Optically variable element
09798055 · 2017-10-24
Assignee
Inventors
Cpc classification
G02B5/286
PHYSICS
International classification
Abstract
The invention relates to an optically variable element as well as a method for the production thereof. In a first area the optically variable element has at least one first color region which in the event of illumination generates a color dependent on the angle of observation and/or angle of illumination. The first color region has two or more zones (41 to 47) arranged next to each other. The two or more zones arranged next to each other have in each case a width and/or length dimension of less than 300 μm. In at least one first zone (41) of the zones (41 to 47) of the first color region a thin-film interference filter (15) is provided with at least one interference layer (17). The interference layer (17) of the thin-film interference filter (15) has a first average thickness (d.sub.1) in the first zone (41). The first average thickness is chosen such that the thin-film interference filter (15) in the event of illumination at least one particular angle of observation and/or angle of illumination generates, by means of interference, a color which differs from at least one color which is generated in the event of illumination at this angle of observation and/or angle of illumination in at least one of the other zones (42 to 47) of the first color region.
Claims
1. An optically variable element comprising a first security feature disposed in a first area of the optically variable element and a second security feature disposed in a second area of the optically variable element separate from the first area, the first security feature comprising at least one first color region which in the event of illumination generates a mixed color dependent on the angle of observation or angle of illumination, wherein the first color region has two or more zones arranged next to each other which have in each case a width or length dimension of less than 300 μm, wherein a first zone of the zones of the first color region comprises a thin-film interference filter with a reflective layer, an interference layer and an absorber layer, wherein in the first zone the interference layer of the thin-film interference filter has a first average thickness (d.sub.1) which is chosen such that in the event of illumination at least one particular angle of observation and/or angle of illumination the thin-film interference filter generates, by means of interference, a color which differs from at least one color which is generated in at least one of the other zones of the first color region in the event of illumination at this angle of observation or angle of illumination, and wherein a second zone of the zones of the first color region has a thin-film interference filter comprising the reflective layer, the interference layer and the absorber layer, wherein the interference layer of the thin-film interference layer filter has a second average thickness (d.sub.2) in the second zone, wherein the first average thickness (d.sub.1) and the second average thickness (d.sub.2) differ from each other by between 20 nm and 500 nm, and wherein the two or more zones of the first color region further comprise one or more sunk zones also comprising a thin film interference layer having the reflective layer, the interference layer and the absorber layer, wherein the average thickness (d.sub.v) of the interference layer in the sunk zones is between 500 nm and 5000 nm, wherein the sunk zones are provided to make the thickness of the interference layer averaged over all zones of the first color region to be identical for all color regions.
2. An optically variable element according to claim 1, wherein the first color region has two or more first or two or more second zones.
3. An optically variable element according to claim 1, wherein in at least one third zone and at least one fourth zone of the zones of the first color region a thin-film interference filter are provided, wherein the interference layer of the thin-film interference filter has a third average thickness (d.sub.3) in the third zone and a fourth average thickness (d.sub.4) in the fourth zone and the third and fourth average thickness (d.sub.3) (d.sub.4) differs from the first and second average thickness (d.sub.1, d.sub.2), the first, second, third and fourth average thicknesses differ from each other in each case by between 20 nm and 500 nm.
4. An optically variable element according to claim 3, wherein the first, second, third and fourth average thickness (d.sub.1, d.sub.2, d.sub.3, d.sub.4) of the interference layer is selected from the group: 90±30 nm, 300±30 nm, 350±30 nm and 425±30 nm.
5. An optically variable element according to claim 3, wherein the first, second, third and fourth average thickness (d.sub.1, d.sub.2, d.sub.3, d.sub.4) is between 50 nm and 1000 nm.
6. An optically variable element according to claim 3, wherein the first, second, third and fourth average thicknesses (d.sub.1, d.sub.2, d.sub.3, d.sub.4) of a first group of first color regions differ from the first, second, third and fourth average thicknesses (d.sub.1, d.sub.2, d.sub.3, d.sub.4) of a second group of first color regions in such a way that, in one or more directions of illumination or observation, one or more of the first color regions of the first group and of the second group generate metameric colors in the event of illumination.
7. An optically variable element according to claim 3, wherein, in a third area a plurality of color regions are provided which are arranged according to a one- or two-dimensional grid and in each case form an image spot of a second motif, and wherein more than 50% of the color regions in the third area are formed by first color regions, and wherein the first, second, third and fourth average thicknesses (d.sub.1, d.sub.2, d.sub.3, d.sub.4) of the first color regions of the first area differ from the first, second, third and fourth average thicknesses (d.sub.1, d.sub.2, d.sub.3, d.sub.4) of the first color regions of the third area in such a way that, in one or more directions of illumination or observation, one or more of the first color regions of the first area and of the third area generate metameric colors in the event of illumination.
