COMPOSTABLE HIGH BARRIER PACKAGING MATERIAL

Abstract

A compostable packaging material having a high barrier to water and oxygen is provided. Such compositions can have a film layer comprising polyhydroxyalkanoate (PHA), a bonding layer, and a substrate layer. The compostable packaging material can be compostable at home or industrially as well as anaerobically digested.

Claims

1. A compostable packaging material comprising: a film layer comprising polyhydroxyalkanoate (PHA); a bonding layer; and a substrate layer; wherein the compostable packaging material has a water vapor transmission rate of from about 0.05 gm/m.sup.2/day to about 7.5 gm/m.sup.2/day at 38 C. and 90% Relative Humidity, and from about 0.001 gm/m.sup.2/day to about 2.0 gm/m.sup.2/day at 25 C. and 50% Relative Humidity, wherein the compostable packaging material is configured to be assembled into a package to contain a food product or pet product and is configured to be compostable.

2. The compostable packaging material of claim 1, wherein the compostable packaging material has an oxygen transmission rate of from about 0.1 cc/m.sup.2/day to about 15 cc/m.sup.2/day at 25 C. at 0% Relative Humidity, and of from about 0.1 cc/m.sup.2/day to about 30 cc/m.sup.2/day at 25 C. at 50% Relative Humidity.

3. The compostable packaging material of claim 1, wherein the film layer comprises a PHA sublayer, a primer sublayer, and a barrier sublayer.

4. The compostable packaging material of claim 3, wherein the barrier sublayer comprises aluminum, aluminum oxide, silicon oxide, graphene, chitin and/or chitosan, chitin and/or chitosan mixed with inorganic clays, or montmorillonite blends.

5. The compostable packaging material of claim 1, wherein the film layer has a thickness of less than about 50 m.

6. The compostable packaging material of claim 1, wherein the substrate layer comprises cellulose acetate, PHA, paper, a pulp, or a board material.

7. The compostable packaging material of claim 6, wherein the substrate layer is PHA having a thickness of from about 5 m to about 90 m.

8. The compostable packaging material of claim 6, wherein the substrate layer is paper having a basis weight of from about 18 gsm to about 600 gsm.

9. The compostable packaging material of claim 6, wherein the substrate layer is a board or pulp having a basis weight of from about 10 gsm to about 1000 gsm.

10. The compostable packaging material of claim 1, wherein the bonding layer is an adhesive layer.

11. The compostable packaging material of claim 10, wherein the adhesive layer has a basis weight of from about 0.1 gsm to about 10 gsm.

12. A compostable package, comprising: a housing configured to contain food therein, the housing including a compostable packaging material comprising: a film layer comprising polyhydroxyalkanoate, a bonding layer, and a substrate layer, wherein the compostable packaging material has a water vapor transmission rate of from about 0.05 gm/m.sup.2/day to about 7.5 gm/m.sup.2/day at 38 C. and 90% Relative Humidity, and from about 0.001 gm/m.sup.2/day to about 2.0 gm/m.sup.2/day at 25 C. and 50% Relative Humidity.

13. The compostable package of claim 12, wherein the compostable packaging material has an oxygen transmission rate of from about 0.1 cc/m.sup.2/day to about 15 cc/m.sup.2/day at 25 C. at 0% Relative Humidity, and of from about 0.1 cc/m.sup.2/day to about 30 cc/m.sup.2/day at 25 C. at 50% Relative Humidity.

14. The compostable package of claim 12, wherein the film layer comprises a PHA sublayer, a primer sublayer, and a barrier sublayer.

15. The compostable packaging material of claim 12, wherein the substrate layer comprises cellulose acetate, PHA, paper, a pulp, or a board material.

16. The compostable package of claim 15, wherein the bonding layer is an adhesive layer with a basis weight of from about 0.1 gsm to about 10 gsm.

17. The compostable package of claim 12, further comprising a food product or a pet product therein.

18. A method of making a compostable package material, comprising: coating polyhydroxyalkanoate (PHA) with a primer sublayer and a barrier sublayer to form a film layer, processing the coated film with a bonding layer to create an intermediate product; and coupling the intermediate product with a substrate layer to create a compostable packaging material, wherein the substrate layer includes at least one of cellulose acetate, PHA, paper, a pulp, or a board, and wherein the compostable packaging material has a water vapor transmission rate of from about 0.05 gm/m.sup.2/day to about 7.5 gm/m.sup.2/day at 38 C. and 90% Relative Humidity, and from about 0.001 gm/m.sup.2/day to about 2.0 gm/m.sup.2/day at 25 C. and 50% Relative Humidity.

19. The method of claim 18, further comprising forming the compostable packaging material into a package.

20. The method of claim 18, wherein the compostable packaging material has an oxygen transmission rate of from about 0.1 cc/m.sup.2/day to about 15 cc/m.sup.2/day at 25 C. at 0% Relative Humidity, and of from about 0.1 cc/m.sup.2/day to about 30 cc/m.sup.2/day at 25 C. at 50% Relative Humidity.

Description

5. BRIEF DESCRIPTION OF THE DRAWINGS

[0021] The subject matter of the application will be more readily understood from the following detailed description when read in conjunction with the accompanying drawings, in which:

[0022] FIG. 1 provides a cross-sectional view of the compostable packaging material layers;

[0023] FIG. 2 provides a flow chart of a manufacturing method to create the compostable packaging material;

[0024] FIG. 3 shows a package having compostable packaging material according to the disclosed subject matter; and

[0025] FIG. 4 shows a blank having compostable packaging material according to the disclosed subject matter.

6. DETAILED DESCRIPTION

[0026] Compostable packaging material, packaging, and methods of making the same are provided. Such compositions advantageously have a high barrier, are recyclable, and are compostable. These and other aspects of the disclosed subject matter are discussed in more detail below.

[0027] For clarity and not by way of limitation, this detailed description is divided into the following sub-portions: [0028] 6.1 Definitions; [0029] 6.2 Compostable Packaging Materials; [0030] 6.3 Compostable Packaging Material Properties; and [0031] 6.4 Packaging and Consumer Products.

6.1. Definitions

[0032] The terms used in this specification generally have their ordinary meanings in the art, within the context of this subject matter, and in the specific context where each term is used. Certain terms are defined below to provide additional guidance in describing the compositions and methods of the disclosed subject matter and how to make and use them.

[0033] As used in the specification and the appended claims, the singular forms a, an, and the include plural referents unless the context clearly dictates otherwise. Thus, for example, reference to a compound includes mixtures of compounds.

[0034] The term about or approximately means within an acceptable error range for the particular value as determined by one of ordinary skill in the art, which will depend in part on how the value is measured or determined, i.e., the limitations of the measurement system. For example, about can mean within three or more than three standard deviations, per the practice in the art. Alternatively, about can mean a range of up to 20%, preferably up to 10%, more preferably up to 5%, and more preferably still up to 1% of a given value. Also, particularly with respect to systems or processes, the term can mean within an order of magnitude, preferably within five-fold, and more preferably within two-fold, of a value.

[0035] As used herein, the terms comprises, comprising, or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but can include other elements not expressly listed or inherent to such process, method, article, or apparatus.

