The present invention relates to a method for producing metallic lithium, and specifically a method for preparing lithium metal according to an embodiment of the present invention, comprises: preparing lithium phosphate; preparinge a mixture by adding a chlorine compound to the lithium phosphate; heating the mixture; obtaining lithium chloride by reacting the lithium phosphate and the chloride compound in the mixture; producing molten lithium metal by electrolyzing the lithium chloride; and recovering the molten lithium metal is disclosed.

The present invention relates to a method for producing metallic lithium, and specifically a method for preparing lithium metal according to an embodiment of the present invention, comprises: preparing lithium phosphate; preparinge a mixture by adding a chlorine compound to the lithium phosphate; heating the mixture; obtaining lithium chloride by reacting the lithium phosphate and the chloride compound in the mixture; producing molten lithium metal by electrolyzing the lithium chloride; and recovering the molten lithium metal is disclosed.

A system to remove sodium and Sulfur from a feed stream containing alkali metal sulfides and polysulfides in addition to heavy metals. The system includes an electrolytic cell having an anolyte compartment housing an anode in contact with an anolyte. The anolyte includes alkali metal sulfides and polysulfides dissolved in a polar organic solvent. The anolyte includes heavy metal ions. A separator includes an ion conducting membrane and separates the anolyte compartment from a catholyte compartment that includes a cathode in contact with a catholyte. The catholyte includes an alkali ion-conductive liquid. A power source applies a voltage to the electrolytic cell high enough to reduce the alkali metal and oxidize Sulfur ions to allow recovery of the alkali metal and elemental sulfur. The ratio of sodium to Sulfur is such that the open circuit potential of the electrolytic cell is greater than about 2.3V.

A system to remove sodium and Sulfur from a feed stream containing alkali metal sulfides and polysulfides in addition to heavy metals. The system includes an electrolytic cell having an anolyte compartment housing an anode in contact with an anolyte. The anolyte includes alkali metal sulfides and polysulfides dissolved in a polar organic solvent. The anolyte includes heavy metal ions. A separator includes an ion conducting membrane and separates the anolyte compartment from a catholyte compartment that includes a cathode in contact with a catholyte. The catholyte includes an alkali ion-conductive liquid. A power source applies a voltage to the electrolytic cell high enough to reduce the alkali metal and oxidize Sulfur ions to allow recovery of the alkali metal and elemental sulfur. The ratio of sodium to Sulfur is such that the open circuit potential of the electrolytic cell is greater than about 2.3V.

There is provided a more versatile technique that is useful for enhancing the sintering delay property of a metal powder. A metal powder surface-treated with at least one coupling agent comprising Si, Ti, Al or Zr, wherein a total adhesion amount of Si, Ti, Al and Zr is 200 to 10,000 μg with respect to 1 g of the surface-treated metal powder, wherein a 1% by mass aqueous solution of the coupling agent indicates a pH of 7 or less, and wherein a sintering starting temperature is 500° C. or higher.

An electrochemical cell for producing metal and chlorine from metal ore and a metal chloride includes a cathode, an anode, and a separator. A catholyte includes (i) water, (ii) a metal hydroxide comprising Q, where Q is an alkali metal, an alkaline earth metal, or a combination thereof, and (iii) suspended metal ore particles comprising M.sub.xO.sub.y where M is a metal and x and y are integers. An anolyte includes (i) water and (ii) a metal chloride comprising Q. An electrowinning process for producing metal and chlorine includes applying a voltage across the electrochemical cell to effect reduction of the M.sub.xO.sub.y in the cathode compartment to provide the metal M and oxidation of chloride ions in the anode compartment to form Cl.sub.2 gas.

An electrochemical cell for producing metal and chlorine from metal ore and a metal chloride includes a cathode, an anode, and a separator. A catholyte includes (i) water, (ii) a metal hydroxide comprising Q, where Q is an alkali metal, an alkaline earth metal, or a combination thereof, and (iii) suspended metal ore particles comprising M.sub.xO.sub.y where M is a metal and x and y are integers. An anolyte includes (i) water and (ii) a metal chloride comprising Q. An electrowinning process for producing metal and chlorine includes applying a voltage across the electrochemical cell to effect reduction of the M.sub.xO.sub.y in the cathode compartment to provide the metal M and oxidation of chloride ions in the anode compartment to form Cl.sub.2 gas.

An apparatus for stripping metal (12, 14) deposited on a cathode plate (16), comprises a first robotic arm (46) carrying a first stripping apparatus (40), the first stripping apparatus having a first gripping apparatus (62, 63) to grip the cathode plate such that the first robotic arm operates to lift the cathode plate out of the stripping station following stripping of the metal sheets from the cathode plate. A second robotic arm (48) carrying a second stripping apparatus (42) is located on a second side of the cathode plate, the second stripping apparatus having a second gripping apparatus (76, 77) for gripping one or both of the first sheet of metal (12) and the second sheet of metal (14). The second robotic arm can be operated to move the first sheet of metal and the second sheet of metal to a metal storage region following stripping from the cathode plate (16). The metal is stripped from the cathode plate without breaking the bridge of metal that interconnects the first sheet of metal and the second sheet of metal.

An apparatus for stripping metal (12, 14) deposited on a cathode plate (16), comprises a first robotic arm (46) carrying a first stripping apparatus (40), the first stripping apparatus having a first gripping apparatus (62, 63) to grip the cathode plate such that the first robotic arm operates to lift the cathode plate out of the stripping station following stripping of the metal sheets from the cathode plate. A second robotic arm (48) carrying a second stripping apparatus (42) is located on a second side of the cathode plate, the second stripping apparatus having a second gripping apparatus (76, 77) for gripping one or both of the first sheet of metal (12) and the second sheet of metal (14). The second robotic arm can be operated to move the first sheet of metal and the second sheet of metal to a metal storage region following stripping from the cathode plate (16). The metal is stripped from the cathode plate without breaking the bridge of metal that interconnects the first sheet of metal and the second sheet of metal.

A method for producing metal titanium by carrying out electrolysis using an anode and a cathode in a molten salt bath, the method using an anode containing metal titanium as the anode, the method comprising a titanium deposition step of depositing metal titanium on the cathode, wherein, in the titanium deposition step, a temperature of the molten salt bath is from 250° C. or more and 600° C. or less, and an average current density of the cathode in a period from the start to 30 minutes later of the titanium deposition step is maintained in a range of 0.01 A/cm.sup.2 to 0.09 A/cm.sup.2.