Semiconductor structure and manufacturing method of the same
11678493 · 2023-06-13
Assignee
Inventors
- Alexander Kalnitsky (San Francisco, CA)
- Sheng-Huang Huang (Hsinchu, TW)
- Harry-Hak-Lay Chuang (Singapore, SG)
- Jiunyu Tsai (Hsinchu, TW)
- Hung Cho Wang (Taipei, TW)
Cpc classification
H10B61/00
ELECTRICITY
H01F10/329
ELECTRICITY
H10B61/20
ELECTRICITY
G11C11/161
PHYSICS
International classification
H01L27/00
ELECTRICITY
G11C11/16
PHYSICS
H01F10/32
ELECTRICITY
H10B61/00
ELECTRICITY
Abstract
The present disclosure provides a semiconductor structure. The semiconductor structure includes an N.sup.th metal layer in a memory region and a periphery region, the periphery region spanning a wider area than the memory region, a plurality of magnetic tunneling junctions (MTJs) over the N.sup.th metal layer, the plurality of MTJs having at least one of mixed pitches and mixed sizes, a top electrode via over each of the plurality of MTJs; and an (N+M).sup.th metal layer over the plurality of MTJs. A method for manufacturing the semiconductor structure is also disclosed.
Claims
1. A semiconductor structure, comprising: an N.sup.th metal layer in a memory region and a periphery region, the periphery region spanning a wider area than the memory region; a plurality of magnetic tunneling junctions (MTJs) over the N.sup.th metal layer, the plurality of MTJs having at least one of mixed pitches and mixed sizes; a top electrode via over each of the plurality of MTJs; and an (N+M).sup.th metal layer over the plurality of MTJs, wherein N is an integer greater than or equal to 1, and M is an integer greater than or equal to 1.
2. The semiconductor structure of claim 1, wherein the periphery region occupies more than 90 percent of the semiconductor structure.
3. The semiconductor structure of claim 1, wherein a periphery of the top electrode via is raised to a higher level than a center of the top electrode via.
4. The semiconductor structure of claim 3, further comprising a sidewall spacer laterally contacting the center portion of the top electrode via.
5. The semiconductor structure of claim 3, further comprising an oxide layer surrounding the plurality of MTJs and supporting the periphery of the top electrode via.
6. The semiconductor structure of claim 1, further comprising a planarization etch stop layer over the plurality of MTJs.
7. The semiconductor structure of claim 6, wherein the planarization etch stop layer has a discrete pattern staggering from the plurality of MTJs from a top view perspective.
8. The semiconductor structure of claim 1, wherein the top electrode via comprises a bottom portion at a center, two inclined sidewalls connected to both ends of the bottom portion, and two upper portions connected to the two inclined sidewalls.
9. The semiconductor structure of claim 8, wherein the bottom portion, the two inclined sidewalls, and the two upper portions of the top electrode via form an upward concave shape.
10. The semiconductor structure of claim 6, wherein the planarization etch stop layer is composed of nitride materials or oxynitride materials.
11. A semiconductor structure, comprising: an N.sup.th metal layer in a memory region and a periphery region; a plurality of magnetic tunneling junctions (MTJs) over the N.sup.th metal layer, the plurality of MTJs having at least one of mixed pitches and mixed sizes; a sidewall spacer layer in the memory region and the periphery region over the plurality of MTJs; an oxide layer in the memory region over the sidewall spacer layer and in the periphery region adjacent to the memory region; and a top electrode via over each of the plurality of MTJs: wherein N is an integer greater than or equal to 1; wherein a periphery portion of the top electrode via is raised to a higher level than a center portion of the top electrode via, and the sidewall spacer layer laterally contacts the center portion of the top electrode via.
12. The semiconductor structure of claim 11, wherein the periphery region occupies more than 90 percent of the semiconductor structure.
13. The semiconductor structure of claim 11, wherein the oxide layer surrounds the plurality of MTJs and supports the periphery portion of the top electrode via.
14. The semiconductor structure of claim 11, further comprising a planarization etch stop layer over the plurality of MTJs.
15. The semiconductor structure of claim 14, wherein the planarization etch stop layer has a discrete pattern staggering from the plurality of MTJs from a top view perspective.
16. The semiconductor structure of claim 11, wherein the top electrode via comprises a bottom portion at a center, two inclined sidewalls connected to both ends of the bottom portion, and two upper portions connected to the two inclined sidewalls.
17. The semiconductor structure of claim 16, wherein the bottom portion, the two inclined sidewalls, and the two upper portions of the top electrode via form an upward concave shape.
18. The semiconductor structure of claim 14, wherein the planarization etch stop layer is composed of nitride materials or oxynitride materials.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) Aspects of the present disclosure are best understood from the following detailed description when read with the accompanying figures. It is noted that, in accordance with the standard practice in the industry, various features are not drawn to scale. In fact, the dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion.