[0036] In the detailed description herein, references to embodiment, an embodiment, one embodiment, in various embodiments, etc., indicate that the embodiment(s) described can include a particular feature, structure, or characteristic, but every embodiment might not necessarily include the particular feature, structure, or characteristic. Moreover, such phrases are not necessarily referring to the same embodiment. Further, when a particular feature, structure, or characteristic is described in connection with an embodiment, it is submitted that it is within the knowledge of one skilled in the art to affect such feature, structure, or characteristic in connection with other embodiments whether or not explicitly described. After reading the description, it will be apparent to one skilled in the relevant art(s) how to implement the disclosure in alternative embodiments.

[0037] The terms biodegradable packaging and compostable packaging refer to packaging compositions that are biodegradable, or compostable. Such packaging can be biodegradable or compostable at home or industrially and/or anaerobically digestible.

[0038] The terms barrier, gas barrier property, barrier property, or barrier performance relate to the barrier provided by the compostable packing material in limiting oxygen and/or water to transmit therethrough over a period of time and is measured by way of an oxygen transmission rate and a water vapor transmission rate, respectively.

[0039] As used herein, the term food product refers to food products for human consumption or non-human consumption. Non-human food products can include animal food products, and more specifically, to pet food products. Pet food products described herein can be any pet food product known in the art. Such pet food products can include, but are not limited to daily feed, kibble, treats, and/or supplements.

[0040] As used herein, the term pet product relates to products for pets including but not limited to chew toys for pets or other non-edible pet products.

6.2. Compostable Packaging Materials

[0041] The presently disclosed subject matter provides for recyclable and compostable packaging material that has a high barrier to oxygen and water vapor transmission. The compostable packaging material can include (i) a film layer comprising polyhydroxyalkanoate (PHA), (ii) a bonding layer, and (iii) a substrate layer. Each of these layers is discussed in further detail below.

6.2.1. Film Layer

[0042] The compostable packaging material comprises a film layer, which is an interior layer of the overall packaging material. The film layer can comprise a single sublayer of PHA. Alternatively, the film layer can comprise three sublayers, including a PHA sublayer, a primer sublayer, and a barrier sublayer.

[0043] Polyhydroxyalkanoate (PHA) is a biodegradable polymer which can be produced using a variety of fungi, bacteria and archaebacteria. PHA, which is a linear polyester, has the following structure:

##STR00001##

where R is a linear or branched alkyl group. When R is three to five carbons in length the PHA is a short chain length PHA, when R is six to fourteen carbons in length the PHA is a medium chain length PHA, and when R is greater than fourteen carbons in length the PHA is a long chain length PHA. The chain length can influence properties such as tensile strength and glass transition temperature. (Sehgal, R. et al. 3 Biotech. 10(12):549.). Often, PHA co-polymers are used, where a mixture of various side chain lengths is in the same polymer backbone. These biodegradable polymers are readily compostable in the presence of bacteria, providing non-toxic products such as water and biomass. (Acharjee, S. A., et al. Water Air Soil Pollut. 234(1):21.). Thus, PHA can be applied as a resin layer for use in the film layer. In the present application, the PHA layer can comprise PHA alone, or a blend of PHA and one or more other compostable polymers, including but not limited to poly(lactic acid) (PLA), poly(butylene succinate) (PBS), poly(butylene adipate-co-terephthalate) (PBAT), and poly(glycolic acid) (PGA). In certain embodiments, the amount of PHA is at least about 50% of the total amount of the PHA layer. In certain embodiments, the PHA layer can be used alone or in combination with a primer sublayer and a barrier sublayer.

[0044] The primer sublayer, when present, acts as a smoothing layer between the PHA sublayer and barrier sublayer. Such primer materials are known in the art, including, but not limited to, poly(vinyl alcohol) (PVOH), ethylene vinyl alcohol (EVOH), polyamides, polyurethanes, and acrylic polymers.

[0045] Any suitable barrier can be used as the barrier sublayer. For example, the barrier can be aluminum, aluminum oxide (AlOx or Al.sub.2O.sub.3), silicon oxide (SiOx or SiO.sub.2), graphene, chitin and/or chitosan, chitin and/or chitosan mixed with inorganic clays, or montmorillonite blends. In particular embodiments, the barrier is aluminum. When the barrier sublayer is aluminum, the film layer is metalized PHA. When the barrier sublayer is aluminum oxide, the film layer is AlOx PHA. When the barrier sublayer is silicon oxide, the film layer is SiOx PHA.

[0046] The barrier sublayer can be adhered to the primer sublayer and PHA sublayer by any suitable means to form the film layer. In certain embodiments, the barrier sublayer is adhered to the primer sublayer by vacuum metallization.

[0047] In a particular embodiment, the film layer can comprise PHA. When used alone, the PHA layer can have a thickness of from about 6 m to about 60 m, from about 8 m to about 40 m, or from about 10 m to about 30 m.

[0048] In an alternative embodiment, the film layer can comprise a PHA sublayer, a primer sublayer, and a barrier sublayer. In these embodiments, the PHA sublayer can have a thickness of from about 6 m to about 60 m, from about 8 m to about 40 m, or from about 10 m to about 30 m. The primer sublayer can have a thickness of from about 0.00001 m to about 12 m, from about 0.00001 m to about 7 m, from about 0.00001 m to about 5 m, from about 0.00001 m to about 2 m, or from about 0.1 m to about 2 m. The barrier sublayer can have a thickness of greater than about 0.5 nm, from about 0.5 nm to about 10 nm, from about 1 nm to about 7 nm, or from about 3 nm to about 5 nm.

[0049] When the film layer comprises a PHA sublayer, a primer sublayer, and a barrier sublayer, the overall film layer has a thickness of from about 0.01 nm to about 20 m, from about 0.1 nm to about 15 m, from about 0.5 nm to about 10 m, or from about 1 nm to about 5 m. In alternative embodiments, when the film layer comprises a PHA sublayer, a primer sublayer, and a barrier sublayer, the overall film layer has a thickness of less than about 50 m, less than about 40 m, less than about 20 m, or less than about 10 m.

6.2.2. Bonding Layer

[0050] In addition to the film layer, the compostable packaging material can also include a bonding layer. The bonding layer can serve to adhere or bond together the film layer to the substrate layer. In certain embodiments, the bonding layer can include an adhesive material. In an alternative embodiment, the bonding layer can include a material that can be heated to assist with thermal bonding of the layers. Alternatively, the bonding layer can be a wet layer comprising a solvent. Alternatively, the bonding layer can be a water-based solvent.

[0051] In alternative embodiments, a bonding layer does not need to be present, where the layers of the compostable packaging material can bound by alternative heat (dry), wet (solvent free, solvent, or water based), or extrusion conditions.

[0052] When the bonding layer is an adhesive layer, any suitable adhesive that is water-based, solvent-based, or solvent-less can be used. A water-based adhesive can include Epotal P100 ECO (BASF), ST6093 (SciTech), or 993-1148 (Sun Chemical), a solvent-based adhesive can include PS255 ECO (Morchem), Adcole BL1001 (Dow), or BE-A 910 (Henkel), and a solvent-less, or dry, adhesive can include LA8195/LA7394 (Henkel) or SFC 100/HAC306 (Sun Chemical). In certain embodiments, the adhesive is a laminating adhesive.

[0053] When an adhesive layer is provided, the adhesive layer can be applied between the film layer and the substrate layer to provide a suitable coating for the substrate to be bonded to the film layer. An adhesive layer comprises an adhesive in a basis weight of from about 0.1 gsm to about 10 gsm, from about 0.1 gsm to about 5 gsm, from about 0.2 gsm to about 10 gsm, or from about 0.3 gsm to about 5 gsm.

