METHOD OF OPERATING GAS GENERATING APPARATUS

Abstract

A gas generating apparatus generates hydrogen having carbon monoxide concentration of 0.1% or less by reacting hydrogen carbide and water together without requiring a platinum catalyst. The gas generating apparatus includes a gas instantaneously-heating mechanism that instantaneously heats a source gas, and a catalyst vessel connected to the gas instantaneously-heating mechanism and containing a catalyst. A high-temperature heated source gas beam generated by the gas instantaneously-heating mechanism, which contains hydrogen carbide and water, is caused to collide with the catalyst to generate a gas. Heat of the source gas is transmitted to a catalyst surface because of the absence of a stagnation layer, and a non-equilibrium reaction efficiently proceeds on the catalyst. Hydrogen can be extracted with a low-cost ruthenium catalyst.

Claims

1. A method of operating a gas generating apparatus having a gas heating mechanism and a catalyst vessel, the catalyst vessel being connected to the gas heating mechanism and containing a catalyst, comprising: by the gas heating mechanism, heating a source gas to above a reaction temperature to generate a high-temperature heated source gas beam; and causing the high-temperature heated source gas beam to collide with the catalyst to (i) heat the catalyst to the reaction temperature, and (ii) generate a gas by a catalytic reaction with the catalyst at the reaction temperature.

2. The method according to claim 1, wherein the catalyst is an aggregate of particles.

3. The method according to claim 1, further comprising: splitting the high-temperature heated source gas beam into a plurality of high-temperature heated source gas beams; and causing the high-temperature heated source gas beams to collide with a surface of the catalyst and converge again to extract a generated gas.

4. The method according to claim 1, wherein the catalyst is a catalyst made of ruthenium-supported alumina.

5. The method according to claim 1, wherein the source gas is a combination between a hydrogen carbide such as methane and water.

6. The method according to claim 1, wherein one component of the generated gas is hydrogen.

7. The method according to claim 1, wherein a heating temperature of the gas heating mechanism ranges from 500° C. to 900° C.

Description

BRIEF DESCRIPTION OF DRAWINGS

[0023] FIG. 1 is a block diagram of a catalyst high-temperature collision gas generating mechanism.

[0024] FIG. 2 is a block diagram of a gas generating apparatus including the catalyst high-temperature collision gas generating mechanism.

[0025] FIG. 3 is a block diagram of a gas generating apparatus including a plurality of high-speed collision heated source gas beams.

[0026] FIG. 4 is flow diagram of operation of the gas generating apparatus.

DETAILED DESCRIPTION

[0027] An embodiment of the present invention is described herein with reference to the accompanying drawings.

[0028] A gas generating apparatus according to the present invention is an apparatus that causes a source gas to collide with a catalyst surface while the catalyst surface is heated to enhance a reaction.

[0029] FIG. 1 shows a mechanical principle of a gas generating apparatus that causes a source gas instantaneously heated to collide with a catalyst surface at a high speed while the catalyst surface is heated. It is assumed that the mechanism is called a catalyst high-temperature collision gas generating mechanism 100. This mechanism 100 includes a gas instantaneously-heating mechanism 102 that instantaneously heat a source gas 101. In the heating mechanism 102, for example, the techniques disclosed in Japanese Patent Application Nos. 2012-107128, 2012-203119, 2013-237211, and 2013-197594 can be used. A gas instantaneously-heating device using the heat exchanger techniques disclosed in the patent literatures is marketed under the trade name of Heat-Beam Cylinder by Philtech Inc. (The University of Tokyo Entrepreneur Plaza 505, 7-3-1 Hongo Bunkyo-ku Tokyo 113-0033) (see the Internet <URL: http://www.philtech.co.jp/>).

[0030] Since a high-speed high-temperature gas beam 103 formed by the heating mechanism 102 has a high speed, the gas beam 103 is incident on like a beam to strongly collide with a catalyst surface 105 of a catalyst 104. With the collision of the high-temperature high-speed beam, a stagnation layer thickness d of a stagnation layer 106 at a collision portion becomes smaller than that at another portion. FIG. 1 typically shows this manner by using the stagnation layer 106 indicated by a broken line.

[0031] When the stagnation layer thickness d of the stagnation layer 106 at the collision portion decreases, a resistor layer for heat exchange decreases to cause the high-speed high-temperature gas to transmit heat to the catalyst surface 105. For this reason, the temperature of the surface becomes a temperature close to the temperature of the high-temperature source gas beam 103.

