Insulated Gate Structure, Wide Bandgap Material Power Device With the Same and Manufacturing Method Thereof
20230187525 · 2023-06-15
Inventors
Cpc classification
H01L21/049
ELECTRICITY
H01L21/441
ELECTRICITY
H01L21/28264
ELECTRICITY
H01L29/42364
ELECTRICITY
H01L29/518
ELECTRICITY
H01L29/24
ELECTRICITY
H01L29/513
ELECTRICITY
International classification
H01L29/16
ELECTRICITY
H01L29/40
ELECTRICITY
Abstract
An insulated gate structure includes a wide bandgap material layer having a channel region of a first conductivity type. A gate insulating layer is arranged directly on the channel region and has a first nitride layer that is arranged directly on the channel region. The gate insulating layer has a concentration of carbon atoms that is less than 10.sup.18 atoms/cm.sup.−3 at a distance of 3 nm from an interface between the wide bandgap material layer and the first nitride layer. An electrically conductive gate electrode layer overlies the gate insulating layer so that the gate electrode layer is separated from the wide bandgap material layer by the gate insulating layer.
Claims
1-14. (canceled)
15. An insulated gate structure comprising: a wide bandgap material layer comprising a channel region of a first conductivity type; a gate insulating layer arranged directly on the channel region, the gate insulating layer comprising a first nitride layer that is arranged directly on the channel region, wherein the gate insulating layer has a concentration of carbon atoms that is less than 10.sup.18 atoms/cm.sup.−3 at a distance of 3 nm from an interface between the wide bandgap material layer and the first nitride layer and wherein the first nitride layer comprises a stochiometric silicon nitride layer, an aluminum nitride layer, a boron nitride layer or a phosphorous nitride layer; and an electrically conductive gate electrode layer over the gate insulating layer so that the gate electrode layer is separated from the wide bandgap material layer by the gate insulating layer.
16. The insulated gate structure according to claim 15, wherein the first nitride layer has a thickness that is less than 20 nm.
17. The insulated gate structure according to claim 15, wherein the first nitride layer has a thickness that is less than 5 nm.
18. The insulated gate structure according to claim 15, wherein the gate insulating layer further comprises an intermediate insulating layer on the first nitride layer, wherein the intermediate insulating layer is made of a material different from that of the first nitride layer.
19. The insulated gate structure according to claim 18, further comprising a second nitride layer is arranged directly on the intermediate insulating layer so that the intermediate insulating layer is sandwiched between the first nitride layer and the second nitride layer.
20. The insulated gate structure according to claim 18, wherein the wide bandgap material layer is a silicon carbide layer and the intermediate insulating layer comprises a high-k dielectric layer that has a dielectric constant higher than that of Si.sub.3N.sub.4.
21. The insulated gate structure according to claim 18, wherein the wide bandgap material layer is a silicon carbide layer and the intermediate insulating layer comprises a silicon oxide layer.
22. A wide bandgap material power device comprising: a wide bandgap material layer comprising a channel region of a first conductivity type and a source region and a drain region of a second conductivity different than the first conductivity type, the source region spaced from the drain region by the channel region; a gate insulating layer arranged directly on the channel region, the gate insulating layer comprising a first nitride layer that is arranged directly on the channel region, wherein the gate insulating layer has a concentration of carbon atoms that is less than 10.sup.18 atoms/cm.sup.−3 at a distance of 3 nm from an interface between the wide bandgap material layer and the first nitride layer and wherein the first nitride layer comprises a stochiometric silicon nitride layer, an aluminum nitride layer, a boron nitride layer or a phosphorous nitride layer; and an electrically conductive gate electrode layer over the gate insulating layer so that the gate electrode layer is separated from the wide bandgap material layer by the gate insulating layer.
23. The device according to claim 22, wherein: the wide bandgap material layer is a silicon carbide layer; the gate insulating layer further comprises an intermediate insulating layer on the first nitride layer and a second nitride layer arranged directly on the intermediate insulating layer; and the intermediate insulating layer comprises a high-k dielectric layer that has a dielectric constant higher than that of Si.sub.3N.sub.4.
24. A method for manufacturing an insulated gate structure, the method comprising: forming a gate insulating layer arranged directly on a channel region of a wide bandgap material layer, the gate insulating layer comprising a first nitride layer that is arranged directly on the channel region, wherein the gate insulating layer has a concentration of carbon atoms that is less than 10.sup.18 atoms/cm.sup.−3 at a distance of 3 nm from an interface between the wide bandgap material layer and the first nitride layer and wherein the first nitride layer comprises a stochiometric silicon nitride layer, an aluminum nitride layer, a boron nitride layer or a phosphorous nitride layer; and forming an electrically conductive gate electrode layer over the gate insulating layer.
