Method for composite flow molding
11623370 · 2023-04-11
Assignee
Inventors
- Erick DAVIDSON (Piedmont, CA, US)
- Ethan ESCOWITZ (Berkeley, CA, US)
- Sean Hennessee (San Francisco, CA, US)
- Riley REESE (Oakland, CA, US)
Cpc classification
B29C70/202
PERFORMING OPERATIONS; TRANSPORTING
B29C70/465
PERFORMING OPERATIONS; TRANSPORTING
B29C2043/3615
PERFORMING OPERATIONS; TRANSPORTING
B29C2045/025
PERFORMING OPERATIONS; TRANSPORTING
B29C45/02
PERFORMING OPERATIONS; TRANSPORTING
B29C2043/3444
PERFORMING OPERATIONS; TRANSPORTING
B29C33/0061
PERFORMING OPERATIONS; TRANSPORTING
B29C45/0046
PERFORMING OPERATIONS; TRANSPORTING
B29C70/461
PERFORMING OPERATIONS; TRANSPORTING
B29C33/10
PERFORMING OPERATIONS; TRANSPORTING
B29C43/361
PERFORMING OPERATIONS; TRANSPORTING
B29C43/58
PERFORMING OPERATIONS; TRANSPORTING
B29C70/08
PERFORMING OPERATIONS; TRANSPORTING
B29C70/48
PERFORMING OPERATIONS; TRANSPORTING
B29C2045/0089
PERFORMING OPERATIONS; TRANSPORTING
B29C70/54
PERFORMING OPERATIONS; TRANSPORTING
B29C43/34
PERFORMING OPERATIONS; TRANSPORTING
B29C2043/5808
PERFORMING OPERATIONS; TRANSPORTING
B29K2105/12
PERFORMING OPERATIONS; TRANSPORTING
International classification
B29C70/48
PERFORMING OPERATIONS; TRANSPORTING
B29C33/00
PERFORMING OPERATIONS; TRANSPORTING
B29C43/34
PERFORMING OPERATIONS; TRANSPORTING
B29C43/36
PERFORMING OPERATIONS; TRANSPORTING
B29C43/58
PERFORMING OPERATIONS; TRANSPORTING
B29C70/34
PERFORMING OPERATIONS; TRANSPORTING
B29C70/46
PERFORMING OPERATIONS; TRANSPORTING
Abstract
An apparatus for molding a part includes a plunger cavity, a plunger, and a mold cavity, wherein the plunger is oriented out-of-plane with respect to a major surface of the mold cavity, and first and second vents couples to respective first and second portions of the mold cavity. In a method, resin and fiber are forced into the mold cavity from a plunger cavity, and at least some of the fibers and resin are preferentially flowed to certain region in the mold cavity via the use of vents.
Claims
1. A method for molding, comprising: placing, in a plunger cavity that is fluidically coupled to a mold cavity, a first plurality of preforms having a first length and a second plurality of preforms having a second length, wherein: (a) a longest axis of the mold cavity, which has a third length, aligns with a direction that is out-of-plane with respect to a stroke axis of a plunger within the plunger cavity, (b) each preform in both the first plurality and the second plurality is a segment of towpreg, each preform in the first plurality therefore consisting essentially of a plurality of unidirectionally aligned fibers coated with resin and having the first length, and each preform in the second plurality consisting essentially of a plurality of unidirectionally aligned fibers coated with resin and having the second length; liquefying the resin in the first plurality of preforms; and flowing the fibers from the first plurality of preforms to and within a first feature of the mold cavity by imparting a shear force via movement of the plunger through the plunger cavity, wherein the first feature has a length that is substantially the same as the first length of the fibers from the first plurality of preforms and substantially shorter than the longest axis of the mold cavity, and wherein, within the first feature, the flowed fibers are substantially aligned with one another and substantially aligned with a longest axis of the first feature.
2. The method of claim 1 wherein placing the first plurality and second plurality of preforms in the plunger cavity further comprises aligning the first plurality of preforms with the longest axis of the first feature.
3. The method of claim 1 wherein placing the first plurality and second plurality of preforms in the plunger cavity further comprises stacking the first plurality and second plurality of preforms, wherein the first group of preforms are placed relatively lower in the stack and closer to the mold cavity than the second group of preforms.
4. The method of claim 1 wherein the second length of the fibers from the second group of preforms is substantially the same as the third length of the mold cavity.
