THERMALLY LAMINATED TAB LINER
20170291399 ยท 2017-10-12
Inventors
Cpc classification
B29C65/7461
PERFORMING OPERATIONS; TRANSPORTING
B32B2250/44
PERFORMING OPERATIONS; TRANSPORTING
B32B15/04
PERFORMING OPERATIONS; TRANSPORTING
B29K2023/083
PERFORMING OPERATIONS; TRANSPORTING
B29K2023/00
PERFORMING OPERATIONS; TRANSPORTING
B29K2067/003
PERFORMING OPERATIONS; TRANSPORTING
B29C65/76
PERFORMING OPERATIONS; TRANSPORTING
B32B37/0053
PERFORMING OPERATIONS; TRANSPORTING
B32B2270/00
PERFORMING OPERATIONS; TRANSPORTING
B29C66/7392
PERFORMING OPERATIONS; TRANSPORTING
B32B2581/00
PERFORMING OPERATIONS; TRANSPORTING
B29C66/73713
PERFORMING OPERATIONS; TRANSPORTING
B29C65/3656
PERFORMING OPERATIONS; TRANSPORTING
B29C66/004
PERFORMING OPERATIONS; TRANSPORTING
B32B3/28
PERFORMING OPERATIONS; TRANSPORTING
B32B37/04
PERFORMING OPERATIONS; TRANSPORTING
B29C66/71
PERFORMING OPERATIONS; TRANSPORTING
B29C66/433
PERFORMING OPERATIONS; TRANSPORTING
B65D51/185
PERFORMING OPERATIONS; TRANSPORTING
B32B27/308
PERFORMING OPERATIONS; TRANSPORTING
B29C66/45
PERFORMING OPERATIONS; TRANSPORTING
B32B3/02
PERFORMING OPERATIONS; TRANSPORTING
B29C66/73921
PERFORMING OPERATIONS; TRANSPORTING
B29L2031/712
PERFORMING OPERATIONS; TRANSPORTING
B29C66/8322
PERFORMING OPERATIONS; TRANSPORTING
B32B27/306
PERFORMING OPERATIONS; TRANSPORTING
B29K2067/003
PERFORMING OPERATIONS; TRANSPORTING
B32B37/06
PERFORMING OPERATIONS; TRANSPORTING
B32B7/10
PERFORMING OPERATIONS; TRANSPORTING
B29C66/1122
PERFORMING OPERATIONS; TRANSPORTING
B29C66/43
PERFORMING OPERATIONS; TRANSPORTING
B29C66/71
PERFORMING OPERATIONS; TRANSPORTING
B65D65/40
PERFORMING OPERATIONS; TRANSPORTING
B32B15/082
PERFORMING OPERATIONS; TRANSPORTING
B29K2023/00
PERFORMING OPERATIONS; TRANSPORTING
B65D77/2024
PERFORMING OPERATIONS; TRANSPORTING
B65D51/20
PERFORMING OPERATIONS; TRANSPORTING
B29C66/72321
PERFORMING OPERATIONS; TRANSPORTING
B32B15/20
PERFORMING OPERATIONS; TRANSPORTING
B29C66/83413
PERFORMING OPERATIONS; TRANSPORTING
B29C66/53461
PERFORMING OPERATIONS; TRANSPORTING
B29K2023/083
PERFORMING OPERATIONS; TRANSPORTING
B32B7/05
PERFORMING OPERATIONS; TRANSPORTING
B32B2331/04
PERFORMING OPERATIONS; TRANSPORTING
International classification
B32B3/28
PERFORMING OPERATIONS; TRANSPORTING
B32B27/30
PERFORMING OPERATIONS; TRANSPORTING
Abstract
Liner having an induction heat sealable layer for sealing to a rim of a container, and a pull tab for ease of removal of the liner from the container rim. A folded insert disposed between multilayer upper and lower components, has a heat bondable polyolefin layer that is thermally laminated to polyolefin layers of the upper and lower components, forming a pull tab between the integrated polyolefin layers. The resulting composite resists delamination and can be formed in a single thermal lamination step, avoiding the multiple lamination steps, associated high equipment costs, and complex layer constructions of the prior art.
