3D PRINTING WITH VARIABLE VOXEL SIZES BASED ON OPTICAL FILTER

Abstract

A three-dimensional printing approach based on stereolithography with variable printing resolutions to solve the trade-off between throughput and resolution. In this technology, the variable fabrication resolutions are achieved by switching light wavelength. The apparatus includes an optical filter based on high-contrast gratings. In one embodiment, the minimum printing resolution of the accordingly constructed stereolithography apparatus is reduced to 37 μm.

Claims

1. A stereolithography apparatus comprising: a light source for providing a first light beam with a first wavelength and a first beam dimension and a second light beam with a second wavelength and a second beam dimension; and a multi-translucent optical filter in optical communication with the light source, the multi-translucent optical filter allowing the first light beam with the first wavelength to pass through with a third beam dimension and allowing the second light beam with the second wavelength to pass through with a fourth beam dimension substantially different from the third beam dimension.

2. The stereolithography apparatus of claim 1, further comprising: a first dimension mirror; a first gyro controlling the first dimension mirror; a second dimension mirror; a second gyro controlling the second dimension mirror; and the first dimension mirror and the second dimension mirror being optically coupled to the multi-translucent optical filter and for optically controlling the first light beam and the second light beam onto a target.

3. The stereolithography apparatus of claim 2, further comprising a focusing lens optically coupled between the multi-translucent optical filter and the two mirrors, and wherein the light source includes a laser source.

4. The stereolithography apparatus of claim 1, wherein the third beam dimension is substantially similar to the first beam dimension.

5. The stereolithography apparatus of claim 1, wherein the first beam dimension and the third beam dimension are a beam diameter of the first light beam, and the second beam dimension and the fourth beam dimension are a beam diameter of the second light beam.

6. The stereolithography apparatus of claim 1, wherein the third beam dimension of the first light beam has a first diameter for the first light beam and the fourth beam dimension of the second light beam has a second diameter for the second light beam, the second diameter being substantially different from the first diameter.

7. The stereolithography apparatus of claim 1, wherein the first beam dimension of the first light beam has a first diameter for the first light beam, wherein the second beam dimension of the second light beam has a second diameter for the second light beam, and wherein the second diameter is substantially similar to the first diameter.

8. The stereolithography apparatus of claim 7, wherein the third beam dimension of the first light beam has a third diameter for the first light beam, wherein the fourth beam dimension of the second light beam has a fourth diameter for the second light beam, and wherein the fourth diameter is substantially different from the third diameter.

9. The stereolithography apparatus of claim 8, wherein the third diameter is substantially similar to the first diameter.

10. The stereolithography apparatus of claim 1, wherein the multi-translucent optical filter includes a grating layer having an aperture portion for allowing the second light beam to pass through with the fourth beam dimension and a grating portion for preventing the second light beam to pass through outside of the fourth beam dimension, and wherein the grating layer further allows the first light beam to pass through with the third beam dimension substantially similar to the first beam dimension.

11. The stereolithography apparatus of claim 10, wherein the multi-translucent optical filter further includes a quartz layer and a planarization layer.

12. The stereolithography apparatus of claim 1, wherein the light source includes a first light source for providing the first light beam and further includes a second light source for providing the second light beam.

13. The stereolithography apparatus of claim 12, wherein the first light source includes a light emitting diode and an optical fiber.

14. The stereolithography apparatus of claim 1, wherein the light source further provides a third light beam with a third wavelength, wherein the multi-translucent optical filter includes a plurality of filters, wherein the plurality of filters include a first filter allowing the second light beam with the second wavelength to pass through with the fourth beam dimension, and a second filter allowing the third light beam with the third wavelength to pass through with a fifth beam dimension substantially different from the third beam dimension and the fourth beam dimension, and wherein the first filter and the second filter allow the first light beam with the first wavelength to pass through with the third beam dimension.

15. A method of changing light beam spot size in a stereolithography apparatus, the method comprising: providing a first light beam with a first wavelength and a first beam dimension; providing a second light beam with a second wavelength and a second beam dimension; allowing the first light beam through a multi-translucent optical filter, the allowed light having the first beam dimension; allowing the second light beam through the multi-translucent optical filter, the allowed light having a third beam dimension substantially different from the first beam dimension; controlling the first light beam to project onto a target; and controlling the second light beam to project onto the target.

