SPIN TRANSPORT ELECTRONIC DEVICE
20170294572 · 2017-10-12
Inventors
- Ron NAAMAN (Yarkona, IL)
- Nirit KANTOR-URIEL (Rehovot, IL)
- Shinto P. MATHEW (Rehovot, IL)
- Yossef Paltiel (Maskeret Batya, IL)
- Oren BEN-DOR (Beit Zayit, IL)
- Shira Yochelis (Ness Ziona, IL)
- Nir PEER (Kfar Vradim, IL)
Cpc classification
G01R33/091
PHYSICS
H03K19/18
ELECTRICITY
G11C11/161
PHYSICS
G11C11/16
PHYSICS
G11C13/04
PHYSICS
International classification
G11C13/04
PHYSICS
Abstract
An electronic device is presented, the device comprises: a spin accumulating structure; a spin selective filter electrically connected at a first end thereof to a first surface of said spin accumulating layer structure; a charge carrier source attached to said spin selective filter at a second end of the spin selective filter; wherein the spin selective filter is configured to allow passage of the charge carriers having a predetermined spin orientation from the charge carrier source to the spin accumulating structure, thereby causing a variation of spin distribution of the charge carriers within the spin accumulating structure. The device comprises further at least first and second pairs of electrical contacts which are connected to the spin accumulating structure and define first and second electrical paths through said spin accumulating structure, said first and second electrical paths intersecting within said spin accumulating structure. The device including a circuit configured to apply an electrical current between the first pair of electrical contacts and to detect the variation of spin-distribution of charge carriers within the spin accumulating structure by determining electrical voltage between the second pair of electrical contacts in response to the applied electrical current.
Claims
1. An electronic device comprising: (a) a spin accumulating structure; (b) a spin selective filter electrically connected, at a first end thereof, to a first surface of said spin accumulating layer structure; (c) a charge carrier source attached to said spin selective filter at a second end of the spin selective filter; (d) at least first and second pairs of electrical contacts which are connected to the spin accumulating layer structure and define first and second electrical paths through said spin accumulating layer, said first and second electrical paths intersecting within said spin accumulating layer structure; thereby providing for detecting variation of spin distribution of charge carriers within the spin accumulating layer structure by determining electrical voltage between the second pair of electrical contacts in response to an electrical current between the first pair of electrical contacts.
2. The electronic device of claim 1, wherein the charge carrier source is in the form of a plurality of nanocrystals configured to generate free charge carriers in response to input electromagnetic radiation of a predetermined frequency.
3. The electronic device of claim 2, wherein said spin selective filter comprises a plurality of molecules having chiral or helical structure of one specific handedness.
4. The electronic device of claim 3, wherein said plurality of nanocrystals comprising nanocrystals attached to said chiral or helical molecules.
5. The electronic device of claim 1, wherein said spin selective filter is configured to allow passage of the charge carriers having a predetermined spin orientation from the charge carrier source to the spin accumulating structure, thereby causing said variation in spin distribution of the charge carriers within the spin accumulating structure.
6. The electronic device of claim 5, wherein said variation in spin distribution within the spin accumulating layer structure is indicative of data pieces being stored in said spin accumulating layer structure.
7. The electronic device of claim 5, wherein said variation in spin distribution within the spin accumulating layer structure is indicative of input data provided to said spin accumulating layer structure.
8. The electronic device of claim 1, wherein said spin accumulating layer structure comprises at least one ferromagnetic layer.
9. The electronic device of claim 8, wherein said at least one ferromagnetic layer is a thin layer to thereby allow generation of out-of-plane magnetization.
10. The electronic device of claim 8, wherein said at least one ferromagnetic layer has thickness below 7 nm.
11. The electronic device of claim 1, wherein said spin accumulating layer structure comprises at least one semiconductor layer.
12. The electronic device of claim 1, wherein said spin accumulating structure comprises two or more layers.
13. The electronic device of claim 1, configured and operable as a spintronics memory unit, in which data pieces are written and stored in the spin accumulating layer structure in the form of said variation of spin distribution of charge carriers within the spin accumulating layer structure, and is readable by passing the electric current through spin accumulating layer structure.