8. An optically variable element according to claim 3, wherein the optically variable element has a layer system which, in the first, second, third and fourth zones, in each case forms the thin-film interference filter, wherein a layer of the layer system in the first, second, third and fourth zones in each case forms the interference layer of the respective thin-film interference filter and this common interference layer has the first, second, third and fourth average thickness respectively in the first, second, third and fourth zones, wherein the layer system also has an absorber layer and a reflective layer and the common interference layer is arranged between the absorber layer and the reflective layer.
9. An optically variable element according to claim 3, wherein the optically variable element has a substrate layer, wherein a surface relief is molded in a surface of the substrate layer and the surface relief differs in terms of the relief depth in the first, second, third and fourth zones.
10. An optically variable element according to claim 1, wherein each of the zones of the first color regions has a width or length of between 150 μm and 10 μm.
11. An optically variable element according to claim 1, wherein the surface proportion of the respective first color region which is covered by first, second, third, or fourth zones is varied to set the color value and the brightness of the respective image spot of the first area.
12. An optically variable element according to claim 1, wherein at least two of the first color regions have two or more first and two or more second zones wherein the two or more first and the two or more second zones are arranged in a pseudorandom arrangement in these color regions or the arrangement of the first and second zones differs in these color regions.
13. An optically variable element according to claim 1, wherein the optically variable element has two or more first color regions which, in the event of illumination at at least one particular angle of observation or angle of illumination, display to the human observer different colors, wherein the thickness of the interference layer of these color regions averaged in each case over the respective color region is identical or almost identical, and wherein the number and surface dimension of the sunk zones of at least one of these color regions is chosen such that the thickness of the interference layer of these color regions averaged in each case over the respective color region is identical.
14. An optically variable element according to claim 1, wherein the proportion of the sunk zones in the surface covered by the respective first color region is less than 20%.
15. An optically variable element comprising a first security feature disposed in a first area of the optically variable element and a second security feature disposed in a second area of the optically variable element separate from the first area, the first security feature comprising a plurality of color regions, each color region generating a mixed color in the event of illumination dependent on the angle of observation or angle of illumination, wherein each color region comprises a plurality of zones, the plurality of zones comprising: a first zone having a width or length dimension of less than 300 μm and comprising a thin film interference filter having a reflective layer, an interference layer and an absorber layer, the interference layer having a first average thickness (d.sub.1) which is chosen such that in the event of illumination at at least one particular angle of observation or angle of illumination generates a first color by means of interference; a second zone arranged next to the first zone, the second zone having a width or length dimension of less than 300 μm and comprising a thin film interference filter having a reflective layer, an interference layer and an absorber layer, the interference layer having a second average thickness (d.sub.2) which is chosen such that in the event of illumination at the at least one particular angle of observation or angle of illumination generates a second color by means of interference, the second color differing from the first color, and wherein the first average thickness (d.sub.1) and the second average thickness (d.sub.2) differ from each other by between 20 nm and 500 nm; and a sunk zone arranged next to at least one of the first and second zones, the sunk zone having a width or length dimension of less than 300 μm and comprising a thin film interference filter having a reflective layer, an interference layer and an absorber layer, the interference layer having an average thickness (d.sub.v) of between 500 nm and 5000 nm, wherein the thickness of the interference layer of the thin film interference filter of the sunk zone is selected to ensure that the average thickness of the interference layer over all zones of each color region is substantially identical.
Description
(1) The invention is explained by way of example below with reference to several embodiment examples with the aid of the attached drawings.
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(25) However, it is also possible that the security document is an ID document, for example an access card or a passport, or a credit card, a phone card, a certificate or the like.
(26) The security document 1 has a carrier substrate 10 to which the optically variable element 11 is applied. The carrier substrate 10 is formed for example by a paper substrate, a plastic substrate or by a multi-layered substrate comprising several paper and plastic layers. Here, security elements, for example watermarks and security threads, can be embedded into the substrate 10. Furthermore it is also possible that still further optically variable security elements are applied to the substrate. Thus, by way of example, an optically variable security element 23 which has a patch-like shaping is shown in
(27) The carrier substrate 10 preferably also has one or more recesses 12 or transparent areas which are covered by the optically variable element 11. The advantage is hereby achieved that the optically variable element 11 is visible both from the front and from the back side, and can thus provide corresponding security features when viewed in reflected light from the front side, when viewed in reflected light from the back side and when viewed with light passing through.
(28) The optically variable element 11 is preferably formed as a laminating film, which has a strip-like shaping and extends completely over the transverse side of the security document 1, as is shown in
(29) Flexible plastic films, for example of PI, PP, MOPP, PE, PPS, PEEK, PEK, PEI, PSU, PAEK, LCP, PEN, PBT, PET, PA, PC, COC, POM, ABS, PVC, preferably come into consideration as carrier films. The carrier film preferably has a thickness of between 5 μm and 700 μm, in particular between 8 μm and 200 μm, particularly preferably between 12 μm and 50 μm.