[0032] When the high-temperature source gas 103 is continuously incident on, the surface temperature is kept at a high temperature. A catalytic reaction proceeds on the catalyst surface 105 at the high temperature. In this case, since the thickness d of the stagnation layer is small, a gas generated with the reaction diffuses and moves at a speed higher than that when the thickness is large, transported by the high-current-speed high-temperature source gas beam 103, and does not flow upstream to the stagnation layer 106. More specifically, the reaction one-directionally proceeds without causing the generated gas to form a space layer for inhibiting the next reaction.

[0033] In other words, a nonequilibrium reaction proceeds in the adjacent space. Thus, a surface space with/on which the source gas collides and is incident is a high-temperature nonequilibrium reaction space 107.

[0034] In a conventional reaction scheme in which the source gas 101 is gently supplied into a catalyst vessel kept at a high temperature, since a stagnation layer also covers a catalyst surface, an equilibrium reaction occurs under diffusion control. In the equilibrium reaction, a backward reaction which decreases the reaction speed of a forward reaction occurs at once. In this embodiment, the characteristic feature of the catalyst high-temperature collision gas generating mechanism 100 is to form the nonequilibrium reaction space 107 which prevents an equilibrium reaction from occurring.

[0035] The nonequilibrium reaction makes material moving irreversibly to increase a reaction speed and to improve generating efficiency. Thus, the catalyst high-temperature collision gas generating mechanism 100 is a mechanism that causes a reaction to proceed at a high speed on the catalyst surface 105 in a nonequilibrium state.

[0036] FIG. 2 shows a gas generating apparatus 200 using the mechanism 100 as a concrete structure of the apparatus. The gas generating apparatus 200 includes a gas instantaneously-heating mechanism unit 201 and a catalytic reaction unit 202 which are connected to each other.

[0037] A source gas 204 is introduced from a source gas inlet 203 at a high speed while being flow-controlled. The source gas 204 is instantaneously heated with the instantaneously-heating mechanism unit 201 to obtain a high-speed heated source gas beam 205. The heated source gas beam 205 collides with and is incident on catalyst particles 207 contained in a catalyst vessel 206. As the instantaneously-heating mechanism unit 201, a fluid heat exchanger based on the heat exchange principles described in Japanese Patent Application Nos. 2012-107128, 2012-203119, 2013-237211, and 2013-197594 is used. A gas instantaneously-heating device which employs the principles is marketed under the trade name of Heat-Beam Cylinder by Philtech Inc. (The University of Tokyo Entrepreneur Plaza 505, 7-3-1 Hongo Bunkyo-ku Tokyo 113-0033) (see the Internet <URL: http://www.philtech.co.jp/>).

[0038] The heated source gas beam 205 being incident on the surfaces of the catalyst particles 207 at a high speed reacts to generate a gas, and a generated gas 208 blows out of a generated gas outlet 209. The catalyst vessel 206 is heat-insulated by a heat-insulating mechanism 210 and kept at a constant temperature.

[0039] Methane and water are introduced as the source gas 204, and a heating set temperature of the gas instantaneously-heating mechanism unit 201 is set to, for example, 700° C. At this time, the source gas 204 reacts on the ruthenium-alumina catalyst particles 207 to generate hydrogen H2, carbon dioxide CO.sub.2 and carbon monoxide CO as the generated gas 208.

First Example

[0040] An example executed with the configuration shown in FIG. 2 will be described below.

[0041] A B-type Heat-Beam Cylinder available from Philtech Inc. was used as the gas instantaneously-heating mechanism unit 201. The heat-beam cylinder is a gas instantaneous heater having a maximum input power of 1500 W, and can increase the temperature up to 1000° C. As the source gas, methane and steam heated to 130° C. or higher were used. Columnar particles made of ruthenium-supported alumina were put as a catalyst in a catalyst vessel 206 which is a 3/8-inch pipe. In order to obtain a high-speed source gas beam, an argon gas was used as a carrier gas. The temperature of the source gas beam was set to 680° C. In order to cool the temperature of the generated gas, a cooling mechanism and a water collecting mechanism are connected to the generated gas outlet 209. When the components of the cooled generated gas were analyzed, the generated gas contains the rest of methane, hydrogen, carbon dioxide, and carbon monoxide, and a carbon monoxide of the generated gas except for Ar was 0.1% or less.

