METHOD OF MANUFACTURING A REDISTRIBUTION LAYER, REDISTRIBUTION LAYER, INTEGRATED CIRCUIT AND METHODS FOR ELECTRICALLY TESTING AND PROTECTING THE INTEGRATED CIRCUIT
20230187389 · 2023-06-15
Assignee
Inventors
Cpc classification
H01L2224/0401
ELECTRICITY
C23C16/45536
CHEMISTRY; METALLURGY
H01L2224/05548
ELECTRICITY
H01L23/3171
ELECTRICITY
H01L2224/04042
ELECTRICITY
H01L2224/05567
ELECTRICITY
H01L21/76834
ELECTRICITY
H01L2224/05008
ELECTRICITY
H01L24/02
ELECTRICITY
H01L23/5226
ELECTRICITY
H01L22/14
ELECTRICITY
G01R31/2886
PHYSICS
International classification
C23C16/455
CHEMISTRY; METALLURGY
Abstract
To manufacture a redistribution layer for an integrated circuit, a first insulating layer is formed on a conductive interconnection layer of a wafer. A conductive body is then formed in electrical contact with the interconnection layer. The conductive body is then covered with an insulating region having an aperture that exposes a surface of the conductive body. The surface of the conductive body and the insulating region are then covered with an insulating protection layer having a thickness less than 100 nm. This insulating protection layer is configured to provide a protection against oxidation and/or corrosion of the conductive body.
Claims
1. A method of manufacturing a redistribution layer for an integrated circuit, comprising the steps of: forming a first insulating layer on a conductive interconnection layer of a wafer; forming a conductive body in electrical contact with said conductive interconnection layer; covering said conductive body with an insulating region having an aperture that exposes a surface of the conductive body; covering said surface of the conductive body and the insulating region with an insulating dielectric protection layer having a thickness less than 100 nm and configured to provide a protection against one or more of oxidation and corrosion of said conductive body.
2. The method of claim 1, wherein the step of forming the insulating dielectric protection layer comprises performing a material deposition selected from the group consisting of: an atomic layer deposition, a thermal atomic layer deposition, a plasma-assisted atomic layer deposition, a chemical vapor deposition, and a plasma-enhanced chemical vapor deposition.
3. The method of claim 1, wherein the insulating dielectric protection layer is made of a dielectric oxide material including Aluminum or Hafnium or a dielectric nitride material including Aluminum.
4. The method of claim 3, further comprising the steps of: locally perforating the insulating dielectric protection layer with a testing probe or testing tip until the conductive body is electrically contacted by said testing probe or testing tip; and carrying out an electrical test of the integrated circuit using said testing probe or testing tip.
5. The method of claim 4, further comprising, after having locally perforated the insulating dielectric protection layer, the steps of: forming a molding layer on the insulating protection layer; forming a first passing hole extending through the molding layer until a surface portion of the insulating dielectric protection layer is exposed; forming a second passing hole extending through the insulating dielectric protection layer until a said surface of the conductive body is exposed; and electrically contacting the conductive body through the first and second passing holes.
6. The method of claim 5, wherein electrically contacting the conductive body includes one of: forming a conductive pillar within said first and second passing holes which is in electrical contact with the conductive body; or carrying out a wire bonding operation on the exposed surface of the conductive body.
7. The method of claim 1, further comprising the step of covering the insulating dielectric protection layer with a further protection layer configured to sustain temperatures up to 300° C. without damages.
8. The method of claim 7, wherein the further protection layer has a coefficient of thermal expansion in a range of 0.5×.Math.10.sup.−6 to 6.0×.Math.10.sup.−6 l/K.
9. The method of claim 7, wherein the further protection layer is of a dielectric or insulating material selected from the group consisting of: a Silicon Nitride, a Silicon Carbon Nitride, a Silicon Oxycarbide, a Silicon Oxide.
10. The method of claim 7, wherein the further protection layer has a thickness in a range of 0.01 μm to 1 μm.
11. The method of claim 7, further comprising the steps of: removing selective portions of the further protection layer; locally perforating the insulating dielectric protection layer with a testing probe or testing tip until the conductive body is electrically contacted by said testing probe or testing tip; and carrying out an electrical test of the integrated circuit using said testing probe or testing tip.