(30) However, it is furthermore also possible that the optically variable element 11 is formed, not by a laminating film, but by the transfer layer of a transfer film and/or the optically variable element has, not a strip-like, but a patch-like shape.
(31) In an area 21 the optically variable element 11 has a security feature with one or more color regions which in the event of illumination generate a color dependent on the angle of observation and/or angle of illumination. Furthermore, in an area 22 the optically variable element 11 preferably also has one or more further security features which are formed for example by a hologram or a diffractive structure, for example a Kinegram®.
(32) As already stated above, in an embodiment example not shown here the optically variable element 11 can also have the form of a transfer film which has a carrier film, an optional detachment layer, a decoration layer and an optional adhesive layer. The decoration layer of such a transfer film preferably has the layers, described below, of the optically variable element 11, with the result that in this respect reference is made to the statements below. The transfer film can also be used to integrate the optically variable element 11 into an ID document.
(33) As already stated above, the optically variable element 11 can also be formed for example by a label or a security document as such which has a corresponding decoration layer. Also in this respect reference is made to the statements below.
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(35) Each of the color regions 31 has two or more zones arranged next to each other which have in each case a width and/or length dimension of less than 300 μm. Preferably, these zones have a width and/or length of between 300 μm and 5 μm, further between 150 μm and 5 μm, in particular between 150 μm and 10 μm, further between 80 μm and 10 μm, preferably between 80 μm and 20 μm. Several such zones, namely the zones 41, 42, 43 and 44, are shown here in
(36) The zones, in particular the zones 41 to 44, preferably have a rectangular, square or circular shape. However, it is also possible that the zones have any other shape and for example have a triangular, a pentagonal, oval or also an L-shaped shape.
(37) By width and width dimension is meant here the minimum of the spacing between two opposite boundary lines of the zone. By length and length dimension is meant here the maximum of the spacing between two opposite boundary lines of the zone.
(38) In the color regions 31, in at least one of the zones, a thin-film interference filter is provided, the interference layer of which has an average thickness which is chosen such that in the event of illumination at least one particular angle of observation and/or angle of illumination the thin-film interference filter generates, by means of interference, a first color which differs from at least one color which is generated in the event of illumination at this angle of observation and/or angle of illumination in at least one of the other zones of the color region 31. The color regions 31 thus have a combination of two or more zones which generate different colors in the event of illumination in a particular angle of observation and/or illumination.
(39) In the embodiment example according to
(40) Furthermore it is also possible that in the color regions 31 still further zones are provided which at the particular angle of observation and/or illumination generate further colors which differ from the first to third colors, or that in the area 31 only two zones, for example the zones 41 and 42, are provided which generate two different colors at the particular angle of observation and/or illumination.
(41) In a further embodiment the second or another of the further zones arranged next to each other, in particular one of the zones 42, 43 or 44, has scattering structures. Such scattering structures distribute incident light at different angles, whereby the color impression of this zone appears dark compared with zones without a scattering structure. Zones that appear dark are particularly suitable for achieving an easily recognizable color contrast. The scattering structures are advantageously randomly or pseudorandomly arranged microstructures, in particular isotropic or anisotropic matte structures. Preferably, the average lateral size of such microstructures is in the range of from 400 nm to 5 μm and particularly preferably in the range of from 500 nm to 2 μm. In an embodiment, the scattering structures are composed of microstructures which have depths which lie in the same range as the thicknesses of the interference layer of the other zones.
(42) As represented by way of example in
(43) By “zones arranged next to each other” is meant in this connection an arrangement of zones such that a color mixing of the colors generated by these zones results when these zones are observed. Zones arranged next to each other thus need not adjoin each other directly, but can also be arranged spatially spaced apart from each other within the color region, wherein in this case the zones are arranged at a distance from each other of less than 300 μm, in particular less than 200 μm, preferably less than 100 μm, i.e. the distance between the boundary lines is less than the above-named values.
(44) It is particularly advantageous here if the color regions 31 have a width and/or length of less than 300 μm, as it is ensured in this way that all of the zones of the color region are arranged next to each other within the meaning of the invention and a color mixing results between the colors, generated by the different zones of the color region. The zones have a width and/or length matched to this which preferably lies between 300 μm and 5 μm, further between 150 μm and 5 μm, in particular between 150 μm and 10 μm, further between 80 μm and 10 μm and in particular preferably between 80 μm and 20 μm.