5. The method of claim 1 wherein the first group of preforms and the second group of preforms differ from one another in a characteristic in addition to the length.
6. The method of claim 5 wherein the characteristic is selected from the group consisting of a composition of the fibers in the preforms and a fiber volume fraction of the preforms.
7. The method of claim 2 wherein placing the first plurality and second plurality of preforms in the plunger cavity further comprises aligning the second plurality of preforms in a direction other than along the longest axis of the first feature.
8. The method of claim 7 wherein placing the first plurality and second plurality of preforms in the plunger cavity further comprises aligning the second plurality of preforms with the longest axis of the mold cavity.
9. The method of claim 1 wherein a length of the plunger cavity along the stroke axis of the plunger is substantially larger than a depth of the mold cavity.
10. The method of claim 1 wherein flowing the fibers to the first feature further comprises opening a vent that is fluidically coupled to the first feature.
11. The method of claim 1 wherein prior to liquefying the resin, the first plurality of preforms are advanced, via the plunger, to the mold cavity.
12. The method of claim 1 wherein the second plurality of preforms are aligned with the stroke axis of the plunger in the plunger cavity.
13. The method of claim 1 comprising adding a preform to the mold cavity prior to actuating the plunger.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION
(18) The following terms, and their inflected forms, are defined for use in this disclosure and the appended claims as follows: “Axial direction or Axially aligned” means, for example, in the context of a plunger or plunger cavity, aligned with the stroke direction of the plunger and, in the context of a mold cavity, means aligned with the long(est) or major axis of the mold cavity. “Transverse or Transversely aligned” means, for example, in the context of a plunger or plunger cavity, orthogonal to the stroke direction of the plunger and, in the context of a mold cavity, aligned with an axis that is rotated 90 degrees, in-plane, with respect to the long(est)/major axis of the mold cavity. “Out-of-plane” means, for example, in the context of a mold cavity, aligned with an axis that is rotated out of the plane of the major surface of the mold cavity. In embodiments of the invention, the stroke axis of the plunger is out-of-plane with respect to a major surface of the mold cavity. “Fiber” means an individual strand of material. A fiber has a length that is much greater than its diameter. For use herein, fibers are classified as (i) continuous or (ii) short. Continuous fibers have a length that is about equal to to the length of a major feature of a mold in which they are placed. And, similarly, continuous fibers have a length that is about equal to that of the part in which they will reside. Short fibers have a length that is shorter than the length of a major feature of the mold in which they are placed, and typically comparable to the length of minor features of the mold, plus some additional length to enable “overlap” with other fibers, such as continuous fibers. The term “short fiber,” as used herein, is distinct from the “chopped fiber” or “cut fiber,” as those terms are typically used in the art. In the context of the present disclosure, short fiber is present in a preform and, as such, will have a defined orientation in the preform, the mold, and the final part. As used generally in the art, chopped or cut fiber has a random orientation in a mold and the final part. Additionally, as used herein, the length of “short fiber” will be based on the length of the smaller features of a mold (they will be comparable in length). In contrast, the length of chopped or cut fiber typically bears no predefined relationship to the length of any feature of a mold/part. “Stiffness” means resistance to bending, as measured by Young's modulus. “Tensile strength” means the maximum stress that a material can withstand while it is being stretched/pulled before “necking” or otherwise failing (in the case of brittle materials). “Continuous” fiber or fiber bundles means fibers/bundles having a length that is about equal to the length of a major feature of a mold in which the fiber/bundles are placed. “Tow” means a bundle of fibers, and those terms are used interchangeably herein unless otherwise specified. Tows are typically available with fibers numbering in the thousands: a 1K tow, 4K tow, 8K tow, etc. “Prepreg” means fibers that are impregnated with resin. “Towpreg” or “Prepreg Tow” means a fiber bundle (i.e., a tow) that is impregnated with resin. “Preform” means a sized, or sized and shaped portion of tow/tow-preg, wherein the cross section of the fiber bundle has an aspect ratio (width:thickness) of between about 0.25 to about 6. The term preform explicitly excludes sized/shaped (i) tape (which typically has an aspect ratio—cross section, as above—of between about 10 to about 30), (ii) sheets of fiber, and (iii) laminates. “About” or “Substantially” means +/−20% with respect to a stated figure or nominal value.