12. The method of claim 1, wherein forming the insulating region includes forming a coating layer of Silicon Nitride that completely covers the conductive body.
13. The method of claim 12, wherein forming the insulating region further includes forming a photosensitive insulating layer on the coating layer.
14. The method of claim 13, wherein said photosensitive insulating layer is made of a material selected from the group consisting of: polyimide, PBO, Epoxy, and photosensitive organic material.
15. The method of claim 1, wherein forming the insulating region includes forming a photosensitive insulating layer that completely covers the conductive body.
16. The method of claim 15, wherein said photosensitive insulating layer is made of a material selected from the group consisting of: polyimide, PBO, Epoxy, and photosensitive organic material.
17. A redistribution layer for an integrated circuit, comprising: a conductive interconnection layer; a conductive body in electrical contract with said conductive interconnection layer; an insulating region around the conductive body having an aperture at a surface of the conductive body; an insulating dielectric protection layer extending on said insulating region and partially on said surface of the conductive body, having a thickness less than 100 nm, and being configured to provide a protection against oxidation and/or corrosion of said conductive body.
18. The redistribution layer of claim 17, wherein the insulating dielectric protection layer is made of a dielectric oxide material including Aluminum or Hafnium or a dielectric nitride material including Aluminum.
19. The redistribution layer of claim 17, further comprising a further protection layer on the insulating dielectric protection layer, the further protection layer being configured to sustain temperatures up to 300° C. without damages.
20. The redistribution layer of claim 19, wherein the further protection layer has a coefficient of thermal expansion in a range of 0.5×.Math.10.sup.−6 to 6.0×.Math.10.sup.−6 l/K.
21. The redistribution layer of claim 19, wherein the further protection layer is made of a dielectric or insulating material selected from the group consisting of: a Silicon Nitride, a Silicon Carbon Nitride, a Silicon Oxycarbide, and a Silicon Oxide.
22. The redistribution layer of claim 19, wherein the further protection layer has a thickness in a range of 0.01 μm to 1 μm.
23. The redistribution layer of claim 17, wherein the insulating region includes a coating layer of Silicon Nitride that completely covers the conductive body.
24. The redistribution layer of claim 23, wherein the insulating region further includes a photosensitive insulating layer on the coating layer.
25. The redistribution layer of claim 24, wherein said photosensitive insulating layer is made of a material selected from the group consisting of: polyimide, PBO, Epoxy, and photosensitive organic material.
26. The redistribution layer of claim 17, wherein the insulating region includes a photosensitive insulating layer that completely covers the conductive body.
27. The redistribution layer of claim 26, wherein said photosensitive insulating layer is made of a material selected from the group consisting of: polyimide, PBO, Epoxy, and photosensitive organic material.
28. The redistribution layer of claim 17, further comprising: a molding layer on the insulating dielectric protection layer having a first passing hole that reaches a surface portion of the insulating dielectric protection layer; wherein the insulating dielectric protection layer has a second passing hole that reaches said surface of the conductive body; and the redistribution layer further comprises an electrical contact element that electrically contacts the conductive body through the first and second passing holes.
29. The redistribution layer of claim 28, wherein the electrical contact element includes one of: a conductive pillar within said first and second passing holes, in electrical contact with the conductive body; or a wire, which is bonded to the exposed surface of the conductive body.
30. An integrated circuit having a redistribution layer according to claim 16.
31. A method of performing an electrical test of an integrated circuit including a redistribution layer according to claim 17, comprising the steps of: locally perforating the insulating protection layer with a testing probe or testing tip until the conductive body is electrically contacted by said testing probe or testing tip; and carrying out said electrical test through the testing probe or testing tip.
32. A method, comprising: manufacturing a redistribution layer for an integrated circuit in accordance with claim 1; forming a molding layer on the protection layer; forming a first passing hole extending through the molding layer until a surface portion of the protection layer is exposed; forming a second passing hole extending through the protection layer until said surface of the conductive body is exposed; and electrically contacting the conductive body through the first and second passing holes.
