The invention relates to a lubricant composition and to the use of same for minimum quantity lubrication in the field of metalworking. The composition comprises 0.05 to 5 wt.% of emulsifier in relation to the total weight of the composition, and an amount of an aliphatic C.sub.16-24 alcohol that makes the composition up to 100%. The emulsifier is selected from fatty alcohol polyalkylene glycol ethers or glycolic acid alkoxylate alkyl ethers or mixtures thereof.

In some embodiments, a compound has the formula (I) where: R.sub.1 and R.sub.2 are alkyl or, together with the carbon atom to which they are attached, cycloalkyl; R.sub.3, R.sub.4 and R.sub.5 are H or alkyl (formula II); R.sub.6 is alkyl or where: R.sub.7 and R.sub.8 are H, alkyl or, together with the carbon atom to which they are attached, cycloalkyl; R.sub.9 is H or alkyl; X is alkylene or is absent; and p is 0, 1, 2 or 3; and m and n are 0, 1, 2 or 3 provided that m is 0 when R.sub.4 and R.sub.5 are H. The compound is suitable for use as a base stock which provides low volatility for a given viscosity profile. The compound may be used in a lubricant composition for an internal combustion engine.

##STR00001##

This disclosure provides a process for producing vinylidene dimer derivatives by subjecting one or more vinylidene dimers and one or more carbonyl-containing compounds to a carbonyl-ene reaction, optionally in the presence of a catalyst, to produce one or more vinylidene dimer derived alcohols. This disclosure also provides a process for producing vinylidene dimer derivatives by reacting one or more vinylidene dimers with one or more carbonyl-containing compounds, optionally in the presence of a catalyst, to produce one or more vinylidene dimer derived alcohols. This disclosure further provides vinylidene dimer derivatives (e.g., vinylidene dimer derived alcohols and esters) produced by these processes. This disclosure still further provides for hydrogenating/reacting the vinylidene dimer derived alcohols with acids or anhydrides to produce vinylidene dimer derived esters. This disclosure yet further relates to lubricating ester oil base stocks, and lubricating oils containing the lubricating ester oil base stocks.

This disclosure provides a process for producing vinylidene dimer derivatives by subjecting one or more vinylidene dimers and one or more carbonyl-containing compounds to a carbonyl-ene reaction, optionally in the presence of a catalyst, to produce one or more vinylidene dimer derived alcohols. This disclosure also provides a process for producing vinylidene dimer derivatives by reacting one or more vinylidene dimers with one or more carbonyl-containing compounds, optionally in the presence of a catalyst, to produce one or more vinylidene dimer derived alcohols. This disclosure further provides vinylidene dimer derivatives (e.g., vinylidene dimer derived alcohols and esters) produced by these processes. This disclosure still further provides for hydrogenating/reacting the vinylidene dimer derived alcohols with acids or anhydrides to produce vinylidene dimer derived esters. This disclosure yet further relates to lubricating ester oil base stocks, and lubricating oils containing the lubricating ester oil base stocks.

Brine-tolerant lubricants are provided. The brine-tolerant lubricants may comprise an oil component, a surfactant component, and, optionally, an additive component. In one aspect, the oil component comprises a fatty acid alkyl ester. In one aspect, the surfactant component comprises at least one of an alkoxylated fatty acid and an alkoxylated fatty alcohol. Also provided are methods for increasing the lubricity of a drilling fluid by contacting the drilling fluid with the brine-tolerant lubricants.

An organogel including a base fluid, cetyl alcohol, and a gelling agent provided in an amount to cause the fluid to change from a liquid state to a gelled state at temperatures below at least 25 C. A nanofluid including an organogel and a nanoparticle component which permits the nanofluid to change from a liquid state to a gelled state at temperatures below at least 25 C., the gelled state helping to maintain the nanoparticle component suspended throughout the base fluid; and a method for preparing a gelled nanofluid.

An all-natural multi-purpose cleaner, lubricant, and protectant composition includes 85-90 percent by weight Ethanol; 5-10 percent by weight D-Limonene: 1-5 percent by weight Lard; and less than 1 percent by weight Beeswax.

A de-icing lubricant composition is provided, including isopropyl alcohol; and mineral oil. The isopropyl alcohol may be 60-90% of the composition by weight. The mineral oil may be 10-30% of the composition by weight. The composition may include a dye and/or a propellant. The propellant may be CO2. A method of restoring mobility to frozen components is also provided by applying a composition as described above to a frozen component.

Refrigeration lubricants with at least one thiophosphorus additive for use in hydrofluorocarbon refrigeration systems. The thiophosphorus additives may improve the stability and metals and/or refrigerant compatibility of the refrigeration lubricant.

The invention relates to industrial gear oil compositions that have been specially designed to have improved storage stability and/or paint compatibility and/or seal compatibility. This improvement is achieved while maintaining good performance in other areas. These improvements are particularly relevant to synthetic lubricants, such as those made with polyalphaolefin (PAO) base oils. This balance of properties has been difficult to achieve in synthetic compositions where problems in the areas of storage stability, paint compatibility and/or seal compatibility of become more pronounced. The invention also relates to processes of making such compositions and methods of using the same.