(45) In addition to the color regions 31, the area 21 can have still further color regions, for example the color regions 32 shown in
(46) By the arrangement of the color regions 31 and optionally 32 in the area 21 various optically variable effects, for example movement effects or transformation effects or high-resolution color effect images, can be generated. It is advantageous here if the proportion of the color regions 31 in the color regions in the area 21 is more than 10%, in particular more than 50%, preferably more than 70%, further preferably more than 90%.
(47) In an advantageous embodiment, the zones 41 to 44 make up 100% of the surface of the color regions.
(48) Furthermore, embodiments in which the color regions of the area 21 in each case form an image spot 30 of a first motif are also particularly interesting. The motif can be a simple pattern such as e.g. a multi-colored flag, a clipart drawing or also a high-resolution color image.
(49) For this, for example as shown in
(50) The color values and brightness values of the image spot 30 are converted into corresponding surface proportions of the zones 41 to 44, with the result that in the case of a corresponding color mixing at a particular angle of illumination and/or observation the color value and the brightness of the image spot of the original image is generated by this. Corresponding to their surface proportion, a corresponding number of zones 41 to 44 is provided in the color region 31. In the embodiment example according to
(51) In the area 21 for generating the above-described effects the optically variable element 11 is constructed for example as described with reference to
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(53) The interference layer 17 has an upper boundary surface 152 and a lower boundary surface 151. The thickness of the interference layer 17 preferably lies between 50 nm and 500 nm, in particular between 70 nm and 400 nm, further preferably between 70 nm and 250 nm. The thickness of the interference layer 17 here is varied such that it has an average layer thickness d.sub.1 in the zones 41 and an average layer thickness d.sub.2 in the zones 42. The layer thicknesses d.sub.1 and d.sub.2 differ here, wherein in the embodiment example according to
(54) The variation in the layer thickness of the interference layer 17 can be achieved for example via a surface relief in the boundary surface 152 of the interference layer 17. The surface relief here is preferably formed by a substantially rectangular surface relief, the edges of which between the elevations and depressions of the surface relief preferably deviate by not more than 30°, further preferably not more than 15° from the perpendicular (Z axis), which is preferably defined by the surface normal of the surface of the layer 14 facing away from the interference layer 17 (by which a plane defined by the X and Y axes is spanned).
(55) The elevations and depressions of the relief structure here, as shown in
(56) The boundary surface 151 of the interference layer 17 is preferably shaped flat (see
(57) In addition, it is preferred if the depth t.sub.2 is smaller than 500 nm, furthermore smaller than 300 nm, preferably smaller than 200 nm and further preferably smaller than 100 nm.
(58) The layer 14 is preferably formed largely transparent (preferably more than 90% transmission) at least in the wavelength spectrum visible to the human observer. The layer 14 preferably consists of a plastic film or a varnish layer.
(59) The layer 19 preferably consists of a varnish layer or adhesive layer, which is preferably formed transparent (preferably more than 90% transmission) in the wavelength range visible to the human observer. However, the layer 19 can also be formed by a reflective layer, for example a metal layer.
(60) The interference layer 17 preferably consists of a high refractive index material, for example of titanium dioxide (TiO.sub.2) or zinc sulfide (ZnS). The high refractive index material can, however, also be a mixture or hybrid material of an organic matrix material and high refractive index particles embedded therein, in particular nanoparticles. High refractive index hybrid materials have the advantage that they can be printed. TiO.sub.2 nanoparticles with a diameter of approx. 50 nm embedded in polyvinyl alcohol (PVA) are an example of such a material.
(61) Furthermore a dark-colored, for example black-colored, layer 20 is also optionally applied to the back side of the thin-film interference filter 15. The layer 20 here can also be applied only partially, for example applied in the form of a logo, writing etc.
(62) Furthermore, it is also possible that further optional layers are provided above the layer 14, for example the layer 13 shown in
(63) The arrangement and shaping of the zones 41 and 42 in a color region 31 is shown by way of example in
(64) In the color region 31, two or more zones arranged next to each other, the zones 41 and 42, are provided, wherein the interference layer 17 of the thin-film interference filter 15 has an average thickness d.sub.1 in one or more zones 41 and has an average thickness d.sub.2 different from this in one or more zones 42 and the thin-film interference filter 15 thus generates different colors dependent on the angle of illumination and/or observation in the zones 41 and 42.
