A method and a device for preparing graphene and hydrogen gas by converting waste plastics with Joule heat are provided according to the present application. The method uses the Joule heat generated when a strong current passes through the mixed plastic material mixed with conductive additive, as the reaction driving energy. By Joule heating, carbon-carbon bonds and carbon-hydrogen bonds are broken, amorphous carbon is converted into sp.sup.2 hybridized high-purity graphene, and hydrogen atoms are converted into hydrogen gas. The reaction device used by the method is mainly composed of three parts: an airtight reaction chamber, a gas collecting system and a power control system.

A method and a device for preparing graphene and hydrogen gas by converting waste plastics with Joule heat are provided according to the present application. The method uses the Joule heat generated when a strong current passes through the mixed plastic material mixed with conductive additive, as the reaction driving energy. By Joule heating, carbon-carbon bonds and carbon-hydrogen bonds are broken, amorphous carbon is converted into sp.sup.2 hybridized high-purity graphene, and hydrogen atoms are converted into hydrogen gas. The reaction device used by the method is mainly composed of three parts: an airtight reaction chamber, a gas collecting system and a power control system.

A method is provided for producing metal hybrid graphene. The method includes providing a ball mill chamber filled with inert gas and metal balls; inserting graphene, nanographite, and nanosized transition metal; into the chamber; turning the chamber; and extracting the metal hybrid graphene. The transition metal is at least one of nickel, copper, cobalt, tungsten, iron, chromium and/or manganese.

A method is provided for producing metal hybrid graphene. The method includes providing a ball mill chamber filled with inert gas and metal balls; inserting graphene, nanographite, and nanosized transition metal; into the chamber; turning the chamber; and extracting the metal hybrid graphene. The transition metal is at least one of nickel, copper, cobalt, tungsten, iron, chromium and/or manganese.

A nanoparticle or agglomerate which contains connected multi-walled spherical fullerenes coated in layers of graphite. In different embodiments, the nanoparticles and agglomerates have different combinations of: a high mass fraction compared to other carbon allotropes present, a low concentration of defects, a low concentration of elemental impurities, a high Brunauer, Emmett and Teller (BET) specific surface area, and/or a high electrical conductivity. Methods are provided to produce the nanoparticles and agglomerates at a high production rate without using catalysts.

A nanoparticle or agglomerate which contains connected multi-walled spherical fullerenes coated in layers of graphite. In different embodiments, the nanoparticles and agglomerates have different combinations of: a high mass fraction compared to other carbon allotropes present, a low concentration of defects, a low concentration of elemental impurities, a high Brunauer, Emmett and Teller (BET) specific surface area, and/or a high electrical conductivity. Methods are provided to produce the nanoparticles and agglomerates at a high production rate without using catalysts.

The present invention provides a method for the manufacture of graphene oxide from Kish graphite.

The invention, belonging to the field of membrane technology, presents a method for the direct growth of ultrathin porous graphene separation membranes. Etching agent, organic solvent and polymer are coated on metal foil, and then they are calcined at high temperature in absence of oxygen; after removal of metal substrate and reaction products, single-layered or multi-layered porous graphene membranes are obtained. Alternatively, the dispersion or solution of etching agent is coated on metal foil, on which a polymer film is then overlaid. The obtained sample is subsequently calcined at high temperature in absence of oxygen; after removal of metal substrate and reaction products, single-layered or multi-layered porous graphene membranes are obtained. The method involved in this invention is simple and highly efficient, and allows direct growth of ultrathin porous graphene separation membranes, without needing expensive apparatuses, chemicals and graphene raw material. Additionally, the graphene membranes prepared with this method have controlled pore size, ultrahigh water flux and strong resistance to irreversible fouling.

The invention, belonging to the field of membrane technology, presents a method for the direct growth of ultrathin porous graphene separation membranes. Etching agent, organic solvent and polymer are coated on metal foil, and then they are calcined at high temperature in absence of oxygen; after removal of metal substrate and reaction products, single-layered or multi-layered porous graphene membranes are obtained. Alternatively, the dispersion or solution of etching agent is coated on metal foil, on which a polymer film is then overlaid. The obtained sample is subsequently calcined at high temperature in absence of oxygen; after removal of metal substrate and reaction products, single-layered or multi-layered porous graphene membranes are obtained. The method involved in this invention is simple and highly efficient, and allows direct growth of ultrathin porous graphene separation membranes, without needing expensive apparatuses, chemicals and graphene raw material. Additionally, the graphene membranes prepared with this method have controlled pore size, ultrahigh water flux and strong resistance to irreversible fouling.

The present invention relates to catalysts or catalytic systems comprising liquid metals, and in particular, to catalysts or catalytic systems comprising liquid metals droplets dispersed in a solvent, as well as to methods and uses of such catalysts or catalytic systems. In some embodiments, the present disclosure provides a ‘green’ carbon capture and conversion technology offering scalability and economic viability for mitigating CO.sub.2 emissions.