A water-based acrylic resin and a method for producing the same are provided. The water-based acrylic resin includes a polymerizable composition. The polymerizable composition includes deionized water, a reactive emulsifier, a first acrylic monomer, a second acrylic monomer, a third acrylic monomer, a fourth acrylic monomer, and an acrylic polyol. The reactive emulsifier is a nonylphenyl-free reactive emulsifier. The first acrylic monomer is an alkyl-containing (meth)acrylate. The second acrylic monomer is a hydroxyl-containing (meth)acrylate. The third acrylic monomer is a carboxyl-containing (meth)acrylate. The fourth acrylic monomer is an ethylenically-unsaturated-functional-groups-containing (meth)acrylate. The acrylic polyol is one or both of a hydroxyl-containing polyester acrylic polyol and a hydroxyl-containing polyether acrylic polyol.

A water-based acrylic resin and a method for producing the same are provided. The water-based acrylic resin includes a polymerizable composition. The polymerizable composition includes deionized water, a reactive emulsifier, a first acrylic monomer, a second acrylic monomer, a third acrylic monomer, a fourth acrylic monomer, and an acrylic polyol. The reactive emulsifier is a nonylphenyl-free reactive emulsifier. The first acrylic monomer is an alkyl-containing (meth)acrylate. The second acrylic monomer is a hydroxyl-containing (meth)acrylate. The third acrylic monomer is a carboxyl-containing (meth)acrylate. The fourth acrylic monomer is an ethylenically-unsaturated-functional-groups-containing (meth)acrylate. The acrylic polyol is one or both of a hydroxyl-containing polyester acrylic polyol and a hydroxyl-containing polyether acrylic polyol.

The present invention provides multilayer coated substrates, prepared using primer and/or sealer compositions comprising waterborne curable film-forming compositions, in turn comprising: a) an aqueous dispersion of a pigment and i) polymeric urethane-shell particles having a care-shell morphology and having hydroxyl functional groups, wherein the core is prepared from a monomer mixture comprising hydrophobic, ethylenically unsaturated monomers and the shell comprises a polyurethane or polyurethane-urea polymer; or ii) polymeric acrylic-shell particles having a core-shell morphology and having hydroxyl functional groups, wherein the core is prepared from a monomer mixture comprising hydrophobic, ethylenically unsaturated monomers and the shell is prepared from a monomer mixture comprising hydrophilic, ethylenically unsaturated monomers; b) a polyisocyanate crosslinking agent; and optionally c) a hydroxyl functional, water dispersible acrylic polymer.

The present invention provides multilayer coated substrates, prepared using primer and/or sealer compositions comprising waterborne curable film-forming compositions, in turn comprising: a) an aqueous dispersion of a pigment and i) polymeric urethane-shell particles having a care-shell morphology and having hydroxyl functional groups, wherein the core is prepared from a monomer mixture comprising hydrophobic, ethylenically unsaturated monomers and the shell comprises a polyurethane or polyurethane-urea polymer; or ii) polymeric acrylic-shell particles having a core-shell morphology and having hydroxyl functional groups, wherein the core is prepared from a monomer mixture comprising hydrophobic, ethylenically unsaturated monomers and the shell is prepared from a monomer mixture comprising hydrophilic, ethylenically unsaturated monomers; b) a polyisocyanate crosslinking agent; and optionally c) a hydroxyl functional, water dispersible acrylic polymer.

Provided herein is a copolymer of ethylene and acrylate(s) having a melt flow index (MFI) greater than or equal to 50 g/10 minutes, obtained by free-radical copolymerisation under high pressure carried out in a tubular reactor, and methods of using the same. Also provided herein is a thermoplastic composition, particularly intended to be extruded or injection moulded, having one or more copolymers of ethylene and acrylate(s) at a content ranging from 0.1 to 20 wt. %, and one or more thermoplastic polymers.

The present invention relates to a copolymer (A) having a glass transition temperature T.sub.g of at least −30° C. obtainable by copolymerization of a mixture of olefinically unsaturated monomers (a) in at least one organic solvent and in the presence of at least one initiator, where the mixture of monomers (a) to be polymerized comprises (a1) 10 to 60 mol % of at least one monomer of the formula (I) below

##STR00001## where R.sub.1=C.sub.1 to C.sub.4 alkoxy, R.sub.2=C.sub.1 to C.sub.4 alkyl, and m=0 to 2, and (a2) 40 to 90 mol % of at least one olefinically unsaturated monomer selected from the group consisting of monomers of the formulae H.sub.2C═CH.sub.2—(C═O)—O—R.sub.x, H.sub.2C═CH(CH.sub.3)—(C═O)—O—R.sub.x, and H.sub.2C═CH.sub.2—O—(C═O)—R.sub.x, where R.sub.x is an alkyl radical having 1 to 20 carbon atoms,
and where the sum total of the molar fractions of the monomers (a1) and (a2), based on the total molar amount of monomers (a) used, is at least 90 mol %, and where the copolymerization is carried out at a temperature from 60 to 200° C. and at a pressure of at least 2 bar.

The present invention relates to a copolymer (A) having a glass transition temperature T.sub.g of at least −30° C. obtainable by copolymerization of a mixture of olefinically unsaturated monomers (a) in at least one organic solvent and in the presence of at least one initiator, where the mixture of monomers (a) to be polymerized comprises (a1) 10 to 60 mol % of at least one monomer of the formula (I) below

##STR00001## where R.sub.1=C.sub.1 to C.sub.4 alkoxy, R.sub.2=C.sub.1 to C.sub.4 alkyl, and m=0 to 2, and (a2) 40 to 90 mol % of at least one olefinically unsaturated monomer selected from the group consisting of monomers of the formulae H.sub.2C═CH.sub.2—(C═O)—O—R.sub.x, H.sub.2C═CH(CH.sub.3)—(C═O)—O—R.sub.x, and H.sub.2C═CH.sub.2—O—(C═O)—R.sub.x, where R.sub.x is an alkyl radical having 1 to 20 carbon atoms,
and where the sum total of the molar fractions of the monomers (a1) and (a2), based on the total molar amount of monomers (a) used, is at least 90 mol %, and where the copolymerization is carried out at a temperature from 60 to 200° C. and at a pressure of at least 2 bar.

Provided herein are aqueous dispersions. The aqueous dispersions can comprise a first copolymer derived from one or more ethylenically unsaturated monomers, and a second carboxy-functional copolymer derived from one or more carboxylic acid-containing monomers. The aqueous dispersions can be used to prepare low- or zero-VOC aqueous coating compositions that possess desirable properties, including good block resistance and scrub resistance. Coatings and coating formulations comprising the aqueous dispersion, as well as methods of making and using the same are also provided.

Provided herein are aqueous dispersions. The aqueous dispersions can comprise a first copolymer derived from one or more ethylenically unsaturated monomers, and a second carboxy-functional copolymer derived from one or more carboxylic acid-containing monomers. The aqueous dispersions can be used to prepare low- or zero-VOC aqueous coating compositions that possess desirable properties, including good block resistance and scrub resistance. Coatings and coating formulations comprising the aqueous dispersion, as well as methods of making and using the same are also provided.

Copolymers and latex paint compositions using such copolymers that are heat-age stable and provide good adhesion, block resistance, and hiding all while using lower amounts of pigment are described herein. In one aspect, the heat-age stable compositions include an acrylic, styrene acrylic, vinyl acrylic copolymer or blends thereof including, as additional polymerizable units, at least one polymerizable phosphate surfactant and at least one linear or branched hydrophobic monomer that are both polymerized into the acrylic, styrene acrylic, vinyl acrylic copolymer backbone.