Claims
1. A liner comprising: three stacked multilayer components thermally laminated together to form a composite liner, the liner having an induction heat sealable lower layer for sealing to a rim of a container and a pull tab for ease of removal of the liner from the rim of the container, the three multilayer components comprising: an upper multilayer component (UMC) comprising an upper support layer and a lower heat bondable polyolefin layer; and a lower multilayer component (LMC) comprising an upper heat bondable polyolefin layer, the lower induction heat sealable layer, and an inductive heating layer therebetween; a folded insert comprising upper and lower multilayer insert portions joined at a fold line, each insert portion comprising an outer heat bondable polyolefin layer and an inner heat resistant separable layer wherein in a folded position the inner separable layers of the insert portions are facing one another and resist bonding by thermal lamination and induction heating to form the pull tab in the liner, the liner being formed by a method comprising: in a first area of the liner the UMC and LMC polyolefin layers are disposed facing one another and are thermally laminated by application of heat and pressure to form an integral polyolefin layer of a non-separable first liner portion; and in a second area of the liner the polyolefin layers of the upper and lower insert portions are disposed facing the UMC and LMC polyolefin layers respectively and thermally laminated, by application of heat and pressure, to form integral polyolefin layers in a second liner portion having the pull tab.
2. The liner of claim 1 wherein the folded insert is formed from a multilayer tube or sheet comprising the heat bondable polyolefin layer and the heat resistant separable layer, the folded insert formed by a method comprising: radially collapsing the tube or folding the sheet to form the fold line and insert portions on opposite sides of the fold line.
3. The liner of claim 1, wherein the liner has a substantially circular perimeter and the fold line intersects and extends across the circular perimeter at a length equal to or less than a diameter of the circular perimeter.
4. The liner of claim 1, wherein the support layer is formed from one or more of polyethylene terephthalate, polyamide, polyethylene naphthalate, polypropylene, or any combination thereof.
5. The liner of claim 1, wherein the folded insert is formed from a multilayer tube, the tube having an outer tube layer comprising the outer polyolefin layer of the insert, and the tube having an inner layer comprising the separable layer of the insert, the tube being collapsed to form the fold line and cut to form a folded tube portion that comprises the folded insert.
6. The liner of claim 1, wherein the liner is punched from a thermally laminated web of the three multilayer components.
7. The liner of claim 1, wherein the polyolefin layers of the liner are thermally laminated by at least partially melting the adjacent polyolefin layers.
8. The liner of claim 1, wherein the polyolefin layers of the liner are formed from at least one of an ethylene-based polymer and a propylene-based polymer.
9. The liner of claim 8, wherein the ethylene-based polymer is an ethylene-alpha olefin copolymer and the propylene-based polymer is a propylene-alpha olefin copolymer.
10. The liner of claim 1, wherein the polyolefin layers of the liner are formed from at least one of ethylene vinyl acetate (EVA) based polymers, ethylene-methyl acrylate (EMA) based polymers, and ethylene-ethyl acrylate (EEA) based polymers.
11. The liner of claim 1, wherein the polyolefin layers of the liner comprise polypropylene, polyethylene, and copolymers and blends thereof.
12. The liner of claim 1, wherein the inductive heating layer comprises a metal foil layer.
13. The liner of claim 1, wherein the multiplayer components are formed by one or more of extrusion, coextrusion, extrusion coating, extrusion lamination, and dry bond lamination.
14. A method of forming a liner comprising: thermally laminating together three stacked multi-layer components to form a composite liner, the liner having an induction heat sealable lower layer for sealing to a rim of a container and a pull tab for ease of removal of the liner from the rim of the container, the three multi-layer components comprising: an upper multilayer component (UMC) comprising an upper support layer and a lower heat bondable polyolefin layer; and a lower multilayer component (LMC) comprising an upper heat bondable polyolefin layer, the lower induction heat sealable layer, and an inductive heating layer therebetween; a folded polymer insert comprising upper and lower multilayer insert portions joined at a fold line, each insert portion comprising an outer heat bondable polyolefin layer and an inner heat resistant separable layer wherein in a folded position the inner separable layers of the two insert portions are facing one another and resist bonding by thermal lamination and induction heating to form the pull tab in the liner, wherein the method includes: disposing a first area of the UMC and LMC polyolefin layers facing one another, disposing the folded insert between a second area of the UMC and LMC polyolefin layers with the polyolefin layers of the upper and lower insert portions disposed facing the UMC and LMC polyolefin layers respectively, and forming a non-separable first liner portion by thermally laminating the facing polyolefin layers in the first area by application of heat and pressure to form an integral polyolefin layer, and forming a second liner portion having the pull tab by thermally laminating the facing polyolefin layers in the second area by application of heat and pressure to form integral polyolefin layers in the second liner portion.
15. The method of claim 14, wherein the polyolefin layers of the liner are formed from at least one of an ethylene-based polymer and a propylene-based polymer.
16. The method of claim 15, wherein the ethylene-based polymer is an ethylene-alpha olefin copolymer and the propylene-based polymer is a propylene-alpha olefin copolymer.
