The invention relates to composite pigment particles containing calcium phosphate, their manufacture and their use in coatings, plastics and laminates. The composite pigment particles contain titanium dioxide pigment particles and precipitated calcium phosphate. In one embodiment, the composite pigment particles additionally contain an inorganic and/or organic filler as an extender, preferably selected from the group comprising Ca, CaMg and Mg carbonates, natural and synthetic silicon dioxide and oxides. The composite pigment particles are manufactured in a combined process of dispersion and precipitation. Depending upon the combination selected, use of composite titanium dioxide pigment particles of the invention can provide improved optical properties such as tinting strength or permits pigment savings with little to no loss of optical properties. In particular, the composite pigment particles of the invention can be used to replace part or all of the titanium dioxide contained in the user's system.

A method for manufacturing pigmentary titanium dioxide particles coated with a SiO.sub.2 coating layer includes steps of (i) forming an aqueous dispersion containing rutile titanium dioxide particles having an average particle size of in a range of 7-1000 nm, (ii) introducing to said dispersion of step (i) a silicon containing compound and a base, (iii) adding to the dispersion obtained from step ii acid, (iv) repeating the steps ii and iii at least once. Finally, the pH of the dispersion is lowered to a value within the range from 1.9 to 9.0 before filtering and washing thus obtained product.

Core particles produced in situ or introduced as preformed core particles are coated with a layer of carbon. Non-carbon as well as some carbon-based core materials can be utilized. The resulting carbon coated particles can find applications in rubber products, for instance as reinforcement for tire components.

A coating film-forming composition includes a hydrolysis-condensation product of a hydrolyzable silane and fine inorganic particles subjected to a special dispersion treatment, that can be formed into a highly heat-resistant, highly transparent coating film capable of exhibiting a high refractive index and having a large thickness and excellent storage stability as a coating composition; and a process for producing the coating film-forming composition.

A dispersion that inorganic oxide microparticles may be dispersed at a high concentration in a solvent, a composition for film formation having high transparency, high refractive index and adhesion to a base layer. Inorganic oxide microparticles wherein an amphiphilic organosilicon compound having one or more selected from a polyoxyethylene group, a polyoxypropylene group, or a polyoxybutylene group as a hydrophilic group, and one or more selected from a C.sub.1-18 alkylene group or a vinylene group as a hydrophobic group bonded to a surface of modified metal oxide colloidal particles (C) having a primary particle diameter of 2 to 100 nm, the modified metal oxide colloidal particles wherein a surface of metal oxide colloidal particles (A) having a primary particle diameter of 2 to 60 nm as a nucleus is coated with a coating material (B) including metal oxide colloidal particles having a primary particle diameter of 1 to 4 nm.

The invention relates to the manufacture of composite pigments containing aluminum hydroxide, and their use for improving the pigment light-scattering efficiency in coatings, plastics, paper and laminates. The composite pigment particles contain pigment particles such as titanium dioxide and precipitated aluminum hydroxide and are manufactured by in-situ precipitation of aluminum hydroxide in an aqueous pigment particle suspension. Use of the composite pigment particles according to the invention, based on titanium dioxide, permits savings on pigment with little or no loss of optical properties. Alternatively, if the pigment content remains unchanged, it is also possible to achieve better optical properties.

A coated powder comprises (a) nanoparticles, and (b) a coating, on the surface of the nanoparticles. The coating comprises (1) silica moieties, (2) organo oxysilane moieties selected from the group consisting of mono-organo oxysilane moieties, bi-organo oxysilane moieties and tri-organo oxysilane moieties, and (3) poly(dialkyl)siloxane moieties.

A pigment composition according to an embodiment includes aluminum flakes coated with a plurality of metal oxide layers and TiO2 coated with a metal oxide layer, thus having explosion stability. The pigment composition may be prepared by mixing with TiO2 coated with a metal oxide layer having lower apparent specific gravity as compared to other plate-shaped inorganic particles. The pigment composition can have stability against a thermite reaction by aluminum and metal oxides while preventing deterioration of saturation and opacity.

The invention relates to a titanium dioxide particle with high opacity and UV-greying resistance comprising two silica coats and at least one alumina coat, to a method for the obtaining the same, and to the use of said particle in a method for obtaining a decorative paper laminate or a dcor foil. The present invention further pertains a decorative paper laminate or a dcor foil containing said coated titanium dioxide particle.

Hollow structure particles which contain titanium oxide and silica, in which the crystal type of the titanium oxide is rutile type; a method for producing the hollow structure particles; a white ink which contains these hollow structure particles as a coloring agent; use of the white ink in inkjet recording; and an inkjet recording method which uses the white ink.