A composition for model materials (4a) is used for shaping an optically shaped article by an inkjet optical shaping method, comprises a monofunctional monomer (A) and an oligomer (B) as a photocurable component, further, comprises no polyfunctional monomer (C) as a photocurable component, or comprises a polyfunctional monomer (C) as a photocurable component at 3.0 parts by weight based on 100 parts by weight of a whole composition for model materials, the oligomer (B) has a hydroxyl group or an amino group, and a total molar fraction of the hydroxyl group and the amino group in a total amount of the photocurable components is less than 5.0%. The composition for model materials (4a) can afford an optically shaped article that has flexibility, and does not crack even when it is bent.

A composition for model materials (4a) is used for shaping an optically shaped article by an inkjet optical shaping method, comprises a monofunctional monomer (A) and an oligomer (B) as a photocurable component, further, comprises no polyfunctional monomer (C) as a photocurable component, or comprises a polyfunctional monomer (C) as a photocurable component at 3.0 parts by weight based on 100 parts by weight of a whole composition for model materials, the oligomer (B) has a hydroxyl group or an amino group, and a total molar fraction of the hydroxyl group and the amino group in a total amount of the photocurable components is less than 5.0%. The composition for model materials (4a) can afford an optically shaped article that has flexibility, and does not crack even when it is bent.

Resins and formulations of individual monomers bearing both vinyl ester and epoxy functionality were either synthesized or formulated such that vinyl ester components capable of polymerizing by photo-induced, free radical polymerization were mixed with step-growth epoxy-amine systems, facilitating sequential cure. The vinyl ester component was photopolymerized using vat photopolymerization (VPP). Additionally, the preparation of bio-based photo curable thermosetting resins that have tailorable thermal and mechanical properties is provided. All monomers and polymers described herein are useful in a variety of applications, including additive manufacturing applications.

Resins and formulations of individual monomers bearing both vinyl ester and epoxy functionality were either synthesized or formulated such that vinyl ester components capable of polymerizing by photo-induced, free radical polymerization were mixed with step-growth epoxy-amine systems, facilitating sequential cure. The vinyl ester component was photopolymerized using vat photopolymerization (VPP). Additionally, the preparation of bio-based photo curable thermosetting resins that have tailorable thermal and mechanical properties is provided. All monomers and polymers described herein are useful in a variety of applications, including additive manufacturing applications.

The invention relates to on-demand debondable pressure sensitive adhesive and laminating adhesive compositions and uses thereof. The debondable pressure sensitive adhesives and laminating adhesives are applied onto a substrate to form a bond, and upon exposure to electron beam or UV light energy source, the adhesive can dissociate from the substrate. The debondable pressure sensitive adhesives and laminating adhesives are particularly suitable for recycling in a circular economy.

Provided are an anti-reflective film including a low-refractive layer having mechanical properties such as high abrasion resistance and scratch resistance, etc., and excellent optical properties, and a hard coating layer, a polarizing plate including the same, and a display device including the same.

Provided are an anti-reflective film including a low-refractive layer having mechanical properties such as high abrasion resistance and scratch resistance, etc., and excellent optical properties, and a hard coating layer, a polarizing plate including the same, and a display device including the same.

The present invention provides a method for crosslinking an acrylic emulsion with a (meth)acrylate monomer or a (meth)acrylate oligomer including adding a base acrylic emulsion to a vessel, adding at least one (meth)acrylate crosslinker to the vessel, incorporating the at least one (meth)acrylate crosslinker into the base acrylic emulsion to create a two-phase system including water and a phase including crosslinkers of the at least one (meth)acrylate crosslinker inside acrylic emulsion particles of the base acrylic emulsion, applying the two-phase system to a surface, and curing the two-phase system to create a final system including a continuous film and crosslinked crosslinkers.

The present invention provides a method for crosslinking an acrylic emulsion with a (meth)acrylate monomer or a (meth)acrylate oligomer including adding a base acrylic emulsion to a vessel, adding at least one (meth)acrylate crosslinker to the vessel, incorporating the at least one (meth)acrylate crosslinker into the base acrylic emulsion to create a two-phase system including water and a phase including crosslinkers of the at least one (meth)acrylate crosslinker inside acrylic emulsion particles of the base acrylic emulsion, applying the two-phase system to a surface, and curing the two-phase system to create a final system including a continuous film and crosslinked crosslinkers.

The present invention provides water-based energy curable compositions that exhibit improved printability, adhesion, opacity, and wash-up properties. The compositions comprise one or more inert water-based polyurethane resins and one or more water-based phosphate esters. Addition of the inert polyurethane resins and phosphate esters improves adhesion of the energy curable compositions to a variety of substrates.