The present invention relates to regulation of the p H of a liquefaction process. Presented is a method for treatment of a biomass feedstock wherein the biomass feedstock is subjected to liquefaction, at a p H of at most 4, by treatment with hot compressed liquid water (HCW) at subcritical and/or supercritical conditions to improve the conversion efficiency. The present invention is also directed to quenching of a liquefaction process according to above, preventing, minimizing or eliminating clogging and/or fouling of sticky biomass components in process equipment during processing as according to above, and to the use of additives in a biomass liquefaction process.

The present invention relates to a method for precipitating lignin from organosolv pulping liquors. For this purpose, the organosolv pulping liquor is introduced as a precipitation medium in an already existing aqueous dispersion of lignin particles or a filtrate of an aqueous dispersion of lignin particles, wherein a separate, lignin-containing phase in a dispersed state is produced.

A selective removal of metal and its anion species that are detrimental to subsequent hydrothermal hydrocatalytic conversion from the biomass feed prior to carrying out catalytic hydrogenation/hydrogenolysis/hydrodeoxygenation of the biomass in a manner that does not reduce the effectiveness of the hydrothermal hydrocatalytic treatment while minimizing the amount of water used in the process is provided.

A selective removal of metal and its anion species that are detrimental to subsequent hydrothermal hydrocatalytic conversion from the biomass feed prior to carrying out catalytic hydrogenation/hydrogenolysis/hydrodeoxygenation of the biomass in a manner that does not reduce the effectiveness of the hydrothermal hydrocatalytic treatment while minimizing the amount of water used in the process is provided.

The present invention is directed to a process for producing spinnable cellulose at least in part from citrus fruits, such as oranges and lemons. In a preferred embodiment, cellulose is extracted from citrus fruits, discarded by the citrus fruits plantations and/or from parts of citrus fruits, waste of the industrial processing of citrus fruits derivatives. Cellulose is extracted from the entire peel of citrus fruits, which includes both albedo and flavedo, or only from albedo. Preferably, cellulose is obtained by chemical extraction, preferably in the absence of chlorine, comprising the treatment of raw materials derived from citrus fruits with hydrogen peroxide under basic conditions. Cellulose obtained by the process of the present invention is optionally mixed with cellulose obtained by different processes, for example with cellulose extracted from wood.

The present invention relates to a method for treating a lignocellulose biomass in order to dissolve the lignin therein, while the cellulose does not dissolve. The cellulose pulp obtained can be used to produce glucose. In addition the lignin can be isolated for subsequent use in the renewable chemical industry as a source for aromatic platform chemicals.

A super strong and tough densified wood structure is formed by subjecting a cellulose-based natural wood material to a chemical treatment that partially removes lignin therefrom. The treated wood retains lumina of the natural wood, with cellulose nanofibers of cell walls being aligned. The treated wood is then pressed in a direction crossing the direction in which the lumina extend, such that the lumina collapse and any residual fluid within the wood is removed. As a result, the cell walls become entangled and hydrogen bonds are formed between adjacent cellulose nanofibers, thereby improving the strength and toughness of the wood among other mechanical properties. By further modifying, manipulating, or machining the densified wood, it can be adapted to various applications.

The invention relates to a method for treating biomass (2). In a step (S10), biomass (2) and an impregnation liquid are fed into a first reactor unit (10) such that the biomass (2) is impregnated with the impregnation liquid while the biomass (2) is transferred through the first reactor unit (10) by a conveyor means (11). In another step (S20), the impregnated biomass (2a) is transferred from the first reactor unit (10) to a separation unit (25), wherein at least a part of the impregnation liquid is separated from the impregnated biomass (2a) within the separation unit. In a step (S30), the separated impregnation liquid is discharged from the separation unit (25), such that a first part (26a) of the impregnation liquid is recirculated back to the first reactor unit (10). The invention further relates to a system for treating biomass (2).

The invention relates to a method for treating biomass (2). In a step (S10), biomass (2) and an impregnation liquid are fed into a first reactor unit (10) such that the biomass (2) is impregnated with the impregnation liquid while the biomass (2) is transferred through the first reactor unit (10) by a conveyor means (11). In another step (S20), the impregnated biomass (2a) is transferred from the first reactor unit (10) to a separation unit (25), wherein at least a part of the impregnation liquid is separated from the impregnated biomass (2a) within the separation unit. In a step (S30), the separated impregnation liquid is discharged from the separation unit (25), such that a first part (26a) of the impregnation liquid is recirculated back to the first reactor unit (10). The invention further relates to a system for treating biomass (2).

A process to separate lignin from a lignocellulosic feedstock, said process comprising the steps of: providing said lignocellulosic feedstock; providing a composition comprising; an acid; a modifying agent selected from the group consisting of: sulfamic acid; imidazole; imidazole derivatives; taurine; a taurine derivative; a taurine-related compound; alkylsulfonic acid; arylsulfonic acid; triethanolamine; and combinations thereof; a peroxide salt; and a peroxide; exposing said lignocellulosic feedstock to said composition for a period of time sufficient to depolymerize substantially all of the lignin present in said lignocellulosic feedstock into lignin oligomers and lignin monomers;
wherein said process is carried out at atmospheric pressure.