Patent classifications
C09K8/885
POLYESTER DIVERTING AGENTS FOR LOW-TEMPERATURE OIL WELLS
A hydraulic fracturing method for recovering oil from a low-temperature subterranean oil formation is disclosed. Before, during, or after inducing hydraulic fracturing within the formation, a particulate, degradable polyester diverting agent is introduced into the formation in an amount effective to improve oil production from the formation. The diverting agent is allowed to degrade, and oil is recovered. The diverting agent has a melting point greater than the average temperature of the formation and is selected from: (i) ethylene glycol succinates; (ii) acid-terminated ethylene glycol succinates; (iii) acid-terminated polyglycolic acids; (iv) acid-terminated polylactic acids; (v) mixtures of any of (i) through (iv) with a half acid ester; and (vi) mixtures of polylactic acids or polyglycolic acids with a half acid ester. These easily synthesized classes of particulate polyester diverting agents degrade more effectively than polylactides under the conditions present in low-temperature wells and should help to enhance well productivity.
Aqueous delayed acid system for well stimulation
The disclosure relates to an aqueous acidizing fluid. In addition to an acid, the fluid contains an organophosphorus surfactant and/or an acid retarder. The organophosphorus surfactant may be an amino phosphonate or a phosphino carboxylate. The acid retarder comprises the combination of urea or a urea derivative and a bifunctional organic compound. Suitable bifunctional organic compounds contain at least one quaternary ammonium or phosphonium and at least one alcohol as well as salts of nitrogen containing heterocyclic rings.
Degradable aliphatic polyester fluid
Viscous degradable fluids for use in fluid loss control, diversion, gravel packing, fracturing, and acidizing operations, method of preparing the viscous degradable fluids, and methods of using the viscous degradable fluids in subterranean operations. At least one aliphatic polyester is dissolved in a solvent comprising triacetin to form a viscous degradable fluid. The viscous degradable fluid can be injected directly into a subterranean formation or mixed with other fluids and/or additives before being injected into the subterranean formation, where it can temporarily block or restrict flow through openings in the formation.
METHODS AND COMPOSITIONS OF DISPERSIBLE FERROELECTRIC NANOPARTICLES, AND USES THEREOF
Methods of forming dispersible ferroelectric nanoparticles, including polyether-ylated barium titanate nanoparticles. Uses of the dispersible ferroelectric nanoparticles, including as a ferroelectric tracer material, optionally for detecting a presence and/or measuring a distribution of an oil or a hydrocarbon in a subsurface formation and/or flowback fluid. Compositions and methods involving an oil or hydrocarbon recovery fluid and the dispersible ferroelectric nanoparticles for detecting a presence, measuring a distribution, or both of an oil or a hydrocarbon in a subsurface formation and/or flowback fluid.
Silane-functionalized polyalkyleneimine clay stabilizer for treatment of subterranean formations
Various embodiments disclosed relate to a silane-functionalized polyalkyleneimine (PAI) clay stabilizer for treatment of subterranean formations. In various embodiments, the present invention provides a method of treating a subterranean formation. The method can include placing in the subterranean formation a silane-functionalized PAI clay stabilizer.
Enzymatic compositions for the degradation of polymers
Provided herein are compositions and methods for degrading polymer systems. These compositions and methods can be used to effectively degrade a range of polymers commonly used in oil and gas operations, including polymers with carbon-carbon backbones such as polyacrylamides. Further, these compositions and methods can simultaneously degrade other organic molecules and pollutants associated with oil and gas operations. The compositions and methods described herein employ reactants that are more environmentally-friendly than conventional methods and components used in, for example, polymer breaking processes.
Thermoassociative polymers in subterranean treatment fluids
Compositions and methods for use in subterranean treatment fluids involving thermoassociative polymers are provided. In some embodiments, the methods include providing a treatment fluid that includes an aqueous base fluid, one or more thermoassociative polymers that include a water soluble polymeric backbone having one or more hydrophobic moieties attached to the polymer backbone, wherein the thermoassociative polymer exhibits thermoassociation at a first temperature T.sub.assoc, and one or more tuning additives that changes the temperature at which at least one of the thermoassociative polymers exhibits thermoassociation from T.sub.assoc to a second temperature T.sub.assoc′; and introducing the treatment fluid into a portion of a subterranean formation.
Cavitation of polymer-containing fluids for use in subterranean formations
Methods for breaking polymer-containing treatment fluids for use in subterranean formations are provided. In one or more embodiments, the methods include providing a treatment fluid comprising a base fluid and a polymer, wherein the treatment fluid was recovered from at least a portion of a subterranean formation located at a wellsite; transporting the treatment fluid from the wellsite to an off-site location; and applying a cavitation technique to at least a portion of the treatment fluid at the off-site location.
HYDRAULIC FRACTURING
A method of preparing a fracturing fluid (YY) that includes (i) selecting an anionic surfactant (AS), for example an anionic sulphonate surfactant; and (ii) contacting the anionic surfactant (AS) with a fracturing fluid (XX) or with a precursor of said fracturing fluid (XX), wherein fracturing fluid (XX) may incorporate a friction reducer formulation.
High temperature treatment fluids with nano-crosslinkers
A treatment fluid system for reducing permeability of high permeability zones in a subterranean reservoir formation comprising a fluid composition comprising a nano-crosslinker, the nano-crosslinker comprising a nanomaterial, and a crosslinker, wherein the crosslinker comprises a chemical group selected from the group consisting of carbonyl, sulfhydryl, amine and imine, wherein the nano-crosslinker is produced by a method selected from the group consisting of pre-treating the nanomaterial with the crosslinker such that the crosslinker has been functionalized onto the nanomaterial, embedding the crosslinker on the nanoparticle, grafting the crosslinker onto the nanomaterial, and coating the crosslinker on the nanomaterial, a base polymer, and a base fluid, the base fluid operable to suspend the fluid composition, wherein the base fluid comprises water, wherein the treatment fluid system is operable to reduce permeability of a high permeability zone in the subterranean reservoir formation.