(65) The width and/or length dimension of the zones 41 and 42 here are chosen smaller than 300 μm, in particular smaller than 150 μm, further preferably smaller than 80 μm. Furthermore, the width and/or length dimensions of the zones 41 and 42 are chosen larger than 3 μm, furthermore larger than 5 μm, in particular larger than 10 μm, particularly preferably larger than 20 μm. For this, for example in the embodiment example according to
(66) In addition to the complex pattern shown in
(67) The color effect generated in the color region 31 is further influenced by the surface proportion of the zones 41 and 42 in the color region 31. The drawing
(68) The optically variable element 11 is produced for example by shaping the surface relief shown in
(69) In this case, a substrate which is formed as follows is used for the layer 14: Preferably a directly thermally replicable substrate such as for example PMMA or PC film (PC=polycarbonate) is used as substrate. The embossed structure can be introduced directly into this with suitable embossing parameters. Furthermore, carrier films with an applied replication layer of thermoplastic material can also be used as substrate. An example of this is a polyester film with an embossable acrylic varnish layer. Optionally, an adhesion promoter layer or a detachment layer can also be provided between the film and the replication layer. The detachment layer preferably consists of a mixture of waxes, polymers and further additives. Furthermore, a UV-curing replication layer can be used as replication layer.
(70) Furthermore, it is also possible that the interference layer 17 is applied to the layer 19 and then the surface relief is molded into the exposed surface of the interference layer 17 by means of a replication tool. For this, it is possible that firstly an embossable interference layer of higher refractive index is deposited onto a smooth substrate and then the variation of the layer thickness of the interference layer is embossed in an embossing process into the layer of higher refractive index. Then the layer 14 is subsequently applied.
(71) Furthermore, it is also possible that the boundary surface 151 is formed flat in the interference layer 17, as is shown in
(72) A smooth boundary surface can, on the one hand, be achieved by a suitable coating or printing technique combined with an optimized viscosity and/or wettability and/or slow evaporation behavior of the solvent. On the other hand, it is also possible to smooth down the boundary surface by an additional tempering step—preferably with a temperature close to or above the so-called glass-transition temperature of the material of the interference layer. Another possibility for smoothing down the surface is to expose it to a suitable solvent vapor.
(73) These different methods can also be combined. Furthermore, it is also possible not to embed the interference layer 17 on both sides in polymer layers, with the result that for example one of the boundary surfaces 151 or 152 acts against air.
(74) In addition, it is also possible that still further zones, in which the interference layer has an average layer thickness which differs from the average layer thickness d.sub.1 and d.sub.2, are provided in the color region 31. Even more complex mixed color effects can be generated hereby in the color region 31.
(75) In addition, corresponding mixed color effects can also be realized by means of an interference layer system consisting of three layers comprising an absorption layer, a spacer layer acting as interference layer and a reflective layer. A corresponding production method is explained below with reference to
(76) For the production of the optically variable element, the process here can thus be as follows:
(77) In a first step, firstly a surface relief with two different depths is impressed into a flexible substrate 14, as is shown in
(78) By using a surface relief with two different depths, three different zones with different layer thicknesses in the interference layer can be produced. By correspondingly increasing the number of depth levels of the surface relief, still further different zones with different thicknesses of the interference layer can be provided.
(79) The embossing depths here are chosen such that they correspond to the difference between the desired layer thicknesses of the interference layer in the zones in which the surface relief is impressed, and the thinnest layer thickness corresponds to the interference layer in the zones in which the surface relief is not molded.
(80) The master structure for the embossing tool can be produced for example by means of electron-beam lithography or laser beam lithography or laser ablation or also by means of photolithography with several illumination masks for the different relief depths. The illumination masks are for example aligned in a mask aligner in such a way that in the event of illumination the zones of different depths are positioned relative to each other with a precision of a few micrometers. Each mask serves to produce one kind of zone with in each case the same depth in the master. For the duplication of these structures in mass production, these structures are molded for example by means of galvanic copying onto corresponding embossing tools and then molded into the substrate 14 by means of replication, for example in a roll-to-roll process.
(81) A semi-transparent absorber layer is then applied, as is shown in
(82) In a next step, which is shown in
(83) The applied quantity here is set such that for example in first zones an average layer thickness of the interference layer 17 of 425 nm, in second zones an average layer thickness of the interference layer 17 of 350 nm and in third zones an average layer thickness of the interference layer 17 of 300 nm results. As already stated above, additional methods can also be used here in order to form the surface of the interference layer 17 facing away from the relief structure as smooth as possible.
(84) A reflective layer 18 is then applied, for example by evaporation or sputtering with a metal layer. The reflective layer here can be formed both opaque and semi-transparent, which can be set for example by the choice of the layer thickness of the metal layer. Thus, for example, an aluminum layer of 50 nm can be applied in order to guarantee a largely opaque appearance, or for example a silver layer of 10 nm can be applied in order to form the reflective layer semi-transparent. This is shown in
(85) Optionally, another layer 19 can then be applied, which is preferably a protective varnish layer and/or adhesive layer. This is shown in
(86) Furthermore, an inverted layer structure is also possible, in which after the embossing step the reflective layer 18 is applied first, then the interference layer 17 and only after that the semi-transparent absorber layer 16. In the case of a non-transparent reflective layer 18, the color effect here is visible from the other side.