33. The method of claim 32, wherein electrically contacting the conductive body includes one of: forming a conductive pillar within said first and second passing holes, in electrical contact with the conductive body; or carry out a wire bonding operation on the exposed surface of the conductive body.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0025] For a better understanding of the present invention, preferred embodiments thereof are now described, purely by way of non-limiting example and with reference to the attached drawings, wherein:
[0026]
[0027]
[0028]
[0029]
[0030]
DETAILED DESCRIPTION
[0031]
[0032]
[0033] The IC 30 further comprises an interconnection layer 33, made of conductive material such as aluminum or copper. In particular, the interconnection layer 33 may be the last metal line (i.e., the upper-most one) of the back end of line (BEOL) of IC 30.
[0034] The redistribution layer 32 may include a dielectric layer 34 extending above the interconnection layer 33 and a passivation layer 36 extending above the dielectric layer 34. One or more further layers (not shown) may be present between the interconnection layer 33 and the dielectric layer 34 (e.g., in case layer 33 is of Cu, a further SiN layer that protects the Cu metallization may be present between the interconnection layer 33 and the dielectric layer 34). In particular, the dielectric layer 34 is made of an insulating material, such as silicon dioxide (SiO.sub.2) or a multi stack dielectric made by SiN and SiO.sub.2; the passivation layer 36 is made of an insulating material, such as silicon nitride (Si.sub.3N.sub.4).
[0035] The dielectric layer 34 and the passivation layer 36 may be replaced by one single layer of insulating or dielectric material. Therefore, in the following, the term “insulating layer 37” refers either to the stack composed of the dielectric layer 34 and the passivation layer 36, or to a stack formed by more than two layers (e.g., three layers), or otherwise a single layer.
[0036] The redistribution layer 32 further comprises a barrier region 38 of conductive material. The barrier region 38 extends across the whole thickness of the insulating layer 37, so as to be in contact with the interconnection layer 33.
[0037] The redistribution layer 32 further comprises a conductive region 40, extending on top of the barrier region 38, and having a top surface 40a and lateral walls (or sidewalls) 40b. In particular, in a top view of the IC 30, not shown in the figures, the conductive region 40 is extending only inside the area defined by the barrier region 38. In the following, the term “conductive body” refers to a stack 41 including the barrier region 38 and the conductive region 40. It is noted that, according to a further embodiment, the barrier region 38 may be omitted; accordingly, in such embodiment, the term “conductive body” refers to the conductive region 40 only.
[0038] The conductive body 41 forms a conductive path from the interconnection layer 33 to the top surface of the insulating layer 37.
[0039] In one embodiment, the barrier region 38 is made of conductive material, such as titanium (Ti), or titanium-tungsten (TiW), or titanium nitride (TiN), and has thickness comprised for instance between 270 nm and 330 nm. In one embodiment, the conductive region 40 is made of conductive material, in particular metal such as copper (Cu), and has thickness comprised for instance between 8 μm and 12 μm.
[0040] The redistribution layer 32 further comprises a coating layer 42 that partially covers the conductive region 40; in particular, the coating layer 42 extends around the conductive region 40 completely covering the lateral walls 40b of the conductive region 40 and partially above the conductive region 40, leaving an opening 42a at the top surface of the conductive region 40, through which the surface 40a of the conductive region 40 is exposed during intermediate manufacturing steps (as better detailed later).
[0041] According to an aspect, the coating layer 42 is made of a dielectric or insulating material, in particular Silicon Nitride, for example with a thickness of about 0.5-1 μm. Other thicknesses may be chosen, according to the needs.
[0042] A further insulating layer 43, such as a photosensitive insulating layer, extends above the insulating layer 37 and above the coating layer 42. The opening 42a is completely contained (in top-plan view, on the xy plane) within the opening 43a (in one embodiment, they have the same dimension). Materials of such further insulating layer 43 include polyimide, PBO, Epoxy, photosensitive organic material, etc.
[0043] A protection layer 50, made of a material that provides a protection of the conductive region 40 against oxidation and/or corrosion phenomena, extends on the insulating layer 43 and partially on the conductive region 40 where the conductive region 40 is not covered by the coating layer 42 (due to manufacturing steps, as better explained later).
[0044] The protection layer 50 has an opening 50a that coincides (in top-plan view, on the xy plane) with the opening 42a; the opening 50a is therefore completely contained (in top-plan view, on the xy plane) within the opening 43a of the insulating layer 43.