16. The method of claim 15, wherein the third beam dimension is substantially similar to the first beam dimension.

17. The method of claim 15, wherein the first beam dimension and the third beam dimension are a beam diameter of the first light beam, and the second beam dimension and the fourth beam dimension are a beam diameter of the second light beam.

18. The method of claim 15, wherein the third beam dimension of the first light beam has a first diameter for the first light beam and the fourth beam dimension of the second light beam has a second diameter for the second light beam, the second diameter being substantially different from the first diameter.

19. The method of claim 15, wherein the first beam dimension of the first light beam has a first diameter for the first light beam, wherein the second beam dimension of the second light beam has a second diameter for the second light beam, and wherein the second diameter is substantially similar to the first diameter.

20. The method of claim 19, wherein the third beam dimension of the first light beam has a third diameter for the first light beam, wherein the fourth beam dimension of the second light beam has a fourth diameter for the second light beam, and wherein the fourth diameter is substantially different from the third diameter.

21. The method of claim 20, wherein the third diameter is substantially similar to the first diameter.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0032] FIG. 1 is a schematic of a stereolithography apparatus.

[0033] FIG. 2 is a side view of the stereolithography apparatus of FIG. 1.

[0034] FIGS. 3A and 3B depict two transmission modes of the optical filter.

[0035] FIG. 4 is a schematic diagram of an exemplary optical filter 70.

[0036] FIG. 5 is a flow chart of a fabrication process.

[0037] FIG. 6 is a SEM image of TiO.sub.2 gratings and quartz substrate.

[0038] FIG. 7 is a chart of experimental and simulated transmission spectrum of TiO.sub.2 gratings.

[0039] FIG. 8 includes charts of a comparison of the line widths of patterns printed by unfiltered beam and filtered beam: (a) 405 nm laser and (b) 445 nm laser.

[0040] FIG. 9 depicts a printed pattern with both big feature (one vertical line, printed by 445 nm laser) and small feature (three horizontal lines, printed by 405 nm laser).

[0041] FIG. 10 illustrates a digital model of a microfluidic device.

[0042] FIG. 11 provides a table of calculated distance of travel of the beam spots for building the microfluidic device in FIG. 10.

[0043] FIG. 12 is a side view of a CNC accumulation apparatus.

[0044] FIGS. 13A and 13B depict two transmission modes of an optical filter with a focusing lens.

[0045] FIGS. 14A and 14B also depict two transmission modes of an optical filter with a focusing lens.

[0046] FIGS. 15A-15D depict multiple transmission modes of an a plurality of optical filters.

[0047] FIGS. 16A and 16B depict two transmission modes of the optical filter with an optical fiber.

DETAILED DESCRIPTION OF THE INVENTION

[0048] Before any embodiments of the invention are explained in detail, it is to be understood that the invention is not limited in its application to the details of construction and the arrangement of components set forth in the following description or illustrated in the following drawings. The invention is capable of other embodiments and of being practiced or of being carried out in various ways. Also, it is to be understood that the phraseology and terminology used herein is for the purpose of description and should not be regarded as limiting. The use of “including,” “comprising,” or “having” and variations thereof herein is meant to encompass the items listed thereafter and equivalents thereof as well as additional items. Unless specified or limited otherwise, the terms “mounted,” “connected,” “supported,” and “coupled” and variations thereof are used broadly and encompass both direct and indirect mountings, connections, supports, and couplings. Further, “connected” and “coupled” are not restricted to physical or mechanical connections or couplings.

[0049] Additionally, the functionality described herein as being performed by one component may be performed by multiple components in a distributed manner. Likewise, functionality performed by multiple components may be consolidated and performed by a single component. Similarly, a component described as performing particular functionality may also perform additional functionality not described herein. For example, a device or structure that is “configured” in a certain way is configured in at least that way, but may also be configured in ways that are not listed. Furthermore, some embodiments described herein may include one or more electronic processors configured to perform the described functionality by executing instructions stored in non-transitory, computer-readable medium. Similarly, embodiments described herein may be implemented as non-transitory, computer-readable medium storing instructions executable by one or more electronic processors to perform the described functionality. Described functionality can be performed in a client-server environment, a cloud computing environment, a local-processing environment, or a combination thereof.