(87) Furthermore, it is also possible to achieve the different average thickness of the interference layer in the different zones by means of a printing process in which the interference layer is constructed in a corresponding height profile on a smooth substrate by one or more printing processes. For this, for example, a smooth substrate is provided either with the absorber layer or with the reflective layer and then the common interference layer is applied by means of printing such that it has in each case a different average thickness in different zones.
(88) In addition, it is also possible to apply either the absorber layer or the reflective layer to the substrate 14, then to apply the material of the interference layer and then to mold into the interference layer a corresponding surface relief profile which generates a corresponding different thickness of the interference layer in the different zones.
(89) Here, preferably, a UV-curable polymer is used as material for the interference layer and the surface relief profile is introduced by means of UV replication. The advantage is hereby achieved that the mechanical loading of the carrier substrate by the replication process is reduced and thus an almost flat surface is achieved on the boundary layer of the interference layer opposite the surface relief. Alternatively, the surface profile can be introduced into the interference layer by means of laser ablation.
(90) Furthermore, it is also possible to mold the surface profile into the substrate 14 and then to apply the absorber layer 16 or reflective layer 18. For this, the reflective layer 18 or absorber layer 16 is applied to a smooth second substrate 14 in an intermediate step. Then the interference layer 17 is applied to one of the two substrates and both substrates are laminated together with the surfaces coated with the absorber layer 16 or reflective layer 18 opposite each other. For this, the material of the interference layer 17 must be flexible enough in order to fill in the depressions of the surface relief profile during the lamination process. For example, the material can even be liquid or middling or highly viscous and can be hardened, e.g. by means of UV radiation, when the correct layer thicknesses have been achieved in the zones of the interference layer.
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(92) As shown in
(93) The semi-transparent absorber layer 16 preferably consists of one of the following materials or of an alloy of the materials: chromium (Cr), nickel (Ni), Inconel alloys, copper (Cu), titanium (Ti), silver (Ag), gold (Au), tin (Sn), palladium (Pd), tungsten (W), molybdenum (Mo), iron (Fe) or carbon (C).
(94) The interference layer 17 preferably consists of a polymer system or hybrid system (mixture of inorganic particles embedded in an organic matrix). Varnish systems are preferably used here which can be applied by means of gravure printing. The interference layer consists for example of a varnish system based on nitrocellulose, epoxy, polyester, colophony, acrylate, alkyl, melamine, PVA, PVC, isocyanate or urethane systems. Varnish systems in which slowly evaporating solvents such as e.g. water, anisole, ethyl acetate or isopropyl alcohol or mixtures with proportions of these solvents are used are preferred. Examples of water-based varnish systems are polyelectrolytes such as polydiallyldimethylammonium chloride (PDADMAC), polyvinylpyridine (P2VP or P4VP), polystyrene sulfonate (PSS), polyacrylic acid (PAA), polymethacrylic acid (PMAA) and the like. Furthermore, UV-curable varnish systems can also be used here. An example of a high refractive index hybrid system is a mixture of 50%.sub.vol PbS nanoparticles in a gelatin matrix. Additional security features, for example fluorescent dyes, magnetic particles or DNA, can additionally also be added to the interference layer 17.
(95) The reflective layer 18 preferably consists of a vapor-deposited or sputtered aluminum layer with a layer thickness of between 30 nm and 50 nm. The reflective layer can also consist for example of Ag, Cu or Cr.
(96) Due to the surface relief profile molded into the substrate 14, the interference layer 17 has an average layer thickness d.sub.1 in the zones 41, an average layer thickness d.sub.2 in the zones 42 and an average thickness d.sub.3 in the zones 43. In the zones 41 to 43 in each case a thin-film interference filter 15 comprising the absorber layer 16, the interference layer 17 and the reflective layer 18 is thus provided by the layer system, with a correspondingly different average thickness d.sub.1, d.sub.2 and d.sub.3 respectively of the respective interference layer. The thicknesses d.sub.1, d.sub.2 and d.sub.3 are chosen for example such that the zones 41, 42 and 43 generate the colors blue (d.sub.3), green (d.sub.2) and red (d.sub.1) respectively for example in the event of perpendicular illumination and observation. It is furthermore advantageous if additionally zones 44—not shown in
(97) Through a combination or by combinations of the zones 41, 42, 43 and 44, it is thus possible for example to generate in the one color region 31 true colors or in the area 21 true-color images in which for example each image spot of the true-color image corresponds to a color region and the color of each color region is determined by a corresponding combination of sub-combination of zones 41, 42, 43 and 44.
(98) The color impression white can be generated here for example by choosing the surface proportion of the zones 41 to 43 in the color region such that the resultant color is positioned on or very close to the white point in the color space or chromaticity diagram (e.g. CIE diagram).
