An apparatus for direct reduction of iron ore in a solid state including a pre-heating furnace for pre-heating iron ore fragments and biomass in briquettes of these materials to a temperature in the range of 400-900° C.; and a reduction assembly for briquettes from the pre-heating furnace. The reduction assembly includes a reaction chamber, a source of electromagnetic energy in the form of microwave energy, a wave guide for transferring microwave energy to the chamber for heating and reducing iron ore in briquettes from the pre-heating furnace, with biomass acting as a reductant, a source of an inert gas, pipework for supplying the inert gas to the chamber to maintain the chamber under anoxic conditions, and an outlet for discharging an offgas and any retained particulates that are generated in the chamber.

An apparatus for direct reduction of iron ore in a solid state including a pre-heating furnace for pre-heating iron ore fragments and biomass in briquettes of these materials to a temperature in the range of 400-900° C.; and a reduction assembly for briquettes from the pre-heating furnace. The reduction assembly includes a reaction chamber, a source of electromagnetic energy in the form of microwave energy, a wave guide for transferring microwave energy to the chamber for heating and reducing iron ore in briquettes from the pre-heating furnace, with biomass acting as a reductant, a source of an inert gas, pipework for supplying the inert gas to the chamber to maintain the chamber under anoxic conditions, and an outlet for discharging an offgas and any retained particulates that are generated in the chamber.

Electrorefining cells and methods for electrorefining ferrous molten metal (e.g. steels), that includes impurities (e.g., carbon), are described. Liquid metal is provided in ladle with a molten electrolyte on top of it to form a metal-electrolyte interface. An electrode connection is put into contact with the metal for electronic conduction therewith, while a counter electrode is put into contact with the electrolyte for forming an electrolyte-counter electrode interface. Both the electrode connection and the counter electrode remain in the solid form in, and inert to, the metal and the electrolyte, respectively. The electrode connection and the counter electrode are made of an electronically conductive material. Therefore, during electrorefining operations, an electromotive force can be supplied between the electrode connection and the counter electrode so as to induce electrochemical reactions to occur at both the metal-electrolyte interface and the electrolyte-counter electrode connection, producing a ferrous molten metal depleted of the impurities.

In accordance with the present invention, there is provided a process for producing hydrogen and graphitic carbon from a hydrocarbon gas comprising: contacting at a temperature between 600° C. and 1000° C. the catalyst with the hydrocarbon gas to catalytically convert at least a portion of the hydrocarbon gas to hydrogen and graphitic carbon, wherein the catalyst is a low grade iron oxide.

In accordance with the present invention, there is provided a process for producing hydrogen and graphitic carbon from a hydrocarbon gas comprising: contacting at a temperature between 600° C. and 1000° C. the catalyst with the hydrocarbon gas to catalytically convert at least a portion of the hydrocarbon gas to hydrogen and graphitic carbon, wherein the catalyst is a low grade iron oxide.

Methods and systems for producing are disclosed. A method for producing iron, for example, comprises: providing an iron-containing ore to a dissolution subsystem comprising a first electrochemical cell; wherein the first anolyte has a different composition than the first catholyte; dissolving at least a portion of the iron-containing ore using an acid to form an acidic iron-salt solution having dissolved first Fe.sup.3+ ions; providing at least a portion of the acidic iron-salt solution to the first cathodic chamber; first electrochemically reducing said first Fe.sup.3+ ions in the first catholyte to form Fe.sup.2+ ions; transferring the formed Fe.sup.2+ ions from the dissolution subsystem to an iron-plating subsystem having a second electrochemical cell; second electrochemically reducing a first portion of the transferred formed Fe.sup.2+ ions to Fe metal at a second cathode of the second electrochemical cell; and removing the Fe metal.

In accordance with the present invention, there is provided a process for producing hydrogen and graphitic carbon from a hydrocarbon gas comprising: contacting at a temperature between 600° C. and 1000° C. the catalyst with the hydrocarbon gas to catalytically convert at least a portion of the hydrocarbon gas to hydrogen and graphitic carbon, wherein the catalyst is a low grade iron oxide.

In accordance with the present invention, there is provided a process for producing hydrogen and graphitic carbon from a hydrocarbon gas comprising: contacting at a temperature between 600° C. and 1000° C. the catalyst with the hydrocarbon gas to catalytically convert at least a portion of the hydrocarbon gas to hydrogen and graphitic carbon, wherein the catalyst is a low grade iron oxide.

A continuous process provides direct reduction of iron ore in a solid state. Briquettes of iron ore fragments and biomass are transported through a preheating chamber and preheated to a temperature of at least 400° C. The preheated briquettes are transported through a heating/reduction chamber that has an anoxic environment, and iron ore and biomass in the briquettes are exposed to electromagnetic energy in the form of microwave energy under anoxic conditions. Microwave energy generates heat within iron ore, and biomass acts as a reductant and reduces iron ore in a solid state, as the briquettes move through the heating/reduction chamber.

A continuous process provides direct reduction of iron ore in a solid state. Briquettes of iron ore fragments and biomass are transported through a preheating chamber and preheated to a temperature of at least 400° C. The preheated briquettes are transported through a heating/reduction chamber that has an anoxic environment, and iron ore and biomass in the briquettes are exposed to electromagnetic energy in the form of microwave energy under anoxic conditions. Microwave energy generates heat within iron ore, and biomass acts as a reductant and reduces iron ore in a solid state, as the briquettes move through the heating/reduction chamber.