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DETAILED DESCRIPTION
(6) The following disclosure provides many different embodiments, or examples, for implementing different features of the provided subject matter. Specific examples of components and arrangements are described below to simplify the present disclosure. These are, of course, merely examples and are not intended to be limiting. For example, the formation of a first feature over or on a second feature in the description that follows may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features may be formed between the first and second features, such that the first and second features may not be in direct contact. In addition, the present disclosure may repeat reference numerals and/or letters in the various examples. This repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various embodiments and/or configurations discussed.
(7) Further, spatially relative terms, such as “beneath,” “below,” “lower,” “above,” “upper” and the like, may be used herein for ease of description to describe one element or feature's relationship to another element(s) or feature(s) as illustrated in the figures. The spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. The apparatus may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein may likewise be interpreted accordingly.
(8) Notwithstanding that the numerical ranges and parameters setting forth the broad scope of the disclosure are approximations, the numerical values set forth in the specific examples are reported as precisely as possible. Any numerical value, however, inherently contains certain errors necessarily resulting from the standard deviation found in the respective testing measurements. Also, as used herein, the term “about” generally means within 10%, 5%, 1%, or 0.5% of a given value or range. Alternatively, the term “about” means within an acceptable standard error of the mean when considered by one of ordinary skill in the art. Other than in the operating/working examples, or unless otherwise expressly specified, all of the numerical ranges, amounts, values and percentages such as those for quantities of materials, durations of times, temperatures, operating conditions, ratios of amounts, and the likes thereof disclosed herein should be understood as modified in all instances by the term “about.” Accordingly, unless indicated to the contrary, the numerical parameters set forth in the present disclosure and attached claims are approximations that can vary as desired. At the very least, each numerical parameter should at least be construed in light of the number of reported significant digits and by applying ordinary rounding techniques. Ranges can be expressed herein as from one endpoint to another endpoint or between two endpoints. All ranges disclosed herein are inclusive of the endpoints, unless specified otherwise.
(9) Embedded MRAM cell in a CMOS structure has been continuously developed. A semiconductor circuit with embedded MRAM cell includes an MRAM cell region and a logic region separated from the MRAM cell region. For example, the MRAM cell region may locate at the center of the aforesaid semiconductor circuit while the logic region may locate at a periphery of the semiconductor circuit. Note the previous statement is not intended to be limiting. Other arrangement regarding the MRAM cell region and the logic region are enclosed in the contemplated scope of the present disclosure.
(10) In the MRAM cell region, a transistor structure can be disposed under the MRAM structure. In some embodiments, the MRAM cell is embedded in the metallization layer prepared in a back-end-of-line (BEOL) operation. For example, the transistor structures in the MRAM cell region and in the logic region are disposed in a common semiconductor substrate, prepared in a front-end-of-line operation, and are substantially identical in the aforesaid two regions in some embodiments.
(11) Conventionally, the MRAM cell is embedded between adjacent metal line layers distributed horizontally parallel to a surface of the semiconductor substrate. For instance, the embedded MRAM can be located between the 4.sup.th metal line layer and the 5.sup.th metal line layer in an MRAM cell region. Horizontally shifted to the logic region, the 4.sup.th metal line layer is connected to the 5.sup.th metal line layer though a 4.sup.th metal via. In other words, taking the MRAM cell region and the logic region into consideration, the embedded MRAM occupies a thickness of at least the 4.sup.th metal via. The number provided for the metal line layer herein is not limiting. In general, people having ordinary skill in the art can understand that the MRAM is located between an N.sup.th metal line layer and an (N+1).sup.th metal line layer, where N is an integer greater than or equal to 1.
(12) The embedded MRAM includes a magnetic tunneling junction (MTJ) composed of ferromagnetic materials. A bottom electrode and a top electrode are electrically coupled to the MTJ for signal/bias conveyance. Following the example previously provided, the bottom electrode is further connected to the N.sup.th metal line layer, whereas the top electrode is further connected to the (N+1).sup.th metal line layer.
(13) Integrated circuit with mixed pitches and/or mixed sizes MTJ array can generate several problems. Conventionally, a backside anti-reflective coating (BARC) is etched back until the exposure of a top electrode of the MTJ. The BARC etch back operation plays an important role in back-end-of-line (BEOL) interconnects in the logic and memory regions. Nevertheless, the BARC etch back encounter various problems when a mixed pitches and/or a mixed sizes MTJ array is to be fabricated. For example, as shown in
(14) The present disclosure provides a manufacturing method achieving a uniform BARC etch back result in a semiconductor structure having a mixed pitches/sizes MTJ array. The semiconductor structure includes a plurality of magnetic tunneling junctions (MTJs) over the N.sup.th metal layer. The plurality of MTJs can be arranged in a mixed pitches and/or a mixed sizes fashion. A top electrode via of each of the MTJs appears an upward-concave shape over each MTJs. A planarization etch stop pattern is staggerly disposed over the plurality of MTJs from a top view perspective.