14. The electronic device of claim 13, wherein the stored information is erased by passing electric current above a predetermined value through said spin accumulating layer structure.
15. The electronic device of claim 1, configured and operable as a spintronics logic unit, in which output data in the form of voltage between the second pair of electrodes is determined in accordance with input data in the form of input illumination.
16. The electronic device according to claim 1, being configured and operable as a Hall sensor.
17. The electronic device according to claim 1, being configured and operable for generating local magnetic fields.
18. An electronic memory device comprising: (a) a spin accumulating structure comprising a ferromagnetic layer; (b) a plurality of molecules having chiral or helical structure adsorbed to a surface of the spin accumulating structure in selected active regions of said spin accumulating structure causing local magnetization of said ferromagnetic layer in said selected regions, said selected regions forming data bits written in said memory device; (c) one or more electrical contacts connected to said ferromagnetic layer, for operating the data bits in the memory device.
19. The electronic memory device of claim 18, configured and operable as a spintronics memory unit, in which data pieces are written and stored in the spin accumulating structure in the form of variation of spin distribution of charge carriers within the spin accumulating structure, and is readable by passing an electric current through said spin accumulating structure.
20. The electronic memory device of claim 18, wherein stored information is erased by passing electric current above a predetermined value through said spin accumulating structure.
21. The electronic memory device according to claim 18, being configured and operable for generating local magnetic fields.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0028] In order to better understand the subject matter that is disclosed herein and to exemplify how it may be carried out in practice, embodiments will now be described, by way of non-limiting example only, with reference to the accompanying drawings, in which:
[0029]
[0030]
[0031]
[0032]
[0033]
[0034]
[0035]
DETAILED DESCRIPTION OF EMBODIMENTS
[0036] The use of chiral and helical molecules as spin filters opens a window for various novel types of electronic devices and operation thereof. Reference is made to
[0037] The device 100 includes a spin accumulating layer structure 110 placed on an electrically insulating substrate 160. A spin selective filter layer 120, e.g. formed by a plurality of chiral or helical molecules having one defined handedness, is electrically connected at a first end thereof to a first surface of the spin accumulating layer structure 110. The spin selective filter 120 is connected at another end thereof to a charge carrier source layer 130. The charge carrier 130 is configured to generate free charged particles (e.g. electrons) in response to input energy. The charge carrier source 130 may be in the form of plurality on nanocrystals (NC), e.g. semiconductor nanocrystals, attached to the spin selective filter 120. For example, each molecule of the spin selective filter 120 may be adsorbed on the surface of the spin accumulating layer structure 110 at one end thereof, and attached at its other end to a NC particle.
[0038] The spin accumulating layer structure 110 is placed in electrical connection with at least first and second pairs of electrically conductive contacts 140 and 150. Each of the at least first and second pairs of electrical contacts 140 and 150 define respectively an electrical path through said spin accumulating layer such that the first and second paths are intersecting within the spin accumulating layer.
[0039] As described above,
[0040] The device 100 may be used in electronic (or spintronics) memory unit, logic gate, switch or any other spintronics based device. According to some embodiments of the invention, pumping energy, e.g. electromagnetic/optical radiation, is used to generate free charge carriers in the charge carrier source 130. The spin selective filter 120 allows charge carriers having spin in one predetermined direction to flow from the charge source 130 to the spin accumulating layer 110 while allowing charge carriers of having spin in the opposite direction to flow from the spin accumulating layer structure 110 to the charge source 130. This varies spin distribution within the spin accumulating layer effectively generating a magnetic moment within the layer.
[0041] The spin selective filter 120 may generally be in the form of plurality of chiral or helical molecules, having one specific predetermined handedness. Such molecules allow transmission of charge carriers/electrons having pone predetermined spin orientation in one direction and the opposite spin orientation in the other direction.