[0045] The protection layer 50 has a thickness in the nanometers range (i.e., lower than 100 nm). For instance, the thickness of the protection layer 50 is uniform and is between 1 nm and 100 nm, more in particular between 5 nm and 50 nm.
[0046] According to embodiments, protection layer 50 is made of an insulating or dielectric material, in particular including Aluminum or Hafnium, or is of an alloy or composite material including Aluminum and/or Hafnium. Exemplary materials are Al.sub.2O.sub.3, HfO.sub.2, Hf.sub.iAl.sub.jO.sub.k (where j and k are freely selectable), AlN, Al.sub.iN.sub.jO.sub.k (where i, j and k are freely selectable), HfN.sub.i (where i is freely selectable). The protection layer 50 may also be a stack formed by a plurality of layers including Aluminum and/or Hafnium and/or their alloys or composites, such as a stack including two or more among HfO.sub.2/Al.sub.2O.sub.3/AlN/HfN.sub.i.
[0047] Other materials or alloys are possible, provided that they can act as protecting layers against corrosion or degradation or oxidation phenomena of the conductive region 40, and can be deposited with a thickness within the above-identified range.
[0048] The protection layer 50 has the following characteristics: good conformity, good continuity, good chemical resistance, good mechanical-electrical properties, and it is not electrically conductive (i.e., it has dielectric or insulating properties). In particular, the conformity and the continuity directly derive from the choice, better discussed later, of depositing this layer by atomic layer deposition (ALD); the chemical resistance, electrical properties and the mechanical-electrical properties are a consequence of the material chosen (as discussed above).
[0049] A molding layer 44 extends above the insulating layer 43, and the protection layer 50. The molding layer 44 has a passing hole 45 aligned with the openings 42a, 43a and 50a, and has (in top plan view) the same dimensions as the opening 50a. In intermediate steps of manufacturing, the conductive region 40 is exposed through the opening 50a and the passing hole 45 (as better detailed later).
[0050] A thick copper layer 46 (pillar) extends within the passing hole 45 and the opening 50a, reaching the top surface 40a of the conductive region 40 and thus providing electrical access to the conductive region 40 and to the interconnection layer 33 from the environment external to the redistribution layer 42.
[0051] As an alternative to the thick copper layer 46, wire bonding can also be used to provide electrical contact to/from the conductive region 40.
[0052] It is noted that the molding layer 44 is physically coupled to (lies on) the protection layer 50. The molding layer 44 adheres to the protection layer 50 without intermediate undesired layers or regions, and delamination or detachments issues are not present. It is noted that, in other embodiments, not explicitly shown in the drawings, further layers or regions may be present at the interface between the protection layer 50 and the molding layer 44, with the aim of improving the adherence, or for other manufacturing or electrical requirements. In any case, it is noted that according to all the embodiments, a corroded or oxidized layer like the undesired layer 23 in
[0053] EWS (“Electrical Wafer Sorting”) testing is normally carried out before the formation of the thick copper layer 46 (and normally before formation of the molding layer 44). In particular, according to an aspect, EWS testing is carried out at a manufacturing step when the conductive layer 40 is completely covered with, and therefore protected by, the protection layer 50.
[0054] As known, EWS testing is carried out using a contacting probe or tip of hard material, typically metal, that is configured to directly contact a conductive surface. Here, during EWS testing, the contacting probe/tip contacts the conductive layer 40. The presence of the protection layer 50 does not significantly impact the execution of EWS tests, since it is thin enough for the contacting probe/tip to “break” it or, more specifically, to pass through it without difficulties. Therefore, during EWS testing, the contacting probe/tip is directed on the protection layer 50 at the conductive layer 40 and pressed on the protection layer 50 until the contacting probe/tip penetrates through the protection layer 50 and reaches (electrically contacts) the conductive layer 40, establishing the required electrical connection for carrying out the tests. The rest of the surface of the conductive layer 40 is, during testing, protected against corrosion or oxidations phenomena that may happen during testing. High temperature testing (up and above 150° C., for example up to 200-300° C.) can be carried out without damaging or causing the formation of undesired layers on the conductive layer 40. Other reliability tests, other the EWS testing or further to EWS testing, may also be carried out at high temperatures (up to 300° C.).