(19) Other than in the examples, or where otherwise indicated, all numbers expressing, for example, quantities of ingredients used in the specification and in the claims are to be understood as being modified in all instances by the term “about.” Accordingly, unless indicated to the contrary, the numerical parameters set forth in the following specification and attached claims are understood to be approximations that may vary depending upon the desired properties to be obtained in ways that will be understood by those skilled in the art. Generally, this means a variation of at least +/−20%.
(20) Also, it should be understood that any numerical range recited herein is intended to include all sub-ranges encompassed therein. For example, a range of “1 to 10” is intended to include all sub-ranges between (and including) the recited minimum value of about 1 and the recited maximum value of about 10, that is, having a minimum value equal to or greater than about 1 and a maximum value of equal to or less than about 10.
(21) The fiber bundles that are sized or sized and shaped to form preforms for use herein includes thousands of individual fibers, typically in multiples of a thousand (e.g., 1 k, 10 k, 24 k, etc.). Such fiber bundles are typically called “tow.” In some embodiments, the fibers in the tow are impregnated with a polymer resin; such material is referred to as “towpreg” or “prepreg tow.” Although all of the towpreg depicted in the Figures are cylindrical (i.e., have a circular cross section), they can have any suitable cross-sectional shape (e.g., oval, trilobal, polygonal, etc.).
(22) The individual fibers can have any diameter, which is typically, but not necessarily, in a range of 1 to 100 microns. Individual fibers can include an exterior coating such as, without limitation, sizing, to facilitate processing, adhesion of binder, minimize self-adhesion of fibers, or impart certain characteristics (e.g., electrical conductivity, etc.).
(23) Each individual fiber can be formed of a single material or multiple materials (such as from the materials listed below), or can itself be a composite. For example, an individual fiber can comprise a core (of a first material) that is coated with a second material, such as an electrically conductive material, an electrically insulating material, a thermally conductive material, or a thermally insulating material.
(24) In terms of composition, each individual fiber can be, for example and without limitation, carbon, glass, natural fibers, aramid, boron, metal, ceramic, polymer filaments, and others. Non-limiting examples of metal fibers include steel, titanium, tungsten, aluminum, gold, silver, alloys of any of the foregoing, and shape-memory alloys. “Ceramic” refers to all inorganic and non-metallic materials. Non-limiting examples of ceramic fiber include glass (e.g., S-glass, E-glass, AR-glass, etc.), quartz, metal oxide (e.g., alumina), aluminasilicate, calcium silicate, rock wool, boron nitride, silicon carbide, and combinations of any of the foregoing. Furthermore, carbon nanotubes can be used.
(25) Any thermoplastic can be used in conjunction with embodiments of the invention. Exemplary thermoplastic resins useful in conjunction with embodiments of the invention include, without limitation, acrylonitrile butadiene styrene (ABS), nylon, polyaryletherketones (PAEK), polybutylene terephthalate (PBT), polycarbonates (PC), and polycarbonate-ABS (PC-ABS), polyetheretherketone (PEEK), polyetherimide (PEI), polyether sulfones (PES), polyethylene (PE), polyethylene terephthalate (PET), polyphenylene sulfide (PPS), polyphenylsulfone (PPSU), polyphosphoric acid (PPA), polypropylene (PP), polysulfone (PSU), polyurethane (PU), polyvinyl chloride (PVC). An exemplary thermoset is epoxy.
(26) The equipment used in conjunction with embodiments of the present invention have some similarities to a process known as “transfer molding.”
(27) Apparatus 100 includes mold 102, mold cavity 104, transfer pot 106, sprue 108, plunger 110, heaters 112, and ejector pin 114, arranged as shown. A feed, which is usually a plastic/resin, is placed in transfer pot 106. Plunger 110 is moved downwardly into transfer pot 106, compressing the plastic in the mold. Heaters 112 heat the mold to a temperature that is sufficient to melt the plastic. The liquid plastic then flows through sprue 108 under pressure and into mold cavity 104. Sprue(s) 108 (there may be several) is typically a small cylindrical opening that leads from transfer pot 106 to mold cavity 104. After the part is formed and the mold is opened, ejector pin 114 is used to push the part out of mold cavity 104. By virtue of the structural arrangement of the apparatus 100, such as the presence of the sprues, fiber, particularly continuous fiber, is typically not used in conjunction with this transfer molding process. To the extent that the feed includes any fiber, it is usually “chopped” fiber, so that it could fit through the sprue.