25. The method according to claim 24, wherein forming the gate insulating layer comprises: depositing a preliminary layer directly on the channel region of the wide bandgap material layer, wherein the preliminary layer comprises silicon, aluminum, boron, or phosphorous or any combination thereof; and nitriding the preliminary layer in a nitrogen containing atmosphere to form the first nitride layer.
26. The method according to claim 25, wherein the nitriding is performed at a temperature in a range between 800° C. and 1400° C.
27. The method according to claim 25, wherein the preliminary layer comprises an amorphous silicon layer.
28. The method according to claim 25, wherein depositing the preliminary layer comprises depositing a layer having a thickness of less than 15 nm.
29. The method according to claim 28, wherein depositing the preliminary layer comprises depositing a layer having a thickness of less than 3.75 nm.
30. The method according to claim 25, wherein forming the gate insulating layer further comprises forming a second nitride layer on the preliminary layer before the nitriding.
31. The method according to claim 25, wherein forming the gate insulating layer further comprises forming a silicon oxide layer on the preliminary layer before the step of nitriding.
32. The method according to claim 25, wherein forming the gate insulating layer further comprises forming an intermediate insulating layer on the first nitride layer.
33. The method according to claim .sub.32, wherein forming the gate insulating layer further comprises forming a second nitride layer on the intermediate insulating layer so that the intermediate insulating layer is sandwiched between the first nitride layer and the second nitride layer.
34. The method according to claim 32, wherein the intermediate insulating layer is a high-k dielectric layer having a dielectric constant higher than that of Si.sub.3N.sub.4.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0030] Detailed embodiments of the invention will be explained below with reference to the accompanying figures, in which:
[0031]
[0032]
[0033]
[0034]
[0035]
[0036]
[0037]
[0038]
[0039]
[0040]
[0041]
[0042]
[0043]
[0044]
[0045] The reference signs used in the figures and their meanings are summarized in the list of references signs. Generally, similar elements have the same reference signs throughout the specification. The described embodiments are meant as examples and shall not limit the scope of the invention.
DETAILED DESCRIPTION OF ILLUSTRATIVE EMBODIMENTS
[0046] In the following an insulated gate structure 101a according to a first embodiment is described with reference to
[0047] In
[0048] A thickness d1 of the first nitride layer 102 is exemplarily less than 20 nm or less than 10 nm, or less than 5 nm. Exemplarily, the thickness d1 of the first nitride layer 102 is at least 3 nm.
[0049] As in the first embodiment, a concentration of carbon atoms in the gate insulating layer 100b is less than 10.sup.18 atoms/cm.sup.−3 or less than 5×10.sup.16 atoms/cm.sup.−3 or less than 10.sup.15 atoms/cm.sup.−3 at a distance of 3 nm from an interface 501 between the silicon carbide layer 50 and the first nitride layer 102. Compared to the known insulated gate structures with a gate insulating layer on silicon carbide, the gate insulating layer 100b has a relatively low carbon concentration close to the interface 501 between the silicon carbide layer 50 and the gate insulating layer 100a, which results, as in the first embodiment, in a high carrier mobility in the channel region 53.
[0050] In
[0051]
[0052] As a comparison,
[0053]
[0054] At the second main side 59 of the SiC layer 50 there is arranged a highly doped n-type drain layer 52, on which is arranged a drain electrode layer 30 on the second main side 59. On a side of the drain layer 52 opposite to the drain electrode layer 30 is arranged an n-type drift layer 57. The first source region 54a and the second source region 54b are in electrical contact to a source electrode layer 32 arranged on the first main side 58. On the first main side 58 there is further arranged a gate insulating layer 100 directly on the first channel region 53a and on the second channel region 53b.
[0055] A gate electrode layer 200 is formed on the gate insulating layer 100 to be separated from the first channel region 53a and from the second channel region 53b by the gate insulating layer 100. The first channel region 53a, the gate insulating layer 100 and the gate electrode layer 200 form an insulated gate structure in form of a first insulated gate structure, and the second channel region 53b, the gate insulating layer 100 and the gate electrode layer 200 form an insulated gate structure in form of a second insulated gate structure in the vertical power MISFET 1000. The first and the second insulated gate structures are respectively structured in accordance with any one of the first, second or third embodiment. Therefore, for details regarding the structure of the first and second insulated gate structure it is referred to the discussion of the insulated gate structure according to the first to third embodiment as described above.
[0056] In the following a method for manufacturing the insulated gate structure 101a according to the first embodiment is described with reference to
[0057] In a second step S200, a preliminary layer is formed directly on the channel region 53. The preliminary layer comprises a silicon layer or an aluminum layer or a boron nitride layer or a phosphorous layer. Exemplarily, the preliminary layer may be an amorphous silicon layer deposited on the silicon carbide layer 50. A thickness of the preliminary layer is exemplarily less than 15 nm or less than 7.5 nm or less than 3.75 nm, and is exemplarily at least 2 nm.