6.2.3. Substrate Layer

[0054] In addition to a film layer and a bonding layer, the compostable packaging material can also include a substrate layer. The substrate layer is bonded to the film layer, either with the use of an intermediate bonding layer, or the substrate layer can be directly bonded to the film layer.

[0055] Any suitable substrate can be used as the substrate layer. In certain embodiments, the substrate is cellulose acetate, PHA, paper, pulp, or a board material. A pulp or board material can include, but is not limited to, chemi-thermo mechanical pulp, solid bleached sulfate board, folding box board, thermo-mechanical pulp, or solid unbleached sulfate board.

[0056] In particular embodiments, when the substrate is PHA, the substrate layer can have a thickness of at least about 1 m, at least about 5 m, at least about 8 m, or at least about 12 m. In alternative embodiments, when the substrate is PHA, the substrate layer can have a thickness of from about 5 m to about 90 m, from about 10 m to about 80 m, from about 12 m to about 70 m, or from about 12 m to about 40 m.

[0057] In particular embodiments, when the substrate is paper, the substrate layer can have a basis weight of at least about 18 gsm, at least about 20 gsm, or at least about 25 gsm. In alternative embodiments, when the substrate is paper, the substrate layer can have a basis weight of from about 18 gsm to about 600 gsm, from about 20 gsm to about 550 gsm, from about 25 gsm to about 100 gsm, from about 25 gsm to about 250 gsm, from about 250 gsm to about 500 gsm, or from about 25 gsm to about 500 gsm.

[0058] In particular embodiments, when the substrate is a board or pulp, the substrate layer can have a basis weight of from about 10 gsm to about 1000 gsm, from about 50 gsm to about 750 gsm, or from about 100 gsm to about 500 gsm.

6.2.4. Additional Components

[0059] The compostable packaging material can further include additional components. Any suitable additional component can be used. For example, additional components can include but are not limited to compostable ink, over print varnish, anti-scuff coatings, cold seal adhesives, cold seal release coatings, or pressure sensitive adhesives.

6.2.5. Compostable Packaging Compositions

[0060] The compostable packaging material of the present disclosure can at least include a film layer, a bonding layer, and a substrate layer. FIG. 1 illustrates a cross-section of the compostable packaging material according to an embodiment of the disclosed subject matter. The compostable packaging material 100 contains a film layer 200, a bonding layer 300, and a substrate layer 400 as shown in FIG. 1.

[0061] In particular embodiments, the compostable packaging material can comprise non-compostable material. The non-compostable material can be one material or a mixture of suitable non-compostable materials. Each individual non-compostable material is present in an amount of greater than about 1 wt. % of the compostable packaging material. The total non-compostable materials present in the compostable packaging material is less than about 5 wt. %.

[0062] In certain embodiments, the compostable packaging material comprises a film layer of metalized PHA, a bonding layer of water-based adhesive, and a substrate layer of paper. In certain embodiments, the compostable packaging material comprises a film layer of metalized PHA, a bonding layer of a water-based adhesive, and a substrate layer of PHA. In certain embodiments, the compostable packaging material comprises a film layer of metalized PHA, a bonding layer of a water-based adhesive, and a substrate layer of a board or pulp. In certain embodiments, the compostable packaging material comprises a film layer of metalized PHA, a bonding layer of a water-based adhesive, and a substrate layer of cellulose acetate.

[0063] In certain embodiments, the compostable packaging material comprises a film layer of metalized PHA, a bonding layer of a solvent-based adhesive, and a substrate layer of paper. In certain embodiments, the compostable packaging material comprises a film layer of metalized PHA, a bonding layer of a solvent-based adhesive, and a substrate layer of PHA. In certain embodiments, the compostable packaging material comprises a film layer of metalized PHA, a bonding layer of a solvent-based adhesive, and a substrate layer of a board or pulp. In certain embodiments, the compostable packaging material comprises a film layer of metalized PHA, a bonding layer of a solvent-based adhesive, and a substrate layer of cellulose acetate.

[0064] In certain embodiments, the compostable packaging material comprises a film layer of metalized PHA, a bonding layer of a solvent-free adhesive, and a substrate layer of paper. In certain embodiments, the compostable packaging material comprises a film layer of metalized PHA, a bonding layer of a solvent-free adhesive, and a substrate layer of PHA. In certain embodiments, the compostable packaging material comprises a film layer of metalized PHA, a bonding layer of a solvent-free adhesive, and a substrate layer of a board or pulp. In certain embodiments, the compostable packaging material comprises a film layer of metalized PHA, a bonding layer of a solvent-free adhesive, and a substrate layer of cellulose acetate.

[0065] In certain embodiments, the compostable packaging material comprises a film layer of AlOx PHA, a bonding layer of a water-based adhesive, and a substrate layer of paper. In certain embodiments, the compostable packaging material comprises a film layer of AlOx PHA, a bonding layer of a water-based adhesive, and a substrate layer of PHA. In certain embodiments, the compostable packaging material comprises a film layer of AlOx PHA, a bonding layer of a water-based adhesive, and a substrate layer of a board or pulp. In certain embodiments, the compostable packaging material comprises a film layer of AlOx PHA, a bonding layer of a water-based adhesive, and a substrate layer of cellulose acetate.

[0066] In certain embodiments, the compostable packaging material comprises a film layer of AlOx PHA, a bonding layer of a solvent-based adhesive, and a substrate layer of paper. In certain embodiments, the compostable packaging material comprises a film layer of AlOx PHA, a bonding layer of a solvent-based adhesive, and a substrate layer of PHA. In certain embodiments, the compostable packaging material comprises a film layer of AlOx PHA, a bonding layer of a solvent-based adhesive, and a substrate layer of a board or pulp. In certain embodiments, the compostable packaging material comprises a film layer of AlOx PHA, a bonding layer of a solvent-based adhesive, and a substrate layer of cellulose acetate.

[0067] In certain embodiments, the compostable packaging material comprises a film layer of AlOx PHA, a bonding layer of a solvent-free adhesive, and a substrate layer of paper. In certain embodiments, the compostable packaging material comprises a film layer of AlOx PHA, a bonding layer of a solvent-free adhesive, and a substrate layer of PHA. In certain embodiments, the compostable packaging material comprises a film layer of AlOx PHA, a bonding layer of a solvent-free adhesive, and a substrate layer of a board or pulp. In certain embodiments, the compostable packaging material comprises a film layer of AlOx PHA, a bonding layer of a solvent-free adhesive, and a substrate layer of cellulose acetate.

[0068] In certain embodiments, the compostable packaging material comprises a film layer of SiOx PHA, a bonding layer of a water-based adhesive, and a substrate layer of paper. In certain embodiments, the compostable packaging material comprises a film layer of SiOx PHA, a bonding layer of a water-based adhesive, and a substrate layer of PHA. In certain embodiments, the compostable packaging material comprises a film layer of SiOx PHA, a bonding layer of a water-based adhesive, and a substrate layer of a board or pulp. In certain embodiments, the compostable packaging material comprises a film layer of SiOx PHA, a bonding layer of a water-based adhesive, and a substrate layer of cellulose acetate.

[0069] In certain embodiments, the compostable packaging material comprises a film layer of SiOx PHA, a bonding layer of a solvent-based adhesive, and a substrate layer of paper. In certain embodiments, the compostable packaging material comprises a film layer of SiOx PHA, a bonding layer of a solvent-based adhesive, and a substrate layer of PHA. In certain embodiments, the compostable packaging material comprises a film layer of SiOx PHA, a bonding layer of a solvent-based adhesive, and a substrate layer of a board or pulp. In certain embodiments, the compostable packaging material comprises a film layer of SiOx PHA, a bonding layer of a solvent-based adhesive, and a substrate layer of cellulose acetate.