[0042] In some embodiments of the present invention the electronic device 100 utilizes plurality of nano crystals (NCs) attached to the spin selective filter at its far end and operate to generate free charge carrier in response to pumping energy. More specifically as illustrated in
[0043] As indicated above, optical excitation of the NC's generates free charge carriers within the charge source 130 (e.g. NC's), the spin selective filter effectively operates to transfer spin torque from the NC's to the spin accumulating layer structure 110. This is illustrated in
[0044] To this end, the device 100 may be operated to write and store data piece by generating a proper variation in spin distribution within the spin accumulating layer structure 110 by illuminating the charge source 130 by optical illumination 170 of suitable wavelength. Readout of the stored data piece may be provided utilizing parallel giant magneto-resistance (at low temperatures) or Hall effects by transmitting electrical current through the spin accumulating layer structure 110 between the first pair of electrodes 140. At low current, this enables detection of Hall voltage, which is measured between a second pair of electrodes 150 defining an intersecting path. Generally the paths defined by the first and second pairs of electrodes are perpendicular to each other to enable detection of Hall voltage due to local magnetization of the spin accumulating structure 110. Additional pairs of electrodes may be used to enable logic operations. Additionally, the device may provide a building block for transistor type elements, e.g. a simple parallel giant magneto-resistance transistor device, as well as and three dimensional spin based logic.
[0045] Thus, the device according to the present invention provides a memory type device enabling write and read of data while not require a static permanent magnet unit. It should be noted that such permanent magnet unit generally requires a complex layered structure and is relatively large in dimension with respect to micrometer size electronic elements. In this connection it should also be noted that the device and technique of the present invention allows the use of permanent magnet enabling readout utilizing parallel giant magneto-resistance as well as anomalous Hall Effect (AHE). However, the device is operable without such permanent magnet to support operations such as writing, reading and erasing data pieces.
[0046] To this end, local probing (readout) of the magnetic field generated by local magnetization of the spin accumulating structure is preferably achieved using Hall sensors configuration. The Hall Effect configuration makes it possible to realize a device with output voltage proportional to the local magnetization within the active region of the device.
[0047] Additional configuration is illustrated in
[0048] The different electrode pairs 150a-150d may be used for probing of the local magnetization in the corresponding active regions 110a and 110b. As indicated above, transmission of electric current between the first electrode pair 140 results in Hall voltage in response to local magnetization in one or more of the active regions. More specifically, detection of Hall voltage between one or more of the electrode pairs 150a-150d provided data indicative of direction and magnitude of local magnetization in the corresponding active region, thereby enabling readout of stored data in the active regions 110a and 110b.
[0049] Additionally, erasing of data generally requires equilibration of the spin distribution within the active regions/spin accumulating structure 110. This is provided by passing relatively high current through the spin accumulating structure 110, i.e. between any selected pair of electrodes 140 and/or 150. Transmission of current above a corresponding threshold will redistribute the spin within the layer and effectively destroy the local magnetization to thereby erase data stored in the active region.
[0050] It should be noted that to provide data storage in the form of local magnetization, the spin accumulating structure 110 preferably configured with a thin film ferromagnetic layer. However, it should be noted that local magnetization may also be stored in semiconductor layer and/or electrically insulating layer of the spin accumulating structure.
[0051] The inventors have prepared two exemplary devices for demonstrating the principles of operation. Two types of spin accumulating structures were utilized. In the first exemplary sample, herein referred to as Si based device, the spin accumulating structure includes a bi-layered spin accumulating structure formed of a 5 nm thick Ni layer located on top of a shallow P doped Si layer (generating a shallow 2D-like hole gas) substantially similar to the example of
[0052] More specifically, an intrinsic Si wafer was Phosphor doped using ion implantation. The process utilized a dose of 10.sup.12 ions/cm.sup.2 with 5 KeV implant energy at 0° implantation angle. This implant yields a 30 nm P doped channel with a peak in ion density around 15 nm depth. Further fabrication of the Si-based spin accumulating structure included the following: etching the Si and patterning a conduction channel; evaporation followed by a liftoff process to provide gold contacts resulting in the pairs of electric contacts; passivation around the channel by deposition of 0.5 μm SiO.sub.2 using Plasma Enhanced Chemical Vapor Deposition (PECVD) followed by wet etching to pattern the active areas; evaporating deposition of 5 nm ferromagnetic Ni layer on top of the active areas of the silicon; adsorbing of the spin selective filter in the form of chiral/helical molecules followed by the NCs adsorption; and capping the samples with evaporation of thin 10 nm Al.sub.2O.sub.3 protection layer. The protection layer is used to prevent Ni oxidation and to protect the active regions of the device.