17. The method of claim 14, wherein the polyolefin layers are formed from at least one of ethylene vinyl acetate (EVA) based polymers, ethylene-methyl acrylate (EMA) based polymers, and ethylene-ethyl acrylate (EEA) based polymers.
18. The method of claim 14, wherein the polyolefin layers comprise polypropylene, polyethylene, and copolymers and blends thereof.
19. The method of claim 14, wherein the folded insert is formed from a multilayer tube or sheet comprising the heat bondable polyolefin layer and the heat resistant separable layer, the folded insert formed by a method comprising: radially collapsing the tube or folding the sheet to form the fold line and insert portions on opposite sides of the fold line.
20. The method of claim 14, wherein the multilayer components are formed by one or more of extrusion, coextrusion, extrusion coating, extrusion lamination, and dry bond lamination.
21. The method of forming the liner of claim 14, wherein the method comprises: providing the stacked three multilayer components; and forming the integral polyolefin layers in a single thermal laminating step.
22. The method of claim 21, wherein the UMC is formed, prior to the thermal laminating step, by one or more of extrusion, coextrusion, extrusion coating, extrusion lamination, and dry bond lamination.
23. The method of claim 21, wherein the LMC is formed, prior to the thermal laminating step, by one or more of extrusion, coextrusion, extrusion coating, extrusion lamination, and dry bond lamination.
24. The method of claim 21, wherein the folded insert is formed from a multilayer tube or sheet comprising the heat bondable polyolefin layer and the heat resistant separable layer, the folded insert formed by a method comprising: radially collapsing the tube or folding the sheet to form the fold line and insert portions on opposite sides of the fold line.
25. The method of claim 21, wherein the polyolefin layers of the UMC, folded polymer insert and are partially melted while pressing between rollers to form the integral polyolefin layers of the liner.
26. The method of claim 25, wherein at least one of the rollers is heated.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION OF THE INVENTION
[0067] Various embodiments of the invention will now be described with regard to the accompanying figures. These examples are nonlimiting and meant to illustrate various embodiments of the liner configuration, materials, and manufacturing processes.
[0068] An induction heat-sealable liner, also referred to as a sealing disk, is provided which includes a hinged tab. The liner has a three layer stacked construction, including a multi-layer upper component, a multi-layer lower component, and disposed between one area of the upper and lower components, a folded insert for forming the hinged tab.
[0069] In various embodiments, the liner includes a lowermost induction heat-sealable layer, an inductive heating layer (e.g., a metal film layer that heats resistively during the induction heat sealing operation) above the lowermost heat-sealable layer, and one or more layers of reinforcing (support) materials for enhancing the mechanical strength of the liner (e.g., enabling the liner to be punched, inserted into a closure, pushed down over the mouth of the container by the closure (e.g. screw cap), induction heat sealed to the container rim, and subsequently pulled from the container rim without rupturing).
[0070] As used herein, a layer or sheet of inductive heating material is any material which heats resistively when it conveys an induced electrical current. Typically the inductive heating layer is a metal foil layer, such as aluminum foil.
[0071] The induction heat sealable (lowermost) layer can be made from any polymeric material that will soften and seal to the rim of a container, while allowing the heat seal bond to be later ruptured by a user (person) grasping the pull tab and pulling the liner away from the container rim. The heat sealable layer is typically made from a material selected from the group comprising polyethylene, polypropylene and copolymers and blends thereof; such materials may be copolymers with ethylene such as with vinyl acetate, methyl acrylate, ethyl acrylate, or with a variety of alpha olefins such as butene, hexane, or octane. The inductive heating layer and the heat sealable layer may be joined by means of a binder (e.g., a two component isocyanate-hydroxyl adhesive). In another embodiment, the inductive heating layer may be coated with a heat sealable material.
[0072] In various embodiments the liner includes multiple (initially separate) layers of polyolefin material that when brought into engagement during the thermal lamination process, i.e., the application of heat and pressure, will be softened or partially melted so as to form an integral polyolefin layer. The polyolefin may be one or more of polyethylene, polypropylene, polyethylene vinyl acetate (EVA), polyethylene-methyl acrylate (EMA), and polyethylene-ethyl acrylate (EEA). The polyolefin material may comprise a single polymer, a copolymer, or blend. Preferably the polyolefin layers are formed from at least one of an ethylene-based polymer and a propylene-based polymer. The ethylene-based polymer may be an ethylene-alpha olefin copolymer, and the propylene-based polymer may be a propylene-alpha olefin copolymer.
