Patent classifications
C08J2325/12
Thermoplastic resin composition and resin molded article
A thermoplastic resin composition containing 25 to 50 parts by mass of a rubber-containing graft copolymer (A) obtained by copolymerizing a monomer mixture containing an aromatic vinyl compound and a vinyl cyanide compound in the presence of a diene-based rubber-like polymer, and 50 to 75 parts by mass of a hard copolymer mixture (B) containing a hard copolymer (B-I) and a hard copolymer (B-II).
ABS molding compound having a good property combination of processability and surface quality
The present invention relates to thermoplastic molding compounds F containing at least two graft rubbers P-I and P-II which are processed by the co-precipitation of a mixture of the respective emulsions containing P-I and P-II. The present invention further relates to a method for producing such thermoplastic molding compounds F and to molded bodies obtained from a thermoplastic molding compound F according to the invention.
CORE AND SHELL POLYMERS FOR 3D-PRINTING
A core/shell polymer material suitable for three-dimensional printing is provided. The core/shell polymer material may include at least one amorphous polymer as a core particle and at least one semicrystalline polymer as a shell material surrounding the core particle.
SINGLE STEP FOAMED POLYMERIC MATERIAL CHARACTERISED BY THE PRESENCE OF TWO OR MORE CELLULAR LAYERS AND AGGREGATES THAT EXHIBIT VARIATION IN CELL SIZE AND CELL DENSITY DISTRIBUTION
The present invention relates to a process for the manufacture of foamed polymeric material characterised by the presence of two or more cellular layers and aggregates that exhibit variations in cell size and cell density distribution. The heterogeneous polymeric material is foamed using a single expansion step, thus eliminating the assembly steps and improving the mechanical proprieties of the foam. The invention allows producing custom foam with predefined profiles of cell size, cell density distribution, and with correlated variations of its physical properties. The key to this invention is that the polymer material before expansion is made in multiple polymerisation steps from the original monomers. In each polymerisation step, a different recipe of monomers and physical blowing agents' concentration is used. These recipes within the final polymer material will expand under the same temperature to produce various aggregates of cell sizes and cell distribution in the final foam.
Thermoplastic resin composition with improved UV resistance
Thermoplastic resin composition comprising: (a1) at least one styrene-acrylonitrile copolymer component A1, (a2) at least one acrylonitrile styrene acrylate graft copolymer A2 as impact modifier, (a3) optionally at least one thermoplastic polymer A3 other than components A1 and A2, (b) at least one pigment B, (c) at least one hindered amine UV light stabilizer C1 and at least one UV absorber C2 different from C1, and (d) optionally further polymer additives D, other than components B, C1, C2, and E, (e) at least one metal scavenger component E.
METHOD TO PREPARE POLYMER MATERIALS WITH INTERLOCKED POROUS STRUCTURES BY FREEZING AND DEMULSIFICATION OF EMULSION
The present invention provides a method to prepare polymer materials with interlocked porous structures by freezing and demulsification, which includes: (1) Preparing an emulsion containing uncrosslinked polymers and crosslinking agents. The uncrosslinked polymers are presented in the organic phase, and the crosslinking agents are presented in the organic phase or water phase. Under freezing, the demulsification is occurred which leads to the interaction between polymers and crosslinking agents, and the crosslinked materials are obtained. (2) After removing the ice crystals, polymer materials with interlocked porous structures are synthesized. The method provided by the present invention is simple to operate, and can well adjust the porous structures of obtained porous polymer materials. In addition, it is suitable for large scale manufacturing. At the same time, this process can form different functional porous polymer materials by simply changing the used monomers. Particularly, it can prepare melt-blown fabrics with antibacterial property, high-throughput vertical porous structures and high-temperature sterilizable feature, therefore, it can be used to manufacture medical products such as masks.
Single step foamed polymeric material characterised by the presence of two or more cellular layers and aggregates that exhibit variation in cell size and cell density distribution
The present invention relates to a process for the manufacture of foamed polymeric material characterised by the presence of two or more cellular layers and aggregates that exhibit variations in cell size and cell density distribution. The heterogeneous polymeric material is foamed using a single expansion step, thus eliminating the assembly steps and improving the mechanical proprieties of the foam. The invention allows producing custom foam with predefined profiles of cell size, cell density distribution, and with correlated variations of its physical properties. The key to this invention is that the polymer material before expansion is made in multiple polymerisation steps from the original monomers. In each polymerisation step, a different recipe of monomers and physical blowing agents' concentration is used. These recipes within the final polymer material will expand under the same temperature to produce various aggregates of cell sizes and cell distribution in the final foam.
POROUS RESIN USED TO SOLID PHASE SYNTHESSIS AND PREPARATION METHOD THEREFOR
A porous resin used to solid phase synthesis and a preparation method therefor, specifically being a porous resin having functional groups being an amino group or a hydroxyl group and a preparation method therefor. Using an olefin compound containing two cyano groups as a modified monomer, using a high internal phase emulsion as a pore-foaming agent, and performing suspension polymerization to prepare the porous resin. And then functionalizing the porous resin to obtain the porous resin having functional groups being an amino group or a hydroxyl group. Different from the existing preparation method, the modified monomer can make the distribution of the functional groups more uniform, and make the swelling degrees of the porous resin in different solvents close. The high internal phase emulsion pore-foaming agent can make the pore size distribution of the carrier narrower. The porous resin can be used as a solid phase synthesis carrier to prepare an oligonucleotide, and the use of the carrier is beneficial for improving the yield and purity of the oligonucleotide.
CORE AND SHELL POLYMERS FOR 3D-PRINTING
A core/shell polymer material suitable for three-dimensional printing is provided. The core/shell polymer material may include at least one amorphous polymer as a core particle and at least one semicrystalline polymer as a shell material surrounding the core particle.
Translucent fibre composite materials comprising chemically modified polymers
The present invention relates to a fibre composite material W of increased translucency and/or mechanical strength, comprising a copolymer C encompassing monomers A-1, where A-1 form covalent bonds with functional groups B-1 on the surface of fibres B embedded in the fibre composite material W, and this fibre composite material W has greater translucency and/or mechanical strength than a fibre composite material Win which the copolymer C contains no A-1. The present invention further embraces a method for producing a fibre composite material W of increased translucency and/or mechanical strength.