LOW FREE POLYURETHANE PREPOLYMER COMPOSITION

Abstract

A polyurethane prepolymer composition may include: (a) a polyurethane prepolymer comprising, as a reaction product, (a1) an excess of diisocyanate and (a2) a polyol; and (b) free diisocyanate monomer in a range of from more than 0 to less than 1.0 wt. %, based on total polyurethane prepolymer weight. The NCO content of the polyurethane prepolymer may be in a range of from 0.2 to 15 wt. %. The polyurethane prepolymer may include less than 75 wt. % of a 2:1 stoichiometric adduct of the diisocyanate and the polyol, based on the total polyurethane prepolymer weight. The polyol (a2) may include two polypropylene glycols with different molecular weights.

Claims

1. A polyurethane prepolymer composition, comprising: (a) a polyurethane prepolymer comprising, as a reaction product, (a1) an excess of diisocyanate and (a2) a polyol; and (b) free diisocyanate monomer in a range of from more than 0 to less than 1.0 wt. %, based on total polyurethane prepolymer weight, wherein the polyurethane prepolymer (a) has an NCO content in a range of from 0.2 to 15 wt. %, wherein the polyurethane prepolymer (a) comprises less than 75 wt. % of a 2:1 stoichiometric adduct of the diisocyanate (a1) and the polyol (a2), based on the total polyurethane prepolymer weight, wherein the polyol (a2) comprises (a2a) a first polypropylene glycol and (a2b) a second polypropylene glycol, wherein the first polypropylene glycol (a2a) has a different molecular weight from the second polypropylene glycol (a2b).

2. The polyurethane prepolymer composition of claim 1, wherein the first polypropylene glycol (a2a) has a weight average molecular weight Mw in a range of from 200 to 800 g/mol, and wherein the second polypropylene glycol (a2a) has a weight average molecular weight Mw of 800 to 2,000 g/mol.

3. The polyurethane prepolymer composition of claim 1, wherein the diisocyanate (a1) comprises methylene diphenyl diisocyanate, para-phenylene diisocyanate, naphthalene diisocyanate, hexamethylene diisocyanate, cyclohexyl diisocyanate, isophorone diisocyanate, toluene diisocyanate.

4. The polyurethane prepolymer composition of claim 1, wherein the diisocyanate (a1) comprises 4,4-methylene diphenyl diisocyanate.

5. The polyurethane prepolymer composition of claim 1, wherein the first polypropylene glycol (a2a) has a weight average molecular weight Mw in a range of from 200 to 600 g/mol.

6. The polyurethane prepolymer composition of claim 1, wherein the polyurethane prepolymer (a) comprises the 2:1 stoichiometric adduct in a range of from more than 30 to less than 75 wt. %.

7. The polyurethane prepolymer composition of claim 1, comprising the free diisocyanate monomer (b) in a range of from more than 0 to less than 0.1 wt. %, based on the total polyurethane prepolymer weight.

8. A curable polyurethane prepolymer composition, comprising: the polyurethane prepolymer composition of claim 1; and a curative, wherein the curative is a diamine, a polyol, or a blend thereof.

9. A method for adhesively joining or sealing two substrates, the method comprising: (1) applying onto a substrate the curable polyurethane prepolymer composition of claim 5; and (2) contacting the curable polyurethane prepolymer composition applied on the substrate to a second substrate such that a bond is formed.

10. An adhesive, comprising: the curable polyurethane prepolymer composition of claim 8.

11. The polyurethane prepolymer composition of claim 1, comprising the free diisocyanate monomer (b) in a range of from more than 0 to less than 0.5 wt. %.

12. The polyurethane prepolymer composition of claim 1, wherein the NCO content of the polyurethane prepolymer (a) is in a range of from 0.2 to 8 wt. %.

13. The polyurethane prepolymer composition of claim 1, wherein the polyol (a2) has a weight average molecular weight (Mw), determined with gel permeation chromatography (GPC), in a range of from 250 to 4,000 g/mol.

14. The polyurethane prepolymer composition according to claim 1, wherein the weight average molecular weight Mw of the first polypropylene glycol (a2a) is in a range of from 400 to 600 g/mol.

15. A curable polyurethane prepolymer composition, comprising: the polyurethane prepolymer composition of claim 1; and 1,4-butanediol and/or hydroquinone bis(2-hydroxyethyl) ether.

16. The polyurethane prepolymer composition of claim 1, wherein the polyurethane prepolymer (a) comprises the 2:1 stoichiometric adduct in a range of from more than 30 to 70 wt. %, based on total prepolymer composition weight.