[0053] The thickness of the Ni layer is generally selected to maximize perpendicular magnetization. To this end a 5 nm Nickel layer is used. As generally known, a thin Ni layer may generally break into domains allowing for a perpendicular magnetization rather than in-plane magnetization which provides limited results. Such perpendicular magnetization can be measured at room temperatures using magnetic atomic force microscopy (AFM) in the 5 nm Ni layer.
[0054] The second exemplary sample, herein referred to as Ni based device, is configured with spin accumulating structure being a single-layered structure formed of a thin Ni layer. The Nickel layer capped with protecting 10 nm gold layer Hall channel was evaporated on a thick SiO.sub.2 insulation layer, followed by gold contacts evaporation. Before the adsorptions of the NC's, the 10 nm thin gold capping layer was etched and the samples were placed under an inert nitrogen environment. The molecules and NC's were than adsorbed without the capping layer. The 7 nm Ni thickness was enough to conduct, however the magnetization was less stable as long lived magnetic domain were achieved at lower temperatures. It should be noted that generally the Nickel layer is preferably below 7 nm in thickness to allow stable out-of-plane magnetization. It should also be noted that generally the gold layer capping may be thinner or thicker than 10 nm.
[0055] In both exemplary samples, the spin selective filter was formed by a layer of organic α helix L-Polyalanine (AHPA-L available by Sigma-Aldrich) and InAs or CdSe NC's. The helical molecules and NC's were adsorbed using several steps. First, the devices were left in absolute ethanol for 20 min before immersed into a 1 mM ethanol solution of the organic molecule for 3 hours. This procedure allows the self-assembled molecules monolayer (SAM) to form a homogeneous, closely packed single layer of molecules. The excess of the organic molecules are removed from the surface by washing the sample with ethanol for several times before the samples are dried under nitrogen. Lastly NCs are attached to the organic layer. For the purpose of the Si based device configuration, InAs NCs were used with average size of 5 nm in diameter and emission peak at 1240 nm. For the Ni based device, core CdSe NCs with emission peak at 610 nm were used.
[0056] To ensure that free charged particles are generated in the NC's and not the Silicon layer or SiO.sub.2 insulating substrate, the energy gap of NC's is selected to be smaller than the smallest gap of the Si channel structure (1 eV for InAs vs. 1.1 eV gap of bulk Si at room temperature). This is selected to enable excitation of the NC's with minimal influence on the Si channel in the Si based device.
[0057] It should be noted that, and as indicated above, stable magnetization of the spin accumulating structure may generally depend of characteristics of the structure in combination with thermal conditions. In this connection the inventors have found that the Si based device, utilizing Al.sub.2O.sub.3 passivation layer and 5 nm Ni layer, showed stable magnetization at room temperatures. This while the 7 nm thick Nickel layer in the Ni based device showed stable magnetization at lower temperatures, while at room temperature, magnetic domains formed within the Ni layer. Generally reduced thickness of the Ni layer may provide stable out of plane magnetization at higher temperatures. Additionally, thin ferromagnetic layers are generally suitable to provide stable magnetization in this configuration.
