C08F222/16

ACRYLIC RUBBER AND CROSSLINKABLE COMPOSITION THEREOF
20220306786 · 2022-09-29 · ·

An acrylic rubber that is a copolymer in which 1 to 3 wt. % of a fumaric acid monoalkyl ester monomer containing an alkyl group having 1 to 8 carbon atoms is copolymerized as a crosslinkable comonomer, wherein 45 to 65 wt. % of n-butyl acrylate, 12 to 32 wt. % of 2-methoxyethyl acrylate, and 11 to 30 wt. % of ethoxyethoxyethyl acrylate are copolymerized in 100 wt. % of comonomers other than the crosslinkable comonomer. This acrylic rubber can suppress the reduction of oil resistance while improving cold resistance represented by a TR-10 value.

ACRYLIC RUBBER AND CROSSLINKABLE COMPOSITION THEREOF
20220306786 · 2022-09-29 · ·

An acrylic rubber that is a copolymer in which 1 to 3 wt. % of a fumaric acid monoalkyl ester monomer containing an alkyl group having 1 to 8 carbon atoms is copolymerized as a crosslinkable comonomer, wherein 45 to 65 wt. % of n-butyl acrylate, 12 to 32 wt. % of 2-methoxyethyl acrylate, and 11 to 30 wt. % of ethoxyethoxyethyl acrylate are copolymerized in 100 wt. % of comonomers other than the crosslinkable comonomer. This acrylic rubber can suppress the reduction of oil resistance while improving cold resistance represented by a TR-10 value.

POLYMERISABLE LC MEDIUM AND POLYMER FILM WITH NEGATIVE OPTICAL DISPERSION

The invention relates to a polymerisable LC medium with negative optical dispersion, a polymer film with negative optical dispersion obtainable from such a medium, and the use of the polymerisable LC medium and polymer film in optical, electro optical, electronic, semiconducting or luminescent components or devices.

ACRYLIC RUBBER BALE EXCELLENT IN STORAGE STABILITY AND PROCESSABILITY
20220267491 · 2022-08-25 · ·

An acrylic rubber bale excellent in storage stability and processability, a method for producing the same, a rubber mixture obtained by mixing the acrylic rubber bale, and a rubber cross-linked product of the rubber mixture are provided. The acrylic rubber bale according to the present invention includes an acrylic rubber having a reactive group and a weight average molecular weight (Mw) of 100,000 to 5,000,000, wherein an amount of gel insoluble in methyl ethyl ketone is 50% by weight or less, and pH is 6 or less.

ACRYLIC RUBBER BALE EXCELLENT IN STORAGE STABILITY AND PROCESSABILITY
20220267491 · 2022-08-25 · ·

An acrylic rubber bale excellent in storage stability and processability, a method for producing the same, a rubber mixture obtained by mixing the acrylic rubber bale, and a rubber cross-linked product of the rubber mixture are provided. The acrylic rubber bale according to the present invention includes an acrylic rubber having a reactive group and a weight average molecular weight (Mw) of 100,000 to 5,000,000, wherein an amount of gel insoluble in methyl ethyl ketone is 50% by weight or less, and pH is 6 or less.

HIGHLY SATURATED NITRILE RUBBER COMPOSITION AND CROSS-LINKED RUBBER
20170253684 · 2017-09-07 · ·

A highly saturated nitrile rubber composition obtained by mixing 7 to 40 wt % of a carboxyl group-containing highly saturated nitrile rubber (A1) containing 15 to 60 wt % of α,β-ethylenically unsaturated nitrile monomer units and 1 to 60 wt % of α,β-ethylenically unsaturated dicarboxylic acid monoester monomer units and having an iodine value of 120 or less, 10 to 78 wt % of a highly saturated nitrile rubber (A2) containing α,β-ethylenically unsaturated nitrile monomer units in 15 to 60 wt %, having a content of α,β-ethylenically unsaturated dicarboxylic acid monoester monomer units of 0.9 wt % or less, and having an iodine value of 120 or less, and 15 to 50 wt % of a polyester resin (B) at a temperature of a melting point of the polyester resin (B) or more is provided.

