The invention refers to lubricant compositions comprising a specific diester together with a viscosity index improver.

Provided herein are grease compositions comprising at least one estolide compound of formula: ##STR00001##
in which n is an integer equal to or greater than 0; m is an integer equal to or greater than 2; R.sub.1, independently for each occurrence, is selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; R.sub.2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R.sub.3 and R.sub.4, independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched. Also provided are methods of making estolide-based grease products.

Provided herein are grease compositions comprising at least one estolide compound of formula: ##STR00001##
in which n is an integer equal to or greater than 0; m is an integer equal to or greater than 2; R.sub.1, independently for each occurrence, is selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; R.sub.2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R.sub.3 and R.sub.4, independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched. Also provided are methods of making estolide-based grease products.

Ester polyol esters are a unique class of lubricants that have adjustable molecular weights, viscosities, and pour points based on the character of their reaction materials and relative ratios. There is provided a method for preparing at least one ester polyol ester, the method comprising esterifying an ester polyol reaction mixture to produce ester polyol, the reaction mixture comprising an ozone acid mixture and at least one primary polyol, wherein the ozone acid mixture comprises at least one dicarboxylic acid and at least one monocarboxylic acid; and capping the ester polyol with at least one capping carboxylic acid to produce ester polyol ester.

Provided herein are estolide compositions having high oxidative stability, said compositions comprising at least one compound of formula: ##STR00001##
in which n is an integer equal to or greater than 0; m is an integer equal to or greater than 1; R.sub.1, independently for each occurrence, is selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; R.sub.2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R.sub.3 and R.sub.4, independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched. Also provided herein are uses for the compositions and methods of preparing the same.

The invention relates to a method for the preparation of estolide esters from a hydroxycarboxylic acid by a reaction of addition of a fatty acid to the hydroxyl function and by a reaction of esterification of the carboxylic acid function with an alcohol. The invention further relates to the use of estolide esters as a base oil in a lubricating composition or as an emollient in a cosmetic or pharmaceutical composition.

The invention relates to a composition preparation method for preparing a composition of estolides, the method comprising reacting an unsaturated compound of a type such as an acid or ester, with a saturated fatty acid; in the presence of a catalyst of a type such as sulphonic acid, the said method including no vacuum distillation step thereby making it possible to separate the monoestolides from the polyestolides. The invention also relates to a composition of estolides that is obtainable by the method according to the invention and the use thereof in lubricating compositions.

Provided are microalgal compositions and methods for their use. The microalgal compositions include lubricants that find use in industrial and other applications.

The present invention addresses the problem of providing a lubricating oil composition having excellent heat resistance (suppression of discoloration in heating) and tackiness while maintaining excellent viscosity properties of a lubricating oil composition using a ricinolic acid polymer. The present invention provides a copolymer (B) containing structural units (a) derived from ricinolic acid, structural units (b) derived from an aliphatic dicarboxylic acid and structural units (c) derived from a diol having 2 to 10 carbon atoms in a specific ratio and having a specific intrinsic viscosity, and provides a lubricating oil composition containing a base oil and the copolymer (B) and having a mass ratio (mass of (A) /mass of (B)) of the base oil (A) to the copolymer (B) of 60/40 to 99.5/0.5.

Provided herein are estolide base oils and oligomeric compounds prepared from processes that include cross metathesis. Exemplary processes include the preparation of terminally-unsaturated fatty acids by cross metathesis, and the subsequent oligomerization of terminally-unsaturated fatty acids to provide estolide compounds, such as the process set forth below: ##STR00001##