17. The polyurethane prepolymer composition of claim 1, wherein the polyurethane prepolymer (a) comprises the 2:1 stoichiometric adduct in a range of from 35 to 65 wt. %, based on total prepolymer composition weight.

18. The polyurethane prepolymer composition of claim 1, wherein the first polypropylene glycol (a2a) comprises PPG-500.

19. The polyurethane prepolymer composition of claim 1, wherein the first polypropylene glycol (a2a) comprises PPG-500, and wherein the second polypropylene glycol (a2b) comprises PPG-1100.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0024] This invention relates to a polyurethane prepolymer composition based on the reaction of an diisocyanate and a polyol, having a low level of residual diisocyanate monomer and a high oligomer content.

[0025] The polyurethane prepolymer composition is the product resulting from the reaction of a polyol containing n (at least 2) OH groups and an diisocyanate. The polyurethane prepolymer reaction product comprises oligomers and perfect prepolymers. The requisite high oligomer content of the prepolymer composition is >20 wt. % or, reciprocally, it can expressed in terms of its perfect prepolymer content which should be <80 wt. %.

[0026] A perfect prepolymer of the present invention in terms of stoichiometry is a prepolymer of n diisocyanate molecules and one polyol molecule. The stoichiometric proportions for the diisocyanate and polyol in the reaction products are 2:1 in the case of diols and 3:1 for triols. The perfect prepolymer is essentially an adduct containing only one molecule of the polyol in each prepolymer molecule. The invention requires that the polyurethane prepolymer composition (1) comprises less than 80 wt. % of a stoichiometric perfect prepolymer based on the total weight of polyurethane prepolymer and (2) comprises more than 0 wt. % and less than 1.0 wt. % unreacted, and thus free, diisocyanate monomer. In a preferred embodiment, the invention requires that this diisocyanate prepolymer reaction product (1) comprises more than 30 wt. % and less than 80 wt. % of a stoichiometric perfect prepolymer and (2) contains more than 0 wt. % and less than 0.1 wt. % unreacted diisocyanate monomer.

[0027] The polyurethane prepolymers of the present invention are controlled structure polyurethane prepolymers comprising the reaction product of a diisocyanate (A) having a functionality (f) of at least two, with a polyol (B) of functionality (f) 2. The polyurethane prepolymer reaction product contains free prepolymer NCO functionality ranging from 0.2 to 15 wt. %, preferably, 0.5 to 8 wt. % and more preferably 5 to 7 wt. %.

[0028] The polyurethane prepolymer compositions of the present invention contain free prepolymer NCO ranging from 0.2 to 15 wt. %, preferably 0.5 to 8 wt. %, more preferably 5 to 7 wt. % and more than 0 wt. % and less than 1.0 wt. % unreacted diisocyanate monomer, preferably less than 0.5 wt. %, and more preferably less than 0.1 wt. %.

[0029] In a preferred embodiment of the present invention, the polyurethane prepolymer comprises at least 30 wt. % perfect prepolymer and less than 80 wt. % perfect prepolymer, preferably less than 75 wt. % perfect prepolymers, more preferably less than 70 wt. %, even more preferably less than 65 wt. % of the prepolymer reaction product obtained by the reaction of the diisocyanate with the polyol, or reciprocally at least 20 wt. % oligomers, preferably at least 25 wt. % oligomers, more preferably at least 30 wt. % oligomers and even more preferably at least 35 wt. % oligomers.

[0030] A perfect prepolymer, or adduct, is the perfect end capping product of a polyol (B) with n diisocyanate molecules (A), where n=the functionality (f) of B. For a difunctional B, the perfect prepolymer is represented as A:B:A.

[0031] Oligomers, for a difunctional B (n=2), are any species with a composition greater than the perfect 2:1 molecular ratio (A:B:A), for example 3:2 (A:B:A:B:A) or 4:3 (A:B:A:B:A:B:A). For a trifunctional B (n=3), the perfect prepolymer is represented as B: 3A. Oligomers in this instance are any species with a composition greater than the perfect 3:1 molecular ratio.

Diisocyanate

[0032] The diisocyanate of the present invention is not particularly limited. Suitable diisocyanates of the present invention include aliphatic diisocyanates, cycloaliphatic diisocyanates, polycyclic diisocyanates, aromatic diisocyanates and aliphatic-aromatic diisocyanates.

