C08G18/2063

Polyether polyol and polyol system liquid

To provide a polyether polyol having a high degree of freedom in the design of a polyurethane foam, and capable of providing a polyol system solution excellent in storage stability. A polyether polyol having a polyoxyalkylene chain consisting of oxyalkylene units, and having a degree of unsaturation of at most 0.020 meq/g, a hydroxy value of from 1 to 80 mgKOH/g, a content of oxyethylene units of from 0 to 50 mass %, and a content of ultra-high molecular weight components which have molecular weights of from 12 to 46 times the number average molecular weight of at most 1,000 mass ppm. The number average molecular weight is a molecular weight as calculated as polystyrene measured by gel permeation chromatography (GPC) method, and the content of ultra-high molecular weight components is a value measured by high performance liquid chromatography (HPLC) method using a charged aerosol detector (CAD).

Vat resin with additives for thiourethane polymer stereolithography printing

A method of three-dimensional stereolithography printing a thiourethane polymer part using the vat resin. Adding a resin to a vat of a three-dimensional stereolithography printer, the resin a liquid mixture including: a first type of monomer including two or more thiol functional groups, a second type of monomer including two or more isocyanate functional groups, a photolatent base, an anionic step-growth polymerization reaction inhibitor and a light absorber. The photolatent base is decomposable upon exposure to a light to form a non-nucleophillic base catalyst having a pKa greater than 7. The anionic step-growth polymerization reaction inhibitor has an acidic group configured to form an acid-base pair with the non-nucleophillic base. The light absorber has an absorbance in the liquid mixture that is greater than an absorbance of the photolatent base at a wavelength of the light used for the exposure.

Low VOC polyurethane adhesive
11584872 · 2023-02-21 · ·

A low-VOC, two-component polyurethane adhesive is provided. The polyurethane adhesive has an A-side that includes an isocyanate and a non-reactive plasticizer, and a B-side that includes an aliphatic polyester polyol, a non-polyester polyol, and a urethane catalyst. The A-side and the B-side are reacted at a volume ratio of 1:1 and formulated at an NCO/OH index within the range of 0.90 to 1.10. The polyurethane adhesive is solvent-free and is particularly suitable for adhering a polymeric membrane to a substrate.

USES OF MICROBIAL DERIVED MATERIALS IN THERMOSET APPLICATIONS

This disclosure provides methods for the chemical modification of microbial derived triglyceride oils, use thereof in polyurethane chemistries, and incorporation thereof in the production of sporting goods equipment, including, for example, alpine skis, touring skis, cross country skis, approach skis, split boards, snowboards, surfboards, paddleboards, and water skis.

USE OF ALIPHATIC ISOCYANATE AS TOXIC FUME SUPRESSANT IN POLYURETHANE FOAMS
20230098959 · 2023-03-30 · ·

The present invention relates to the field of polyurethane foams and the way to reduce the smoke and the toxic compounds created when the foam burns.

VISCOELASTIC POLYURETHANE FOAM WITH AQUEOUS POLYMER DISPERSANT

A reaction system for forming a viscoelastic polyurethane foam includes an isocyanate component and an isocyanate-reactive component that includes at least a polyol component, an additive component, and a preformed aqueous polymer dispersant. The mixture includes 50.0 wt % to 99.8 wt % of the polyol component, 0.1 wt % to 49.9 wt % of the additive component, and 0.1 wt % to 6.0 wt % of the preformed aqueous polymer dispersant. The aqueous polymer dispersant has a pH from 6.0 to 12.0 and includes from 5 wt % to 60 wt % of a polymeric component and from 40 wt % to 95 wt % of a fluid medium. The polymeric component includes at least one base polymer derived from 20 wt % to 100 wt % of at least one hydrophilic acid monomer having at least one carbonyl group, phosphate group, phosphonate group, or sulfonyl group, and optionally derived from at least one hydrophobic terminally unsaturated hydrocarbon monomer.

SPRAY POLYURETHANE ELASTOMERS AND METHODS FOR PRODUCING THE SAME
20220340704 · 2022-10-27 ·

The present disclosure relates to spray polyether and polyester polyurethane elastomeric articles and associated methods of producing such elastomer articles. More specifically, the invention provides spray polyester polyurethane elastomer articles that exhibit excellent tensile and tear strength, superior elongation performance and improved abrasion resistance performance with tunable tensile modulus.

Methods for reducing aldehyde emissions in polyurethane foams

Polyurethane foams are made by curing a reaction mixture that contains an aromatic polyisocyanate, at least one isocyanate-reactive material having an average functionality of at least 2 and an equivalent weight of at least 200 per isocyanate-reactive group, at least one blowing agent, at least one surfactant and at least one catalyst, at least one cyclic 1,3-diketone compound, at least one aminoalcohol or alkylhydroxylamine and an alkali metal, phosphonium or ammonium sulfite. Foams so produced emit low levels of formaldehyde, acetaldehyde, acrolein and propionaldehyde.

PU COMPOSITE RESINS
20220332945 · 2022-10-20 ·

Disclosed herein is a fiber composite material including: (a) a polyurethane obtained reaction of at least the components: (i) a polyisocyanate composition; and (ii) a polyol composition including at least 15% by weight of an at least trifunctional alcohol (ii.1), which exhibits at least two primary hydroxyl groups (ii.1); and (b) fibers which are at least partially embedded in the compact polyurethane.

Further disclosed herein are a process for producing a fiber composite material, a fiber composite material obtained by this process, and a method of using the fiber composite material for producing a pipe, in particular a conical pipe, a pipe connector, a pressure vessel, a storage tank, an insulator, a mast, a bar, a roller, a torsion shaft, a profile, a piece of sports equipment, a molded part, a cover, an automotive exterior part, a rope, a cable, an isogrid structure or a semi-finished textile product.

Methods for reducing aldehyde emissions in polyurethane foams

Polyurethane foams are made by curing a reaction mixture that contains an aromatic polyisocyanate, at least one isocyanate-reactive material having an average functionality of at least 2 and an equivalent weight of at least 200 per isocyanate-reactive group, at least one blowing agent, at least one surfactant and at least one catalyst, a polyethyleneamine mixture having a number average molecular weight of 175 to 450 and an alkali metal, phosphonium or ammonium sulfite. Foams so produced emit low levels of formaldehyde, acetaldehyde, acrolein and propionaldehyde.