[0050] Stereolithography Setup

[0051] The stereolithography process uses photocurable resin, which consists of monomers that can be polymerized into large molecules. In the apparatus 10 of FIG. 1, a laser source 15 creates a laser beam 20 that is deflected by two gyro-mirrors 25 and 30. Next, the laser beam 20 is projected on the surface 35 of a resin 40 in a liquid tank 45 and traces a cross-section of the object that is being printed. A Z stage 50 stays below the liquid resin surface at a depth that is smaller than the light curing depth. After a layer has been cured, the Z stage 50 moves down a distance of the thickness of a layer. Other stereolithography systems may operate differently from the apparatus 10 discussed herein.

[0052] FIG. 2 shows the stereolithography setup used according to the schematic of FIG. 1. A light beam 20 was created by a collimated laser source 15, including collimated lens 55 (FIG. 1). Lasers with 405 and 445 nm wavelength were used in the experiment. Other wavelengths are envisioned for the system of FIG. 2. The beam 20 was then focused by the focusing lens 60. Next, the beam was deflected by the Y mirror and X mirror 25 and 30, respectively, to scan on the resin surface 35. The testing target 65 was a silicon wafer coated with photocurable resin. A filter 70 was installed next to the focusing lens.

[0053] FIG. 12 shows a computer numerical control (CNC) accumulation tool. The following reference nos. relate to the figure: 200—optical fiber no. 1; 205—optical fiber no. 2; 210—X Axis; 215—Y Axis; 220—Z Axis; 225—C Axis, 230—A Axis; 235—LED no. 1; 240—LED no. 2; 255—motion controller; 260—force sensor; 270—resin tank.

[0054] Optical Filter Design and Fabrication

[0055] The optical filter 70 in this disclosure has different transmission rates for 405 and 445 nm light, as shown in FIGS. 3A and 3B. FIGS. 13 and 14 show multiple ways of placing the filter 70. FIGS. 13A and 13B depict a first arrangement with two transmission modes of an optical filter 70 with a focusing lens 60 to a focal plane 72. FIGS. 14A and 14B depict a second arrangement with two transmission modes of an optical filter 70A with a focusing lens 60A to a focal plane 72A. As shown in FIGS. 13A and 13B, one arrangement includes placing the filter 70 in close proximity of the lens 60. Diffraction is ignored in this case since the lens 60 and the filter 70 are close. The second arrangement includes placing the lens 60A away from the filter 70A. The 445 nm light still passes the filter 70A and gives a larger spot. The 405 nm light starts to expand after the filter 60A due to diffraction. The lens 70A collects the light and projects the image of the aperture on the focal plane 72A, providing a small laser spot.

[0056] In addition to using one filter 70 and two laser wavelengths to achieve two laser spot sizes, multiple filters can be stacked to achieve more than two laser spot sizes. For example, in the FIGS. 15A-15D, three filters 70B, 70C, and 70D are stacked and four wavelengths are used to give four laser spot sizes. Wavelength λ.sub.1 can pass all three filters and give the largest beam spot. The first filter 70B works as an aperture only for λ.sub.2 and is transparent to other wavelengths. Wavelength λ.sub.2 gives the second largest laser spot size. The second filter 70C works as an aperture only for λ.sub.3 and is transparent to other wavelengths. λ.sub.3 gives the third largest laser spot size. The third filter 70D works as an aperture only for λ.sub.4 and is transparent to other wavelengths. λ.sub.4 gives the smallest laser spot size.

[0057] FIGS. 16A and 16B depict two transmission modes of an optical filter 70 on a single CNC accumulation tool having optical fibers 200 and 205 (FIG. 12). For the 445 nm light, most light can pass the filter, which gives a large beam size. For the 405 nm light, incident light on most area of the filter was reflected, and only a beam with a smaller diameter passes. Only part of the filter 70 allows transmission of the 405 nm light. Therefore, the filter works as an aperture. Similarly, the filter 70 can include multiple filters as shown in FIGS. 15A-15D.