[0073] Additional layers of the liner may include a reinforcing layer, such as a bi-axially oriented polyester film having a thickness of between 4 and 100 micrometers. The overall liner thickness may typically range between 100 and 600 micrometers.
[0074] As used herein, thermal lamination means the application of heat and pressure in order to thermally bond adjacent polyolefin layers to form a composite liner construction, including the hinged pull tab, that resists delamination in use during the removal of the liner from the container finish. The heat and pressure may be applied for example, by feeding the various layers jointly between rotating rollers, wherein one or more of the rollers may be heated. Other methods are known for applying heat and pressure to accomplish thermal lamination, and the invention is not limited to a particular method of thermal lamination. As used herein, the starting multi-layer components may be formed by lamination, coextrusion, extrusion coating, dry bond lamination (which may include water, solvent, or solvent less adhesive), or any of various methods know in the art for forming multi-layer sheet materials.
[0075] Various examples of the invention will now be described.
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[0078] The laminated web 50 includes at least one strip, here a collapsed coextruded tube 70, aligned in the lengthwise direction, that will form the multilayer folded insert. The collapsed coextruded tube 70 comprises an inner tubular layer 71 of a separable (heat resistant) material and a concentric outer tubular layer 72 of a polyolefin (heat bondable) material (as shown in
[0079] The multi-layer liner 10 is punched from both the two component (A1) and three component (A2) areas of the web 50, to form a multi-layer folded insert 80 having a fold line F, the fold line comprising one of the two folded edges F1, F2 of the collapsed tube 70 in the web 50. In this embodiment the folded insert 80 has a substantially circular perimeter P and the fold line F intersects and extends across the circular perimeter P at a length equal to or less than the length of the diameter of the circular tab liner.
[0080] The punched liner 10 (of
[0081] The punched liner 10 thus includes a portion of the collapsed or folded coextruded tube 70, now referred to as a multi-layer folded insert 80 of the liner 10. In this embodiment, the folded insert 80 is semi-circular in shape, comprising a portion of the folded tube 70 that includes a straight fold line F (same as F1 of web 50) extending across a diameter D of the disk, separating the disk into roughly two equal semi-circular portions, i.e., a non-separable first liner portion 16 to the right of the fold line F, and a second liner area 14 including and to the left of the fold line F, forming the pull tab 12. The second liner portion 16 includes the upper and lower components 52, 56, with the folded insert 80 therebetween. The folded insert includes facing upper and lower semi-circular surfaces 81U, 81L of the heat resistant inner tube layer 71 that are hinged at the fold line F (like a clam shell). The folded insert 80 further includes upper and lower semi-circular surfaces 82U, 82L, of the heat bondable polyolefin outer tube layer 72 thermally laminated to facing heat bondable polyolefin layers of each of the lowermost layer 20 of upper component 52, and uppermost layer 30 of the lower component 56, respectively. The upper 82U/20 and lower 82L/30 composite layers (following thermal lamination) are joined at the fold line F, wherein upper composite layers 82U/20 are movable between a first (closed) position adjacent to the lower composite layers 82L/30, to a second (open) position rotated about the hinge (fold line F) and thus spaced apart from the lower composite so as to form the pull tab 12.
[0082] In summary, the separation between the upper 82U/20 and lower 82L/30 composite layers (in liner portion 14) is due to the separable inner layers 81U, 81L of the folded insert 80. In liner portion 16, the upper and lower multi-layer components 20, 30 are thermally laminated together without the folded insert 80, and thus are not separable.
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[0085] The lower multi-layer component 56 has an upper layer 58, also formed from polyolefin material, that will be thermally bonded either to the adjacent lower polyolefin layer 54 of the upper component 52, in a first area A1, or to an adjacent outer polyolefin layer 72L of the collapsed coextruded tube 70 disposed between the upper and lower components 52, 56 in a second area A2. Similarly, the lower polyolefin layer 54 of the upper component 52 will be bonded to an adjacent outer polyolefin layer 72U of the collapsed coextruded tube 70, in the first area A1. The lower component 56 further includes: a lowermost induction heat sealable layer 60, and an inductive heating layer 59 (here aluminum foil) provided between the lower heat sealable layer 60 and the upper polyolefin layer 58.
[0086] While the detailed embodiment described herein utilizes a collapsed (folded) tube for making the folded insert, in other embodiments the folded insert is made without a tube, e.g., by folding a multi-layer sheet. Furthermore, there may be one or more other layers in the liner, such as other reinforcing layers (e.g., of PET, nylon or other suitable materials known in the art).
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[0099] These and other embodiments of the invention will be apparent to the skilled person.