[0033] In a preferred embodiment, the diisocyanate of the present invention is methylene diphenyl diisocyanate (MDI), para-phenylene diisocyanate (PPDI), naphthalene diisocyanate (NDI), hexamethylene diisocyanates (HDI), cyclohexyl diisocyanates (CHDI), isophorone diisocyanate (IPDI), or toluene diisocyanate (TDI).

[0034] In a more preferred embodiment, the polyurethane prepolymer is prepared using 4,4-methylene-bis-(phenyl isocyanate) (4,4-MDI).

Polyol

[0035] The present invention is not limited by the use of a particular polyol and more than one may be used. A polyol suitable for the present invention may be selected from any polyol known in the art.

[0036] Polyols include compounds having more than one hydroxyl groups. Thus, polyols suitable for the present invention comprise diols, triols, and/or higher average hydroxyl functionality. The average hydroxyl functionality can range from 2 to 8, preferably 2 to 3 and more preferably from 2 to 2.5. The formation of such polyols is well known in the art.

[0037] In many embodiments, diols are preferred over triols or polyols with higher hydroxyl functionality.

[0038] In some embodiments of the present invention, the polyol comprises at least one polyester polyol, at least one polyether polyol, at least one polycaprolactone polyol, at least one polycarbonate polyol, or combinations thereof.

[0039] Preferred polyols are polypropylene oxide based polyether polyols, also known as polypropylene glycols (PPG), which include, but are not limited to, polypropylene polyether polyols with functionality of two or greater, average equivalent weight between 100 and 8,000. Also included are ethylene oxide capped PPGs and low monol containing PPGs.

[0040] Additional polyols which may be used include alkylene diols such as diethylene glycol (DEG), other di- or multi-functional alkylene ether polyols such as poly(tetramethylene ether) glycol (PTMEG) and polyethylene oxide, polyester polyols, polyester polyols from polycaprolactones and hydroxyl terminated polybutadienes.

[0041] The above polyether and polyester polyols are commonly used for producing polyurethane prepolymers. The polyol can be blended such that the at least one polyol, either the single polyol or a blend, used in making the prepolymer has an average molecular weight (Mw) ranging from about 50 to 16,000 g/mol, preferably 250 to 4,000 g/mol and preferably from 500 to 1,100 g/mol. In another preferred embodiment, the at least one polyol comprises two polypropylene glycols with different molecular weight. Average molecular weight can be determined with GPC.

Process for Preparing Polyurethane Prepolymer

[0042] Polyurethane prepolymer according to this present invention is prepared by the reaction of an excess of diisocyanate with at least one polyol.

[0043] In preferred embodiments, the polyurethane prepolymer of the present invention is prepared by reaction of at least one polyol with MDI.

[0044] In some embodiments, the polyurethane prepolymers are prepared by reaction of at least one diisocyanate with polypropylene glycol.

[0045] A polyurethane prepolymer of the present invention can be prepared under the conditions of heating a reaction mixture of the polyol and the diisocyanate at 50 C. to 150 C. for 10 min to 24 h, preferably 60 C. to 100 C. for 2 h to 6 h.

[0046] Methods for synthesizing polyurethane prepolymers are generally known in the art. Generally, the polyurethane prepolymers of the present invention are made using standard reaction processes and conditions as known in the art for the production of polyurethane prepolymers generally.

[0047] The polyurethane prepolymer of the present invention is typically prepared using an excess of diisocyanate monomer resulting in a polyurethane prepolymer composition comprising unreacted monomer, e.g., unreacted or free diisocyanate. Levels of 20 wt. % or more of free diisocyanate monomer based on the polyurethane prepolymer composition, may be encountered.

[0048] The polyurethane prepolymer of the present invention is a low free monomer polyurethane prepolymer (also known as low free or LF or low isocyanate=LNCO).

[0049] Understood by one of ordinary skill in the art to have lower amounts of free monomer isocyanate groups than conventional polyurethane prepolymers, i.e. the polyurethane prepolymer compositions of the present invention have less than 1.0 wt. % free diisocyanate monomers based on the total weight of the polyurethane prepolymer.

[0050] The unreacted diisocyanate monomer in the prepolymer reaction product is removed to a concentration of more than 0 wt. % and less than 1 wt. %, preferably less than 0.5 wt. %, most preferably less than 0.1 wt. %. Polyurethane prepolymer without any residual free diisocyanate monomer would have an unfavored high viscosity.