[0070] In certain embodiments, the compostable packaging material comprises a film layer of SiOx PHA, a bonding layer of a solvent-free adhesive, and a substrate layer of paper. In certain embodiments, the compostable packaging material comprises a film layer of SiOx PHA, a bonding layer of a solvent-free adhesive, and a substrate layer of PHA. In certain embodiments, the compostable packaging material comprises a film layer of SiOx PHA, a bonding layer of a solvent-free adhesive, and a substrate layer of a board or pulp. In certain embodiments, the compostable packaging material comprises a film layer of SiOx PHA, a bonding layer of a solvent-free adhesive, and a substrate layer of cellulose acetate.

[0071] The compostable packaging material of the present disclosure can be manufactured using any suitable manufacturing method. Advantageously, the compostable packaging material can be manufactured using existing methods of manufacturing packaging. In certain embodiments, the compostable packaging material composition can be blown into a desired compostable packaging. In particular embodiments, the compostable packaging material composition can be extruded into a desired compostable packaging.

[0072] The compostable packaging material can be manufactured in different steps to create the monolithic material. As provided in FIG. 2 in certain embodiments, the compostable package is manufactured by coating polyhydroxyalkanoate (PHA) 110 with a primer sublayer and a barrier sublayer to create a film layer 120, processing the film layer with bonding layer to create an intermediate product 130, and coupling the intermediate product with a substrate layer to create a compostable packaging material 140. The material can then be formed into a compostable package 150 with any desired specifications.

6.3. Compostable Packaging Material Properties

[0073] The compostable packaging material of the present disclosure will have specific mechanical and thermal properties. These properties include an oxygen transmission rate, water vapor transfer rate, coefficient of friction, lamination bond strength, and tensile strength all within predetermined acceptable ranges.

6.3.1. Oxygen Transmission Rate

[0074] As used herein, the oxygen transmission rate relates to a measurement of the amount of oxygen gas that passes through the compostable packaging material at a controlled temperature and humidity. The oxygen transmission rate of the present disclosure is measured at 25 C. and 0% Relative Humidity (RH) and at 25 C. and 50% RH based on the ASTM D-3985 method.

[0075] In certain embodiments, the, the compostable packaging material of the present disclosure has an oxygen transmission rate at 25 C. and 0% RH of from about 0.10 cc/m.sup.2/day to about 15 cc/m.sup.2/day, from about 0.20 cc/m.sup.2/day to about 12 cc/m.sup.2/day, or from about 0.30 cc/m.sup.2/day to about 10 cc/m.sup.2/day.

[0076] In alternative embodiments, the, the compostable packaging material of the present disclosure has an oxygen transmission rate at 25 C. and 50% RH of from about 0.10 cc/m.sup.2/day to about 30 cc/m.sup.2/day, from about 0.20 cc/m.sup.2/day to about 10 cc/m.sup.2/day, or from about 0.25 cc/m.sup.2/day to about 8 cc/m.sup.2/day.

6.3.2. Water Vapor Transmission Rate

[0077] As used herein, the water transmission rate relates to a measurement of the amount of water vapor that passes through the compostable packaging material at a controlled temperature and humidity. Water vapor transmission rate of the present disclosure is measured at 38 C. and 90% RH, 25 C. and 50% RH, and 35 C. and 85% RH using the ASTM F-1249 method.

[0078] In certain embodiments, the compostable packaging material of the present disclosure has an water vapor transmission rate at 38 C. and 90% RH of from about 0.05 gm/m.sup.2/day to about 7.5 gm/m.sup.2/day, from about 0.1 gm/m.sup.2/day to about 5.0 gm/m.sup.2/day, or from about 0.15 gm/m.sup.2/day to about 3.0 gm/m.sup.2/day.

[0079] In alternative embodiments, the compostable packaging material of the present disclosure has a water vapor transmission rate at 25 C. and 50% RH of from about 0.001 gm/m.sup.2/day to about 2.0 gm/m.sup.2/day, from about 0.005 gm/m.sup.2/day to about 1.0 gm/m.sup.2/day, or from about 0.01 gm/m.sup.2/day to about 0.5 gm/m.sup.2/day.

[0080] In alternative embodiments, the compostable packaging material of the present disclosure has a water vapor transmission rate at 35 C. and 85% RH of from about 0.01 gm/m.sup.2/day to about 1.5 gm/m.sup.2/day, or from about 0.05 gm/m.sup.2/day to about 1.2 gm/m.sup.2/day.

6.3.3. Coefficient of Friction

[0081] As used herein, the coefficient of friction (COF) relates to a measurement of friction between the compostable packaging material. Both the inside-to-inside and outside-to-outside COF of the present disclosure is measured using the ASTM D1894 method.

[0082] In certain embodiments, the static inside-to-inside COF of the compostable packaging material is from about 0.05 to about 1, from about 0.1 to about 0.75, or from about 0.2 to about 0.5. In particular embodiments, the kinetic inside-to-inside COF is from about 0.05 to about 0.75, from about 0.1, to about 0.5, or from about 0.2 to about 0.45.

[0083] In certain embodiments, the static outside-to-outside COF of the compostable packaging material is from about 0.05 to about 1, from about 0.1 to about 0.75, or from about 0.2 to about 0.5. In particular embodiments, the kinetic outside-to-outside COF is from about 0.05 to about 0.75, from about 0.1, to about 0.5, or from about 0.2 to about 0.45.

6.3.4. Lamination Bond Strength

[0084] As used herein, the lamination bond strength relates to a measurement of the force required to peel or remove a laminate from a substrate. The lamination bond strength of the present disclosure is measured based on the ASTM F-1306 method.

[0085] In certain embodiments, the lamination bond strength of the compostable packaging material is from about 5 N to about 15 N, or from about 7 N to about 13 N, or from about 9 N to about 11 N.

6.3.5. Tensile Strength and Elongation

[0086] As used herein, tensile strength and elongation percent are a measure of the amount of stress that can be applied before the material breaks. The tensile strength and elongation percent cut in both the machine direction and cross direction of the compostable packaging material is measured using a modified ASTM D-882 method.

[0087] In particular embodiments, the compostable packaging of the present disclosure has a machine direction tensile strength of from about 1,000 lb/in.sup.2 to about 50,000 lb/in.sup.2, from about 5,000 lb/in.sup.2 to about 25,000 lb/in.sup.2, or from about 8,000 lb/in.sup.2 to about 10,000 lb/in.sup.2, or alternatively, from about 10 N/mm.sup.2 to about 500 N/mm.sup.2, from about 25 N/mm.sup.2 to about 250 N/mm.sup.2, from about 40 N/mm.sup.2 to about 100 N/mm.sup.2, or from about 50 N/mm.sup.2 to about 75 N/mm.sup.2. In certain embodiments, the compostable packaging material has a machine direction elongation percent of from about 1% to about 150%, from about 10% to about 125%, from about 20% to about 40%, or from about 70% to about 100%.

