produce color plots of varying shape (
[0103] We next designed and fabricated two azimuth detectors arranged perpendicular to each other for omnidirectional light-field detection (
[0104] A direct application of the light-field sensor based on pixelated perovskite nanocrystal arrays is 3D imaging and Light Detection and Ranging (LIDAR) (
[0105] Another important application of pixelated color conversion is phase contrast imaging in the ultra-broad wavelength range from X-rays to visible light (0.002-500 nm). In phase contrast imaging with a conventional Shack-Hartmann wavefront sensor, arrays of microlenses record the angle of incidence onto a series of grid points that determine the wavefront (
[0106] The fabrication of nanocrystal light-field sensors is highly robust with high uniformity over a large area compared with microlens array fabrication. In our experiment, the spatial sampling density is 400 points/mm.sup.2, angular resolution is 0.015, and the dynamic angular range is greater than 90 degrees. In contrast, commercial Shack-Hartmann sensors (Thorlabs WFS30-5C) typically have a low sampling density of 44 points/mm.sup.2 and a small dynamic angular range of <2. The nanocrystal light-field sensor is also applicable to a wider spectral range.
[0107] In conclusion, we have presented a pixelated color conversion strategy based on perovskite nanocrystal arrays for 3D light field detection, absolute spatial positioning, 3D imaging, and visible light/X-ray phase contrast imaging. With its current design, we have achieved a vector sensitivity of 0.0018 and a wavelength response range of 0.002-700 nm, which are nearly 100 times and 200 times better than conventional microlens-based detection methods, respectively. Further improvement in angular precision is possible by integrating high-end color detectors. For example, a 30-bit color display with 10-bit color depth can yield 1.07 billion possible combinations. With advanced lithography methods and state-of-the-art processing, azimuth detector densities in excess of 104 pixels/mm.sup.2 should be achievable, which could greatly improve spatial resolution in imaging. Moreover, the pixelated color encoding strategy for light-field detection and imaging can be readily extended to optical materials beyond the perovskite nanocrystals presented here. Sn-based perovskite nanocrystals, near-infrared-responsive upconversion nanoparticles or black phosphorus with tunable bandgaps can expand angular detection to the near-infrared and even the micrometer wavelength range. In addition, compared to Shack-Hartmann sensors, light-field sensors based on nanocrystal arrays can be directly integrated into the on-chip optical systems to measure wavefronts or phase. Since azimuth detectors can only distinguish the average vector direction of incident light, not the light from multiple directions like a light-field camera, our light-field sensors measure the average vector direction of light at each pixel. As with light-field cameras, nanocrystal light-field sensors must balance between angular and spatial resolution. Scanning light-field imaging systems can be coupled with nanocrystal arrays to further improve spatial resolution. Nonetheless, the ability to map the wavefront of high-energy X-rays provides powerful solutions for optics testing and beam characterization, while opening new applications ranging from phase-contrast imaging to gravitational wave detection.
Methods
Chemicals
[0108] Cesium carbonate (Cs.sub.2CO.sub.3, 99.9%), lead (II) chloride (PbCl.sub.2, 99.99%), lead (II) bromide (PbBr.sub.2, 99.99%), lead (II) iodide (PbI.sub.2, 99.99%), oleylamine (technical grade 70%), oleic acid (technical grade 90%), 1-octadecene (technical grade 90%) and cyclohexane (chromatography grade 99.9%) were purchased from Sigma-Aldrich. A Sylgard 184 silicone elastomer kit was purchased from Dow Corning for the preparation of polydimethylsiloxane (PDMS) substrates. ZnS/CdSe phosphorus powders were purchased from Xiucai Chemical Co., Ltd. (Foshan, China).
Synthesis and Characterization
[0109] CsPbX.sub.3 (X=Cl, Br, or I) perovskite nanocrystals were synthesized according to a method described in the literature. First, cesium oleate was synthesized as a cesium precursor, and then CsPbX.sub.3 perovskite nanocrystals were synthesized using the modified hot-injection method.