[0051] Any process suitable in reducing the amount of free diisocyanate monomer in the polyurethane prepolymer composition to the low levels of the present invention may be employed. A variety of methods is known for reducing the residual isocyanate content of polyisocyanate monomers to a minimum such as wiped film evaporation, solvent aided distillation/co-distillation, molecular sieves, and solvent extraction. Distillation under reduced pressure is preferred, in particular thin film or agitated film evaporation under vacuum.

Curable Polyurethane Prepolymer Composition

[0052] The invention further relates to a curable polyurethane prepolymer composition, comprising the polyurethane prepolymer composition of the present invention and at least one curative.

Curative

[0053] Suitable curatives for the curable polyurethane prepolymer composition of the present invention include diamines, polyols, or blends thereof.

[0054] Examples of diamines include both aromatic and aliphatic diamines, primary and secondary amine terminated polyether polyols, and difunctional, trifunctional, and polymeric amines.

[0055] Examples of polyols include polyester or polyether polyols, which can be diols, triols and tetrols, having primary, secondary and/or tertiary alcohol groups. These polyols may be mixed with the diamines.

[0056] The ratio of the prepolymer to the curative is typically in the range of from 0.5:1 to 1.5:1, preferably from 0.7:1 to 1.2:1, and more preferably from 1.1:1 to 0.90:1.

Additives

[0057] The curable polyurethane prepolymer composition of the present invention optionally comprises further additives, such as catalysts; thickening agents; tackifying resins, for example abietic acid, abietic ester, terpene resins, terpene phenol resins or hydrocarbonaceous resins; fillers, for example silicates, talcum, calcium carbonates, clays or carbon black; plastizicers, for example phthalates: thixotropiczing agents, for example bentones, pyrogenic silicas, urea derivatives, fibrillated or pulped short fibers; color agents, for example color pastes and pigments or drying agents.

[0058] Optional catalysts include tertiary amine catalysts and suitable organometallic catalysts, such as those derived from tin, zirconium, and bismuth.

Adhesive

[0059] The present invention is also related to a method for adhesively joining or sealing two substrates, comprising the steps of: [0060] (1) applying onto a substrate the curable polyurethane prepolymer composition of the present invention, and [0061] (2) contacting the curable polyurethane prepolymer composition applied on the substrate to a second substrate such that a bond is formed.

[0062] In one embodiment, the polyurethane adhesive composition used in the method of the present invention comprises the above-described polyurethane prepolymer reaction product which can be prepared by reacting a diisocyanate, preferably 4,4-MDI with a polypropylene polyether polyol with an average molecular weight of 500 to 1,100 g/mol.

[0063] Substrates that may be bonded with the adhesive include cold rolled steel, aluminum, fiberglass reinforced polyester (FRP), sheet molding compound (SMC), plastics, wood, and glass.

[0064] Thus, the present invention relates further to the use of the curable polyurethane prepolymer composition of the present invention as an adhesive. In a preferred embodiment, a polyurethane prepolymer composition comprising a polyurethane prepolymer obtained by the reaction of 4,4-MDI with at least one polypropylene glycol, and comprising more than 0 wt. % and less than 1.0 wt. %, preferably less than 0.5 wt. % and more preferably less than 0.1 wt. % free 4,4-MDI monomer based on the total weight of the polyurethane prepolymer, wherein the polyurethane prepolymer comprises less than 80 wt. % perfect prepolymers.

[0065] The present invention encompasses also the use of the curable polyurethane prepolymer composition of the present invention as an adhesive at room temperature, as a holt-melt adhesive and as a one component foam (OCF).

[0066] The use of a polyurethane prepolymer composition of the present invention in an adhesive composition provides adhesives showing improved shear strength after 1 or 7 days curing at room temperature compared to adhesive compositions based on non-inventive polyurethane prepolymers with low amounts of oligomers or non-inventive conventional polyurethane prepolymers with high amounts of residual diisocyanate monomers, and the health and safety benefits associated with lower levels of volatile diisocyanate monomer of less than 1.0 wt. %.

