METHOD FOR PRODUCING MULTI-LAYERED THERMOPLASTIC PLATES BY MEANS OF THERMAL WELDING OF DIFFERENT PLATES

Abstract

The invention relates to a process for the production of at least two-layer thermoplastic sheets via thermal welding of at least one thinner thermoplastic sheet with density (D1) and of at least one second thinner thermoplastic sheet with density (D2), where the density (D1) of the first thinner thermoplastic sheet is smaller than the density (D2) of the second thinner thermoplastic sheet. The process introduces at least one first heating element and at least one second heating element along mutually offset planes between the two thinner thermoplastic sheets, where the surfaces of the thinner thermoplastic sheets do not touch the surfaces of the heating elements. The first heating element transfers a quantity of energy (E1) to the surface of the first thinner thermoplastic sheet, and the second heating element transfers a quantity of energy (E2) to the surface of the second thinner thermoplastic sheet, where the quantity of energy (E1) is smaller than the quantity of energy (E2).

Claims

1.-14. (canceled)

15. A process for the production of at least two-layer thermoplastic sheets via thermal welding of at least one first thinner thermoplastic sheet with density (D1) and of at least one second thinner thermoplastic sheet with density (D2), where the density (D1) of the first thinner thermoplastic sheet is smaller than the density (D2) of the second thinner thermoplastic sheet, comprising the following steps a) to e): a) orienting the first thinner thermoplastic sheet and the second thinner thermoplastic sheet parallel to one another at a distance (a) from one another, thus forming an intervening space, b) introducing at least one first heating element and at least one second heating element along mutually parallel offset planes into the intervening space in a manner that is parallel to the two thinner thermoplastic sheets, where the surfaces of the thinner thermoplastic sheets and the surfaces of the heating elements do not touch one another and with a distance (a1) between the first heating element and the first thinner thermoplastic sheet and a distance (a2) between the second heating element and the second thinner thermoplastic sheet, c) introducing the heating elements between the two thinner thermoplastic sheets to an extent such that, in relation to every location on the surface of the first thinner thermoplastic sheet, the first heating element has been present at least temporarily between the two thinner thermoplastic sheets, and to such an extent that, in relation to every location on the surface of the second thinner thermoplastic sheet, the second heating element has been present at least temporarily between the two thinner thermoplastic sheets, where the first heating element transfers a quantity of energy (E1) to the surface of the first thinner thermoplastic sheet and the second heating element transfers a quantity of energy (E2) to the surface of the second thinner thermoplastic sheet, where the quantity of energy (E1) that the first heating element transfers to the surface of the first thinner thermoplastic sheet is smaller than the quantity of energy (E2) that the second heating element transfers to the surface of the second thinner thermoplastic sheet, d) removing the heating elements entirely from the intervening space, e) pressing at least one of the two thinner thermoplastic sheets against the surface of the respective other thinner thermoplastic sheet.

16. The process according to claim 15, wherein i) the quantity of energy (E1) that the first heating element transfers to the first thinner thermoplastic sheet is adjusted via the distance (a1) between the first heating element and the first thinner thermoplastic sheet, or ii) the quantity of energy (E2) that the second heating element transfers to the second thinner thermoplastic sheet is adjusted via the distance (a2) between the second heating element and the second thinner thermoplastic sheet.

17. The process according to claim 15, wherein the quantity of energy (E1) that the first heating element transfers to the first thinner thermoplastic sheet is adjusted via the temperature (T1) of the first heating element, or ii) the quantity of energy (E2) that the second heating element transfers to the second thinner thermoplastic sheet is adjusted via the temperature (T2) of the second heating element.

18. The process according to claim 15, wherein i) the density (D1) of the first thinner thermoplastic sheet is in the range from 10 to 70 g/l, or ii) the density (D2) of the second thinner thermoplastic sheet is in the range from 25 to 100 g/l, or iii) the density (D1) is smaller by at least 1 g/l than the density (D2).

19. The process according to claim 15, wherein when the heating elements have been introduced into the intervening space they are kept there for a time in the range from 0.2 to 10 seconds.

20. The process according to claim 15, wherein i) the first thinner thermoplastic sheet is a foam sheet based on a polymer selected from the group consisting of polystyrene, polystyrene copolymers, polyether sulfone, polysulfone, polyethylene terephthalate, polyurethane, polyolefins, polyolefin copolymers and acrylic polymers, or ii) the second thinner thermoplastic sheet is a thermoplastic polymer selected from the group consisting of polystyrene, polystyrene copolymers, polyether sulfone, polysulfone, polyethylene terephthalate, polyurethane, polyolefins, polyolefin copolymers and acrylic polymers.

21. The process according to claim 15, wherein the thickness of the weld formed by the thermal welding process is from 30 to 500 μm.

22. The process according to claim 15, wherein i) the first thinner thermoplastic sheet is a foam sheet, where the surface to be welded is free from the foam skin, or ii) the second thinner thermoplastic sheet is a foam sheet, where the surface to be welded is free from foam skin.

23. The process according to claim 15, wherein in step b) two heating elements are introduced from respectively mutually opposite directions into the intervening space or in step d) two heating elements are in turn removed in respectively mutually opposite directions from the intervening space.

24. The process according to claim 15, wherein i) the distance (a1) between the first heating element and the first thinner thermoplastic sheet is in the range from 0.5 to 10 mm, or ii) the distance (a2) between the second heating element and the second thinner thermoplastic sheet is in the range from 0.2 to 7.5 mm.

25. The process according to claim 15, wherein i) precisely two heating elements are used or the heating elements are heating plates, preferably heating plates with a surface temperature in the range from 200 to 700° C., heated indirectly by means of IR sources, or ii) the heating elements in steps b) or d) are moved with a velocity of from 0.1 to 5 m/s.

