METHOD FOR MANUFACTURING A MONOCRYSTALLINE SAPPHIRE SEED AS WELL AS A SAPPHIRE SINGLE-CRYSTAL WITH A PREFERRED CRYSTALLOGRAPHIC ORIENTATION AND EXTERNAL PART AND FUNCTIONAL COMPONENTS FOR WATCHMAKING AND JEWELLERY
20230133632 · 2023-05-04
Assignee
Inventors
Cpc classification
C01F7/02
CHEMISTRY; METALLURGY
C01P2002/76
CHEMISTRY; METALLURGY
C30B15/34
CHEMISTRY; METALLURGY
C30B17/00
CHEMISTRY; METALLURGY
International classification
C30B15/34
CHEMISTRY; METALLURGY
C30B17/00
CHEMISTRY; METALLURGY
C01F7/02
CHEMISTRY; METALLURGY
Abstract
A method for manufacturing a sapphire single-crystal, including melting alumina and/or sapphire in a crucible, and bringing the molten alumina and/or sapphire in contact with a monocrystalline sapphire seed to make the molten alumina and/or sapphire crystallise progressively according to a growth direction to form the sapphire single-crystal. The monocrystalline sapphire seed has a rhombohedral crystallographic structure defining three crystallographic axes [A], [C] and [M] perpendicular to each other and respectively perpendicular to the crystallographic planes. The monocrystalline sapphire seed is a plate delimited by two planar faces which extend parallel to and at a distance from each other, is obtained from an initial sapphire single-crystal which is cut so that one of the crystallographic axes of the monocrystalline sapphire plate forms with a normal to the planar faces of the monocrystalline sapphire plate an angle whose value is comprised between 5 and 85°.
Claims
1. A method for manufacturing a monocrystalline sapphire seed, the monocrystalline sapphire seed having a rhombohedral crystallographic structure defining three crystallographic axes [A], [C] and [M] perpendicular to each other and respectively perpendicular to the crystallographic planes A (11-20), C (0001) and M (10-10), the monocrystalline sapphire seed being a plate delimited by two planar faces which extend parallel to and at a distance from each other, the monocrystalline sapphire plate being obtained from an initial sapphire single-crystal that is cut so that one of the crystallographic axes [A], [C] or [M] of the monocrystalline sapphire plate forms with a normal to the planar faces of the monocrystalline sapphire plate an angle whose value is comprised between 5 and 85°.
2. A method for manufacturing a monocrystalline sapphire seed, the monocrystalline sapphire seed having a rhombohedral crystallographic structure defining three crystallographic axes [A], [C] and [M] perpendicular to each other and respectively perpendicular to the crystallographic planes A (11-20), C (0001) and M (10-10) of the rhombohedral structure, the monocrystalline sapphire seed being a monocrystalline sapphire bar obtained beforehand from an initial sapphire single-crystal which is cut so that one of the crystallographic axes [A], [C] or [M] of the monocrystalline sapphire bar forms with a normal to a cross-section of the monocrystalline sapphire bar an angle whose value is comprised between 5 and 85°.
3. A method for manufacturing a sapphire single-crystal, the method comprising the step of melting alumina and/or sapphire in a crucible, then bringing the melting alumina and/or sapphire in contact with a monocrystalline sapphire seed obtained by implementing the method according to claim 1 in order to make the melting alumina and/or sapphire crystallise progressively according to a growth direction to form the sapphire single-crystal.
4. A method for manufacturing a sapphire single-crystal, the method comprising the step of melting alumina and/or sapphire in a crucible, then bringing the melting alumina and/or sapphire in contact with a monocrystalline sapphire seed obtained by implementing the method according to claim 2 in order to make the melting alumina and/or sapphire crystallise progressively according to a growth direction to form the sapphire single-crystal.
5. A method for manufacturing a monocrystalline sapphire cylinder, the monocrystalline sapphire cylinder having a rhombohedral crystallographic structure defining three crystallographic axes [A], [C] and [M] perpendicular to each other and respectively perpendicular to the crystallographic planes A (11-20), C (0001) and M (10-10) of the rhombohedral structure, the method comprising the step of performing, by means of a cutting tool, in a sapphire single-crystal ball that has been grown according to one of the crystallographic axes [A] or [M] or [C] a core drilling according to a direction which forms with the growth crystallographic axis of the sapphire single-crystal ball an angle whose value is comprised between 5 and 85°.
