C08K5/098

Composition, thermoplastic resin composition using same, and molded article of same

Provided are: a composition that can impart a thermoplastic resin with excellent transparency and physical properties; a thermoplastic resin composition containing the same; and a molded article thereof. The composition contains: (A) a cyclic organophosphate aluminum salt represented by Formula (1) below, wherein R.sup.1 to R.sup.4 each independently represent a hydrogen atom or a linear or branched alkyl group having 1 to 9 carbon atoms and R.sup.5 represents an alkylidene group having 1 to 4 carbon atoms; (B) a sodium carboxylate; and (C) a fatty acid metal salt represented by Formula (2) below, wherein R.sup.6 represents a group which is introduced to an aliphatic organic acid having 10 to 30 carbon atoms and M.sup.1 represents lithium or potassium, wherein the following ranges are satisfied in terms of molar ratio:(C)/(B)=0.30 to 5.00, and (A)/{(B)+(C)}=0.15 to 0.70. ##STR00001##

Composition, thermoplastic resin composition using same, and molded article of same

Provided are: a composition that can impart a thermoplastic resin with excellent transparency and physical properties; a thermoplastic resin composition containing the same; and a molded article thereof. The composition contains: (A) a cyclic organophosphate aluminum salt represented by Formula (1) below, wherein R.sup.1 to R.sup.4 each independently represent a hydrogen atom or a linear or branched alkyl group having 1 to 9 carbon atoms and R.sup.5 represents an alkylidene group having 1 to 4 carbon atoms; (B) a sodium carboxylate; and (C) a fatty acid metal salt represented by Formula (2) below, wherein R.sup.6 represents a group which is introduced to an aliphatic organic acid having 10 to 30 carbon atoms and M.sup.1 represents lithium or potassium, wherein the following ranges are satisfied in terms of molar ratio:(C)/(B)=0.30 to 5.00, and (A)/{(B)+(C)}=0.15 to 0.70. ##STR00001##

Composition, thermoplastic resin composition using same, and molded article of same

Provided are: a composition that can impart a thermoplastic resin with excellent transparency and physical properties; a thermoplastic resin composition containing the same; and a molded article thereof. The composition contains: (A) a cyclic organophosphate aluminum salt represented by Formula (1) below, wherein R.sup.1 to R.sup.4 each independently represent a hydrogen atom or a linear or branched alkyl group having 1 to 9 carbon atoms and R.sup.5 represents an alkylidene group having 1 to 4 carbon atoms; (B) a sodium carboxylate; and (C) a fatty acid metal salt represented by Formula (2) below, wherein R.sup.6 represents a group which is introduced to an aliphatic organic acid having 10 to 30 carbon atoms and M.sup.1 represents lithium or potassium, wherein the following ranges are satisfied in terms of molar ratio:(C)/(B)=0.30 to 5.00, and (A)/{(B)+(C)}=0.15 to 0.70. ##STR00001##

Room temperature moisture-curable silicone gel composition, and cured product and article therefrom

Provided is a room temperature moisture-curable silicone gel composition containing: (A) diorganopolysiloxane, both terminals of which are blocked by silanol groups; (B) hydrolysable organosilicon compound represented by Formula (2) and/or a partial hydrolysate thereof ##STR00001##
(where R.sup.2 is a monovalent hydrocarbon group, R.sup.3 is an alkyl group or a cycloalkyl group, and a is 2 or 3.); (C) a curing catalyst; and (D) a heat-resistant aid containing a homogeneous mixture of (D-a), (D-b), and (D-c) (where (D-a) is organopolysiloxane having a viscosity of 10-10,000 mPa.Math.s at 25° C., (D-b) is carboxylate of cerium, and (D-c) is a titanium compound and/or a partial hydrolytic condensate thereof). This room temperature moisture-curable silicone gel composition can be a silicone gel cured product which has a small variation rate of low-stress properties evaluated by the index such as penetration even under heat-resistant conditions exceeding 230° C. and which has excellent heat-resistance.

Room temperature moisture-curable silicone gel composition, and cured product and article therefrom

Provided is a room temperature moisture-curable silicone gel composition containing: (A) diorganopolysiloxane, both terminals of which are blocked by silanol groups; (B) hydrolysable organosilicon compound represented by Formula (2) and/or a partial hydrolysate thereof ##STR00001##
(where R.sup.2 is a monovalent hydrocarbon group, R.sup.3 is an alkyl group or a cycloalkyl group, and a is 2 or 3.); (C) a curing catalyst; and (D) a heat-resistant aid containing a homogeneous mixture of (D-a), (D-b), and (D-c) (where (D-a) is organopolysiloxane having a viscosity of 10-10,000 mPa.Math.s at 25° C., (D-b) is carboxylate of cerium, and (D-c) is a titanium compound and/or a partial hydrolytic condensate thereof). This room temperature moisture-curable silicone gel composition can be a silicone gel cured product which has a small variation rate of low-stress properties evaluated by the index such as penetration even under heat-resistant conditions exceeding 230° C. and which has excellent heat-resistance.