[0088] In particular embodiments, the compostable packaging material of the present disclosure has a cross direction tensile strength of from about 1,000 lb/in.sup.2 to about 50,000 lb/in.sup.2, from about 4,000 lb/in.sup.2 to about 20,000 lb/in.sup.2, or from about 6,000 lb/in.sup.2 to about 9,000 lb/in.sup.2, or alternatively, from about 10 N/mm.sup.2 to about 250 N/mm.sup.2, from about 20 N/mm.sup.2 to about 100 N/mm.sup.2, or from about 30 N/mm.sup.2 to about 60 N/mm.sup.2. In certain embodiments, the compostable packaging material has a machine direction elongation percent of from about 1% to about 200%, from about 10% to about 175%, from about 20% to about 40%, or from about 100% to about 150%.

[0089] In addition, the compostable packaging material is home compostable or industrially compostable. In certain embodiments, the compostable packaging material is anaerobically digestible. In particular embodiments, the compostable packaging material is recyclable.

6.4. Consumer Products

[0090] The compostable packaging material of the present disclosure can be used to create packaging for any suitable consumer product. The consumer product can be a food product or a pet product. Non-limiting examples of a food product or a pet product include granola or protein bars, confections, dried fruit, bakery items (e.g., brownies, cookies), snack foods, coffee, tea, pet treats, pet kibble, and/or pet chew toys. The compostable packaging material can be used to form a blank or a box to form a package for a suitable consumer product.

[0091] FIG. 3 provides a compostable package material provided as a blank. The blank can be manipulated to form a box, such as the box of FIG. 4. The blank has zones corresponding to the different parts of the box that can interact together to form a package, such as a box. The blank includes a base 501 that is flanked by two sides 600 and 700, the latter also being flanked by the upper part 800. The base 500 and the side 700 and the top 800 are provided with flaps 510 and 520, 710 and 720, and 810 and 820, respectively. These flaps can be adhesively bonded to one another to form the box, the flaps 510, 710, and 810, on the one hand, and 520, 720, and 820, on the other, thus forming the third and fourth sides 900 and 1000, respectively. The box comprising the compostable packaging comprises a housing configured to contain food therein, the housing including a compostable packaging material comprising a film layer, a bonding layer, and a substrate layer, wherein the compostable packaging material has an oxygen transmission rate of from about 0.1 cc/m.sup.2/day to about 15 cc/m.sup.2/day at 25 C. at 0% Relative Humidity, and of from about 0.1 cc/m.sup.2/day to about 30 cc/m.sup.2/day at 25 C. at 50% Relative Humidity, and/or a water vapor transmission rate of from about 0.05 gm/m.sup.2/day to about 7.5 gm/m.sup.2/day at 38 C. and 90% RH, and of from about 0.001 gm/m.sup.2/day to about 2.0 gm/m.sup.2/day at 25 C. and 50% RH.

7. EXAMPLES

[0092] The following examples are merely illustrative of the presently disclosed subject matter and they should not be considered as limiting the scope of the subject matter in any way.

[0093] The properties of various compostable packaging materials were measured, as described below. In Example 1, an unprinted compostable packaging material having a film layer of metalized PHA, and a substrate layer of cellulose acetate was studied. In Example 2, has a film compostable packaging that has text printing and logos thereon and comprising a film layer of metalized PHA and a substrate layer of cellulose acetate was studied. In Example 3, a compostable packaging material that has text printing and logos thereon and comprising a film layer of metalized PHA and a substrate layer of PHA was studied. In Example 4, an unprinted compostable packaging material having a film layer of metallized PHA, and a substrate layer of paper was studied.

Example 1

[0094] In Example 1, multiple samples of an unprinted compostable packaging material having a film layer of metalized PHA, and a substrate layer of cellulose acetate were tested, as shown in Tables 1-9. The testing included a review of each sample's coefficient of friction, oxygen transmission rate, water vapor transition rate, penetration tests, and various tensile strengths.

[0095] The coefficient of friction is measured with a 200 g sled moving 6 inches per minute using the ASTM D1894 method. Both the inside-to-inside and outside-to-outside coefficient of friction was measured. The results are shown in Table 1.

TABLE-US-00001 TABLE 1 Coefficient of Friction Measurements. Inside-Inside Coefficient of Outside-Outside Coefficient of Friction Friction Sample Static COF Kinetic COF Static COF Kinetic COF 1 0.34 0.28 0.44 0.34 2 0.48 0.35 0.36 0.24 3 0.41 0.37 0.43 0.24 4 0.32 0.4 0.45 0.26 5 0.45 0.35 0.39 0.25 Avg 0.40 0.35 0.41 0.27 Std Dev 0.07 0.04 0.04 0.04 Min 0.32 0.28 0.36 0.24 Max 0.48 0.40 0.45 0.34

[0096] As shown in the data above in Table 1, the average inside-inside static coefficient of friction is 0.40 with a standard deviation of 0.07 and the average inside-inside kinetic coefficient of friction is 0.35 with a standard deviation of 0.04.

[0097] As shown in the data above in Table 1, the average outside-outside static coefficient of friction is 0.41 with a standard deviation of 0.04 and the average outside-outside kinetic coefficient of friction is 0.27 with a standard deviation of 0.04.

[0098] The oxygen transmission rate was tested in a MOCON oxygen transmission rate unit at 25 C. at 0% relative humidity (RH) and 25 C. at 50% RH until transmission equilibrium was achieved using a method based on the ASTM D-3895 method. The results are shown in Table 2.

TABLE-US-00002 TABLE 2 Oxygen Transmission Rates at 25 C. and 0% RH and 50% RH. 25 C./0% RH 25 C./50% RH Sample OTR (cc/m.sup.2/day) OTR (cc/m.sup.2/day) 1 0.42 0.24 2 0.36 0.6 Average OTR 0.39 0.42 Film Thickness 0.062 0.062 (mm)

[0099] As shown in the data above in Table 2, the average OTR at 25 C. at 0% RH was 0.39 cc/m.sup.2/day and at 25 C. at 50% RH was 0.42 cc/m.sup.2/day. These exceptionally good values, demonstrate that the compostable packaging provides suitable protection from oxidation for a number of consumer products.

[0100] The water vapor transmission rate was tested in a MOCON water vapor transmission rate unit at 38 C. at 90% RH and 25 C. at 50% RH until transmission equilibrium was achieved using the ASTM F-1249 method. The results are shown in Table 3.

TABLE-US-00003 TABLE 3 Water Vapor Transmission Rates at 38 C. and 90% RH and 25 C. and 50% RH. 38 C./90% RH 25 C./50% RH Sample WVTR (gm/m.sup.2/day) WVTR (gm/m.sup.2/day) 1 0.289 0.053 2 0.256 0.047 Average WVTR 0.2725 0.05 Film Thickness 0.062 0.062 (mm)

[0101] As shown in the data above the average WVTR at 38 C. at 90% RH was 0.27 gm/m.sup.2/day and at 25 C. at 50% RH was 0.05 gm/m.sup.2/day. These are exceptionally good values that provide significant protection for consumer products. Particularly, this is suitable for consumer products where moisture adsorption would alter the texture or create lumping in the product because of moisture ingress and prevents moisture from leaving products where they would dry out and become unsuitable for consumption.

[0102] The slow rate penetration resistance was measured at 1 in. per min. intervals, with the test set to stop at a 20% sudden loss of comprehensive load using the ASTM F-1306 method. The results are shown in Table 4.

