The present invention provides: a water-soluble film that is superior in cold water solubility and in practical properties such as strength and stiffness and that can resist deterioration in various properties such as chemical resistance over time; and a modified polyvinyl alcohol used for the water-soluble film. The present invention relates to a modified polyvinyl alcohol containing 0.05 to 10 mol % of a monomer unit having two carboxyl groups. In .sup.1H-NMR spectroscopy of the modified polyvinyl alcohol, an integral (X) from 6.8 to 7.2 ppm and an integral (Y) from 5.3 to 5.5 ppm satisfy the following expression:
0.60X/(X+Y)<1.0.

The present invention provides: a water-soluble film that is superior in cold water solubility and in practical properties such as strength and stiffness and that can resist deterioration in various properties such as chemical resistance over time; and a modified polyvinyl alcohol used for the water-soluble film. The present invention relates to a modified polyvinyl alcohol containing 0.05 to 10 mol % of a monomer unit having two carboxyl groups. In .sup.1H-NMR spectroscopy of the modified polyvinyl alcohol, an integral (X) from 6.8 to 7.2 ppm and an integral (Y) from 5.3 to 5.5 ppm satisfy the following expression:
0.60X/(X+Y)<1.0.

The present invention relates to an aqueous polymer emulsion comprising at least 30 wt. % of a vinyl copolymer (A), said vinyl copolymer comprising: (I) from 10 to 90 wt. % of 2-octyl acrylate monomer; (II) from 10 to 90 wt. % of at least one itaconate ester monomer according to formula (1) ##STR00001##
in which A and B may be different or the same and A and B are independently an alkyl group or an aryl group; and (III) from 0 to 80 wt. % of ethylenically unsaturated monomer other than (I) and (II); whereby the summed amount of (I), (II) and (III) is 100 wt. % and whereby the amount of vinyl copolymer (A) is given relative to the total weight amount of the polymers present in the emulsion.

A modified vinyl alcohol polymer powder having a structural unit derived from a derivative of an ethylenically unsaturated dicarboxylic acid, and containing a reduced amount of methanol, and a trace amount of a component that does not dissolve in water. The present invention relates to a modified vinyl alcohol polymer powder containing a structural unit derived from a derivative (A) of an ethylenically unsaturated dicarboxylic acid in a content (X) of 0.05 mol % or more and 10 mol % or less, and having a degree of saponification of 80.0 mol % or more and 99.9 mol % or less, the modified vinyl alcohol polymer powder has a methanol content of 0.01 weight % or more and less than 3.0 weight %, the modified vinyl alcohol polymer powder contains 0.1 ppm or more and less than 2,000 ppm of a component that is insoluble in a 90 C., 5 weight % aqueous solution.

A modified vinyl alcohol polymer powder having a structural unit derived from a derivative of an ethylenically unsaturated dicarboxylic acid, and containing a reduced amount of methanol, and a trace amount of a component that does not dissolve in water. The present invention relates to a modified vinyl alcohol polymer powder containing a structural unit derived from a derivative (A) of an ethylenically unsaturated dicarboxylic acid in a content (X) of 0.05 mol % or more and 10 mol % or less, and having a degree of saponification of 80.0 mol % or more and 99.9 mol % or less, the modified vinyl alcohol polymer powder has a methanol content of 0.01 weight % or more and less than 3.0 weight %, the modified vinyl alcohol polymer powder contains 0.1 ppm or more and less than 2,000 ppm of a component that is insoluble in a 90 C., 5 weight % aqueous solution.

Oligomers of certain glyceride compounds are generally disclosed herein. In some embodiments, the glyceride compounds include natural oil glycerides, such as glycerides derived from natural oils, such as palm oil, soybean oil, canola oil, and the like. Compositions containing such glyceride oligomers are also disclosed herein. Processes for making such glyceride oligomers are also disclosed herein. In some embodiments, the processes for making such compounds include reacting a plurality of unsaturated glyceride compounds in the presence of a metathesis catalyst.

Oligomers of certain glyceride compounds are generally disclosed herein. In some embodiments, the glyceride compounds include natural oil glycerides, such as glycerides derived from natural oils, such as palm oil, soybean oil, canola oil, and the like. Compositions containing such glyceride oligomers are also disclosed herein. Processes for making such glyceride oligomers are also disclosed herein. In some embodiments, the processes for making such compounds include reacting a plurality of unsaturated glyceride compounds in the presence of a metathesis catalyst.

A resin composition is provided, which includes 1 part by weight of (a) thermally conductive resin with a biphenyl group, 1.0 to 10.0 parts by weight of (b) polyphenylene oxide, 0.01 to 5.0 parts by weight of (c) hardener, and 0.1 to 5.0 parts by weight of (d) inorganic filler. (d) Inorganic filler is boron nitride, aluminum nitride, silicon nitride, silicon carbide, aluminum oxide, carbon nitride, octahedral carbon, or a combination thereof with a surface modified by iron-containing oxide. (d) Inorganic filler is sheet-shaped or needle-shaped.

A resin composition is provided, which includes 1 part by weight of (a) thermally conductive resin with a biphenyl group, 1.0 to 10.0 parts by weight of (b) polyphenylene oxide, 0.01 to 5.0 parts by weight of (c) hardener, and 0.1 to 5.0 parts by weight of (d) inorganic filler. (d) Inorganic filler is boron nitride, aluminum nitride, silicon nitride, silicon carbide, aluminum oxide, carbon nitride, octahedral carbon, or a combination thereof with a surface modified by iron-containing oxide. (d) Inorganic filler is sheet-shaped or needle-shaped.

Provided is an optical component comprising a methacrylic resin composition having excellent surface processability and displaying excellent preservability of formed surface processing. The optical component contain a methacrylic resin including a structural unit (X) having a cyclic structure-containing main chain that is at least one selected from the group consisting of an N-substituted maleimide monomer-derived structural unit, a glutarimide-based structural unit, and a lactone ring structural unit. The methacrylic resin composition has a Vicat softening temperature of 120 C. to 160 C. Among methacrylic acid ester monomer-derived structural units, a ratio (S/H) of the integrated intensity (S) of a syndiotactic fraction (rr) relative to the integrated intensity (H) of a heterotactic fraction (mr), as determined by .sup.1H-NMR measurement, is 1.20 to 1.50. The amount of methanol-soluble content is 5 mass % or less relative to 100 mass %, in total, of methanol-soluble content and methanol-insoluble content.