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(30) In mold 210, as in many molds consistent with the present teachings: the stroke axis of the plunger is out-of-plane with respect to a major surface of the mold cavity by an amount within the range of 45 to 90 degrees; the cross-sectional area of the mouth of the plunger cavity is substantially smaller than the cross-sectional area of the mold cavity; the length of the plunger cavity along the stroke axis is substantially greater than a depth of the mold cavity.
(31) The material that is used to form the part; that is, preforms 216′, are positioned within plunger cavity 212 on a portion of mold cavity 200′; in this embodiment, on portion 202′. The embodiment shown in
(32) The number of preforms 216′ that are required for fabricating scoop 200 (or any part) is determined by matching the mass of the preforms to the mass of the fabricated scoop. In this embodiment, the length of preforms 216′ matches the width of plunger cavity 212. The preforms could be shorter, but relatively longer fibers ultimately result in better material properties for the finished part.
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(34) Furthermore, the degree of fiber overlap can be varied based on fiber length and parameters that affect the final position of the fibers in the mold cavity, such as vents. That is, sequencing the actuation of vents 207 during the stroke of the plunger 214 can provide a staged delivery of fibers.
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(36) Once again, vents (not depicted in
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(39) For very thin features, such as are present in scoop 200, it can be beneficial to use such a combination of shorter fibers and longer fibers. The shorter fibers more reliably fill any thin/small/intricate features. Meanwhile, the longer and shorter fibers intermingle and overlap, thereby coupling the thin/intricate feature to the rest of the part.
(40) For example, in scoop 200, if mold filling is an issue, fibers from shorter preforms 216′ at the bottom of the feed stack would flow first into cavity portion 206′ (the tines), and more easily fill this portion than would longer fibers from preforms 216″. Although not depicted, vents, as previously discussed, are advantageously fluidically coupled to the terminus of each of the tines (i.e., mold-cavity portion 206′). Referring now to
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(42) For example, one or more of the tines may differ in length from the other tines, or one or more of the tines may experience greater stresses during use than other of the tines. In such cases, the longer tines or tines experiencing greater stresses would benefit from relatively longer fibers, or fibers made from a relatively stronger material, or from material having a relatively higher fiber-volume fraction.
(43) To direct two (or more) groups of preforms having fibers that differ in some characteristic to different locations in a mold requires that the two (or more) groups of preforms be stacked in an appropriate order in the plunger cavity. Thus, when the plunger is actuated (to force fiber and liquefied resin into the mold cavity), and an appropriate one or more vents are actuated (to create a decrease in pressure at certain discrete regions of the mold cavity), fibers from the group of preforms lowest in the plunger cavity enter the mold cavity (along with liquefied resin) and flow to such discrete regions. After those discrete regions fill, and with the plunger still moving downwardly, and one or more different vents actuating, fiber from the next group of preforms in the stack (along with liquefied resin) enters the mold cavity and flow to fill other portions of the mold cavity that are at reduced pressure.
(44) With continuing reference to
(45) At time T.sub.1, the plunger (e.g., plunger 214,
(46) Actuation of later-opened vents (such as Vent-1 and Vent-3) can be controlled passively, using relief valves on the vents, for example. In such an embodiment, when the pressure in the mold cavity exceeds some value (as discrete regions fill while fiber and resin continue to be forced into the mold cavity), the relief valve actuates, thereby opening the initially closed vent. Alternatively, the vents can be actively controlled, such as by using position control on the plunger and controlling for volume. That is, knowing how much material is forced into the mold cavity per unit movement of the plunger, and how much material must be delivered to fill portions of the mold cavity that are to be filled first, one can determine the requisite change in position of the plunger to deliver that amount of material. Thus, once the plunger moves the determined amount, a second set of vents are actuated.
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(49) The amount of fiber and resin in the first group of preforms is sufficient to fill the tines. The second group of preforms includes the fiber and resin required to fill the rest of the mold cavity.
(50) By time T.sub.1, the resin in at least the first (lower) group of preforms is liquefied. At time T.sub.1, the plunger as well as Vent-1, Vent-2, and Vent-3 are actuated. The relatively lower pressure in the tines draws the relatively shorter fibers from the first group of preforms into the tines.
