Patent classifications
C08K5/3435
COMPOSITIONS AND METHODS FOR CROSSLINKING POLYMERS IN THE PRESENCE OF ATMOSPHERIC OXYGEN
An organic peroxide formulation comprises at least one organic peroxide, at least one drying oil, and at least one free radical trap. A process comprises curing mixtures that include at least one elastomer and the organic peroxide formulation in the presence of oxygen. Elastomer compositions, methods of manufacturing elastomer articles, and elastomer articles made from the elastomer compositions are also disclosed.
COMPOSITIONS AND METHODS FOR CROSSLINKING POLYMERS IN THE PRESENCE OF ATMOSPHERIC OXYGEN
An organic peroxide formulation comprises at least one organic peroxide, at least one drying oil, and at least one free radical trap. A process comprises curing mixtures that include at least one elastomer and the organic peroxide formulation in the presence of oxygen. Elastomer compositions, methods of manufacturing elastomer articles, and elastomer articles made from the elastomer compositions are also disclosed.
LIQUID AND MELTABLE SOLID GRADES OF SCORCH PROTECTED PEROXIDES
Embodiments of organic peroxide formulations provide longer scorch time protection and require fewer additives. The peroxide formulations may include, for example, at least one organic peroxide, at least one nitroxide-containing compound (e.g., 4-hydroxy-TEMPO), and at least one quinone-containing compound (e.g., mono-tert-butylhydroquinone). Embodiments of the present invention relate to organic peroxide compositions comprising scorch retarders. Embodiments of the invention also relate to crosslinkable elastomer compositions, processes for curing the elastomers, and products made by such processes.
LIQUID AND MELTABLE SOLID GRADES OF SCORCH PROTECTED PEROXIDES
Embodiments of organic peroxide formulations provide longer scorch time protection and require fewer additives. The peroxide formulations may include, for example, at least one organic peroxide, at least one nitroxide-containing compound (e.g., 4-hydroxy-TEMPO), and at least one quinone-containing compound (e.g., mono-tert-butylhydroquinone). Embodiments of the present invention relate to organic peroxide compositions comprising scorch retarders. Embodiments of the invention also relate to crosslinkable elastomer compositions, processes for curing the elastomers, and products made by such processes.
LIQUID AND MELTABLE SOLID GRADES OF SCORCH PROTECTED PEROXIDES
Embodiments of organic peroxide formulations provide longer scorch time protection and require fewer additives. The peroxide formulations may include, for example, at least one organic peroxide, at least one nitroxide-containing compound (e.g., 4-hydroxy-TEMPO), and at least one quinone-containing compound (e.g., mono-tert-butylhydroquinone). Embodiments of the present invention relate to organic peroxide compositions comprising scorch retarders. Embodiments of the invention also relate to crosslinkable elastomer compositions, processes for curing the elastomers, and products made by such processes.
Double initiated fast crosslinking EVA adhesive film
The invention provides a dual-initiated and fast cross-linked EVA (ethylene/vinyl acetate copolymer) film for the encapsulation of solar modules, which greatly enhances the speed of the encapsulation. The EVA film is mainly prepared from the following raw materials: 100 parts by mass of ethylene/vinyl acetate copolymer, 0.01 to 1.5 parts by mass of a free-radical photoinitiator, 0.01 to 1.5 parts by mass of a free-radical thermal initiator, 0.5 to 10 parts by mass of an auxiliary cross-linking agent, 0.1 to 5 parts by mass of a tackifier and 0.01 to 5 parts by mass of a light stabilizer. The present invention adds photothermal dual-initiated free-radical initiators and the auxiliary cross-linking agent of multi-functional acrylates or methacrylates to the EVA and use a thermal-UV dual curing process to prepare the solar module. The curing time is shorten to 5 to 10 min and the yield is high; meanwhile, the EVA film has advantages of uniform curing, high crosslink density, high bonding strength between the film and glass, and good anti-aging property.
Double initiated fast crosslinking EVA adhesive film
The invention provides a dual-initiated and fast cross-linked EVA (ethylene/vinyl acetate copolymer) film for the encapsulation of solar modules, which greatly enhances the speed of the encapsulation. The EVA film is mainly prepared from the following raw materials: 100 parts by mass of ethylene/vinyl acetate copolymer, 0.01 to 1.5 parts by mass of a free-radical photoinitiator, 0.01 to 1.5 parts by mass of a free-radical thermal initiator, 0.5 to 10 parts by mass of an auxiliary cross-linking agent, 0.1 to 5 parts by mass of a tackifier and 0.01 to 5 parts by mass of a light stabilizer. The present invention adds photothermal dual-initiated free-radical initiators and the auxiliary cross-linking agent of multi-functional acrylates or methacrylates to the EVA and use a thermal-UV dual curing process to prepare the solar module. The curing time is shorten to 5 to 10 min and the yield is high; meanwhile, the EVA film has advantages of uniform curing, high crosslink density, high bonding strength between the film and glass, and good anti-aging property.
COMPOSITIONS AND METHODS FOR CROSSLINKING POLYMERS IN THE PRESENCE OF ATMOSPHERIC OXYGEN
Embodiments of organic peroxide formulations provide significant improvements in surface tackiness (often including tack-free surfaces) when curing elastomers in the presence of oxygen. The peroxide formulations may include, for example, one or more compounds selected from sulfur-containing compounds, organophosphite compounds, HALS (Hindered Amine Light Stabilizer) compounds, aliphatic allyl urethane compounds, and blends comprising nitroxides (e.g., 4-hydroxy-TEMPO) and quinones (e.g., mono-tert-butylhydroquinone).
COMPOSITIONS AND METHODS FOR CROSSLINKING POLYMERS IN THE PRESENCE OF ATMOSPHERIC OXYGEN
Embodiments of organic peroxide formulations provide significant improvements in surface tackiness (often including tack-free surfaces) when curing elastomers in the presence of oxygen. The peroxide formulations may include, for example, one or more compounds selected from sulfur-containing compounds, organophosphite compounds, HALS (Hindered Amine Light Stabilizer) compounds, aliphatic allyl urethane compounds, and blends comprising nitroxides (e.g., 4-hydroxy-TEMPO) and quinones (e.g., mono-tert-butylhydroquinone).
Coating material with high scratch resistance
The present invention relates to a coating material comprising at least one aliphatic or cycloaliphatic polyisocyanate having an NCO functionality of at least 2, preferably 2.8 to 6, optionally at least one binder, preferably a hydroxyl-containing binder, at least one adduct of an isocyanatotrialkoxysilane and a polyhydric alcohol, with more than 90, more preferably more than 95, most preferably more than 99 percent of the hydroxyl groups in the polyhydric alcohol having been converted by reaction with the isocyanatotrialkoxysilane, and less than 0.1 wt % of the isocyanate groups from the isocyanatotrialkoxysilane being reactive in the adduct, at least one catalyst selected from the group consisting of Lewis acids, phosphoric acid or phosphorous acid and esters thereof, blocked or non-blocked sulphonic acids, sulphuric acid, carboxylic acids having a melting point >60° C. and tetraalkylammonium carboxylates, optionally at least one auxiliary, preferably at least one further crosslinker, and/or adjuvant, and optionally organic solvents, and also to a process comprising providing, applying to a surface and curing the coating material, to a coating obtainable by curing the coating material, and to use of the coating material for coating a metal, glass, plastic or wood surface.