[0058] The reflection of the 405 nm light is achieved, in one implementation, by high-contrast gratings that have been used in many applications owing to their high reflectance and broad reflection band properties. In addition, the thickness of the high-contrast grating is smaller than that of other reflectors such as dielectric reflector.

[0059] The schematic of an optical filter is shown in FIG. 4. The filter 70 includes a bottom quartz layer 75, a TiO.sub.2 grating layer 80, and a top planarization layer 85. Gratings 90 at center area 95 are etched off to provide an aperture for the 405 nm light. A period of the gratings is P. Edge length and thickness of the TiO.sub.2 grating is L and H, respectively.

[0060] The working principle of high-contrast gratings 90 can be described as following: When light is incident on the gratings 90, lateral guided modes are generated, resulting in resonance and reradiation. When the transmitted waves interfere destructively, transmission disappears, and strong reflection occurs. In the area 95 where gratings were etched off, there is no high refractive index contrast. Therefore, no strong reflection would occur. As a result, light can get through this area 95. However, in this area 95, some quartz gratings might be created during the process of etching off TiO.sub.2 gratings. Hence, a planarization layer 85 that has similar refractive index as quartz was applied to eliminate undesired resonance. The reflection spectrum can be tuned by adjusting the geometry of the gratings, including P, L, and H in FIG. 4. In this implementation, TiO.sub.2 was selected because among all materials with low loss at this wavelength range, TiO.sub.2 has the highest refractive index. Since the light sources are polarized, the filter was designed for this specific polarization (TM), and 1D grating design was used.

[0061] The fabrication process 100 is summarized in FIG. 5. The gratings 90 were fabricated by using nanoimprint lithography. First (105), a Si mother mold was fabricated by interference lithography. Then, a glass mold (110) was duplicated from the Si mother mold by transferring pattern to a layer of UV-curable resist on a glass substrate. The filter substrate was prepared by deposition of a 400 nm thick TiO.sub.2 thin film using direct current magnetron sputtering on top of a quartz substrate (115). The grating pattern was transferred (120) from the glass mold to the TiO.sub.2 layer via nanoimprint, lift-off, and RIE etching process. In the lift-off process, 10 nm thick chrome mask was made by electron beam deposition and worked as etching mask in the following RIE etching. An RIE etching recipe that was developed by Liu et al. with a gas combination of SF.sub.6, C.sub.4F.sub.8 and O.sub.2 was used. FIG. 6 shows a SEM image of finished TiO.sub.2 gratings.

[0062] After TiO.sub.2 gratings were fabricated, an additional step 125 of photolithography and RIE etching was carried out to etch away TiO.sub.2 gratings in a circular area with a diameter of 96 μm. This area can virtually be any shape depending on the requirement of application. Finally, a planarization layer was applied for aforementioned reason. Two-hundred nanometer thick UV curable resist was spin coated and cured to be the planarization layer.

[0063] Transmission of the Filter

[0064] Optical transmission of the grating area was measured and compared with simulation in FIG. 7. Numerical simulation was performed via finite-difference time-domain (FDTD) method using Lumerical FDTD solutions software. In the spectrum, the measured center wavelength of reflection matches the simulation result very well at 405 nm. Transmission at 405 nm is 10% while at 445 nm is about 80%, which means 405 nm light will be mostly reflected by the gratings while 445 nm light will pass.

[0065] Printing Demonstration

[0066] The design purpose of the filter is to greatly reduce the spot size of 405 nm laser while keeping the spot size of 445 nm laser similar to the unfiltered one. The values 405 nm and 445 nm are exemplary. Moreover, the filter transmission sizes and transmission rates are exemplary. Four groups of lines were printed to verify this effect. The target surface was a quarter of 4-in. Si wafer coated with 0.4 ml liquid photocurable resin. After patterns were printed, the sample was rinsed by isopropanol to remove uncured liquid resin. Finally, linewidths were characterized by an optical micro-scope. FIG. 8 compares the linewidths of lines printed by the unfiltered beam and the filtered beam for both the 405 nm laser and the 445 nm laser. The beam spot size of the 405 nm laser was much more reduced than the 445 nm laser. For example, at laser power of 120 mW, spot size of 405 nm light was reduced from 372 to 50 μm while spot size of 445 nm light was only reduced from 332 to 258 μm due to slight reflection and material loss. There is no corresponding data for some power values since the resin cannot be fully cured in such low power. Additionally, the unfiltered beam of power below 30 mW could not print solid pattern, which confirms that small pattern below 100 μm can only be printed with the filter.