(51) At time T.sub.2, Vent-4, Vent-5, Vent-6, and Vent-7 are actuated, created low pressure regions to the sides of mold body portion 204′. The plunger continues its downward movement, forcing fiber from the second group of preforms as well as liquefied resin into the mold cavity. The portion of these longer fibers that reside in body portion 204′ tend to curve toward either of the sides thereof, crossing the portion of fibers extending from the tines. As previously discussed, the vents need not be closed when the cavity portions they control are filled since it would take a substantially increased pressure to force additional material into those regions.
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(54) As depicted in
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(56) Thus, fibers 316f′ from lower, axially-aligned preforms 316′ will preferentially fill horizontal tab portions 304′ (
(57) Preforms follow the path of least resistance, which typically means flowing along the long axis of the mold cavity and towards regions of lowest pressure. The latter parameter—pressure—can be altered through the use of strategically located vents, as previously disclosed. This technique can be used to selectively direct the flow of resin and fibers to a particular location.
(58) Thus, in the present embodiment, vents (not depicted) are situated to vent pressure at the terminus of horizontal tab portions 304′ and at the top of vertical tab portions 308′ of the mold cavity (
(59) As a consequence of vertical tabs 308, it is likely that gravity will result in resin/fiber flowing preferentially to horizontal tab portions 304′ and then, as the level of resin rises, fibers/resin will eventually flow to vertical tab portions 308′. Although some mixing will occur, fibers 316f″ from bundles 316″ will primarily end up in vertical tabs 308, aligned with the axis C-C (see
(60) Mixing between fiber orientations occurs near the middle of bracket 300, such as at location 320. This facilitates strong connections between all features of bracket 300. And overlap between fibers flowing around holes 306 in different directions, such as at location 322, results in good hoop strength for those features.
(61) Fiber bundles at other angles (i.e., not aligned with axes A-A or C-C) could also be included. In some embodiments, axially aligned preforms 316′ are made from carbon fiber towpreg and transversely aligned preforms 316″ are made from glass fiber towpreg, both incorporating the same resin. This results in vertical tabs 308 being more compliant than horizontal tabs 304. Moreover, fiber volume fraction could be varied across the stack to engineer different material properties for different portions of bracket 300.
(62) In a further embodiment, part strength is increased in select areas using a preform that is placed in mold cavity 300′ prior to flowing the preforms into the mold cavity. For example, if an amount of hoop strength is required that is greater than what is nominally expected from the methods disclosed herein (i.e., that which results from the overlap of flowing fibers coming from both sides of fastener holes 306), a helical, spiral, or circular fiber-bundle preform, such as preform 318, is placed around one or more of holes 306. The flowing fibers from the method described herein overlap and couple to preform 318 and connect it to the rest of the part during the molding process.
(63) In accordance with the present method, to fabricate scoop 200 (
(64) All fibers are weighed to check that the weight of the fiber/resin matches the expected final part weight. The total weight of the preforms can slightly exceed the expected part weight since some of the resin, and even fiber, will flow into the vents of the mold.
(65) Preforms are then stacked in the plunger cavity in the requisite order and orientation. The plunger is then placed in the plunger cavity. The entire mold, including the plunger cavity, plunger, and mold cavity are heated. In some embodiments, cartridge heaters or the like, which are inserted through holes into the mold, are used to heat the plunger, the plunger cavity, and the mold cavity. In some other embodiments, the mold is situated on a heated platen, which is used to heat the mold. For large molds, an insulating blanket can be placed around the mold to reduce radiative and convective heat losses. In most embodiments in which plural groups (different types) of preforms are used, there is no need to differentially heat the different groups of preforms. Depending on the manner in which the preforms are stacked, after mixing in the plunger cavity of different fibers from different preforms is minimal. To the extent it may, in certain applications, be desirable to melt one type of preform before another type, this can be accomplished by operating the mold cavity at a higher temperature than the plunger/plunger cavity.
(66) After heating, the plunger is pressed against the preforms, thereby compressing the fibers and resin and forcing them into the mold cavity. After an appropriate amount of time under heat and pressure in accordance with compression molding protocols, heating ceases. In some embodiments, the mold is actively cooled, such by passing air, water, steam, or oil through cooling channels. After cooling, the mold is disassembled, as necessary, to remove the composite part formed by this process.
(67) It is to be understood that the disclosure describes a few embodiments and that many variations of the invention can easily be devised by those skilled in the art after reading this disclosure and that the scope of the present invention is to be determined by the following claims.