[0110] Transmission electron microscopy (TEM) of the synthesized perovskite nanocrystals was performed using a FEI Tecnai G20 transmission electron microscope with an accelerating voltage of 200 kV. Under visible light or X-ray excitation, perovskite quantum dots (QDs) give off narrow and color-tunable visible emission. Photoluminescence and radioluminescence spectra were obtained using an Edinburgh FS5 fluorescence spectrophotometer (Edinburgh Instruments Ltd, UK) equipped with a miniature X-ray source (AMPEK, Inc.). An advantageous property of perovskites as detectors is their linear response to X-ray dose rate or excitation light power with coverage up to several orders of magnitude. The lowest detectable dose rate for X-ray detection was demonstrated to be 10.8-13 nGy s.sup.1, and the lowest detectable power for optical detection was 1 pW/mm.sup.2. Perovskite QDs also exhibit a very fast response (decay time, =10.4 ns) to pulsed excitation. These nanocrystals show high photostability under successive or repeated cycles of X-ray irradiation and photoexcitation.
Fabrication and Integration of 3D Light-Field Sensor Arrays
[0111] The 3D light-field sensor based on pixelated perovskite nanocrystal arrays were fabricated by a simple moulding process (
[0112] In current 3D printed molds, the size can be adjusted from tens of micrometers to several millimeters. Large-scale manufacturing is possible through repeated demolding. This method eliminates the need for complex semiconductor processes and special gases, which greatly reduces processing costs. Fabrication errors typically include random defects and alignment errors. Since the demolding process used in this work has high machining accuracy and edge defects can be controlled within 0.1%, the random defect error of the entire azimuth detector pixel is almost negligible. A layer alignment error occurs during processing, due to the need to align upper and lower layers. In cases where the image distance is much greater than a single color pixel's thickness, alignment deviation will not affect angle measurement.
Calibration of the 3D Light-Field Sensor
[0113] The 3D light-field sensor based on perovskite nanocrystal arrays was calibrated under a collimated LED light source. A motorized rotation stage (Daheng Optics, GCD-011060M), a pitch platform, and a linear stage were connected to rotate the 3D light-field sensor in and directions. The image sensor was attached to the pitch platform. The pitch platform moves in the direction, and the rotatory stage moves in the direction. A linear stage is used to compensate the off-axis movement of the image sensor when it rotates in direction. We present selected raw color images captured during the calibration process to illustrate the working principle of 3D light-field sensor (
3D Imaging Procedure
[0114] The home-built optical setup for 3D imaging consists of a light source and an optical grating to generate multiline structured light on the 3D scene to be imaged (
Spherical X-Ray Wavefront Measurement
[0115] A 3D light-field sensor was used to measure the wavefront of spherical hard X-rays (14 keV) (
Phase Contrast Imaging Procedure
[0116] In phase contrast imaging utilizing collimated UV/visible light, the object is a patterned PDMS substrate with a strip thickness of 0.6 mm. The light-field imaging sensor is placed directly behind the object to capture an image of the changed wavefront. To obtain a nearly collimated beam for X-ray phase contrast imaging, a copper-column collimator is positioned behind the radiation source. Two commercial PMMA rods of 1 mm and 2 mm in diameter are placed behind the radiation source, and the light-field imaging sensor detects the changed wavefront. Specifically, the light-field imaging sensor acquires pixelated beam angles, which characterize the phase gradient distribution. After performing median filtering and integration on the phase gradient, phase mapping can be achieved.
The Positioning Principle and Error Analysis
[0117] The photoluminescence part of the azimuth detector consists of three sets of CsPbX.sub.3 nanocrystals, which emit red, green, and blue light. Since the absorption of light or radiation of each part changes with the incident direction of light, there is a mapping between the color of luminescence and the azimuth angle of excitation light. Each azimuth detector can determine the angle a of the incident beam with respect to the reference plane, so three such azimuth detectors can be arranged to locate the spatial position of the excitation source. In the three-dimensional Cartesian coordinate system, detector A and detector B are perpendicular to the XOY plane at coordinates (b, 0, 0) and coordinates (0, 0, 0), and cylinder C is arranged parallel to the XOY plane along the Y axis. Assuming that the X axis is the reference direction, the projection of the light or radiation source S onto the XOY plane is S, the angle between the line (connecting S and detector A) and the reference direction is 1, and the angle between the line (connecting S and detector B) and the reference direction is 2. The angle between the line (connecting S and the detector C) and the XOY plane is 3. 1, 2, and 3 are determined by the color of the luminescence of azimuth detectors A, B and C, respectively. Therefore, the spatial position (x, y, z) of the source S can be solved by the following formula:
[0118] The positioning errors dx, dy and dz of the source S depend on the angular detection error d of each azimuth detector, the distance b, and the position coordinates x, y, and z of the source. The dx, dy and dz as a function of d are:
[0119] Theoretical analysis shows that dx, dy, and dz are all positively correlated with d, dx is positively correlated with b, and dy and dz are negatively correlated with b. Positioning errors are closely related to position of S.