6. A method for manufacturing a sapphire single-crystal obtained by crystallisation in the molten state at a top of a die, the method comprising the step of melting alumina and/or sapphire in a crucible, then bringing throughout channels of the die the molten alumina and/or sapphire in contact with a monocrystalline sapphire seed obtained beforehand in order to make the molten alumina and/or sapphire crystallise progressively according to a growth direction to form the sapphire single-crystal, the monocrystalline sapphire seed having a rhombohedral crystallographic structure defining three crystallographic axes [A], [C] and [M] perpendicular to each other and respectively perpendicular to the crystallographic planes A (11-20), C (0001) and M (10-10) of the rhombohedral structure, the monocrystalline sapphire seed being a first plate delimited by two planar faces which extend parallel to and at a distance from each other, one of the crystallographic axes [A], [C] or [M] being perpendicular to the planar faces of the first monocrystalline sapphire plate, the first monocrystalline sapphire plate being inclined by an angle whose value is comprised between 5 and 85° with respect to a perpendicular to the plane defined by the channels of the die, the sapphire single-crystal resulting from the crystalline growth being a second monocrystalline sapphire plate delimited by two planar faces which extend parallel to and at a distance from each other, the second monocrystalline sapphire plate having a disorientation of one of its crystallographic axes [A], [M] or [C] with respect to the normal to its planar faces which corresponds to the inclination by the angle of the first plate with respect to the channels of the die.
7. The manufacturing method according to claim 3, wherein the crystallographic axis [A], [M] or [C] forms with the normal to the planar faces of the monocrystalline sapphire plate an angle whose value is comprised between 25 and 35°.
8. The manufacturing method according to claim 4, wherein the crystallographic axis [A], [M] or [C] forms with the normal to the planar faces of the monocrystalline sapphire plate an angle whose value is comprised between 25 and 35°.
9. The manufacturing method according to claim 7, wherein the crystallographic axis [A], [M] or [C] forms with the normal to the planar faces of the monocrystalline sapphire plate an angle whose value is comprised between 5 and 15°.
10. The manufacturing method according to claim 8, wherein the crystallographic axis [A], [M] or [C] forms with the normal to the planar faces of the monocrystalline sapphire plate an angle whose value is comprised between 5 and 15°.
11. The manufacturing method according to claim 3, wherein the crystallographic axis [A], [M] or [C] forms with the normal to the cross-section of the monocrystalline sapphire bar an angle whose value is comprised between 25 and 35°.
12. The manufacturing method according to claim 4, wherein the crystallographic axis [A], [M] or [C] forms with the normal to the cross-section of the monocrystalline sapphire bar an angle whose value is comprised between 25 and 35°.
13. The manufacturing method according to claim 11, wherein the crystallographic axis [A], [M] or [C] forms with the normal to the cross-section of the monocrystalline sapphire bar an angle whose value is comprised between 5 and 15°.
14. The manufacturing method according to claim 12, wherein the crystallographic axis [A], [M] or [C] forms with the normal to the cross-section of the monocrystalline sapphire bar an angle whose value is comprised between 5 and 15°.
15. The manufacturing method according to claim 3, wherein the method for manufacturing the sapphire single-crystal is selected from among the EFG, HEM, Kyropoulos, Czochralski, Bridgman Vertical, Bridgman Horizontal and Micro Pulling Down processes.
16. The manufacturing method according to claim 4, wherein the method for manufacturing the sapphire single-crystal is selected from among the EFG, HEM, Kyropoulos, Czochralski, Bridgman Vertical, Bridgman Horizontal and Micro Pulling Down processes.
17. The manufacturing method according to claim 5, wherein the method for manufacturing the sapphire single-crystal is selected from among the EFG, HEM, Kyropoulos, Czochralski, Bridgman Vertical, Bridgman Horizontal and Micro Pulling Down processes.
18. The manufacturing method according to claim 6, wherein the method for manufacturing the sapphire single-crystal is selected from among the EFG, HEM, Kyropoulos, Czochralski, Bridgman Vertical, Bridgman Horizontal and Micro Pulling Down processes.
19. The manufacturing method according to claim 15, wherein the alumina and/or the sapphire that are molten are pure or doped.
20. The manufacturing method according to claim 19, wherein sapphire scraps are used.
21. The manufacturing method according to claim 3, wherein, once the sapphire single-crystal is obtained, external part or functional components for watchmaking or jewellery are cut in the sapphire single-crystal.
22. The manufacturing method according to claim 4, wherein, once the sapphire single-crystal is obtained, external part or functional components for watchmaking or jewellery are cut in the sapphire single-crystal.