[0058] As indicated above, data pieces may be stored within a spin accumulating structure of the device 100 utilizing optical illumination of the charge source (NC's). This is exemplified in
[0059] The use of linear polarizer 1200 and QWP 1300 is to enable comparison between the effects of right/left circular polarization illumination (RCP/LCP) for both Hall configurations. This is provided using a linear polarizer in the optical path at angular orientations of 45° or 315° with respect to axis of the QWP. The coming laser intensity was monitored by splitting 1400 the signal between an intensity detector 1500 and the device 100 of the invention. A simple mechanical shutter is placed along the optical path to provide comparison between light and dark measurements.
[0060] To this end, the NC's of the device 100 are illuminated in cycles of 60 seconds light, followed by 60 seconds of darkness to demonstrate temporary magnetization of the spin accumulating structure. The absolute response is calculated by subtracting the offset from the Hall resistance response normalized by the total resistance.
[0061] Reference is made to
[0062] The large difference (asymmetry ratio of 1:4) measured between right and left circular polarizations indicated that the chiral/helical molecules layer provides spin selective filter and that local magnetization is generated even when exciting the system with non-polarized light. The measured Hall coefficient can be evaluated based on the density of holes in the p-doped Si layer (effectively operating as channel). This provides estimated local magnetization of about 120G.
[0063] As indicated, above, the Nickel based device may generally be more flexible and simpler structure, and allows the use of a more adaptable choice of NC's. An additional advantage of the Ni-based device is that this configuration opens the way to connecting logic structures in series.
[0064] As shown in
[0065] Additionally,
[0066] Generations of local magnetization in different temperatures in the Ni based exemplary device are shown in
[0067] At higher temperatures, i.e. 27K and above, Δρ.sub.xy LCP-RCP is increasing until the Ni demagnetization effect becomes strong. This is shown by the large increase in the asymmetry factor between measurements at 1.5K to 50K as compared to the smaller increase between the measurements at 50K to 225K. Also shown in
[0068] Thus, the device of the present invention utilizes chiral induced spin-selectivity effect (CISS) to provide transistor or memory type electronic device. More specifically, it should be noted that the induced local magnetization may be stored within the spin accumulating structure for predetermined time period. Additionally, the operation of the device can be considered as generating voltage between a second pair of electrodes (150) in response to electric current between a first pair of electrodes (140) under the condition that local magnetization of the active region (spin accumulating layer 110) is provided.
[0069] Also, it should be noted that as the NCs relevant spin coherence time T1 at ambient temperatures is typically longer than 100 ps, which is more than an order of magnitude larger than transport times through the chiral molecules. The radiative life time is in the order of ns. Therefore, a reasonable assumption would be that the excited state of the spin does not change dramatically before charge transfer occurs. In this case changes in the Hall voltage between diffracted polarization excitations predominantly originate from the overlap between the excited state and the spin filtering direction. Thus, local magnetization may be provided utilizing the spin selective filtering of the chiral/helical molecules and may be generated utilizing illumination in linear or no polarization.
[0070] Additionally, as indicated above, as charged particles having one spin orientation are passing from the NC's to the spin accumulating layer, corresponding particles having the opposite spin orientation are transferred from the spin accumulating layer to the NC's to preserve charge. This enhances the spin accumulation and the local magnetization of the spin accumulating structure. In other words, even without charging the surface of the spin accumulating structure, the oscillating charges are passing a spin torque to the spin accumulating structure as exemplified in
[0071] The present invention provides an electronic device configured to generate local magnetization in response to input illumination, and enables detection of the local magnetization in the form of perpendicular voltage in response to current passing through the device. The device of the invention may be used in a transistor for generating logic gates, as well as in combination with electrically conducting ferromagnetic layer allowing to utilizing a combination with an additional magnetic device. Also, the spin accumulating layer of the device may be configured to maintain magnetization for a predetermined time period to thereby operate the device as a memory unit omitting the need for static permanent magnet for read and write operations. Such device may also be used for producing strong local magnetization pulses for nuclear magnetic resonance (NMR) or Electron paramagnetic resonance (EPR) systems. In such configurations, the spin accumulating structure may include a parallel magnetized ferromagnetic layer configured to generate local perpendicular magnetization in response to spin injection through the spin selective filter layer.