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(101)
(102) A technical obstacle during the production of the optically variable elements by means of wet-chemical coating, in particular by means of printing, of the interference layer is as follows:
(103) In the case of a wet-chemical coating, a certain amount of solid is applied, dissolved in solvent, homogeneously over the relief structure. In the case of roll-to-roll printing methods, the applied amount of solid is usually given in g/m.sup.2. The density of printed varnishes is often approximately 1 g/cm.sup.3. For a varnish layer that is for example 425 nm thick after drying, an applied solids quantity of 0.425 g/m.sup.2 is consequently required. If there is a solids content of 10% and a solvent proportion of 90% in the varnish, this means that the wet layer thickness of the varnish layer at the start of the drying phase is approximately 4.25 μm homogeneously over the relief structure. The solid must now be distributed in the drying phase such that the necessary average (dry) layer thicknesses in the different zones are achieved.
(104) To generate the different thickness of the interference layer in the different zones or to smooth down the boundary layer or boundary surface opposite the surface relief, material must flow from zones with a smaller average thickness of the interference layer to zones with a larger average thickness of the interference layer. This occurs, even in the case of print layers that dry relatively quickly, at a sufficiently small spacing of the corresponding zones.
(105) If a desired motif consists of larger, uniform color surfaces, e.g. the German flag sketched in
(106) It is particularly advantageous to ensure that the thickness of the interference layer averaged over all zones of the color regions 31 is identical or almost identical for all color regions 31.
(107) This can be achieved via the insertion of so-called sunk zones. Such sunk zones are characterized by a much greater embossing depth t.sub.v compared with the color-generating zones. The method, described above with reference to
(108) In respect of the design of the layers and of the basic procedure of the method, reference is made in respect of the embodiment example according to
(109)
(110) For this, the delimitation of the lateral expansion of the color regions 31 to less than 300 μm is furthermore helpful. This has the result that the boundary layer or boundary surface opposite the surface relief is smoothed down better.
(111)
(112) The number of sunk zones required in each color region depends on the sought color impression of the respective color region. This can be explained with reference to the flag from
(113) The lower, yellow band of the flag—color region 313—is composed of 50% red and 50% green color-generating zones. Let the thickness of the interference layer in the green zones be 350 nm. In this case, the insertion of approximately V=5% sunk zones with the thickness of the interference layer d.sub.v of 1095 nm is sufficient to obtain roughly the same thickness, averaged over all zones, of the interference layer as in the color regions 311 and 312 (425 nm=(50%−V/2)×425 nm+(50%−V/2)×350 nm+1095 nm×V).
(114) Preferably, the proportion V of the sunk zones in each color region 31 is less than 50%, further preferably less than 30%, in particular less than 20% and in particular preferably less than 10%. The smaller the proportion V of the sunk zones, the less the color impression of the color region is impaired.
(115) The relief depth of the zones 41 to 45 was defined in
(116) Furthermore it is advantageous, as already described above, to provide in the area 21 color regions 31 which display metameric colors at one or more angles of illumination or observation. Metameric colors here are colors which call up the same color impression for the human observer but are generated by the color mixing of different color pairs. The drawing
(117) Alternatively or in addition, the design of the security feature can have an optical interplay or interaction with printed images which directly adjoin the security feature. The printed images can also be arranged only very close to the security feature.
(118) A further possible structure of the optically variable element 11 in the area 21 is shown by way of example in
(119)
(120) In respect of the possible structure of the thin-film interference filter 15, reference is furthermore also made to the above statements about
(121) In the area 21, for one thing, zones 41 are thus provided in which the colored varnish layer 25 is not provided, and thus a color is generated for the observer by the thin-film interference filter 15 by means of interference. In the zones 45, the partial areas 26 of the colored varnish layer 25 are provided, with the result that in the zones 45 the color is generated by the dyes and/or pigments provided in the partial areas 26 in the event of illumination. Correspondingly, further zones 46 and 47 are provided in which a respective color is generated by the dyes and/or pigments provided in the partial areas 27 and 28 respectively. The zones 41, 45, 46 and 47 here have the width and/or length dimensions already stated above which preferably lie in a range of from 5 μm to 300 μm, in particular 10 μm to 150 μm and particularly preferably in the range of from 20 μm to 80 μm. The optically variable element thus has one or more color regions in which the color being displayed at a particular angle of illumination and observation is produced by a color mix effect between the color generated in the zones 41 by means of interference and the color generated in one or more of the zones 45 to 47 by a dye and/or a pigment.
(122) Furthermore, it is also possible to provide in the area 21 another number of different zones provided with a colored varnish layer displaying a different color and/or to combine this embodiment example with one of the previously described embodiment examples. It is thus advantageous to provide, not just one type of zones, but different types of zones in which the color is provided in the event of illumination by interference by means of a thin-film interference filter which has a different average thickness of the interference layer 17 in these zones.
