Patent classifications
C01B2203/1082
Catalytically heated fuel processor with replaceable structured supports bearing catalyst for fuel cell
A highly compact heat integrated fuel processor, which can be used for the production of hydrogen from a fuel source, suitable to feed a fuel cell, is described. The fuel processor assembly comprises a catalytic reforming zone (29) and a catalytic combustion zone (28), separated by a wall (27). Catalyst able to induce the reforming reactions is placed in the reforming zone and catalyst able to induce the combustion reaction is placed in the combustion zone, both in the form of coating on a suitable structured substrate, in the form of a metal monolith. Fe—Cr—Al—Y steel foils, in corrugated form so as to enhance the available area for reaction, can be used as suitable substrates. The reforming and the combustion zones can be either in rectangular shape, forming a stack with alternating combustion/reforming zones or in cylindrical shape forming annular sections with alternating combustion/reforming zones, in close contact to each other. The close placement of the combustion and reforming catalyst facilitate efficient heat transfer through the wall which separates the reforming and combustion chambers.
Efficient Catalytic Greenhouse Gas-Free Hydrogen and Aldehyde Formation from Alcohols
Catalytic preparation of hydrogen and aldehyde(s) from alcohols, including bioalcohols, without production of carbon monoxide or carbon dioxide.
Monolith catalyst for carbon dioxide reforming reaction, preparation method for same, and preparation method for synthesis gas using same
The present invention relates to a monolith catalyst for a carbon dioxide reforming reaction and to a preparation method for same, and more specifically the invention provides a preparation method for a monolith catalyst for a methane reforming reaction using carbon dioxide, the method comprising a step of mixing and impregnating a support in a metal precursor solution, coating a monolith substrate with the solution resulting from the mixing and impregnating, drying same and then calcining the monolith substrate coated with the solution resulting from the mixing and impregnating.
Clay mineral supported catalysts
Disclosed is a hydrocarbon gas reforming supported catalyst, and methods for its use, that includes a catalytic material capable of catalyzing the production of a gaseous mixture comprising hydrogen (H.sub.2) and carbon monoxide (CO) from a hydrocarbon gas and a clay support material comprising a clay mineral, wherein the catalytic material is chemically bonded to the clay support material, and wherein the chemical bond is a M1-M2 bond, where M1 is a metal from the catalytic material and M2 is a metal from the clay support material, or the chemical bond is a M1-O bond, where M1 is a metal from the catalytic material and oxygen (O) is from the clay support material, wherein the supported catalyst comprises at least 70% or more by weight of the clay support material.
Catalyst Support, Recycle Reactor and Method for Releasing Hydrogen
A catalyst support may be provided that comprises: an inner core, which includes at least one phase change material; a coating layer around the inner core, which includes at least one metal oxide; a catalytically active layer, which is positioned in interstices of the coating layer and/or lying on the coating layer, wherein at least one catalytically active substance is included in the catalytically active layer; and a supporting layer which is positioned under the coating layer. A recycle reactor may be provided comprising a reservoir for accommodating a chemical hydrogen storage substance; the catalyst support; a screw conveyor for input and transport of the catalyst support; and a heating device with which the catalyst support can be heated. A method for releasing hydrogen from a chemical hydrogen storage substance may be provided.
PROCESS AND PLANT FOR PRODUCING HYDROCARBONS WITH REDUCED CO2-FOOTPRINT AND IMPROVED HYDROGEN INTEGRATION
Process and plant for producing hydrocarbon products from a feedstock originating from a renewable source, where a hydrogen-rich stream and on off-gas stream comprising hydrocarbons is formed. A portion of the hydrogen-rich stream is used as a recycle gas stream in a hydroprocessing stage for the production of said hydrocarbon products, and another portion may be used for hydrogen production, while the off-gas stream is treated to remove its H.sub.2S content and used as a recycle gas stream in the hydrogen producing unit, from which the hydrogen produced i.e. make-up hydrogen, is used in the hydroprocessing stage. The invention enables minimizing natural gas consumption in the hydrogen producing unit as well as steam reformer size.
Nano-Structured Catalysts
The present invention provides novel systems, methods, and processes for producing and synthesizing, through cost-effective thermal processes, highly active and stable carbide-based nano-structured catalysts and compositions that can be used in dry reforming of methane, natural gas, and biogas, for example, to synthesis gas (syngas). The invention provides for using carbon-containing raw materials for synthesizing and producing carbon-encapsulated metal-core nanoparticles such as nickel-based, tungsten-based, and molybdenum-based nano-structured catalysts that can be used in dry reforming gas to syngas.
METHOD OF OPERATING GAS GENERATING APPARATUS
A gas generating apparatus generates hydrogen having carbon monoxide concentration of 0.1% or less by reacting hydrogen carbide and water together without requiring a platinum catalyst. The gas generating apparatus includes a gas instantaneously-heating mechanism that instantaneously heats a source gas, and a catalyst vessel connected to the gas instantaneously-heating mechanism and containing a catalyst. A high-temperature heated source gas beam generated by the gas instantaneously-heating mechanism, which contains hydrogen carbide and water, is caused to collide with the catalyst to generate a gas. Heat of the source gas is transmitted to a catalyst surface because of the absence of a stagnation layer, and a non-equilibrium reaction efficiently proceeds on the catalyst. Hydrogen can be extracted with a low-cost ruthenium catalyst.
Method of obtaining paraffinic hydrocarbons from natural fat
A method of obtaining paraffinic hydrocarbons from fat, by an exemplary method, whereby the method is performed in two stages, in a coupled flow-type system, under atmospheric pressure conditions, in the presence of heterogeneous catalysts, after their thermal activation, so that in Stage I the fat and/or waste fat is heated at a temperature range of 100-500° C., in the presence of an inert gas, in the presence of a catalyst in the form of a metal oxide on an oxide support or in the form of a mixture of at least two metal oxides on an oxide support. The product obtained in Stage I is treated, in the presence of an inert gas, at a temperature range of 100-500° C., in the presence of a metallic catalyst on an oxide support, with hydrogen gas or with a mixture of hydrogen and carbon monoxide, obtained in the selective decomposition of methanol.
Porous alumina material, process for producing same, and catalyst
Provided is a production method for a porous alumina material, comprising the steps of: mixing an alkoxysilane solution that comprises an alkoxysilane, a mixed solvent comprising water and an alcohol, and an inorganic acid, with an aluminum solution comprising an aluminum compound and water, to prepare a mixed solution in which the aluminum compound and the alkoxysilane are dissolved in the mixed solvent; co-precipitating aluminum hydroxide with a silicon compound in the mixed solution, to form a precipitate; and baking the precipitate to form a porous alumina material comprising aluminum oxide and silicon oxide.