HIGHLY SATURATED NITRILE RUBBER COMPOSITION AND CROSS-LINKED RUBBER
20170253684 · 2017-09-07 · ·

A highly saturated nitrile rubber composition obtained by mixing 7 to 40 wt % of a carboxyl group-containing highly saturated nitrile rubber (A1) containing 15 to 60 wt % of α,β-ethylenically unsaturated nitrile monomer units and 1 to 60 wt % of α,β-ethylenically unsaturated dicarboxylic acid monoester monomer units and having an iodine value of 120 or less, 10 to 78 wt % of a highly saturated nitrile rubber (A2) containing α,β-ethylenically unsaturated nitrile monomer units in 15 to 60 wt %, having a content of α,β-ethylenically unsaturated dicarboxylic acid monoester monomer units of 0.9 wt % or less, and having an iodine value of 120 or less, and 15 to 50 wt % of a polyester resin (B) at a temperature of a melting point of the polyester resin (B) or more is provided.

ACRYLIC RUBBER SHEET EXCELLENT IN STORAGE STABILITY AND PROCESSABILITY
20220235190 · 2022-07-28 · ·

An acrylic rubber sheet excellent in storage stability and processability, a method for producing the same, an acrylic rubber bale obtained by laminating the sheets, a mixture obtained by mixing the acrylic rubber sheet and the acrylic rubber bale, a method for producing the mixture and a rubber cross-linking product obtained by cross-linking the mixture. The acrylic rubber sheet comprises, an acrylic rubber mainly composed of a (meth) acrylic acid ester and having a weight average molecular weight (Mw) of 100,000 to 5,000,000 and a ratio (Mz/Mw) of a Z-average molecular weight (Mz) and a weight average molecular weight (Mw) is 1.3 or more, and the acrylic rubber sheet contains a phenolic anti-aging agent, and a gel amount is 50 wt % or less. The acrylic rubber sheet is extremely excellent in storage stability and processability and the sheet can be easily produced by the claimed method.

ACRYLIC RUBBER SHEET EXCELLENT IN STORAGE STABILITY AND PROCESSABILITY
20220235190 · 2022-07-28 · ·

An acrylic rubber sheet excellent in storage stability and processability, a method for producing the same, an acrylic rubber bale obtained by laminating the sheets, a mixture obtained by mixing the acrylic rubber sheet and the acrylic rubber bale, a method for producing the mixture and a rubber cross-linking product obtained by cross-linking the mixture. The acrylic rubber sheet comprises, an acrylic rubber mainly composed of a (meth) acrylic acid ester and having a weight average molecular weight (Mw) of 100,000 to 5,000,000 and a ratio (Mz/Mw) of a Z-average molecular weight (Mz) and a weight average molecular weight (Mw) is 1.3 or more, and the acrylic rubber sheet contains a phenolic anti-aging agent, and a gel amount is 50 wt % or less. The acrylic rubber sheet is extremely excellent in storage stability and processability and the sheet can be easily produced by the claimed method.

VINYLIDENE FLUORIDE-BASED POLYMER COMPOSITION OBTAINED USING NON-FLUORINATED SURFACTANT AND PRODUCTION METHOD THEREFOR

The vinylidene-fluoride-based polymer composition according to the present invention comprises a vinylidene-fluoride-based polymer and a specific surfactant and contains no fluorinated surfactant, wherein the specific surfactant is contained in an amount of 10 ppm or larger but less than 100 ppm in terms of mass ppm of the solid components of the composition and has an HLB value of 10 or greater. The method for producing a vinylidene-fluoride-based polymer according to the present invention comprises emulsion-polymerizing specific monomers in an aqueous medium in the presence of a specific emulsifier and an initiator without using any fluorinated surfactant, the use amount of the emulsifier being 8.5 ppm or larger but less than 100 ppm in terms of mass ppm of the monomers.