[0067] In order to demonstrate changing pixel size by switching wavelength, a test pattern was printed, which is shown in FIG. 9. FIG. 9 depicts a printed pattern with both big feature (one vertical line, printed by 445 nm laser) and small feature (three horizontal lines, printed by 405 nm laser). Area between the features is the surface of silicon wafer. The microscope was focusing at the top of the features. Black areas are shadows that are on the surface of the wafer and are enlarged due to out of focus. With optical filter installed in the printing system, variable spot size was achieved by only switching wavelength. The optical filter was installed in the stereolithography system during the printing process. The thinner lines (37 lm wide) were first printed by the 405 nm laser. Then, the wavelength of laser was changed to 445 nm to print the thicker lines (272 μm wide).

[0068] Efficiency Test Based on Digital Model

[0069] The purpose of having a variable beam spot is to improve the manufacturing efficiency when the object that is to be built has both small features and large features. To demonstrate the improvement, a digital model of a microfluidic device is created as shown in FIG. 10. The device has an overall dimension of 40 mm (length)×20 mm (width)×2 mm (height). A channel inside the block has a cross-section of 200×200 μm. The beam sizes are taken from the data of 120 mW laser power in FIG. 8. The small spot is 50 μm in diameter from the 405 nm laser, and the large spot is 258 μm in diameter from the 445 nm laser. Variable pixel sizes from 37 to 417 μm have been demonstrated in some embodiments. A maximum spot size can be as large as 700 μm. The distances of travel of the beam spots to build this device are shown in Table 1 (FIG. 11). The distances are calculated using small beam spot only and using small and large beam spots together. The speed of the spots is a constant during real manufacturing process. So, the distance of travel is proportional to manufacturing time. If both of the spots are used, the small spot can build features of the channel, and the large spot can fill other volume in the block. If only one spot can be used, in order to keep the resolution of the channel the same, the small spot will be used to build the whole object. As a result, using the two different beam spots saves 87.6% of manufacturing time, which is a significant improvement.

[0070] Discussion

[0071] The measured transmission spectrum did not match the simulation result perfectly, but provided effectiveness. Several factors might affect the filter's performance. First, TiO.sub.2 has some surface roughness that can be observed from the SEM image. Also, the sidewall profile was not strictly vertical. Additionally, the deposited TiO.sub.2 has larger loss than the ideal value used in the simulation, especially in short wavelength range, which was not included in the simulation model.

[0072] A high-contrast grating is chosen in this implementation for its small thickness compared with a conventional multilayer coated optical filter. Two wavelengths are used in this implementation for concept demonstration. The filter can be placed at close proximity of the surface of the resin and multiple layers of high-contrast gratings can be integrated into a single filter which can give more beam shapes for multiple wavelengths. In comparison, the conventional filter, if being used in a similar way, will suffer more reduction of resolution in beam shapes due to diffraction of light that travels through thicker material.

[0073] Generally, 405 nm laser is able to cure more resin than 445 nm laser at same power level due to higher photon energy. However, when the filter was being used, the 405 nm laser printed thinner lines than the 445 nm laser, which confirms the effectiveness of the filter.

[0074] In summary, an optical filter based on high-contrast gratings is designed and fabricated by nanoimprint lithography. The function of cropping 405 nm light beam and transmitting 445 nm light beam is achieved. By using the filter, the minimum printing resolution of the current setup is reduced to 37 μm. Variable beam spot size is realized by exchanging wavelength. This implementation shows a promising way to optimize the manufacturing efficiency of the stereolithography process.

[0075] Accordingly, the invention provides new and useful stereolithography apparatus and method of changing light beam size. Various features and advantages of the invention are set forth in the following claims.