The present invention provides methods for removing arsenic from an aqueous solution containing dissolved arsenic using a continuous-flow air-cathode iron electrocoagulation device and current densities of from at least 30 mA.Math.cm.sup.2 to about 250 mA.Math.cm.sup.2. The present invention also provides continuous-flow air-cathode iron electrocoagulation devices having barriers for reducing electrode fouling and maintaining faradaic efficiency for longer periods of time.

Aspects of the invention include a porous and water-permeable electrode for electrocatalysis comprising: a porous and water-permeable reactive electrochemical membrane (REM) comprising: a porous and water-permeable support membrane; wherein the support membrane comprises a titanium metal; and an electrocatalytic coating on at least a portion of the metal support membrane, the electrocatalytic coating being a tin oxide bilayer comprising: a first layer adjacent to and directly contacting the metal support membrane; wherein the first layer comprises tin oxide doped with antimony; and a second layer adjacent to and directly contacting the first layer; wherein the second layer forms a surface of the REM such that the second layer is in direct contact with an aqueous solution when the REM is in contact with the aqueous solution; wherein the second layer comprises tin oxide doped with antimony and nickel or cerium. Preferably, the support membrane is formed of a titanium metal.

The present invention discloses a filter material for a culture system, and a preparation method and use thereof. The filter material comprises an anode material and a cathode material, wherein the anode material is an active metal, and the cathode material is an inactive metal or a conductive non-metal. The filter material can significantly improve the water quality in the culture system, be used for in-situ treatment of the water body in the culture system and be convenient to use. The filter material does not require additional application of voltage or current, and thus is safer. At the same time, the filter material has a long service life and does not need to be changed frequently. In addition, the preparation method of the filter material is simple, efficient, and environmentally friendly, and is advantageous for large-scale production.

Various aspects described herein relate to electrochemical devices, e.g., for separation of one or more target organic or inorganic molecules (e.g., charged or neutral molecules) from solution, and methods of using the same. In particular embodiments, the electrochemical devices and methods described herein involve at least one redox-functionalized electrode, wherein the electrode comprises an immobilized redox-species that is selective toward a target molecule (e.g., charged molecule such as ion or netural molecule). The selectivity is based on a Faradaic/redox-activated chemical interaction (e.g., directional hydrogen binding) between the oxidized state of the redox species and a moiety of the target molecule (e.g., charged molecule such as ion or netural molecule).

Devices, apparatus, and methods to treat Per- and polyfluoroalkyl substances (PFAS) and related telomeres including perfluorooctanoic acid (PFOA) and Perfluorooctanesulfonic (PFOS), and other recalcitrant highly stable organic compounds, substances, organic matter, infectious fluids, bacteria, viruses and other pathogens, endocrine disruptors, pharmaceutical, and otherwise oxidizable material contaminants in water, aqueous fluids, condensates, concentrates, brines, and spent solid adsorbent media. The system can include hydrodynamic cavitation; acoustic sonication; electrochemical oxidation; in-line static mixing; and supplemental reagent precursors to create powerful oxidizing conditions within the equipment, and oxidants by the system that destroy said contaminants.

Methods and apparatus for controlling electrolysis in an electrolytic cell in order to maintain constant concentration of the disinfectant irrespective of the rate of electrolyte concentration or oxidant production in the electrolytic cell.

An apparatus includes a conduit including an inlet to receive a liquid and an outlet to discharge the liquid. A first porous electrode, a second porous electrode, and a third porous electrode are disposed in the conduit between the inlet and the outlet. A first porous separator is interposed between the first porous electrode and the second porous electrode. A second porous separator is interposed between the second porous electrode and the third porous electrode. A power source configured to provide power to the first porous electrode, the second porous electrode, and the third porous electrode. While the liquid is flowing through the conduit, the power source supplies a first type of voltage to the first porous electrode and the third porous electrode, and supplies a second type of voltage to the second porous electrode, the second type being opposite to the first type.

A water treatment device includes, between at least two flat sheet-shaped grounded electrodes vertically disposed so as to be parallel to each other, a sheet-shaped high-voltage electrode having two edges opposing the respective grounded electrodes. The sheet-shaped high-voltage electrode is supported by a plurality of support members, and thus deformation of the high-voltage electrode in an up/down direction and a horizontal direction is suppressed, and the distance between each edge of the high-voltage electrode and the corresponding grounded electrode, i.e., an electric discharge gap length, can be kept even. Accordingly, uniform electric discharge can be maintained between the high-voltage electrode and the grounded electrode, whereby highly efficient water treatment can be realized.

An electrolytic ozone generator includes an anode with a longitudinal edge, a cathode with a longitudinal edge spaced apart from the cathode, and an isolator. The isolator electrically separates the cathode from the anode and is semi-impermeable. The anode and cathode are impermeable for generating ozone in a flow area fluidly coupling longitudinal edges of the anode and the cathode. Ozone water apparatus, methods of making electrolytic ozone generators, and methods of generating ozone using electrolytic ozone generators are also described.

Disclosed is an electrode assembly and a method for inactivating organic material in water, and a water treatment system that includes the electrode assembly. The electrode assembly includes a longitudinal axis and at least an anode and a cathode, each having a first electrode member that includes a perforated portion for water to pass through and a second electrode member arranged at an angle with respect to the first electrode member, and also having a perforated portion for water to pass through. The first and second electrode members of the anode correspond to and are arranged in close proximity to the first and second electrode members of the cathode. The first and second electrode members are inclined with respect to the assembly's axis.