C08F222/103

COMBINATION OF CROSSLINKERS TO IMPROVE COATING PROPERTIES
20230012924 · 2023-01-19 ·

Multiphase polymers comprising crosslinking monomers and polyfunctional amine are disclosed. The multiphase polymer comprises a first phase polymer having a Tg from 60° C. to 240° C., a second phase polymer having a Tg from 40° C. to 240° C., and a soft phase polymer having a Tg from -25° C. to 30° C. The crosslinking monomers include a triacrylate such as trimethylol propane triacrylate, an unsaturated alkoxysilane, and an unsaturated keto monomer reactive with the polyfunctional amine. In contrast to conventional knowledge, incorporation of trimethylolpropane triacrylate reduces the minimum film forming temperature of multiphase polymers. This unusual reduction in MFFT helps to reduce the VOC requirement to form a good film at low VOC. The other crosslinking monomers including unsaturated alkoxy silane and unsaturated keto monomer which react with the polyfunctional amine improve print resistance, block resistance and lower the tackiness of paint films. The multiphase polymer is particularly suitable for use in deep base paints.

SURFACE PROTECTIVE FILM FOR OPTICAL MEMBER

The present invention provides a surface protective film which includes an adhesive layer on one surface of a substrate film, wherein the adhesive layer is a cured product of a composition containing: a urethane-based resin having a photoreactive group at the end or side chain thereof; a monofunctional (meth)acrylate monomer; a crosslinking agent having two or more photoreactive groups at the end thereof; a peel strength adjusting agent; and a photoinitiator, the composition being solvent-free; and the adhesive layer has peel strength of 0.5 gf/in to 10 gf/in, as measured on glass at a peel angle of 180° and a peel rate of 1.8 m/min.

SURFACE PROTECTIVE FILM FOR OPTICAL MEMBER

The present invention provides a surface protective film which includes an adhesive layer on one surface of a substrate film, wherein the adhesive layer is a cured product of a composition containing: a urethane-based resin having a photoreactive group at the end or side chain thereof; a monofunctional (meth)acrylate monomer; a crosslinking agent having two or more photoreactive groups at the end thereof; a peel strength adjusting agent; and a photoinitiator, the composition being solvent-free; and the adhesive layer has peel strength of 0.5 gf/in to 10 gf/in, as measured on glass at a peel angle of 180° and a peel rate of 1.8 m/min.

UV CURABLE COMPOSITIONS FOR DIRT PICK-UP RESISTANCE
20230220239 · 2023-07-13 ·

The present technology provides a UV curable coating composition, methods for forming a photocured coating on a substrate, and articles that include a substrate and a photocured coating. The UV curable coating composition includes an ethylenically unsaturated polymerizable compound, a functionalized siloxane compound, and optionally a micronized inorganic particle(s). The cured coating may provide improved dirt and/or brake dust pick-up resistance.

UV CURABLE COMPOSITIONS FOR DIRT PICK-UP RESISTANCE
20230220239 · 2023-07-13 ·

The present technology provides a UV curable coating composition, methods for forming a photocured coating on a substrate, and articles that include a substrate and a photocured coating. The UV curable coating composition includes an ethylenically unsaturated polymerizable compound, a functionalized siloxane compound, and optionally a micronized inorganic particle(s). The cured coating may provide improved dirt and/or brake dust pick-up resistance.

Optical film and image display device including same

The present invention relates to an optical film including a light-transmitting substrate film such as a polyester-based substrate film and an antiglare layer, and more specifically, to an optical film capable of effectively suppressing the occurrence of interference fringes derived from the substrate film, realizing excellent antiglare properties, and having excellent scratch resistance, and excellent adhesion between the substrate film and the antiglare layer, and the like, and to an image display device including the same.

Optical film and image display device including same

The present invention relates to an optical film including a light-transmitting substrate film such as a polyester-based substrate film and an antiglare layer, and more specifically, to an optical film capable of effectively suppressing the occurrence of interference fringes derived from the substrate film, realizing excellent antiglare properties, and having excellent scratch resistance, and excellent adhesion between the substrate film and the antiglare layer, and the like, and to an image display device including the same.

ACTIVE-ENERGY-RAY-CURABLE RESIN COMPOSITION AND CURED PRODUCT THEREOF
20230220142 · 2023-07-13 ·

The present invention aims to provide a curable resin composition that can retain low viscosity and exhibit properties appropriate for application, even when the curable resin composition contains a high viscosity component. The present invention relates to an active energy ray-curable resin composition containing: a crosslinkable compound (A); an oligomer (B) having a viscosity at 25° C. of 1000 mPa.Math.s or higher or a viscosity at 60° C. of 400 mPa.Math.s or higher; and a polymerization initiator (C), the crosslinkable compound (A) being represented by the following formula (1):

##STR00001##

wherein Z is an n-valent linking group, with n being an integer of 2 or greater.

ACTIVE-ENERGY-RAY-CURABLE RESIN COMPOSITION AND CURED PRODUCT THEREOF
20230220142 · 2023-07-13 ·

The present invention aims to provide a curable resin composition that can retain low viscosity and exhibit properties appropriate for application, even when the curable resin composition contains a high viscosity component. The present invention relates to an active energy ray-curable resin composition containing: a crosslinkable compound (A); an oligomer (B) having a viscosity at 25° C. of 1000 mPa.Math.s or higher or a viscosity at 60° C. of 400 mPa.Math.s or higher; and a polymerization initiator (C), the crosslinkable compound (A) being represented by the following formula (1):

##STR00001##

wherein Z is an n-valent linking group, with n being an integer of 2 or greater.

PRESSURE-SENSITIVE ADHESIVE SHEET, OPTICAL MEMBER, AND TOUCH PANEL

An object of the present invention is to provide a pressure-sensitive adhesive sheet enables a pressure-sensitive adhesive layer to be formed, wherein the pressure-sensitive adhesive layer has a low dielectric constant, is excellent in level difference conformability while maintaining adhesive strength and adhesion reliability at high temperatures, and suitable for laminating a metal mesh film and the like. The pressure-sensitive adhesive sheet of the present invention is a pressure-sensitive adhesive sheet having a pressure-sensitive adhesive layer, the pressure-sensitive adhesive layer containing an acrylic polymer (A) and a hydrogenated polyolefinic resin (B) that exhibits liquid flowability at 25° C. The pressure-sensitive adhesive layer has a dielectric constant at a frequency of 1 MHz of from 2.3 to 3.5. The pressure-sensitive adhesive sheet has a 180° peel adhesive strength to a glass plate at a tensile speed of 300 mm/minute at 65° C. of 6 N/20 mm or more. In the pressure-sensitive adhesive sheet, the proportion of the 180° peel adhesive strength to a glass plate at a tensile speed of 300 mm/minute at 65° C. to the 180° peel adhesive strength to a glass plate at a tensile speed of 300 mm/minute at 25° C. (180° peel adhesive strength to a glass plate at a tensile speed of 300 mm/minute at 65° C./180° peel adhesive strength to a glass plate at a tensile speed of 300 mm/minute at 25° C.×100) is 30 or more.