[0055]
[0056] With reference to
[0057] The dielectric layer 34 is formed above the interconnection layer 33. In particular, the dielectric layer 34 is made of an insulating material, such as silicon dioxide (SiO.sub.2), and has thickness comprised for instance between 900 nm and 1200 nm.
[0058] The passivation layer 36 is formed above the dielectric layer 34. In particular, the passivation layer 36 is made of an insulating material, such as silicon nitride (Si.sub.3N.sub.4), and has thickness comprised for instance between 500 nm and 650 nm. In the following, the term “insulating layer” refers, as already said, to the stack 37 formed by the dielectric layer 34 and the first passivation layer 36, or to a stack formed by more than two dielectric/insulating layers, or even to a single layer of insulating or dielectric or passivation material.
[0059] Then, in
[0060] Then, in
[0061] In particular, the barrier layer 38 is made of conductive material, such as titanium (Ti), or titanium-tungsten (TiW), or titanium nitride (TiN). Moreover, the thickness of the barrier layer 38 may be lower than the combined thickness of the dielectric layer 34 and the first passivation layer 36, and in particular is comprised for instance between 270 nm and 330 nm. Then, a seed layer 39 is formed above the barrier layer 38, partially filling the via 67. For instance, the seed layer 39 is deposited by PVD.
[0062] In particular, the seed layer 39 is made of conductive material, such as copper (Cu), and has thickness comprised for instance between 180 nm and 220 nm, such that the via 67 is only partially filled by the seed layer 39.
[0063] Then, in
[0064] In particular,
[0065] Then, in
[0066] In particular, the conductive layer 70 is made of the same conductive material of the seed layer 39, such as copper (Cu), and has thickness comprised for instance between 8 μm and 12 μm.
[0067] In particular, the conductive layer 70 is formed by electrodeposition. Then, the photolithography mask 70′ is removed by a wet removal process, exposing portions of the seed layer 39 not covered by the conductive layer 70.
[0068] Then, in
[0069] Then, the exposed portions of the barrier layer 38 are removed, for instance by wet etching, up to exposing the portions of the first passivation layer 36 underneath, without affecting the portions of the barrier layer 38 below the conductive layer 70, for instance by employing standard photolithography techniques by or directly using layer 40 as a mask for the underlying layer 38. As a consequence, the barrier layer 38 of the redistribution layer 32 of
[0070] Then, in
[0071] The coating layer 42 completely covers the conductive region 40 and the passivation region 36
[0072] Then, in
[0073] The aperture 43a is formed through the insulating layer 43, by patterning the insulating layer 43 through photolithographic techniques, to form an access to the coating layer 42. As said above, the insulating layer 43 is a photosensitive material. Region 43a is formed through photolithographic patterning known per se to the one skilled in the art (e.g., exposure to suitable radiation through a photolithographic mask, followed by chemical development step that removed the photosensitive material where exposed (or not exposed, depending on resin type, which can be of a positive or negative type).
[0074] Then, in
[0075] A native oxide can grow on the exposed surface of the conductive layer 40. A cleaning step can be carried out to remove the native oxide, for example using a chemistry based on HF.
[0076] With reference to
[0077] The protection layer 50 completely and uniformly covers the conductive region 40 (where exposed through aperture 43a) as well as the insulating layer 43.
[0078] Plasma-assisted ALD or thermal ALD can be used interchangeably to form the protection layer 50.
[0079] The process for forming the protection layer 50 includes the following parameters: temperature range during deposition, for plasma-assisted ALD: 20-300° C.; temperature range during deposition, for thermal ALD: 150-500° C.; type of precursors used (at least one among): TMA, H.sub.2O, HfCl.sub.4, O.sub.3+TEMAHf, N.sub.2H.sub.4, NH.sub.3; typically, two precursors are used together, such as H.sub.2O+TMA to obtain Al.sub.2O.sub.3, or HfCl.sub.4+H.sub.2O to obtain HfO.sub.2; pressure range during deposition, for plasma-assisted ALD: equal to or less than 1 Torr; and pressure range during deposition, for thermal ALD: from 1 mTorr to 20 Torr.
[0080] The protection layer 50 thus formed has the following properties: density (@ 20° C.) in the range 2-11 g/cm.sub.3; and refractive index (at 550 nm-633 nm wavelength) in the range 1.6-2.3.