Principle of Three-Dimensional Light-Field Detection
[0120] Two azimuth detectors arranged perpendicular to each other can perform 3D omnidirectional light-field detection. In spherical coordinates, for a beam incident from any direction (, ), detector 1 detects the angle a1 between the projection of the beam onto the YOZ plane and the Z axis, while detector 2 detects the angle a2 between the projection of the beam onto the XOZ plane and the Z axis. The relationships between a1, a2 and , are as follows:
where a1 and a2 are encoded for the color output of detectors 1 and 2, respectively. In a specific experiment, a1 and a2 are obtained from the CIE tristimulus value of the color output of detectors 1 and 2, respectively. The azimuth angle and elevation angle of the beam are then obtained from the following expressions derived from equations:
[0121] We further designed a 3D light-field image array using perovskite nanocrystals in which adjacent pixels are perpendicular to each other. For simplicity, the angle detected by detectors parallel to the x-axis is denoted by a.sub.i,j (i and j refer to the rows and columns of the nanocrystal arrays), and the angle detected by detectors parallel to the y-axis is denoted by .sub.i,j. Each of the two azimuth detectors, which are perpendicular to each other, can reconstruct the angle of the beam incident at the center of the two pixels. For example, a1,1 and 1,2 can be used to calculate the 3D angle of the beam incident at point s11, whereas 2,1 and a1,1 can be used to calculate the 3D angle of the beam incident at point s21.
Geometric Model of the 3D Imaging System
[0122] The 3D imaging scheme used was the triangulation method based on multiline structured light illumination. For simplicity, we first analyzed the situation under single-line structured light illumination (
[0123] According to the geometric relations in
where s and s1 represent the dimensions of a single pixel of the detector in the X and Y directions, respectively.
[0124] In a specific experiment, a, z, D, d, and l need to be calibrated in advance. 1 and 1 are obtained from the color output of angle detection, and then the coordinates x, y, z of object P are solved by formulae.
Parameter Selection of the 3D Imaging System.
[0125] In the 2D scheme of the designed imaging system in
[0126] According to the geometric relationship in
where f1 is the focal length of lens 1 and z is the angle between the optical axis of lens 1 and the coordinate axis OX.
[0127] The object distance l2 and the image distance l2 of lens 2 are:
where f2 is the focal length of lens 2.
[0128] The vertical magnifications of lens 1 (1), lens 2 (2), and the combined system (B) are:
[0129] Therefore, the height of images on the primary imaging plane and the detector imaging plane are:
where y.sub.l=l.sub.l tan (.sub.1.sub.2).
[0130] The angle between the light beam incident onto the primary image plane and the optical axis is:
[0131] The angle between the light beam incident onto the detector imaging plane and the optical axis is:
[0132] The goal of parameter optimization is to minimize the change of y2 with distance z and the maximum change of 0 with z. Therefore, we analyzed the relationship between y2/z and 0/z and the system parameters D, a, z, d, f1 and f2. Considering the resolution and the detectable range of distance, we set the system parameters as D=50 mm, a=90, z=78, f1=75 mm, f2=25 mm, and d=145 mm. Optimal imaging parameters are listed in Table 1.