TABLE-US-00004 TABLE 4 Slow Rate Penetration Test Results. Penetration Force Penetration Force Sample (lbf) (N) 1 4.31 19.17 2 4.52 20.10 3 4.60 20.46 4 4.69 20.86 5 4.90 21.80 6 4.56 20.28 7 4.93 21.93 8 4.78 21.26 9 4.42 19.66 10 5.00 22.24 Avg 4.67 20.78 Std Dev 0.23 1.02 Min 4.31 19.17 Max 5.00 22.24

[0103] As shown in the data above in Table 4, the average penetration force 4.67 lbf or 20.78 N. This demonstrates that the compostable packaging material can be used for a variety of consumer products, including products with sharp edges.

[0104] The tensile strength and elongation % were measured base using the ASTM D-882 method. The sample was cut into 1 in. side in both the machine and cross direction and tested using an Instron machine, with grips separating at a rate of 12 in. per min. The results are shown in Tables 5-8.

TABLE-US-00005 TABLE 5 Machine Direction Tensile Strength. MD MD Cross- Tensile Tensile Sectional Peak Strength Strength Width Thickness Area Force (lb./sq. (N/sq. Sample (In.) (in.) (sq. in.) (lbf.) in.) mm) 1 1 0.002441 0.002441 21.24 8701.35 59.99 2 1 0.002441 0.002441 21.35 8746.42 60.30 3 1 0.002441 0.002441 21.41 8771.00 60.47 4 1 0.002441 0.002441 22.38 9168.37 63.21 5 1 0.002441 0.002441 22.86 9365.01 64.57 Average 1 0.002441 0.002441 21.848 8950.43 61.71 Std 0 0 0 0.73 298.01 2.05 Min 1 0.002441 0.002441 21.24 8701.35 59.99 Max 1 0.002441 0.002441 22.86 9365.01 64.57

TABLE-US-00006 TABLE 6 Machine Direction Tensile Elongation %. Initial Elongation Total MD Length at Break Length at Elongation Sample (in.) (in.) Break (in.) % 1 4 1.37 5.37 34.25 2 4 1.37 5.37 34.25 3 4 1.4 5.4 35.00 4 4 1.54 5.54 38.50 5 4 1.55 5.55 38.75 Average 4 1.446 5.446 36.15 Std 0 0.09 0.09 2.28 Min 4 1.37 5.37 34.25 Max 4 1.55 5.55 38.75

TABLE-US-00007 TABLE 7 Cross Direction Tensile Strength. MD MD Cross- Tensile Tensile Sectional Peak Strength Strength Width Thickness Area Force (lb./sq. (N/sq. Sample (In.) (in.) (sq. in.) (lbf.) in.) mm) 1 1 0.002441 0.002441 16.87 6911.10 47.65 2 1 0.002441 0.002441 16.53 6771.81 46.69 3 1 0.002441 0.002441 14.68 6013.93 41.46 4 1 0.002441 0.002441 16.87 6911.10 47.65 5 1 0.002441 0.002441 16.46 6743.14 46.49 Average 1 0.002441 0.002441 16.282 6670.22 45.99 Std 0 0 0 0.92 374.97 2.59 Min 1 0.002441 0.002441 14.68 6013.93 41.46 Max 1 0.002441 0.002441 16.87 6911.10 47.65

TABLE-US-00008 TABLE 8 Cross Direction Tensile Elongation %. Initial Elongation Total MD Length at Break Length at Elongation Sample (in.) (in.) Break (in.) % 1 4 1.51 5.51 37.75 2 4 1.56 5.56 39.00 3 4 0.94 4.94 23.50 4 4 1.64 5.64 41.00 5 4 1.48 5.48 37.00 Average 4 1.426 5.426 35.65 Std 0 0.28 0.28 6.96 Min 4 0.94 4.94 23.5 Max 4 1.64 5.64 41

[0105] As shown in the data above in Tables 5-6, the average machine direction tensile strength was 8950.43 lb/in.sup.2 or 61.71 N/mm.sup.2 and the elongation percent was 36.15%. As shown in the data above in Tables 7-8, the average machine direction tensile strength was 6670.22 lb/in.sup.2 or 45.99 N/mm.sup.2 and the elongation percent was 37.75%.

[0106] In particular, the compostable packaging material with a film layer of metalized PHA and a substrate layer of cellulose acetate exhibited ideal oxygen transmission and water vapor transmission rates.

Example 2

[0107] The properties of a compostable packaging material that has text printing and logos thereon and comprises a film layer of metalized PHA and a substrate layer of cellulose acetate were measured, as shown in Tables 9-16.

[0108] The oxygen transmission rate was tested in a MOCON oxygen transmission rate unit at 25 C. at 0% relative humidity (RH) and 25 C. at 50% RH until transmission equilibrium was achieved using a method based on the ASTM D-3895 method. The results are shown in Table 9.

TABLE-US-00009 TABLE 9 Oxygen Transmission Rates at 25 C. and 0% RH and 50% RH. 25 C. / 0% RH 25 C. / 50% RH Sample OTR (cc/m.sup.2/day) OTR (cc/m.sup.2/day) 1 0.36 0.66 2 0.54 0.36 Average OTR 0.45 0.51 Film Thickness 0.066 0.066 (mm)

[0109] As shown in the data above in Table 9, the average OTR at 25 C. at 0% RH was 0.45 cc/m.sup.2/day and at 25 C. at 50% RH was 0.51 cc/m.sup.2/day. These exceptionally good values, demonstrate that the compostable packaging provides suitable protection from oxidation for a number of consumer products.

[0110] The water vapor transmission rate was tested in a MOCON water vapor transmission rate unit at 38 C. at 90% RH and 25 C. at 50% RH until transmission equilibrium was achieved using the ASTM F-1249 method. The results are shown in Table 10.

TABLE-US-00010 TABLE 10 Water Vapor Transmission Rates at 38 C. and 90% RH and 25 C. and 50% RH. 38 C. / 90% RH 25 C. / 50% RH Sample WVTR (gm/m.sup.2/day) WVTR (gm/m.sup.2/day) 1 0.199 0.022 2 0.246 0.033 Average WVTR 0.2225 0.0275 Film Thickness 0.066 0.066 (mm)

[0111] As shown in the data above in Table 10, the average WVTR at 38 C. at 90% RH was 0.22 gm/m.sup.2/day and at 25 C. at 50% RH was 0.03 gm/m.sup.2/day. These are exceptionally good values that provide significant protection for consumer products. Particularly, this is suitable for consumer products where moisture adsorption would alter the texture or create lumping in the product because of moisture ingress and prevents moisture from leaving products where they would dry out and become unsuitable for consumption.

[0112] The slow rate penetration resistance was measured at 1 in. per min. intervals, with the test set to stop at a 20% sudden loss of comprehensive load using the ASTM F-1306 method. The results are shown in Table 11.

TABLE-US-00011 TABLE 11 Slow Rate Penetration Test Results. Penetration Penetration Sample Force (lbf) Force (N) 1 4.97 22.11 2 5.35 23.80 3 5.44 24.20 4 5.29 23.53 5 5.39 23.97 6 5.33 23.71 7 5.23 23.26 8 5.13 22.82 9 5.16 22.95 10 5.14 22.86 Avg 5.24 23.32 Std Dev 0.14 0.64 Min 4.97 22.11 Max 5.44 24.20

[0113] As shown in the data above in Table 11, the average penetration force 5.21 lbf or 23.32 N. This demonstrates that the compostable packaging material can be used for a variety of consumer products, including products with sharp edges.

[0114] The tensile strength and elongation % were measured base using the ASTM D-882 method. The sample was cut into 1 in. side in both the machine and cross direction and tested using an Instron machine, with grips separating at a rate of 12 in. per min. The results are shown in Tables 12-15.