(15) Referring to
(16) In some embodiments, the metal layer referred herein includes metal lines and metal vias composed of copper, gold or another suitable metal or alloy. Metal lines and metal vias in different metal layers form an interconnect structure composed of substantially pure copper (for example, with a weight percentage of copper being greater than about 90 percent, or greater than about 95 percent) or copper alloys, and may be formed using the single and/or dual damascene processes. Metal lines and metal vias may be, or may not be, substantially free from aluminum. Interconnect structure includes a plurality of metal layers, namely M.sub.1, M.sub.2 . . . M.sub.N, Metal layers M.sub.1 through M.sub.N are formed in inter-metal dielectrics (IMDs) 127, which may be formed of oxides such as un-doped Silicate Glass (USG), Fluorinated Silicate Glass (FSG), low-k dielectric materials, or the like. The low-k dielectric materials may have k values lower than 3.8, although the dielectric materials of IMDs 127 may also be close to 3.8. In some embodiments, the k values of the low-k dielectric materials are lower than about 3.0, and may be lower than about 2.5. The N.sup.th metal layer 121A′, 121B′ and the (N+1).sup.th metal layer 125A′, 125B′ may be formed by a variety of techniques, e.g., electroplating, electroless plating, high-density ionized metal plasma (IMP) deposition, high-density inductively coupled plasma (ICP) deposition, sputtering, physical vapor deposition (PVD), chemical vapor deposition (CVD), low-pressure chemical vapor deposition (LPCVD), plasma-enhanced chemical vapor deposition (PECVD), and the like. In some embodiments, the upper metal layer may be (N+M).sup.th metal layer, where M is an integer greater than 1.
(17) In
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(19) In
(20) Referring to
(21) The planarization etch stop layer 201 functions as an etch stop to a passivation operation, for example, a chemical mechanical polishing (CMP) operation. The planarization etch stop layer 201 shall possess an etch rate different from that of the oxide layer 129 coplanar therewith. In some embodiments, the planarization etch stop layer 201 can be composed of nitride materials. Alternatively, the planarization etch stop layer 201 can be composed of oxynitride materials.
(22) Referring back to
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(32) Subsequent processing may further include forming various contacts/vias/lines and multilayer interconnect features (e.g., metal layers and interlayer dielectrics) over the substrate, configured to connect the various features or structures of the integrated circuit device. The additional features may provide electrical interconnection to the device including the formed metal gate structures. For example, a multilayer interconnection includes vertical interconnects, such as conventional vias or contacts, and horizontal interconnects, such as metal lines. The various interconnection features may implement various conductive materials including copper, tungsten, and/or silicide. In one example a damascene and/or dual damascene process is used to form a copper related multilayer interconnection structure.
(33) Some embodiments of the present disclosure provide a semiconductor structure including a memory region. The memory region includes an N.sup.th metal layer, a plurality of magnetic tunneling junctions (MTJs) over the N.sup.th metal layer, the plurality of MTJs having at least one of mixed pitches and mixed sizes, a top electrode via concaving upward over each of the plurality of MTJs, and an (N+M).sup.th metal layer over the plurality of MTJs. N is an integer greater than or equal to 1, and M is an integer greater than or equal to 1.
(34) Some embodiments of the present disclosure provide a method for manufacturing a semiconductor structure. The method includes (1) forming an N.sup.th metal layer, (2) forming a plurality of magnetic tunneling junctions (MTJs) over the N.sup.th metal layer, the plurality of MTJs having at least one of mixed pitches and mixed sizes, (3) forming a top electrode via concaving upward over each of the plurality of MTJs, and (4) forming an (N+M).sup.th metal layer over the plurality of MTJs. N is an integer greater than or equal to 1, and M is an integer greater than or equal to 1.
(35) Some embodiments of the present disclosure provide a method for manufacturing a semiconductor structure. The method includes (1) forming an N.sup.th metal layer in a memory region and a periphery region, (2) forming a plurality of magnetic tunneling junctions (MTJs) over the N.sup.th metal layer in the memory region, the plurality of MTJs having at least one of mixed pitches and mixed sizes, (3) forming a top electrode via concaving upward over each of the plurality of MTJs in the memory region, and (4) forming an (N+M).sup.th metal layer in the memory region and the periphery region. N is an integer greater than or equal to 1, and M is an integer greater than or equal to 1.
(36) The foregoing outlines features of several embodiments so that those skilled in the art may better understand the aspects of the present disclosure. Those skilled in the art should appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments introduced herein. Those skilled in the art should also realize that such equivalent constructions do not depart from the spirit and scope of the present disclosure, and that they may make various changes, substitutions, and alterations herein without departing from the spirit and scope of the present disclosure.
(37) Moreover, the scope of the present application is not intended to be limited to the particular embodiments of the process, machine, manufacture, composition of matter, means, methods and steps described in the specification. As one of ordinary skill in the art will readily appreciate from the disclosure of the present invention, processes, machines, manufacture, compositions of matter, means, methods, or steps, presently existing or later to be developed, that perform substantially the same function or achieve substantially the same result as the corresponding embodiments described herein may be utilized according to the present invention. Accordingly, the appended claims are intended to include within their scope such processes, machines, manufacture, compositions of matter, means, methods, or steps.