Provided are an adsorbent which can be used in water, particularly even under strong acid conditions, and which has excellent adsorptivity, a method for efficiently separating a separation object substance from a liquid containing the separation object substance using the adsorbent, and further a method for producing a liquid having a separation object substance reduced. More specifically, provided are a method for separating a separation object substance and a liquid using polyarylene sulfide resin particles as an adsorbent from the liquid containing the separation object substance, wherein the liquid contains water, and further a method for producing a liquid having a separation object substance reduced, comprising efficiently separating a separation object substance from a liquid containing the separation object substance using an adsorbent which can be used in water, particularly even under strong acid conditions, and which has excellent adsorptivity.

Provided are an adsorbent which can be used in water, particularly even under strong acid conditions, and which has excellent adsorptivity, a method for efficiently separating a separation object substance from a liquid containing the separation object substance using the adsorbent, and further a method for producing a liquid having a separation object substance reduced. More specifically, provided are a method for separating a separation object substance and a liquid using polyarylene sulfide resin particles as an adsorbent from the liquid containing the separation object substance, wherein the liquid contains water, and further a method for producing a liquid having a separation object substance reduced, comprising efficiently separating a separation object substance from a liquid containing the separation object substance using an adsorbent which can be used in water, particularly even under strong acid conditions, and which has excellent adsorptivity.

A preparation method of a polyarylene sulfide that may produce a polyarylene sulfide having properties equal to or higher than those of the conventional method with a high molecular weight at a high yield by optimizing the content and molar ratio of an amide-based compound in a polymerization step.

The production method of the present invention includes a step of supplying an organic polar solvent, a sulfur source, and a dihalo aromatic compound as reaction raw materials to at least one of a plurality of reaction vessels mutually communicated via a gas phase; a step of removing at least a portion of the water present in the reaction vessels; and a step of performing a polymerization reaction. These steps are carried out in parallel, and the reaction mixture is sequentially moved between reaction vessels. At that time, the internal temperatures of the reaction vessels are all not less than 150° C.

The production method of the present invention includes a step of supplying an organic polar solvent, a sulfur source, and a dihalo aromatic compound as reaction raw materials to at least one of a plurality of reaction vessels mutually communicated via a gas phase; a step of removing at least a portion of the water present in the reaction vessels; and a step of performing a polymerization reaction. These steps are carried out in parallel, and the reaction mixture is sequentially moved between reaction vessels. At that time, the internal temperatures of the reaction vessels are all not less than 150° C.

The present disclosure relates to a preparation method of a polyarylene sulfide, and this method may produce a polyarylene sulfide having properties equal to or higher than those of the conventional method at a high yield by adding an acidic compound in addition to existing materials for dehydration.

The present disclosure relates to a preparation method of a polyarylene sulfide, and this method may produce a polyarylene sulfide having properties equal to or higher than those of the conventional method at a high yield by adding an acidic compound in addition to existing materials for dehydration.

The present disclosure relates to a preparation method of a polyarylene sulfide, and this method may produce a polyarylene sulfide having properties equal to or higher than those of the conventional method at a high yield by adding an aliphatic amino acid hydrochloride in addition to existing materials for dehydration.

Provided is a method for producing a polyarylene sulfide resin, the method including subjecting a dihaloaromatic compound and a sulfidizing agent to a polymerization reaction in the presence of an aliphatic cyclic compound having a ring openable by hydrolysis, in which corrosion of a production apparatus is suppressed. More particularly, provided is a method for producing a polyarylene sulfide resin, the method including a dehydration step (1) in which a water-containing sulfidizing agent and an aliphatic cyclic compound having a ring openable by hydrolysis are heated in the presence of a dihaloaromatic compound to a liquid temperature in the range of 90° C. or higher and 170° C. or lower under the atmospheric pressure, and then dehydration is performed while maintaining the liquid temperature and reducing the pressure to a pressure in the range of 30 [kPa abs] or higher and 80 [kPa abs] or lower to thus obtain a mixture.

Provided is a method for producing a polyarylene sulfide resin, the method including subjecting a dihaloaromatic compound and a sulfidizing agent to a polymerization reaction in the presence of an aliphatic cyclic compound having a ring openable by hydrolysis, in which corrosion of a production apparatus is suppressed. More particularly, provided is a method for producing a polyarylene sulfide resin, the method including a dehydration step (1) in which a water-containing sulfidizing agent and an aliphatic cyclic compound having a ring openable by hydrolysis are heated in the presence of a dihaloaromatic compound to a liquid temperature in the range of 90° C. or higher and 170° C. or lower under the atmospheric pressure, and then dehydration is performed while maintaining the liquid temperature and reducing the pressure to a pressure in the range of 30 [kPa abs] or higher and 80 [kPa abs] or lower to thus obtain a mixture.