TABLE-US-00012 TABLE 12 Machine Direction Tensile Strength. MD MD Cross- Tensile Tensile Sectional Peak Strength Strength Width Thickness Area Force (lb./sq. (N/sq. Sample (In.) (in.) (sq. in.) (lbf.) in.) mm) 1 1 0.002598 0.002598 21.93 8441.11 58.20 2 1 0.002598 0.002598 22.35 8602.77 59.31 3 1 0.002598 0.002598 22.41 8625.87 59.47 4 1 0.002598 0.002598 22.18 8537.34 58.86 5 1 0.002598 0.002598 22.31 8587.37 59.21 Average 1 0.002598 0.002598 22.236 8558.89 59.01 Std 0 0 0 0.19 73.42 0.51 Min 1 0.002598 0.002598 21.93 8441.11 58.20 Max 1 0.002598 0.002598 22.41 8625.87 59.47

TABLE-US-00013 TABLE 13 Machine Direction Tensile Elongation %. Initial Elongation Total MD Length at Break Length at Elongation Sample (in.) (in.) Break (in.) % 1 4 1.4 5.4 35.00 2 4 1.4 5.4 35.00 3 4 1.46 5.46 36.50 4 4 1.45 5.45 36.25 5 4 1.49 5.49 37.25 Average 4 1.44 5.44 36 Std 0 0.04 0.04 0.98 Min 4 1.4 5.4 35 Max 4 1.49 5.49 37.25

TABLE-US-00014 TABLE 14 Cross Direction Tensile Strength. MD MD Cross- Tensile Tensile Sectional Peak Strength Strength Width Thickness Area Force (lb./sq. (N/sq. Sample (In.) (in.) (sq. in.) (lbf.) in.) mm) 1 1 0.002598 0.002598 17.38 6689.76 46.12 2 1 0.002598 0.002598 16.09 6193.23 42.70 3 1 0.002598 0.002598 16.79 6462.66 44.56 4 1 0.002598 0.002598 15.56 5989.22 41.29 5 1 0.002598 0.002598 16.73 6439.57 44.40 Average 1 0.002598 0.002598 16.51 6354.89 43.82 Std 0 0 0 0.70 269.62 1.86 Min 1 0.002598 0.002598 15.56 5989.22 41.29 Max 1 0.002598 0.002598 17.38 6689.76 46.12

TABLE-US-00015 TABLE 15 Cross Direction Tensile Elongation %. Total Initial Elongation Length MD Length at Break at Break Elongation Sample (in.) (in.) (in.) % 1 4 1.68 5.68 42.00 2 4 1.37 5.37 34.25 3 4 1.54 5.54 38.50 4 4 1.15 5.15 28.75 5 4 1.53 5.53 38.25 Average 4 1.454 5.454 36.35 Std 0 0.20 0.20 5.06 Min 4 1.15 5.15 28.75 Max 4 1.68 5.68 42

[0115] As shown in the data above in Tables 12 and 13, the average machine direction tensile strength was 8558.98 lb/in.sup.2 or 59.01 N/mm.sup.2 and the elongation percent was 36%. As shown in the data above in Tables 7-8, the average machine direction tensile strength was 6354.89 lb/in.sup.2 or 43.82 N/mm.sup.2 and the elongation percent was 36.35%.

[0116] As shown in comparing the testing values of the unprinted compostable packaging material of Example 1 with the compostable packaging material that has text printing and logos thereon and comprises a film layer of metalized PHA and a substrate layer of cellulose acetate of Example 2, the printing addition to the packaging had minimal effect on the tested properties above.

Example 3

[0117] The properties of a compostable packaging material that has text printing and logos and comprises a film layer of metalized PHA and a substrate layer of PHA was measured, as shown in Tables 16-23.

[0118] The oxygen transmission rate was tested in a MOCON oxygen transmission rate unit at 25 C. at 0% relative humidity (RH) and 25 C. at 50% RH until transmission equilibrium was achieved using a method based on the ASTM D-3895 method. The results are shown in Table 16.

TABLE-US-00016 TABLE 16 Oxygen Transmission Rates at 25 C. and 0% RH and 50% RH. 25 C. / 0% RH 25 C. / 50% RH Sample OTR (cc/m.sup.2/day) OTR (cc/m.sup.2/day) 1 0.54 0.36 2 0.78 0.3 Average OTR 0.66 0.33 Film Thickness 0.074 0.074 (mm)

[0119] As shown in the data above in Table 16, the average OTR at 25 C. at 0% RH was 0.66 cc/m.sup.2/day and at 25 C. at 50% RH was 0.39 cc/m.sup.2/day. These exceptionally good values, demonstrate that the compostable packaging provides suitable protection from oxidation for a number of consumer products.

[0120] The water vapor transmission rate was tested in a MOCON water vapor transmission rate unit at 38 C. at 90% RH and 25 C. at 50% RH until transmission equilibrium was achieved using the ASTM F-1249 method. The results are shown in Table 17.

TABLE-US-00017 TABLE 17 Water Vapor Transmission Rates at 38 C. and 90% RH and 25 C. and 50% RH. 38 C. / 90% RH 25 C. / 50% RH Sample WVTR (gm/m.sup.2/day) WVTR (gm/m.sup.2/day) 1 0.179 0.041 2 0.233 0.048 Average WVTR 0.206 0.0445 Film Thickness 0.074 0.074 (mm)

[0121] As shown in the data above in Table 17, the average WVTR at 38 C. at 90% RH was 0.21 gm/m.sup.2/day and at 25 C. at 50% RH was 0.04 gm/m.sup.2/day. These are exceptionally good values that provide significant protection for consumer products. Particularly, this is suitable for consumer products where moisture adsorption would alter the texture or create lumping in the product because of moisture ingress and prevents moisture from leaving products where they would dry out and become unsuitable for consumption.

[0122] The slow rate penetration resistance was measured at 1 in. per min. intervals, with the test set to stop at a 20% sudden loss of comprehensive load using the ASTM F-1306 method. The results are shown in Table 18.

TABLE-US-00018 TABLE 18 Slow Rate Penetration Test Results. Penetration Penetration Sample Force (lbf) Force (N) 1 12.21 54.31 2 11.52 51.24 3 11.80 52.49 4 12.92 57.47 5 11.44 50.89 6 12.16 54.09 7 13.21 58.76 8 11.72 52.13 9 12.58 55.96 10 12.81 56.98 Avg 12.24 54.43 Std Dev 0.62 2.76 Min 11.44 50.89 Max 13.21 58.76

[0123] As shown in the data above in Table 18, the average penetration force 12.24 lbf or 54.43 N. This demonstrates that the compostable packaging material can be used for a variety of consumer products, including products with sharp edges.

[0124] The tensile strength and elongation % were measured base using the ASTM D-882 method. The sample was cut into 1 in. side in both the machine and cross direction and tested using an Instron machine, with grips separating at a rate of 12 in. per min. The results are shown in Tables 19-22.