23. The manufacturing method according to claim 5, wherein, once the sapphire single-crystal is obtained, external part or functional components for watchmaking or jewellery are cut in the sapphire single-crystal.
24. The manufacturing method according to claim 6, wherein, once the sapphire single-crystal is obtained, external part or functional components for watchmaking or jewellery are cut in the sapphire single-crystal.
25. The manufacturing method according to claim 21, wherein the external part or functional components are watch bridges, plates, cases and dials or else wristlet links.
26. A monocrystalline sapphire seed having a rhombohedral crystallographic structure defining three crystallographic axes [A], [C] and [M] perpendicular to each other and respectively perpendicular to the crystallographic planes A (11-20), C (0001) and M (10-10) of the rhombohedral structure, the monocrystalline sapphire seed being a plate delimited by two planar faces which extend parallel to and at a distance from each other, one of the crystallographic axes [A], [C] or [M] of the monocrystalline sapphire plate forming with a normal to the planar faces of the monocrystalline sapphire plate an angle whose value is comprised between 5 and 85°.
27. A monocrystalline sapphire seed having a rhombohedral crystallographic structure defining three crystallographic axes [A], [C] and [M] perpendicular to each other and respectively perpendicular to the crystallographic planes A (11-20), C (0001) and M (10-10) of the rhombohedral structure, the monocrystalline sapphire seed being monocrystalline sapphire bar one of the crystallographic axes [A], [C] or [M] of which forms with a normal to a cross-section of the monocrystalline sapphire bar an angle whose value is comprised between 5 and 85°.
28. A watch glass blank delimited by two faces which extend at a distance from each other and at least one of which is planar, the blank being made of monocrystalline sapphire having a rhombohedral crystallographic structure defining three crystallographic axes [A], [C] and [M] perpendicular to one another and respectively perpendicular to the crystallographic planes A (11-20), C (0001) and M (10-10) of the rhombohedral structure, one of the crystallographic axes [A], [C] or [M] forming with a normal to the planar face of the blank an angle whose value is comprised between 5 and 85°, so that the crystallographic axis [C] is not comprised in the planar face of the watch glass blank.
29. External part and functional components for watchmaking and jewellery cut in a sapphire single-crystal obtained by implementing the manufacturing method according to claim 3.
30. External part and functional components for watchmaking and jewellery cut in a sapphire single-crystal obtained by implementing the manufacturing method according to claim 4.
31. External part and functional components for watchmaking and jewellery cut in a sapphire single-crystal obtained by implementing the manufacturing method according to claim 5.
32. External part and functional components for watchmaking and jewellery cut in a sapphire single-crystal obtained by implementing the manufacturing method according to claim 6.
33. The external part and functional components according to claim 29, wherein these consist of watch bridges, plates, glasses, cases and dials or else of wristlet links.
Description
BRIEF DESCRIPTION OF THE FIGURES
[0039] Other features and advantages of the present invention will appear more clearly from the following detailed description of an example of implementation of the method according to the invention, this example being given only for purely illustrative and non-limiting purposes with reference to the appended drawings wherein:
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[0050]
DETAILED DESCRIPTION OF THE INVENTION
[0051] The present invention is based on the inventive general idea which consists in producing watch glasses in particular from a blank cut in a sapphire single-crystal obtained by crystalline growth in the molten state in a crucible in contact with a monocrystalline sapphire seed in the form of a plate or a bar. The originality of the invention lies in particular in that the monocrystalline sapphire seed that is used to make the sapphire single-crystal grow in which the glass blanks are cut is, itself, cut in a sapphire single-crystal so that the crystallographic axis [C] that is perpendicular to the crystallographic plane (0001) of the primitive cell of the sapphire single-crystal in which these glass blanks are cut is not contained in the plane of the latter. More specifically, the first sapphire single-crystal is cut so that a monocrystalline sapphire seed is obtained in the form of a plate with planar faces wherein one of the crystallographic axes [A], [C] or [M] forms with a normal to the planar faces of the plate, respectively with a cross-section of the bar, an angle whose value is comprised between 5 and 85°. Next, the disorientation of the crystallographic axes [A], [C] or [M] in the monocrystalline sapphire seed is found in the sapphire single-crystal that is grown in contact with this monocrystalline sapphire seed, then in the blanks of watch glasses that are cut in this sapphire single-crystal. Finally, the crystallographic axis [C] does not lie in the plane of the glass blanks and therefore does not cross the edges of these blanks. Thus, the greatest fragility to machining that is usually noticed when the crystallographic axis [C] crosses the edges of the blanks of the watch glasses is avoided. Thus, the blanks of watch glasses are less fragile and consequently easier to machine. In particular, the risks of chipping are considerably reduced.