[0081] Another process for forming the protection layer 50 (which can be applied in the context of the embodiment of
[0082] After the steps of
[0083] Then,
[0084] The steps for forming the molding layer 44 are carried out during the back-end process. Selective portions of the molding layer 44 are then removed (for example by a LiSI— “Laser Induced Strip Interconnect”—process step), thereby forming the passing hole 45.
[0085] A step of forming a conductive connection region 46, in the form of pillar (analogously to the pillar 25 of
[0086] The described process is one of the possible alternatives to form Copper Direct Interconnect (that is, providing electrical connection between die and package without resorting to wire bonding). Alternatives may foresee the use of materials different from the molding for packaging, and techniques different for LiSI, such as an aEASI process. Moreover, alternatively to the step of forming a conductive connection region 46 in the form of pillar, a wire bonding can be implemented, as apparent to the skilled person in the art. In case of wire bonding, the layer 44 is formed afterwards and partially covers the wire.
[0087]
[0088] The redistribution layer of
[0089]
[0090] The redistribution layer of
[0091] The second protection layer 84 is made of a material having a low thermal expansion coefficient in the range 0.5.Math.×10.sup.−6-6.0×≠10.sup.−6 l/K, to provide a further protection to the conductive region 40 during high-temperature EWS testing. In particular, the second protection layer 84 provides a further protection against corrosion/oxidation/degradation of the conductive region 40 in case, during high-temperatures EWS processes, the protection layer 50 locally breaks or cracks.
[0092] Exemplary materials that can be used for the second protection layer 84 are insulators or dielectrics, such as Silicon Nitrides (e.g., Si.sub.3N.sub.4), Silicon Carbon Nitrides (SiCN), Silicon Oxides (e.g., SiO.sub.2), Silicon Oxycarbides (SiOC). The second protection layer 84 can also be formed as a stack including one or more of the above-listed materials.
[0093] The second protection layer 84 has a thickness in the range 0.01 μm-1 μm (for example, between 0.1 μm and 1 μm).
[0094] In general, the material of the second protection layer 84 is chosen such that it can sustain high temperatures (up to 300° C.) during high-temperature testing (such as EWS tests) without damages. In particular, such damages include cracking, fractures, etc., which may cause electromigration phenomena, electrochemical migrations, etc.
[0095] The process steps for manufacturing the embodiment of
[0096] The advantages of the structures and processes described previously, according to the various embodiments, emerge clearly from the foregoing description.
[0097] In particular, the protection layer 50 is considerably thin and can be deposited by ALD with a highly controlled thickness, and good conformity. Is also provides a good diffusion barrier for the underlying Copper region 40 (it acts as a corrosion migration barrier); it further enables EWS testing without the need for a preliminary etching step, thus preserving the thermomechanical stability.
[0098] Further advantages include cost saving, due to a simpler manufacturing process than the prior art; improved oxidation protection during taping and reduced delamination in case of BSM (back side metal) needs; no risk of unstable EWS test at high temperatures; no risk of contamination of the photosensitive insulating layer 43 during front-end processes and reduced contamination risk during EWS; no risk of contamination of the conductive layer 40 during front-end (FE) processes and reduced contamination risk during EWS; low risk of corrosion when the device is stored in an uncontrolled environment before during/after EWS and shipment; low risk of corrosion of the conductive layer 40 during back grinding (tape contamination) and around pad opening (during LiSI or, generally, during direct Cu interconnect assembly).
[0099] Finally, it is clear that modifications and variations may be made to what has been described and illustrated herein, without thereby departing from the scope of the present invention, as defined in the annexed claims.
[0100] For example, insulating layers 37 and 43 may be of a same material, so that at the end of manufacturing they result in a single insulating region or insulating layer.
[0101] In particular, even though the advantages and specific application of the present invention has been discussed with explicit reference to EWS testing, the present invention is advantageous, and can be used, to protect the conductive layer 40 from corrosion/oxidation phenomena during all phases of the FE (front-end) and BE (back-end) process flow (and between FE and BE), guaranteeing at the same time the electrical testability without degradation or pad probe instability (in particular during EWS/PT carried out between FE and BE phases).