Polyester resin composition, molded article, and composite molded article

A composite molded article obtained by laser welding molded article composed of a polyester resin composition having a crystallinity of 15% or more as calculated with fast scanning calorimetry by a calculation method, wherein the calculation method includes using fast scanning calorimetry, the polyester resin composition is heated from 30° C. to 260° C. at 10000° C./second, then maintained at 260° C. for 0.1 second, then cooled to 80° C. at 5000° C./second, maintained at 80° C. for 0.1 second, then cooled to −70° C. at 5000° C./second, and then heated to 260° C. at 1000° C./second, after which the curve obtained is used to calculate the crystallinity.

Polyester resin composition, molded article, and composite molded article

A composite molded article obtained by laser welding molded article composed of a polyester resin composition having a crystallinity of 15% or more as calculated with fast scanning calorimetry by a calculation method, wherein the calculation method includes using fast scanning calorimetry, the polyester resin composition is heated from 30° C. to 260° C. at 10000° C./second, then maintained at 260° C. for 0.1 second, then cooled to 80° C. at 5000° C./second, maintained at 80° C. for 0.1 second, then cooled to −70° C. at 5000° C./second, and then heated to 260° C. at 1000° C./second, after which the curve obtained is used to calculate the crystallinity.

Polyester resin composition, molded article, and composite molded article

A composite molded article obtained by laser welding molded article composed of a polyester resin composition having a crystallinity of 15% or more as calculated with fast scanning calorimetry by a calculation method, wherein the calculation method includes using fast scanning calorimetry, the polyester resin composition is heated from 30° C. to 260° C. at 10000° C./second, then maintained at 260° C. for 0.1 second, then cooled to 80° C. at 5000° C./second, maintained at 80° C. for 0.1 second, then cooled to −70° C. at 5000° C./second, and then heated to 260° C. at 1000° C./second, after which the curve obtained is used to calculate the crystallinity.

A STABLE PVC COMPOSITION COMPRISING AN ENVIRONMENT-FRIENDLY PLASTICIZER

The present invention refers to a polyvinyl chloride composition with high stability, said composition comprising: a) 100 phr (parts per hundred resin) of a polyvinyl chloride resin, b) 10-150 phr of pentaerythritol tetravalerate as plasticizer, said pentaerythritol tetravalerate having an acid value of less than 0.05 mg KOH/g and being obtained through esterification of valeric acid and high purity pentaerythritol having a purity of at least 98%, an ash content of less than 200 ppm and a dipentaerythritol content of 0.1-2 wt%, c) 0.3-14 phr of at least one stabilizer, and optionally d) at least one additive, wherein and the amount of free acid in the polyvinyl chloride composition is less than 30 ppm, preferably less than 20 ppm. The invention further refers to a polyvinyl chloride article comprising said composition and having an amount of free acid less than 30 ppm, preferably less than 20 ppm. The present invention also refers to a method for analyzing the amount of free acid in a polyvinyl chloride sample.

A STABLE PVC COMPOSITION COMPRISING AN ENVIRONMENT-FRIENDLY PLASTICIZER

The present invention refers to a polyvinyl chloride composition with high stability, said composition comprising: a) 100 phr (parts per hundred resin) of a polyvinyl chloride resin, b) 10-150 phr of pentaerythritol tetravalerate as plasticizer, said pentaerythritol tetravalerate having an acid value of less than 0.05 mg KOH/g and being obtained through esterification of valeric acid and high purity pentaerythritol having a purity of at least 98%, an ash content of less than 200 ppm and a dipentaerythritol content of 0.1-2 wt%, c) 0.3-14 phr of at least one stabilizer, and optionally d) at least one additive, wherein and the amount of free acid in the polyvinyl chloride composition is less than 30 ppm, preferably less than 20 ppm. The invention further refers to a polyvinyl chloride article comprising said composition and having an amount of free acid less than 30 ppm, preferably less than 20 ppm. The present invention also refers to a method for analyzing the amount of free acid in a polyvinyl chloride sample.