[0052]
[0053] According to the invention, the monocrystalline sapphire seed 1 is cut in a first sapphire single-crystal so that, for example, the crystallographic axis [C] of the resulting plate 2 is rotated about the crystallographic axis [M] to form with a normal D1 to the planar faces 4 of this plate 2 an angle α whose value is comprised between 5 and 85°, for example 10°. The crystallographic axes [A], [C] and [M] being perpendicular to each other, the crystallographic axis [A] is also shifted by the same angle α with respect to the planar faces 4 of the plate 2, whereas the crystallographic axis [M] rotates by 10° about itself and therefore does not move.
[0054] It should be noted that the techniques for cutting a monocrystalline sapphire seed in a sapphire single-crystal according to a preferred direction are known to a person skilled in the art in the field of sapphire single-crystal growth and therefore will not be detailed herein.
[0055] As it arises from
[0056] In accordance with the invention, the monocrystalline sapphire seed 1 is used to make the sapphire single-crystals 6 grow in which the blanks 8 of watch glasses 10 will be cut. These blanks 8 of watch glasses 10 are delimited by two faces which extend at a distance from each other and at least one of which 12 is planar. The monocrystalline sapphire seed 1 is in the form of a plate 2 itself cut in an initial sapphire single-crystal so that, for example, its crystallographic axis [C] is rotated about the crystallographic axis [M] to form with a normal D1 to the planar faces 4 of the plate 2 an angle α whose value is comprised between 5 and 85°, for example 10°. Next, the disorientation of the crystallographic axes [A] and [C] in the monocrystalline sapphire seed 1 is found in the sapphire single-crystals 6 that are grown in contact with this monocrystalline sapphire seed 1, then in the blanks 8 of watch glasses 10 that are cut in these sapphire single-crystals 6.
[0057] Finally, as shown in
[0058]
[0059] According to the invention and as illustrated in
[0060] In
[0061] It should be noted that the techniques for cutting according to a preferred direction a monocrystalline sapphire seed in a sapphire single-crystal ball obtained beforehand, for example of the Kyropoulos type, whether this seed is in the form of a plate 2 with planar faces 4 or in the form of a bar 16A, are known to a person skilled in the art in the field of sapphire single-crystal growth and therefore will not be detailed herein.
[0062] Finally, because of the disorientation of the crystallographic axis [A] with respect to the normal to a cross-section S of the monocrystalline sapphire bar 16A, the crystallographic axis [C] does not generally lie in the planar face 12 of the blanks 8 of the watch glasses 10 and therefore does not generally cross the edges 14 of these blanks 8. Thus, the greatest fragility that is usually noticed at the locations where this crystallographic axis [C] crosses the edges 14 of the blanks 8 of the watch glasses 10 is avoided. Thus, the blanks 8 of the watch glasses 10 are less fragile and consequently easier to machine. In particular, the risks of chipping are considerably reduced and the losses are lesser.
[0063] It goes without saying that the present invention is not limited to the modes of implementation that have just been described and that various simple modifications and variants could be considered without departing from the scope of the invention as defined by the appended claims. In particular, rather than preparing a monocrystalline sapphire seed in the form of a plate a crystallographic axis of which forms a non-zero angle with respect to the normal to the planar faces that delimit this plate as explained hereinabove, it may also be considered, as illustrated in
[0064]
[0065] As illustrated in
NOMENCLATURE
[0066] 1. Monocrystalline sapphire seed [0067] 2. Plate [0068] 4. Planar faces [0069] a Angle [0070] D1 Normal [0071] L Growth direction [0072] 6. Sapphire single-crystal [0073] 8. Blanks [0074] 10. Watch glasses [0075] 12. Planar face [0076] 14. Edges [0077] 16A. Monocrystalline sapphire bar [0078] 16B. Monocrystalline sapphire cylinder [0079] 16C. Monocrystalline sapphire cylinder [0080] 18A. Sapphire single-crystal ball [0081] 18B. Sapphire single-crystal ball [0082] 18C. Sapphire single-crystal ball [0083] D2 Normal [0084] S Cross-section [0085] D3 Growth direction [0086] 20. Cutting tool [0087] 22. Monocrystalline sapphire seed [0088] 24. First plate [0089] 26. Planar faces [0090] 28. Sapphire single-crystals [0091] 30. Die [0092] 32. Channels [0093] 34. Planar faces