Second Example

[0042] The same experiment as described above was executed such that only the temperature was changed into 540° C. The measured carbon monoxide temperature was similarly 0.1% or less. As a result, an advantage of nonequilibrium reaction caused by collision was great, and hydrogen having a low carbon monoxide concentration could be obtained even with a low-price ruthenium catalyst.

[0043] As a structure that causes the heated source gas to collide with the catalyst surface, other various structures can be conceived.

[0044] FIG. 3 shows a catalyst high-temperature collision gas generating apparatus in which the high-speed high-temperature heated source gas beam 205 are split into a plurality of high-speed high-temperature source gas beams 302, the high-temperature heated source gas beams 302 are caused to collide with the surface of a catalyst plate 301 to heat a catalyst surface, react on the surface, converged again, and extracted as the generated gas 208.

[0045] A generated gas is determined depending on a source gas. For example, when the gas contains methane and water, a heating set temperature of the gas instantaneously-heating mechanism 201 is set to 500° C. to 900° C., and the catalyst particles 207 made of ruthenium-supported alumina are used. As a result, the gas reacts to generate hydrogen H.sub.2, carbon dioxide CO.sub.2, and carbon monoxide CO.

[0046] A gas containing propane or other petroleum hydrogen carbides is selected and mixed with water to make it possible to generate a gas containing hydrogen.

[0047] When the gas is caused to pass through the apparatus once, a CO concentration is typically 0.1% or less. However, when the gas is caused to pass through the apparatus two or more times, the CO concentration can be more reduced.

[0048] As described above, according to the embodiment, the source gas beam heated to a high temperature collides with the catalyst, and the collision reduces a stagnation layer to cause a nonequilibrium reaction. For this reason, at the same time, heat of the source gas is also efficiently transmitted to the catalyst surface through the thin stagnation layer to make it possible to keep the surface temperature at a high temperature.

[0049] Since the reaction efficiency is high, a catalyst can be made of ruthenium without using platinum. Ruthenium/alumina is one of candidates for a low-price catalyst, and a catalyst having a lower price may be used by searching.

[0050] Hydrogen containing less carbon monoxide can be directly extracted from a hydrogen carbide gas by a single reaction. Furthermore, a temperature can be arbitrarily selected from the temperatures ranging from 500° C. to 900° C. In the structure of a heat exchanger configured by the heat-beam cylinder, a temperature difference between a gas temperature and the temperature of a heater of a heating unit can be reduced to 100° C. or less. For this reason, unlike in a heat exchanger using another principle, the temperature of metal constituting the heat exchanger can be reduced to 1000° C. or less at which deterioration failure rarely occurs.

[0051] FIG. 4 illustrates operation of the gas generating apparatus. Specifically, steps 400-402 describe operating a gas generating apparatus having a gas heating mechanism and a catalyst vessel, the catalyst vessel being connected to the gas heating mechanism and containing a catalyst.

[0052] At 400, the gas heating mechanism heats a source gas to above a reaction temperature to generate a high-temperature heated source gas beam.

[0053] At 402, the high-temperature heated source gas beam is caused to collide with the catalyst to (i) heat the catalyst to the reaction temperature, and (ii) generate a gas by a catalytic reaction with the catalyst at the reaction temperature.

[0054] The embodiment of the present invention has been described in detail with reference to the accompanying drawings. However, the concrete configuration of the invention is not limited to the embodiment, and includes a design or the like without departing from the spirit and scope of the invention.

Reference Signs List

[0055] 100: catalyst high-temperature collision gas generating mechanism [0056] 101: source gas [0057] 102: gas instantaneously-heating mechanism [0058] 103: high-speed high-temperature source gas beam [0059] 104: catalyst [0060] 105: catalyst surface [0061] 106: stagnation layer [0062] 107: nonequilibrium reaction space [0063] d: stagnation layer thickness at collision portion [0064] 200: gas generating apparatus [0065] 201: gas instantaneously-heating mechanism unit [0066] 202: catalyst reaction unit [0067] 203: source gas inlet [0068] 204: source gas [0069] 205: high-speed high-temperature heated source gas beam [0070] 206: catalyst vessel [0071] 207: catalyst particle [0072] 208: generated gas [0073] 209: generated gas outlet [0074] 210: heat-insulating mechanism [0075] 301: catalyst plate [0076] 302: plurality of high-speed high-temperature heated source gas beam [0077] 400-402: Steps in operation of gas generating apparatus