An aqueous polyurethane resin composition including: an aqueous polyurethane resin which is a chain-extended product obtained from a neutralized product of an isocyanate-terminated prepolymer which is a reaction product of (A) a polyisocyanate, (B) polyols, and (C) a diol having a carboxy group and/or a carboxylate group, by using (D) a polyamine having two or more amino groups and/or imino groups in one molecule, wherein (B) the polyols contain (b-1) a polypropylene glycol having a number average molecular weight of 600 to 10,000 and (b-2) a polytetramethylene glycol having a number average molecular weight of 1,000 to 4,000, a total amount of (b-1) the polypropylene glycol and (b-2) the polytetramethylene glycol accounts for 50% by mass or more of an entire amount of (B) the polyols, and a mass ratio between (b-1) the polypropylene glycol and (b-2) the polytetramethylene glycol is (b-1):(b-2)=0.5:99.5 to 60:40.

Disclosed are a polyurethane foam composition for sound-absorbing materials, a method for manufacturing a polyurethane foam and a polyurethane foam manufactured using the method. Particularly, disclosed are a composition containing a polyol mixture including a polyol and an additive, and isocyanate, and the manufacture of a low-density polyurethane foam for sound-absorbing materials, which is imparted with improved appearance formability, reduced smell and enhanced sound absorption performance by controlling the content of the composition and the conditions for foaming the composition.

Disclosed are compositions that may be useful for forming synthetic membranes, methods of forming membranes therefrom, and membranes. In an embodiment, a membrane comprises a free hydrophilic polymer and a polyurethane, the polyurethane comprising a backbone comprising the reaction product of a diisocyanate, a polymeric aliphatic diol, and, optionally, a chain extender, wherein the backbone comprises a C.sub.2-C.sub.16 fluoroalkyl or C.sub.2-C.sub.16 fluoroalkyl ether, or the polyurethane comprises an endgroup comprising a C.sub.2-C.sub.16 fluoroalkyl or C.sub.2-C.sub.16 fluoroalkyl ether.

The present invention relates to a multi-aziridine compound having: a) at least 2 of the following structural units (A): (A) whereby R.sub.1 is H; R.sub.2 and R.sub.4 are independently chosen from H, a linear group containing from 1 to 8 carbon atoms and optionally containing one or more heteroatoms, a branched or cyclic group containing from 3 to 8 carbon atoms and optionally containing one or more heteroatoms, phenyl, benzyl, or pyridinyl; R.sub.3 is chosen from a linear group containing from 1 to 8 carbon atoms and optionally containing one or more heteroatoms, a branched or cyclic group containing from 3 to 8 carbon atoms and optionally containing one or more heteroatoms, phenyl, benzyl, or pyridinyl; or R.sub.2 and R.sub.3 (in case R.sub.2 is different than H) may be part of the same cyclic group containing from 3 to 8 carbon atoms; R′ and R″ are independently H or an aliphatic hydrocarbon group containing from 1 to 12 carbon atoms; and b) a molecular weight from 600 to 20000 Daltons, wherein the molecular weight is determined using MALDI-TOF mass spectrometry according to the description.

##STR00001##

The present invention relates to a multi-aziridine compound having: a) from 2 to 6 of the following structural units (A): whereby R′, R″ are as defined herein m is an integer from 1 to 6; b) one or more linking chains wherein each one of these linking chains links two of the structural units A; and c) a molecular weight in the range from 840 Daltons to 5000 Daltons. The multi-aziridine compound can be used for example for crosslinking of for example carboxylic acid functional polymers dissolved and/or dispersed in an aqueous medium.

##STR00001##

The present invention relates to an aqueous coating composition comprising a multi-aziridine compound and a carboxylic acid functional polymer, characterized in that (i) the composition is an aqueous dispersion having a pH ranging from 8 to 14, (ii) the aqueous dispersion comprises particles X which particles X comprise multi aziridine compound and particles Y which particles Y comprise carboxylic acid functional polymer, and (iii) said multi-aziridine compound has: a) from 2 to 6 of the following structural units A: b) one or more linking chains wherein each one of these linking chains links two of the structural units A; and c) a molecular weight in the range from 500 to 10000 Daltons.

##STR00001##

The present disclosure provides a polymeric material including a polymerized reaction product of a polymerizable composition including components and has a solids content of 90% or greater. The components include a uretdione-containing material including a reaction product of a diisocyanate reacted with itself; a first hydroxyl-containing compound; an optional second hydroxyl-containing compound having a single OH group, wherein; and an epoxy component. The first hydroxyl-containing compound has more than one OH group and the optional second hydroxyl-containing compound is a primary alcohol or a secondary alcohol. The present disclosure also provides a two-part composition, in which the polymeric material is included in the first part and the second part includes at least one amine. Further, a method of adhering two substrates is provided, including obtaining a two-part composition; combining at least a portion of the first part with at least a portion of the second part to form a mixture; disposing at least a portion of the mixture on a first substrate; and contacting a second substrate with the mixture disposed on the first substrate. The disclosure also provides a polymeric material and a method of making a two-part composition. Advantageously, two-part compositions according to the present disclosure can be used as coatings and adhesive systems with handling and performance similar to existing two-part urethane systems, but with less sensitivity to water.

A process for preparing ionic silylated copolyurethanes comprising two ureido-alkylene-alkoxysilane end groups, comprises: (i) forming a composition of copolyurethanes having—NCO end groups by carrying out a polyaddition reaction between a polyisocyanate, a carboxylic diol and a polyol composition comprising a polyol having an Mn of greater than or equal to 2500 g/mol and a polyol having an Mn of less than 2500 g/mol; (ii) neutralizing the formed product with a tertiary amine; and (iii) reacting with an aminosilane derived from a secondary amine. A composition of ionic silylated copolyurethanes comprising two ureido-alkylene-alkoxysilane end groups, said composition being able to be obtained by means of the process. A crosslinkable adhesive and/or sealant composition comprising the composition and a filler.

A polymeric material includes a polyisobutylene-polyurethane block copolymer. The polyisobutylene-polyurethane block copolymer includes soft segments, hard segments, and end groups. The soft segments include a polyisobutylene diol residue. The hard segments include a diisocyanate residue. The end groups are bonded by urea bonds to a portion of the diisocyanate residue. The end groups include a residue of a mono-functional amine.

The present disclosure relates to a process for producing polyurethanes including mixing (a) polyisocyanate, (b) polymeric compounds having isocyanate-reactive groups, (c) catalysts and optionally (d) blowing agents, (e) chain-extending and/or crosslinking agents and (f) auxiliaries and/or additives to afford a reaction mixture and reacting the reaction mixture to afford polyurethane. The polymeric compounds having isocyanate-reactive groups (b) are a polyesterol (b1) obtainable by polycondensation of an acid component with an alcohol component. The acid component includes malonic acid and/or derivatives thereof and the alcohol component includes an aliphatic dialcohol having 4 to 12 carbon atoms. The present disclosure further relates to a polyurethane obtainable by such a process and to a method of using in enclosed spaces.