(123) Preferably gravure printing, flexographic printing or silk-screen printing is used as printing technique for printing on the colored varnish layer 25. The zones 45 to 47 can thus display for example a blue, a green and a black color. The thin-film interference filter 15 arranged in the zones 41 displays for example a color change from red to green in the event of tilting. For example, for this, the absorption layer 16 is formed as an 8-mm chromium layer, the interference layer 17 is formed as a 600-nm MgF.sub.2 layer and the reflective layer 18 is formed as a 50-nm Al layer.
(124) According to a further preferred embodiment, the optically variable element 11 provides a window security feature. For this, for example in the three-layered structure shown above both the absorber and the reflective layer is formed as a semi-transparent layer, for example formed by a 10 nm thick silver layer. In this case, the same color effect image appears on both sides, but mirrored. Furthermore, it is also possible to apply a further layer 14 to the back side of the reflective layer 18 in order to form a window security feature, to emboss this further layer and then to apply a further thin-film interference filter 15 in reversed order. In such a structure, different images can be realized in the event of observation from different sides, or also identical, but not mirrored, color effect images. This embodiment can be combined with all of the above-described embodiments.
(125) A further embodiment in which the optically variable element 11 provides a window security feature provides that the reflective layer of the thin-film interference filter 15 is partially removed, in particular by means of known demetallization methods. A replication varnish and/or photoresist which can optionally be dyed is applied to the partially demetallized reflective layer. Optionally, diffractive structures or anisotropic matte structures can e.g. be replicated into this varnish layer. The varnish layer is then optionally coated with a second reflective layer or a second thin-film interference filter 15, in particular a layer system with three layers, an absorption layer, a spacer layer acting as interference layer and a reflective layer. The second thin-film interference filter 15 here can be constructed as described in this document from color regions 31 and zones 41 to 47. The varnish is then illuminated from the back side with UV radiation, wherein the partially demetallized first reflective layer acts as a photomask. Finally, the dyed varnish layer is partially removed in a washing step or the second reflective layer or the second thin-film interference filter is demetallized in a lift-off process. This embodiment of the optically variable element 11 has, observed from the front or back side, either an optically variable effect and a dyed pattern or two optically variable effects, wherein the demetallized area and the dyed pattern or the two demetallized areas are present registered precisely relative to each other, i.e. positionally accurate or register accurate relative to each other.
(126) A further possibility for making it easier to form a second boundary surface of the interference layer 17 that is as smooth as possible is to provide in the relief structure one or more webs which are molded between two zones or two color regions. Preferably, the webs here are arranged such that the surface relief has one web in the boundary areas between two zones, if neither of the two zones represent a zone with the minimum layer thickness of the interference layer 17.
(127) This is shown by way of example in
(128)
(129) The application of the absorber layer 16 and the reflective layer 18 can also be dispensed with. This is the case in particular when the thin-film interference filter is realized according to
(130) In the zones 41 to 43 the interference layer 17 has a different layer thickness, with the result that in this area different colors are generated by means of interference under the same illumination and observation conditions. Webs 149 are additionally provided which reach up to the vertical level of the zones with the smallest thickness of the interference layer 17. In this way, a type of support point for the formation of a smooth, second boundary surface of the interference layer 17 is created. The width of the webs 149 in this example is approximately 15% of the width of the zones 41 to 43. The webs 149 make it easier to keep under control the forces which intend to emulate the structure of the boundary surface oriented to the substrate 14 in the exposed boundary surface during the application of the material of the interference layer 17, in particular during printing and/or subsequent drying of the interference layer.
(131) The width of the webs 149 is preferably between 500 nm and 100 μm, in particular 2 μm to 50 μm and particularly preferably between 5 μm and 30 μm. Preferably, the zones 41 to 43 have in each case lateral dimensions at least twice as large as those of the webs. Particularly preferably, the lateral dimension of the zones 41 to 43 is at least three times as large as that of the webs 149.
(132) Furthermore, it is also possible that the webs 149 at least partially frame, not the individual zones, but the color region. The drawing
(133)
(134) The webs 149 are represented continuously in the previously represented embodiment examples. However, it is also possible to use the webs with a break which likewise achieves the desired effect for forming a smooth, second boundary surface in the boundary layer. Preferably, the zones and color regions should be at least 50%, preferably at least 70% framed by webs.
(135) Furthermore, it is also possible that the webs 149 are arranged in a grid which comprises several color regions 31. Usefully, the spacing of the webs in x- and in y-direction here is to be chosen in the range of from 30 μm to 1 mm, in particular in the range of from 50 μm to 500 μm, further preferably in the range of from 50 μm to 200 μm.