EXAMPLES

[0067] The following materials were used in the Examples:

TABLE-US-00001 Mondur M diphenylmethane 4,4-diisocyanate; MDI; CAS No.: 101-68-8; (Commercially available from Covestro) Lupranol 1200 polypropylene glycol; PPG-500; Mw = 500 g/mol; CAS No.: 25322-69-4; (Commercially available from BASF) Lupranol 1100/1 polypropylene glycol; PPG-1100; Mw = 1100 g/mol; CAS No.: 25322-69-4; (Commercially available from BASF) Tri(propylene)glycol tripropylene glycol; TPG; CAS No.: 24800-44-0; (Commercially available from Sigma Aldrich)

Adhesive Experiments

TABLE-US-00002 Quadrol polyol (Ethylenedinitrilo)tetra-2-propanol; CAS No.: 102-60-3; Commercially available from Sigma Aldrich Microtuff 325F talc; Commercially available from Barretts Minerals Arcol Polyol PPG-2000 polypropylene glycol; PPG-2000; Mw = 2,000 g/mol; Commercially available from Covestro Cab-o-sil TS 720 fumed silica; Commercially available from Cabot Aluminum Powder, 325 Mesh, Grade 101 Commercially available from Toyal America Microbeads (10 mm) Commercially available from Cataphote Aluminum coupon Commercially available from AlKemix Methyl ethyl ketone (MEK) Commercially available from Sigma Aldrich Chemlok 218 One-coat adhesive (Commercially available from Lord) 1,4-butanediol (BDO) Commercially available from Sigma Aldrich Hydroquinone bis(2-hydroxyethyl) ether (HQEE) Commercially available from Sigma Aldrich

Example 1 (Inventive)

[0068] 6046 g of 4,4-Methylene diisocyanate (4,4-MDI) were added to a reactor and heated to 50 C. 2896 g of PPG-500 and 1646 g of PPG-1100 was then added. The reaction temperature was held at 80 C. for 4 hours. Excess residual 4,4-MDI monomer was removed by thin-film distillation under reduced pressure from the reaction product to a level of less than 0.1 wt. % residual 4,4-MDI, and total % NCO content of 6.05 wt. %.

Example 2 (Inventive)

[0069] 2880 g of 4,4-MDI were added to a reactor and heated to 50 C. 603 g of PPG-500 and 1017 g PPG-1100 was then added. The reaction temperature was held at 80 C. for 4 hours. Excess residual 4,4-MDI monomer was removed by thin-film distillation under reduced pressure from the reaction product to a level of less than 0.1 wt. % residual 4,4-MDI, and total % NCO content of 6.10 wt. %.

Example 3 (Comparative)

[0070] 4182 g of 4,4-MDI were added to a reactor and heated to 50 C. 443 g of PPG-500 and 1500 g PPG-1100 was then added. The reaction temperature was held at 80 C. for 4 hours. Excess residual 4,4-MDI monomer was removed by thin-film distillation under reduced pressure from the reaction product to a level of less than 0.1 wt. % residual 4,4-MDI, and total % NCO content of 5.87 wt. %.

Example 4 (Comparative)

[0071] 1584 g of 4,4-MDI were added to a reactor and heated to 50 C. 900 g of PPG-500 and 1516 g of PPG-1100 was then added. The reaction temperature was held at 80 C. for 4 hours. The reaction product had a % NCO content of 5.90 wt. %. The residual 4,4-MDI monomer content is >5 wt. %.

[0072] Table 1 presents the % NCO, residual free MDI and oligomer content for the MDI/PPG polymers of Examples 1-4.

TABLE-US-00003 TABLE 1 Characteristics of the prepolymer compositions Measured % of residual Oligomer % NCO theoretical MDI content Example Polyol [wt. %] NCO [wt. %] [wt. %] 1* PPG-500/PPG-1100 6.05 76 <0.1 53.8 2* PPG-500/PPG-1100 6.10 86 <0.1 28.5 3 PPG-500/PPG-1100 5.87 92 <0.1 18.2 4 PPG-500/PPG-1100 5.90 N/A >5 >50 *Inventive examples

[0073] The inventive examples 1 and 2 show a residual 4,4-MDI content of less than 0.1 wt. % based on the total weight of the polyurethane prepolymer, and a oligomer content of more than 20 wt. %. Thus, the amount of perfect prepolymer is less than 80 wt. % in the inventive examples 1 and 2.

Example 5

[0074] The prepolymer compositions of Examples 1-4 were evaluated in the following structural adhesive composition by room temperature curing on an aluminum coupon:

TABLE-US-00004 TABLE 2 Components of the adhesive composition Part A wt. % Part B wt. % Prepolymer (Ex. 1-4) 60 Arcol PPG-2000 16.7 Aluminum Powder 38 Quadrol 33.3 Cab-o-sil TS720 2 Microtuff 325F 27 Cab-o-sil TS720 1 Aluminum Powder 22

[0075] The adhesive composition was prepared by mixing Part A and Part B in an NCO:OH ratio of 1:0.9 while adding 1 wt. % of microbeads. The substrates were prepared according to the steps of the following substrate preparation process:

(1) Abrasion

[0076] The aluminum coupon was partly abraded with 20/40 crushed glass @ 80 psi Nozzle to part distance 6. The expected profile on the aluminum coupon was 2 to 3 mm.

