The present disclosure relates to a Michael Addition curable composition, coating composition containing the same and coated article made therefrom. In particular, the Michael Addition curable composition, comprises A) at least one reactive donor capable of providing two or more nucleophilic carbanions; B) at least one reactive acceptor comprising two or more carbon-carbon double bonds; C) at least one catalyst for catalyzing the Michael Addition crosslinking reaction between the reactive donor and the reactive acceptor; and D) at least one hardness improver, wherein the at least one reactive donor has a backbone based on an epoxy resin; and wherein the at least one hardness modifier is one or more selected from silica and urea formaldehyde resin, and the at least one hardness modifier has a particle size in micrometers and the at least one hardness modifier has a pH value of 6.5 or higher.

Provided is a surface-treated metallic material with easy control of glossiness and a manufacturing method therefor, the surface-treated metallic material comprising: a metallic material; and a coating layer which is formed on at least one side of the metallic material and on which an ultraviolet curable coating composition is cured, wherein the coating layer consists of a plurality of protrusions, which have a volume of 3 to 16 pico liters and are arranged at a density of 5 to 610 per 1 mm.sup.2 of the metallic material. As such, the surface-treated steel sheet is excellent in adhesion, scratch resistance and corrosion resistance, and has easy control of glossiness.

Provided is a surface-treated metallic material with easy control of glossiness and a manufacturing method therefor, the surface-treated metallic material comprising: a metallic material; and a coating layer which is formed on at least one side of the metallic material and on which an ultraviolet curable coating composition is cured, wherein the coating layer consists of a plurality of protrusions, which have a volume of 3 to 16 pico liters and are arranged at a density of 5 to 610 per 1 mm.sup.2 of the metallic material. As such, the surface-treated steel sheet is excellent in adhesion, scratch resistance and corrosion resistance, and has easy control of glossiness.

A curable resin composition that is capable of forming a cured product having impact resistance and a high elastic modulus, and has a low viscosity, thereby being suitable for three-dimensional shaping. The curable resin composition contains: (A) an α-(unsaturated alkoxyalkyl)acrylic acid or an ester thereof; (B) a bifunctional radically polymerizable oligomer; optionally (C) a radically polymerizable compound other than the component (A) and the component (B); (D) rubber particles; and (E) a radical polymerization initiator, wherein the component (A) is represented by the following formula (1).

##STR00001##

A curable resin composition that is capable of forming a cured product having impact resistance and a high elastic modulus, and has a low viscosity, thereby being suitable for three-dimensional shaping. The curable resin composition contains: (A) an α-(unsaturated alkoxyalkyl)acrylic acid or an ester thereof; (B) a bifunctional radically polymerizable oligomer; optionally (C) a radically polymerizable compound other than the component (A) and the component (B); (D) rubber particles; and (E) a radical polymerization initiator, wherein the component (A) is represented by the following formula (1).

##STR00001##

A hard coating film comprising a cured (meth)acrylate-based resin having a water contact angle of 40° or less and a pencil hardness of 6H or greater at a 1 kilogram load, a hard coating composition used for the formation of the hard coating film, a method of forming the hard coating film, a laminate including the hard coating film, and an article including the laminate.

A hard coating film comprising a cured (meth)acrylate-based resin having a water contact angle of 40° or less and a pencil hardness of 6H or greater at a 1 kilogram load, a hard coating composition used for the formation of the hard coating film, a method of forming the hard coating film, a laminate including the hard coating film, and an article including the laminate.

To provide a low-viscosity curable resin composition capable of obtaining a cured product excellent in impact resistance. The curable resin composition contains core-shell type rubber particles, a radically polymerizable compound having one or more radically polymerizable functional groups in the molecule, and a radical polymerization initiator, and the core-shell type rubber particles have a core layer and a shell layer containing a polymer having an alicyclic hydrocarbon group in a side chain, and the radically polymerizable compound contains a radically polymerizable compound having a molecular weight of 500 or more in a ratio of 2 mass % to 70 mass %.

An active energy curable white ink composition contains a nitrogen atom-containing monofunctional monomer (A), a nitrogen atom-free monofunctional monomer (B) having a glass transition temperature of 15 degrees or higher, a polyfunctional monomer (C), a polymerizable oligomer (D), an acylphosphine oxide-based polymerization initiator (E), and a white pigment (F), wherein the proportion of (D) in the active energy curable white ink composition is 0.2% by mass or less, the proportion of (E) in the active energy curable white ink composition is from 6% to 10% by mass, and the proportion of (F) in the active energy curable white ink composition is from 12% to 17% by mass.

An active energy curable white ink composition contains a nitrogen atom-containing monofunctional monomer (A), a nitrogen atom-free monofunctional monomer (B) having a glass transition temperature of 15 degrees or higher, a polyfunctional monomer (C), a polymerizable oligomer (D), an acylphosphine oxide-based polymerization initiator (E), and a white pigment (F), wherein the proportion of (D) in the active energy curable white ink composition is 0.2% by mass or less, the proportion of (E) in the active energy curable white ink composition is from 6% to 10% by mass, and the proportion of (F) in the active energy curable white ink composition is from 12% to 17% by mass.