TABLE-US-00019 TABLE 19 Machine Direction Tensile Strength. MD MD Cross- Tensile Tensile Sectional Peak Strength Strength Width Thickness Area Force (lb./sq. (N/sq. Sample (In.) (in.) (sq. in.) (lbf.) in.) mm) 1 1 0.002598 0.002598 26.3 10123.17 69.80 2 1 0.002598 0.002598 25.7 9892.22 68.20 3 1 0.002598 0.002598 23.97 9226.33 63.61 4 1 0.002598 0.002598 22.26 8568.13 59.08 5 1 0.002598 0.002598 24.92 9591.99 66.13 Average 1 0.002598 0.002598 24.63 9480.37 65.36 Std 0 0 0 1.59 610.74 4.21 Min 1 0.002598 0.002598 22.26 8568.13 59.08 Max 1 0.002598 0.002598 26.3 10123.17 69.80

TABLE-US-00020 TABLE 20 Machine Direction Tensile Elongation %. Total Initial Elongation Length MD Length at Break at Break Elongation Sample (in.) (in.) (in.) % 1 4 4.11 8.11 102.75 2 4 3.81 7.81 95.25 3 4 3.36 7.36 84.00 4 4 3.22 7.22 80.50 5 4 4.02 8.02 100.50 Average 4 3.704 7.704 92.6 Std 0 0.40 0.40 9.91 Min 4 3.22 7.22 80.5 Max 4 4.11 8.11 102.75

TABLE-US-00021 TABLE 21 Cross Direction Tensile Strength. CD CD Cross- Tensile Tensile Sectional Peak Strength Strength Width Thickness Area Force (lb./sq. (N/sq. Sample (In.) (in.) (sq. in.) (lbf.) in.) mm) 1 1 0.002598 0.002598 22.13 8518.09 58.73 2 1 0.002598 0.002598 21.54 8290.99 57.16 3 1 0.002598 0.002598 20.01 7702.08 53.10 4 1 0.002598 0.002598 19.44 7482.68 51.59 5 1 0.002598 0.002598 22.25 8564.28 59.05 Average 1 0.002598 0.002598 21.074 8111.62 55.93 Std 0 0 0 1.28 491.32 3.39 Min 1 0.002598 0.002598 19.44 7482.68 51.59 Max 1 0.002598 0.002598 22.25 8564.28 59.05

TABLE-US-00022 TABLE 22 Cross Direction Tensile Elongation %. Total Initial Elongation Length MD Length at Break at Break Elongation Sample (in.) (in.) (in.) % 1 4 5.21 9.21 130.25 2 4 4.83 8.83 120.75 3 4 4.86 8.86 121.50 4 4 4.46 8.46 111.50 5 4 4.8 8.8 120.00 Average 4 4.832 8.832 120.8 Std 0 0.27 0.27 6.65 Min 4 4.46 8.46 111.5 Max 4 5.21 9.21 130.25

[0125] As shown in the data above in Tables 19 and 20, the average machine direction tensile strength was 9480.37 lb/in.sup.2 or 65.36 N/mm.sup.2 and the elongation percent was 92.6%. As shown in the data above in Tables 21 and 22, the average machine direction tensile strength was 8111.62 lb/in.sup.2 or 55.93 N/mm.sup.2 and the elongation percent was 120.8%.

[0126] In particular, the compostable packaging material that has text printing and logos thereon and comprises a film layer of metalized PHA and a substrate layer of PHA performed comparably to the compostable packaging material with the cellulose acetate substrate layer.

Example 4

[0127] In Example 4, multiple samples of an unprinted compostable packaging material having a film layer of metalized PHA, and a substrate layer of paper were prepared by laminating metalized PHA to Ahlstrom commercial paper (UC300 or UC400). Laminations were performed using Sun Chemical SunLam adhesive SFC100/HAC306 at a coat weight of either 1.5 grams per square meter (gsm) or 2.4 gsm as shown in Table 23. Various properties of each sample were tested as shown in Tables 24-27. The testing included a review of each sample's oxygen transmission rate, water vapor transition rate, bond strength, and penetration tests.

TABLE-US-00023 TABLE 23 Paper-Based Compostable Packaging Material Samples. Paper Adhesive Coat Sample Substrate Weight (gsm) 1 UC300 1.5 2 UC300 2.4 3 UC400 1.5 4 UC400 2.4

[0128] The oxygen transmission rate was tested in a MOCON oxygen transmission rate unit at 25 C. at 50% relative humidity (RH) until transmission equilibrium was achieved using a method based on the ASTM D-3895 method. The results are shown in Table 24.

TABLE-US-00024 TABLE 24 Oxygen Transmission Rates at 25 C. at 50% RH. OTR (cc/m.sup.2/day) at Sample 25 C. / 50% RH 1 0.2-0.6 2 0.54-0.66 3 0.24-0.84 4 0.96-1.62

[0129] As shown in the data above in Table 24, the OTR at 25 C. and 50% RH of the samples varied between 0.2-0.6 cc/m.sup.2/day to 0.96-1.62 cc/m.sup.2/day. These exceptionally good values demonstrate that the compostable packaging provides suitable protection from oxidation for a number of consumer products.

[0130] The water vapor transmission rate was tested in a MOCON water vapor transmission rate unit at 35 C. at 85% RH until transmission equilibrium was achieved using the ASTM F-1249 method. The results are shown in Table 25.

TABLE-US-00025 TABLE 25 Water Vapor Transmission Rates at 35 C. at 85% RH. WVTR (gm/m.sup.2 /day) at Sample 35 C. / 85% RH 1 0.07-0.1 2 0.538-1.103 3 0.09-0.091 4 0.245-0.531

[0131] As shown above in Table 25, the WVTR at 35 C. at 85% RH of the samples varied between 0.07-0.1 g/m.sup.2/day and to 0.538-1.103 gm/m.sup.2/day. These are exceptionally good values that provide significant protection for consumer products. Particularly, this is suitable for consumer products where moisture adsorption would alter the texture or create lumping in the product because of moisture ingress and prevents moisture from leaving products where they would dry out and become unsuitable for consumption.

[0132] The lamination bond strength was tested using the ASTM F904 method. The results are shown in Table 26.

TABLE-US-00026 TABLE 26 Bond Strength. Sample Bond Strength (N) 1 10.1 2 2 10.8 2 3 9.09 2 4 9.03 2

[0133] As shown above in Table 26, the lamination bond strength of the samples varied between 9.032 N and 10.82 N. This demonstrates that the lamination of the compostable packaging maintains structural integrity during use as a packaging material for consumer products.

[0134] The slow rate penetration resistance was measured at 1 in. per min. intervals, with the test set to stop at a 20% sudden loss of comprehensive load using the ASTM F-1306 method. The results are shown in Table 27.

TABLE-US-00027 TABLE 27 Slow Rate Penetration Test Results. Penetration Sample Force (N) 1 11.2 2 3 11.8 4

[0135] As shown in the data above in Table 27, Samples 1 and 3 exhibited penetration forces of 11.2 N and 11.8 N, respectively. This demonstrates that the compostable packaging material can be used for a variety of consumer products, including products with sharp edges.

[0136] In addition to the various embodiments depicted and claimed, the disclosed subject matter is also directed to other embodiments having other combinations of the features disclosed and claimed herein. As such, the particular features presented herein can be combined with each other in other manners within the scope of the disclosed subject matter such that the disclosed subject matter includes any suitable combination of the features disclosed herein. The foregoing description of specific embodiments of the disclosed subject matter has been presented for purposes of illustration and description. It is not intended to be exhaustive or to limit the disclosed subject matter to those embodiments disclosed.

[0137] It will be apparent to those skilled in the art that various modifications and variations can be made in the systems and methods of the disclosed subject matter without departing from the spirit or scope of the disclosed subject matter. Thus, it is intended that the disclosed subject matter include modifications and variations that are within the scope of the appended claims and their equivalents.

[0138] Various patents and patent applications are cited herein, the contents of which are hereby incorporated by reference herein in their entireties.