(2) Solvent Wash

[0077] The surface was washed with acetone followed by air dry.

[0078] The adhesive composition was then applied to one side of a 2.5412.7 cm aluminum coupon to cover at least 3.23 cm.sup.2 of area then mated with a second substrate coupon to give a total lapshear overlap of 3.23 cm.sup.2. Samples were cured at room temperature and 50% humidity. Samples were prepared and tested according to ASTM D10002-10 (Standard Test Method for Apparent Shear Strength of Single-Lap-Joint Adhesively Bonded Metal Specimens by Tension Loading (Metal-to-Metal)) after 1 day and 7 days. All testing done at room temperature.

TABLE-US-00005 TABLE 3 Lap Shear Strength data without bonding agent Shear strength [MPa] Shear strength [MPa] Prepolymer Cure** after 1 day after 7 days Ex 1* RT 12.3 13.0 Ex 2* RT 12.0 11.8 Ex 3 RT 9.0 9.1 Ex 4 RT 10.5 10.6 *Inventive examples; **50% humidity

[0079] The results in Table 3 show that adhesive compositions based on the inventive polyurethane prepolymer examples 1 and 2 have higher shear strength after 1 and 7 days of cure compared to adhesive compositions based on non-inventive prepolymers with low amounts of oligomers (Example 3) or non-inventive conventional high amounts of free diisocyanate monomer (Example 4).

Example 6

[0080] The adhesive testing procedure was repeated as described in Example 5 with the exception that, as a third step in the substrate preparation process, a bonding agent was applied on the abraded and washed surface of the aluminum coupon before the adhesive composition was applied, according as followed:

(3) Bonding Agent

[0081] A bonding agent consisting of a 50:50 blend of methyl ethyl ketone (MEK) & Chemlok 218 adhesive was prepared. The aluminum coupons were dipped into the bonding agent and hung vertically to dry.

[0082] The results of the shear strength tests are shown in table 4.

TABLE-US-00006 TABLE 4 Lap Shear Strength data with bonding agent Shear strength [MPa] Shear strength [MPa] Prepolymer Cure** after 1 day after 7 days Ex 1* RT 11.4 12.8 Ex 2* RT 11.6 12.0 Ex 3 RT 10.5 11.2 Ex 4 RT 11.2 11.9 *Inventive examples; **50% humidity

[0083] The data in Table 4 shows that comparable shear strength between the adhesive composition based on inventive prepolymer compositions and non-inventive prepolymer compositions can only be achieved, by using and additional, unfavored, process step of applying a binding agent.

Example 7

[0084] Cast elastomers were prepared by conventional techniques using the prepolymers of Examples 1 to 4. The polyurethane prepolymer compositions were cured with 1,4 butane diol (BDO) or hydroquinone bis(2-hydroxyethyl) ether (HQEE) at 98% stoichiometry, and afterwards post-cured at 115 C. for 16 hours. Physical properties were obtained using the following ASTM test methods: Hardness (ASTM D2240); Split Tear (ASTM D-470); Trouser Tear (ASTM D-1938); Die-C Tear (ASTM D-624). Tables 5 and 6 show the data.

TABLE-US-00007 TABLE 5 Physical properties of cast elastomers based on polyurethane prepolymer compositions cured with HQEE Prepolymer Hardness Split Tear Trouser Tear Die-C Tear Example [Shore A/D] [kN/m] [kN/m] [kN/m] 1* 70D 22.8 73.9 118.3 2* 96A 19.8 45.1 97.3 3 95A 15.8 29.5 81.7 4 94A 22.2 43.7 76.1 *inventive

TABLE-US-00008 TABLE 6 Physical properties of cast elastomers based on polyurethane prepolymer compositions cured with BDO Prepolymer Hardness Split Tear Trouser Tear Die-C Tear Example [Shore A/D] [kN/m] [kN/m] [kN/m] 1* 97A/60D 15.1 63.3 48.4 2* 80A 6.0 19.1 26.3 3 62A 3.8 7.5 25.4 4 75A 6.2 12.9 32.3 *inventive

[0085] The low monomeric, high oligomer prepolymers of inventive Examples 1 and 2 show superior split tear, trouser tier and Die-C tear strength in comparison to non-inventive Examples 3 and 4.