Provided is a powder material for forming a three-dimensional object, the powder material containing granulated particles containing: a resin; and inorganic particles of which primary particles have a volume average particle diameter of 1 micrometer or less, wherein the granulated particles have a volume average particle diameter of 10 micrometers or greater but 70 micrometers or less and a BET specific surface area of 6 m.sup.2/g or greater but 8 m.sup.2/g or less.

A provided glass composition includes, in mass %: 50≤SiO.sub.2≤65; 20≤B.sub.2O.sub.3≤30; and 5≤Al.sub.2O.sub.3≤20, and further includes: at least one selected from the group consisting of MgO and CaO; and at least one selected from the group consisting of Li.sub.2O, Na.sub.2O, and K.sub.2O. In the glass composition, 0.1≤(MgO+CaO)<5, 0≤(Li.sub.2O+Na.sub.2O+K.sub.2O)≤4, and 0.50<MgO/(MgO+CaO)≤1.00 are satisfied. The glass composition is suitable for manufacturing a glass filler that has a low permittivity and that can exhibit an excellent water resistance.

A provided glass composition includes, in mass %: 50≤SiO.sub.2≤65; 20≤B.sub.2O.sub.3≤30; and 5≤Al.sub.2O.sub.3≤20, and further includes: at least one selected from the group consisting of MgO and CaO; and at least one selected from the group consisting of Li.sub.2O, Na.sub.2O, and K.sub.2O. In the glass composition, 0.1≤(MgO+CaO)<5, 0≤(Li.sub.2O+Na.sub.2O+K.sub.2O)≤4, and 0.50<MgO/(MgO+CaO)≤1.00 are satisfied. The glass composition is suitable for manufacturing a glass filler that has a low permittivity and that can exhibit an excellent water resistance.

Near-infrared absorbing material particles contain composite tungsten oxide particles represented by a general formula M.sub.xW.sub.yO.sub.z, wherein the element M is one or more of elements selected from H, He, an alkali metal, an alkaline earth metal, a rare earth element, Mg, Zr, Cr, Mn, Fe, Ru, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, Al, Ga, In, Tl, Si, Ge, Sn, Pb, Sb, B, F, P, S, Se, Br, Te, Ti, Nb, V, Mo, Ta, Re, Be, Hf, Os, Bi, and I, wherein the W is tungsten, wherein the O is oxygen, and wherein the x, y, and z satisfy 0.001≤x/y≤1 and 3.0<z/y.

Near-infrared absorbing material particles contain composite tungsten oxide particles represented by a general formula M.sub.xW.sub.yO.sub.z, wherein the element M is one or more of elements selected from H, He, an alkali metal, an alkaline earth metal, a rare earth element, Mg, Zr, Cr, Mn, Fe, Ru, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, Al, Ga, In, Tl, Si, Ge, Sn, Pb, Sb, B, F, P, S, Se, Br, Te, Ti, Nb, V, Mo, Ta, Re, Be, Hf, Os, Bi, and I, wherein the W is tungsten, wherein the O is oxygen, and wherein the x, y, and z satisfy 0.001≤x/y≤1 and 3.0<z/y.

The present invention is directed to a flame retardant thermal interface material. The material contains a bio-based material and associated functional additives, wherein the bio-based material includes a protein and the functional additives include at least one of a char forming promotor, a char reinforce agent, a foaming agent, a thermal conductive agent, a flame suppression agent and other additives. The char forming promotor, the char reinforce agent and the flame suppression agent are used to adjust the combustion behavior of the material to render the material having desired flame retardation performance. The foaming agent and thermal conductive agent are used to adjust thermal conductivity of the material. The present invention is also directed to a process method of making a flame retardation thermal interface material.

The present invention is directed to a flame retardant thermal interface material. The material contains a bio-based material and associated functional additives, wherein the bio-based material includes a protein and the functional additives include at least one of a char forming promotor, a char reinforce agent, a foaming agent, a thermal conductive agent, a flame suppression agent and other additives. The char forming promotor, the char reinforce agent and the flame suppression agent are used to adjust the combustion behavior of the material to render the material having desired flame retardation performance. The foaming agent and thermal conductive agent are used to adjust thermal conductivity of the material. The present invention is also directed to a process method of making a flame retardation thermal interface material.

A polymerizable composition for 3D printing includes a photocurable polymer resin and metal diboride nanosheets. The resulting polymer nanocomposite includes a polymer matrix and metal diboride nanosheets dispersed throughout the polymer matrix. A method of synthesizing a nanomaterial-containing resin for 3D printing includes preparing a dispersion of metal diboride nanosheets in a solvent, and combining the dispersion with a liquid polymer resin to yield the nanomaterial-containing resin. A method of fabricating a nanocomposite structure from the nanomaterial-containing resin includes providing the nanomaterial-containing resin to a three-dimensional printer, forming a three-dimensional structure with the three-dimensional printer, and processing the three-dimensional structure to yield the nanocomposite structure.

A polymerizable composition for 3D printing includes a photocurable polymer resin and metal diboride nanosheets. The resulting polymer nanocomposite includes a polymer matrix and metal diboride nanosheets dispersed throughout the polymer matrix. A method of synthesizing a nanomaterial-containing resin for 3D printing includes preparing a dispersion of metal diboride nanosheets in a solvent, and combining the dispersion with a liquid polymer resin to yield the nanomaterial-containing resin. A method of fabricating a nanocomposite structure from the nanomaterial-containing resin includes providing the nanomaterial-containing resin to a three-dimensional printer, forming a three-dimensional structure with the three-dimensional printer, and processing the three-dimensional structure to yield the nanocomposite structure.

A liquid repellent structure includes a surface to which liquid repellency is to be imparted, and a liquid repellent layer formed on the surface. In the structure: the liquid repellent layer contains a binder resin containing a fluorine-containing resin, and a filler dispersed in the binder resin; the filler contains a first filler having a BET specific surface area M of 100 m.sup.2/g to 400 m.sup.2/g; and the ratio M/F of the BET specific surface area M of the first filler to a mass F (mass %) of the fluorine-containing resin relative to the total mass of the liquid repellent layer is 4.1 to 20.0.