[0058] In a third step S300 a nitridation of the preliminary layer is performed to form a first nitride layer. In case that the preliminary layer is a silicon layer, the first nitride layer is a silicon nitride layer such as stoichiometric Si.sub.3N.sub.4, in case that the preliminary layer is an aluminum layer the first nitride layer is an aluminum nitride (AlN) layer, in case that the preliminary layer is a boron layer, the first nitride layer is a boron nitride (BN) layer, and in case that the preliminary layer is a phosphorous layer, the first nitride layer is a phosphorous nitride (PN) layer. The resulting thickness of the first nitride layer is exemplarily less than 20 nm, less than 10 nm or less than 5 nm. Nitridation in the third step S300 is exemplarily performed in a nitrogen containing atmosphere such as in N.sub.2 at a temperature in a range between 800° C. and 1400° C., or in a range between 900° C. and 1350° C. Alternatively, nitridation may be performed in a plasma assisted process in a nitrogen containing atmosphere at a temperature between 200° C. and 500° C. Such plasma assisted process may be followed by an annealing in nitrogen containing atmosphere at a higher temperature in a range between 800° C. and 1400° C., or in a range between 900° C. and 1350° C.
[0059] The two-step process of forming the first nitride layer 102, which comprises the second step S200 of forming the preliminary layer and of the subsequent third step S300 of nitridation ensures that no reaction with the silicon carbide layer 50 takes place and no or only very little carbon from the silicon carbide layer 50 is incorporated into the gate insulating layer bow. As the inventors found out, such process in which no or only little carbon from the silicon carbide layer 50 is incorporated in the gate insulating layer results in a relatively high carrier mobility in the channel region.
[0060] In a fourth step S400 a second nitride layer 106 is formed on the first nitride layer 102 by a deposition process such as chemical vapor deposition (CVD) or plasma enhanced CVD (PECVD). The second nitride layer 106 may comprise the same nitride material as the first nitride layer 102. In case that the second nitride layer 106 is a silicon nitride layer, it may be formed by PECVD from SiH.sub.4 and NH.sub.3, for example.
[0061] In a fifth step S500, the resulting layer stack including the first nitride layer 102 and second nitride layer 106 is annealed in nitrogen (N.sub.2) to densify and heal defects in the first and second nitride layers.
[0062] Finally, in a sixth step S700, a gate electrode layer 15 is formed on the second nitride layer 106 to obtain an insulated gate structure as shown in
[0063] The resulting insulated gate structure 101a exhibits a high carrier mobility in the channel region 50 as discussed above.
[0064]
[0065]
[0066]
[0067]
[0068] In an exemplary embodiment a method for manufacturing a silicon carbide power device may comprise any one of the above exemplary embodiments of methods for forming an insulated gate structure. In case that the silicon carbide power device is a MISFET as shown in
[0069] In the above embodiments the silicon carbide power device was described to be a vertical power MISFET. However, the concept of the invention may also be applied to any other SiC power device comprising an insulated gate structure, such as to a lateral power MISFET, a gate-all around MISFET, a tri-gated MISFET or an insulated gate bipolar thyristor (IGBT).
[0070] It will be apparent for persons skilled in the art that modifications of the above described embodiment are possible without departing from the scope of the invention as defined by the appended claims.
[0071] The additional method step S150 of annealing the silicon carbide layer 50 in N.sub.2 before the step of forming the preliminary layer was discussed only as a modification of the method of
[0072] In all above embodiments the conductivity types may be switched, i.e. in any embodiment, all n-type regions may be p-type and all p-type regions may be n-type.
[0073] It should be noted that the term “comprising” does not exclude other elements or steps and that the indefinite article “a” or “an” does not exclude the plural. Also elements described in association with different embodiments may be combined.
LIST OF REFERENCE SIGNS
[0074] 1 stack-gate MIS structure
[0075] 10 insulating layer
[0076] 12 SiN.sub.x layer
[0077] 13 SiO.sub.xN.sub.y layer
[0078] 14 SiO.sub.2 layer
[0079] 15 gate electrode layer
[0080] 20 substrate
[0081] 25 interface
[0082] 30 drain electrode
[0083] 32 source electrode
[0084] 50 wide bandgap material layer
[0085] 51 drain region
[0086] 52 buffer layer
[0087] 53, 53a, 53b channel region
[0088] 54a, 54b source region
[0089] 57 drift layer
[0090] 58 first main side
[0091] 59 second main side
[0092] 100, 100a, 100b, 100c gate insulating layer
[0093] 101a, 101b, 101c insulated gate structure
[0094] 102 first nitride layer
[0095] 104 intermediate insulating layer
[0096] 106 second nitride layer
[0097] 200 gate electrode layer
[0098] 501 interface
[0099] 1000 vertical power MISFET
[0100] d1 thickness (of first nitride layer 102)
[0101] d2 thickness (of second nitride layer 104)