TABLE-US-00001 TABLE 1 Optimal parameters for imaging 500 mm distance range Imaging .sub.0 .sub.0 y.sub.1 y.sub.2 parameter (degree) (degree) (mm) (mm) z = 500 mm 6.2894 28.5180 9.7266 6.9476 z = 500.1 mm 6.2905 28.5218 9.728 6.9486 z = 700 mm 7.9144 33.5093 11.6873 8.3481
[0133] When the distance z is changed by 0.1 mm, the angle 0 of the light incident on the detector changes by approximately 0.0038, and the light spot moves on the detector by approximately 1 m, which is indistinguishable for a conventional CCD with a pixel size of 3-10 m. By attaching the light-field imaging film onto the CCD, the distance change of 0.1 mm can be differentiated by angle detection. Under optimized system parameters, a distance change of 200 mm causes the spot on the detector to move by 1.4 mm. It should be noted that the selection of imaging parameters depends largely on the distance z, so the system parameters must be determined according to the distance range of the application.
Calibration of the 3D Imaging System
Calibration of the Emission Angle of Multiline Structured Light
[0134] The system uses an optical grating after a light source to generate multiline structured light and scans the object surface in a normal incidence mode. The angle between the two edge light planes of the structured light is a, the angle between each structured light plane and the XOY plane is ai, and the angle between the structured light planes is w (
[0135] Where n represents the number of the line-structured light plane.
[0136] In the actual calibration, the structured light was vertically incident on a white flat plate, OO is the optical axis of the light source, and points A, B, C, and D were the four corner points of the edge light strip on the surface. Points A, B, C, and D are the four corner points of the edge light strip after the flat plate moves a certain distance. The coordinates of A, B, C, D, A, B, C, and D are measured, and the plane equations of plane AADD and plane BCCB can be established in the Cartesian coordinate system:
[0137] Then the angle a between the two edge light planes of the structured light is:
Calibration of Homemade Camera Parameters
[0138] The conversion formula of the world coordinate system (xw, yw, zw) and the pixel coordinate system (u, v) of the CCD is:
[0139] Where s is the scale factor, K is the internal parameter matrix of the camera, R is the rotation matrix of the camera in the world coordinate system, and T is the translation matrix. The Zhang calibration method was used to determine internal parameters, external parameters, and distortion parameters of the camera. First, we printed a piece of paper with a black and white grid, and then took several images of the paper from different angles with the camera to be calibrated. Further, the camera calibration library toolbox_calib of Matlab was used to identify and process the feature points in the collected images to obtain the internal and external parameters as well as the distortion parameters of the camera.
Wavefront Detection Principle
[0140] Wavefront detection for extreme ultraviolet (EUV) light or X-rays typically uses Hartmann (e.g., Shack-Hartmann) wavefront sensing techniques in which a beam passes through a hole array (e.g., microlens array) and is projected onto a CCD camera that detects the beam sampled from each hole (e.g., microlens). The positions of individual point centroids are then measured and compared with reference positions. This enables the wavefront's local slopes to be measured at a large number of points by the following formula:
[0141] In our light-field sensor-based wavefront measurements, the local slope of the wavefront is directly obtained by the angle detectors without the need for an array of apertures or microlenses.
[0142] The wavefront's local slopes can be written according to the following expressions:
where W (x, y) represents the optical path difference and (x, y) is the spatial phase. Integration of the measured derivative function enables reconstruction of the incident beam wavefront.
[0143] It will be appreciated that many further modifications and permutations of various aspects of the described embodiments are possible. Accordingly, the described aspects are intended to embrace all such alterations, modifications, and variations that fall within the spirit and scope of the appended claims.
[0144] Throughout this specification and the claims which follow, unless the context requires otherwise, the word comprise, and variations such as comprises and comprising, will be understood to imply the inclusion of a stated integer or step or group of integers or steps but not the exclusion of any other integer or step or group of integers or steps.
[0145] Throughout this specification and the claims which follow, unless the context requires otherwise, the phrase consisting essentially of, and variations such as consists essentially of will be understood to indicate that the recited element(s) is/are essential i.e. necessary elements of the invention. The phrase allows for the presence of other non-recited elements which do not materially affect the characteristics of the invention but excludes additional unspecified elements which would affect the basic and novel characteristics of the method defined.
[0146] The reference in this specification to any prior publication (or information derived from it), or to any matter which is known, is not, and should not be taken as an acknowledgment or admission or any form of suggestion that that prior publication (or information derived from it) or known matter forms part of the common general knowledge in the field of endeavour to which this specification relates.