26. The process according to claim 15, wherein i) the first thinner thermoplastic sheet comprises at least one flame retardant, or ii) the second thinner thermoplastic sheet comprises at least one flame retardant, or iii) during the thermal welding process the surface of the first thinner thermoplastic sheet is heated to temperatures of from 50 to 300° C. above the glass transition temperature in the case of amorphous thermoplastic foams or from 50 to 100° C. above the melting point in the case of semicrystalline thermoplastic foams, or iv) during the thermal welding process the surface of the second thinner thermoplastic sheet is heated to temperatures of from 50 to 300° C. above the glass transition temperature in the case of amorphous thermoplastic foams or from 50 to 100° C. above the melting point in the case of semicrystalline thermoplastic polymers.

27. The process according to claim 15, wherein i) the total duration of the steps h) to e) is at most 20 seconds, or ii) the process is carried out in a thermally insulated enclosure and in the thermal enclosure a temperature is maintained that is constant to the extent of +/−10° C. in the range from 40 to 200° C.

28. The process according to claim 15, wherein i) the length (x-direction) of the first thinner thermoplastic sheet in step a) is from 500 to 2800 mm, its width (y-direction) being from 500 to 1250 mm, and its thickness (z-direction) being from 20 to 200 mm, or the length (x-direction) of the second thinner thermoplastic sheet in step a) is from 500 to 2800 mm, its width (y-direction) being from 500 to 1250 mm, and its thickness (z-direction) being from 20 to 200 mm, or iii) the length (x-direction) of the first heating element is the same as or at most 10% greater than the length (x-direction) of the first thinner thermoplastic sheet, and the width (y-direction) of the first heating element is from 30 to 120% of the width (y-direction) of the first thinner thermoplastic sheet, or iv) the length (x-direction) of the second heating element is the same as or at most 10% greater than the length (x-direction) of the second thinner thermoplastic sheet, and the width (y-direction) of the second heating element is from 30 to 120% of the width (y-direction) of the second thinner thermoplastic sheet, or v) the heating elements are moved in a manner that is parallel to the xy-plane and along the y-direction (width) of the two thinner thermoplastic sheets.

29. The process according to claim 18, wherein the density (D2) of the second thinner thermoplastic sheet is in the range from 30 to 100 g/l.

30. The process according to claim 18, wherein the density (D2) of the second thinner thermoplastic sheet is in the range from 30 to 75 g/l.

Description

EXAMPLES

Thinner Thermoplastic Sheets

[0120] The following thinner thermoplastic sheets were used:

Styropor density 15 g/l: foamed sheets made of Styropor® F15E (BASF SE)
Styrodur density 32 g/l: Styrodur® 3035 CS (BASF SE)
Styrodur density 46 g/l: Styrodur® 5000 CS (BASF SE)
Neopor density 15 g/l: foamed sheets made of Neopor® 2200(BASF SE)
PS/PPE density 48 g/l: sheet foamed in pilot plant (XPS process), made of Noryl® FN215X (Sabic)
PET foam density 80 g/l: AC 80 (Armacell)
PET foam density 100 g/l: AC 100 (Armacell)
PES foam density 50 g/l: Dinvinylcell F50 (Diab)
SAN foam density 33 g/l: sheet foamed in pilot plant (XPS process), made of Luran 368R (Styrolution)
PMMA: sheets made of Plexiglas® WH46SC (Evonik)
ABS/ASA: sheets made of Formaterm (Röchling)

Production of Two-Layer Thermoplastic Sheets

[0121] The first thinner thermoplastic sheet and the second thinner thermoplastic sheet were oriented parallel to one another at a distance (a) from one another (see Table 1), so that they formed an intervening space.

[0122] Table 1 states the density (D1) and (D2) of the first thinner thermoplastic sheet and of the second thinner thermoplastic sheet, together with the other production parameters, and also the properties of the two-layer thermoplastic sheets produced in the invention.

[0123] A first and a second heating element were introduced along offset mutually parallel planes into the intervening space in a manner that was parallel to the two thinner thermoplastic sheets. The distance (a1) between the first thinner thermoplastic sheet and the first heating element is stated in Table 1, as also is the distance (a2) between the second thinner thermoplastic sheet and the second heating element. The temperature of the first heating element was the same as that of the second heating element (T in Table 1). The two heating elements were allowed to remain between the two thinner thermoplastic sheets for a time (t).

[0124] The heating elements were then removed from the intervening space between the two thinner thermoplastic sheets, and one sheet was pressed against the surface of the respective other thinner thermoplastic sheet.

[0125] The resultant two-layer thermoplastic sheet had the tensile strength stated in Table 1. Tensile strength was determined in accordance with DIN EN ISO 1798:2008.

TABLE-US-00001 TABLE 1 Tensile First Second D1 D2 T t a1 a2 a strength Example sheet sheet [g/l] [g/l] [° C.] [sec] [mm] [mm] [mm] [N/mm.sup.2] 1 Styropor Styrodur 15 32 350 1.6 2.0 0.7 32.7 0.23 2 Styrodur Styrodur 32 46 350 1.6 0.7 0.3 31.0 0.53 3 Neopor Styrodur 15 32 350 1.6 2.4 0.7 33.1 0.21 4 E-Por Styrodur 25 32 350 1.6 1.4 0.7 32.1 0.28 5 Styrodur PS/PPE 32 48 370 3.0 1.4 0.7 32.1 0.40 6 PET PET 80 100 360 2.5 1.3 0.8 32.1 0.45 7 PES PMMA 45 1180 390 3.0 5.05 0.5 35.5 0.28 8 SAN ASA 33 1030 360 1.8 4.0 0.7 34.7 0.39